CN103788840A - Quick-drying and greening-proof unsaturated polyester furniture coating as well as production and construction processes thereof - Google Patents
Quick-drying and greening-proof unsaturated polyester furniture coating as well as production and construction processes thereof Download PDFInfo
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- CN103788840A CN103788840A CN201210530976.0A CN201210530976A CN103788840A CN 103788840 A CN103788840 A CN 103788840A CN 201210530976 A CN201210530976 A CN 201210530976A CN 103788840 A CN103788840 A CN 103788840A
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Abstract
The invention discloses quick-drying and greening-proof unsaturated polyester furniture coating as well as production and construction processes thereof. The furniture coating includes a main ingredient A part, a B part containing cobalt iso-octoate and a C part containing methyl ethyl ketone peroxide, wherein the A part consists of the following components in parts by weight: 60-80 parts of unsaturated polyester resin, 0.01-0.03 part of a polymerization inhibitor, 10-25 parts of inorganic filler, 3-5 parts of zinc stearate, 4-8 parts of a solvent, 0.3-0.5 part of an anti-settling agent, 0.1-0.3 part of an antifoaming agent and 0.2-0.5 part of a flatting agent. The furniture coating disclosed by the invention adopts a composite accelerant consisting of cobalt iso-octoate and vanadium iso-octoate, and formed trivalent cobalt ion is represented as purple; a paint film is finally represented as quite light orange, a technical problem that the paint film of the unsaturated polyester furniture coating becomes green and a problem of slow drying at low temperature are solved; the furniture coating can well show texture of substrate when being applied to light-colored wood and stuck furniture, so as to keep color of the substrate, and the paint film is good in transparency.
Description
Technical field
The present invention relates to a kind of unsaturated polyester coatings for furniture, particularly the unsaturated polyester coatings for furniture of the anti-greening of a kind of quick-drying and production thereof, construction technology.
Background technology
The once thick painting of unsaturated polyester coatings for furniture, paint film are plentiful, hardness, solvent resistance, fillibility, collapse are good, generally apply at furniture industry, general furniture application is mainly PE unsaturated polyester coatings for furniture with coatings for furniture, unsaturated polyester coatings for furniture curing reaction is free radicals copolymerization reaction, in solidify reaction process, need to add promotor cobalt naphthenate or cobalt iso-octoate (Lan Shui) and initiator methylethyl ketone peroxide (plain boiled water), pass through redox reaction, in promotor, cobalt salt makes decomposition of initiator produce the free free radical of high activity, unsaturated double-bond in free radical attack unsaturated polyester molecular chain and the unsaturated double-bond of monomer styrene, make it to produce free radical, thereby generation crosslinking reaction, make polyester form the paint film of tridimensional network.
But the divalence cobalt color that cobalt naphthenate or cobalt iso-octoate form in reaction process is for green, the color greening blackout of last paint film, has destroyed the color of furniture ground, and simultaneously at temperature during lower than 10 ℃ of states, unsaturated polyester coatings for furniture is dry slow.Unsaturated polyester coatings for furniture on market all can not change this problem of greening now.Unsaturated polyester coatings for furniture paint film color turns green, affects appearance of film, is unfavorable for light ground transparent coating.This technical problem has restricted the development in an all-round way of unsaturated polyester coatings for furniture, therefore improves the anti-greening of film and cryodrying just very important.
Summary of the invention
Technical problem to be solved by this invention overcomes the deficiencies in the prior art exactly, and a kind of unsaturated polyester coatings for furniture and production, construction technology that can greening be provided.
The technical scheme that the present invention solves its technical problem employing is:
A unsaturated polyester coatings for furniture for the anti-greening of quick-drying, the B part that comprise host A part, comprises cobalt iso-octoate and the C part that comprises methylethyl ketone peroxide, the component that this A part comprises following parts by weight:
60～80 parts of unsaturated polyester resins, 0.01～0.03 part of stopper, 10～25 parts of mineral fillers, 3～5 parts of Zinic stearass, 4～8 parts of solvents, 0.3～0.5 part of anti-settling agent, 0.1～0.3 part of defoamer, 0.2～0.5 part of flow agent, 0.1～0.3 part of dispersion agent.
Preferably, the component that described B part comprises following parts by weight: 70～90 parts of cobalt iso-octoates, 10～30 parts of isocaprylic acid vanadium; The component that this C part comprises following parts by weight: 100 parts of methylethyl ketone peroxides.
Preferably, the component that described solvent comprises following parts by weight: 1～3 part of toluene, 3～5 parts of vinyl acetic monomers.
Preferably, described unsaturated polyester resin is selected the unsaturated polyester resin that the solid content of vinylbenzene dilution is 78%.
Preferably, described anti-settling agent is selected aerosil; Described defoamer is selected non-organic defoamer.
Preferably, described flow agent is selected fluorin modified crylic acid ester class flow agent; Described stopper is selected Resorcinol.
Preferably, talcum powder and/or transparent powder are selected in described mineral filler.
A production technique for the unsaturated polyester coatings for furniture of the anti-greening of quick-drying as the aforementioned, A part of production comprises the steps:
First unsaturated polyester resin is dropped in container; Then, add successively partial solvent and stopper middling speed to be uniformly dispersed; Then, add successively anti-settling agent, defoamer, flow agent, dispersion agent middling speed to disperse 5 minutes; Then, add mineral filler and Zinic stearas middling speed to disperse 30 minutes to fineness≤55 micron; Finally, add residual solvent.
Preferably, described partial solvent is that parts by weight are the toluene of 1～3 part, and described residual solvent is that parts by weight are 3～5 parts of vinyl acetic monomers.
A construction technology for the unsaturated polyester coatings for furniture of the anti-greening of quick-drying as the aforementioned, when construction, by A part: B part: C part=100:2:2 is deployed to stir, add appropriate thinner and be transferred to working viscosity, adopt spraying method construction.
Compared with prior art, the present invention has obtained following superior technique effect:
By using isocaprylic acid vanadium and cobalt iso-octoate compound accelerant, accelerate speed of response, formation trivalent cobalt ion is red-purple, and the color that paint film final body reveals is extremely shallow orange, close with wood color.Product of the present invention has solved unsaturated polyester coatings for furniture paint film color completely and has turned green technical problem, more can manifest the texture of ground in the time of light solid wood and the application of paster furniture, keeps the color of ground, and the paint film transparency is good.
Embodiment
Describe content of the present invention in detail below in conjunction with specific embodiment:
The present invention relates to the unafforested unsaturated polyester coatings for furniture of a kind of quick-drying, comprise independent three parts of preserving, host A part, the B part that comprises cobalt iso-octoate and the C part that comprises methylethyl ketone peroxide.
The formula of A part comprises: unsaturated polyester resin, stopper, Zinic stearas, mineral filler, solvent, anti-settling agent, defoamer, flow agent and dispersion agent.
It is 78% unsaturated polyester resin that described unsaturated polyester resin is selected the solid content with vinylbenzene dilution that Jiangsu Fang Xin company limited produces, and model is 988;
Described stopper is selected the Resorcinol of French Rhodia;
Described mineral filler is talcum powder and/or transparent powder, the TP-1250 talcum powder that talcum powder can select Guangzhou Gui Hua Chemical Industry Science Co., Ltd to produce, the TM-2600 transparent powder that transparent powder can select Hou Sheng Chemical Co., Ltd. of Foshan City to produce;
The BT1819 Zinic stearas that described Zinic stearas can select hundred sharp combination work (middle mountain) company limiteds to produce;
Described solvent can be selected toluene and/or vinyl acetic monomer, and wherein toluene can adopt the toluene of Maoming Petrochemical, and vinyl acetic monomer can adopt the ethyl acetate of Guangzhou solvent factory;
Described anti-settling agent can be selected the A200 aerosil of Ying Chuan Degussa company production or the M-5 aerosil that U.S.'s Cabot (CABOT) company produces;
The EFKA2720 antifoaming agent of non-silicone that described defoamer can select Dutch EFKA company to produce;
The EFKA3777 fluorin modified crylic acid ester that described flow agent can select Dutch EFKA company to produce;
Described dispersion agent is 912 dispersion agents of Taiwan De Qian company.
The concrete production method of A part of this unsaturated polyester coatings for furniture and the parts by weight of each component are as described in embodiment 1～5:
embodiment 1:
Formula: 80 parts of unsaturated polyester resins, 0.02 part of stopper, 2 parts of talcum powder, 8 parts of transparent powders, 3 parts of Zinic stearass, 2 parts of toluene, 3 parts of vinyl acetic monomers; Anti-settling agent: 0.3 part of A200 aerosil, defoamer: 0.3 part of EFKA2720 antifoaming agent of non-silicone, flow agent: 0.3 part of EFKA3777 fluorin modified crylic acid ester class flow agent, dispersion agent: 912 0.3 part of dispersion agent.
Production technique: first unsaturated polyester resin is dropped in container; Then, add successively partial solvent and stopper middling speed to be uniformly dispersed; Then, add successively anti-settling agent, defoamer, flow agent, dispersion agent middling speed to disperse 5 minutes; Then, add mineral filler and Zinic stearas middling speed to disperse 30 minutes to fineness≤55 micron; Finally, add residual solvent.
The unsaturated polyester coatings for furniture outward appearance of gained is: translucent, micro-yellow thick liquid.
embodiment 2:
Formula: 70 parts of unsaturated polyester resins, 0.02 part of stopper, 5 parts of talcum powder, 15 parts of transparent powders, 3 parts of Zinic stearass, 2 parts of toluene, 3 parts of vinyl acetic monomers; Anti-settling agent: 0.4 part of A200 aerosil, defoamer: 0.3 part of EFKA2720 antifoaming agent of non-silicone, flow agent: 0.3 part of EFKA3777 fluorin modified crylic acid ester class flow agent, dispersion agent: 912 0.3 part of dispersion agent.
Production method: with embodiment 1;
The unsaturated polyester coatings for furniture outward appearance of gained is: translucent, micro-yellow thick liquid.
embodiment 3:
Formula: 60 parts of unsaturated polyester resins, 0.02 part of stopper, 5 parts of talcum powder, 20 parts of transparent powders, 3 parts of Zinic stearass, 2 parts of toluene, 3 parts of vinyl acetic monomers; Anti-settling agent: 0.5 part of A200 aerosil, defoamer: 0.3 part of EFKA2720 antifoaming agent of non-silicone, flow agent: 0.2 part of EFKA3777 fluorin modified crylic acid ester class flow agent, dispersion agent: 912 0.2 part of dispersion agent;
Production method: with embodiment 1.
The unsaturated polyester coatings for furniture outward appearance of gained is: translucent, micro-yellow thick liquid.
embodiment 4:
Formula: 80 parts of unsaturated polyester resins, 0.01 part of stopper, 10 parts of transparent powders, 4 parts of Zinic stearass, 1 part of toluene, 3 parts of vinyl acetic monomers; Anti-settling agent: 0.3 part of M-5 aerosil, defoamer: 0.2 part of EFKA2720 antifoaming agent of non-silicone, flow agent: 0.5 part of EFKA3777 fluorin modified crylic acid ester class flow agent, dispersion agent: 912 0.2 part of dispersion agent;
Production method: first unsaturated polyester resin is dropped in container; Then, add successively toluene and stopper middling speed to be uniformly dispersed; Then, add successively anti-settling agent, defoamer, flow agent, dispersion agent middling speed to disperse 5 minutes; Then, add transparent powder and Zinic stearas middling speed to disperse 30 minutes to fineness≤55 micron; Finally, add vinyl acetic monomer.
The unsaturated polyester coatings for furniture outward appearance of gained is: translucent, micro-yellow thick liquid.
embodiment 5:
Formula: 60 parts of unsaturated polyester resins, 0.03 part of stopper, 20 parts of talcum powder, 5 parts of Zinic stearass, 3 parts of toluene, 5 parts of vinyl acetic monomers; Anti-settling agent: 0.4 part of M-5 aerosil, defoamer: 0.1 part of EFKA2720 antifoaming agent of non-silicone, flow agent: 0.2 part of EFKA3777 fluorin modified crylic acid ester class flow agent, dispersion agent: 912 0.1 part of dispersion agent;
Production method: first unsaturated polyester resin is dropped in container; Then, add successively toluene and stopper middling speed to be uniformly dispersed; Then, add successively anti-settling agent, defoamer, flow agent, dispersion agent middling speed to disperse 5 minutes; Then, add talcum powder and Zinic stearas middling speed to disperse 30 minutes to fineness≤55 micron; Finally, add vinyl acetic monomer.
The unsaturated polyester coatings for furniture outward appearance of gained is: translucent, micro-yellow thick liquid.
The formula of B part comprises: cobalt iso-octoate and isocaprylic acid vanadium.
The EC-cobalt iso-octoate product that described cobalt iso-octoate selects Changfeng Chemical Plant, Shanghai to produce, content is 6%; The isocaprylic acid vanadium product that described isocaprylic acid vanadium selects Shenyang Zhangming Chemical Co., Ltd to produce, content is 4%.
The parts by weight of the formula Raw of the B part of this unsaturated polyester coatings for furniture are as described in embodiment 6～8:
embodiment 6:70 parts of cobalt iso-octoates, 30 parts of isocaprylic acid vanadium.
embodiment 7:80 parts of cobalt iso-octoates, 20 parts of isocaprylic acid vanadium.
embodiment 8:90 parts of cobalt iso-octoates, 10 parts of isocaprylic acid vanadium.
C part is the methylethyl ketone peroxide of 100 parts of parts by weight.
The Butanox M-50 methylethyl ketone peroxide product that described methylethyl ketone peroxide can select Dutch AKZO NOBEL company to produce.
When construction, by A part: B part: C part=100:2:2 is deployed to stir, add appropriate thinner and be transferred to working viscosity, adopt spraying method construction.Surface drying time≤30 minute of paint film after spraying application; Do solid work time 10h; Time≤the 12h that can polish 25 ℃ time, hardness >=2H; Sticking power: 2 grades.
Design focal point of the present invention is: by using cobalt iso-octoate and isocaprylic acid vanadium compound accelerant, form trivalent cobalt ion and be red-purple, the color that paint film final body reveals is extremely shallow orange, close with wood color.Product of the present invention has solved unsaturated polyester coatings for furniture paint film color completely and has turned green technical problem, more can manifest the texture of ground in the time of light solid wood and the application of paster furniture, keeps the color of ground, and the paint film transparency is good.
The above, it is only preferred embodiment of the present invention, not technical scope of the present invention is imposed any restrictions, therefore any trickle modification, equivalent variations and modification that every foundation technical spirit of the present invention is done above embodiment all still belong in the scope of technical solution of the present invention.
Claims (10)
1. a unsaturated polyester coatings for furniture for the anti-greening of quick-drying, is characterized in that: the B part that comprise host A part, comprises cobalt iso-octoate and the C part that comprises methylethyl ketone peroxide, and the component that this A part comprises following parts by weight:
60～80 parts of unsaturated polyester resins, 0.01～0.03 part of stopper, 10～25 parts of mineral fillers, 3～5 parts of Zinic stearass, 4～8 parts of solvents, 0.3～0.5 part of anti-settling agent, 0.1～0.3 part of defoamer, 0.2～0.5 part of flow agent, 0.1～0.3 part of dispersion agent.
2. the unsaturated polyester coatings for furniture of the anti-greening of quick-drying according to claim 1, is characterized in that, the component that described B part comprises following parts by weight: 70～90 parts of cobalt iso-octoates, 10～30 parts of isocaprylic acid vanadium; The component that this C part comprises following parts by weight: 100 parts of methylethyl ketone peroxides.
3. the unsaturated polyester coatings for furniture of the anti-greening of quick-drying according to claim 1, is characterized in that: the component that described solvent comprises following parts by weight: 1～3 part of toluene, 3～5 parts of vinyl acetic monomers.
4. the unsaturated polyester coatings for furniture of the anti-greening of quick-drying according to claim 1, is characterized in that: described unsaturated polyester resin is selected the unsaturated polyester resin that the solid content of vinylbenzene dilution is 78%.
5. the unsaturated polyester coatings for furniture of the anti-greening of quick-drying according to claim 1, is characterized in that: described anti-settling agent is selected aerosil; Described defoamer is selected non-organic defoamer.
6. the unsaturated polyester coatings for furniture of the anti-greening of quick-drying according to claim 1, is characterized in that: described flow agent is selected fluorin modified crylic acid ester class flow agent; Described stopper is selected Resorcinol.
7. the unsaturated polyester coatings for furniture of the anti-greening of quick-drying according to claim 1, is characterized in that: talcum powder and/or transparent powder are selected in described mineral filler.
8. a production technique for the unsaturated polyester coatings for furniture of the anti-greening of quick-drying as claimed in claim 1, is characterized in that, this A part of production comprises the steps:
First unsaturated polyester resin is dropped in container; Then, add successively partial solvent and stopper middling speed to be uniformly dispersed; Then, add successively anti-settling agent, defoamer, flow agent, dispersion agent middling speed to disperse 5 minutes; Then, add mineral filler and Zinic stearas middling speed to disperse 30 minutes to fineness≤55 micron; Finally, add residual solvent.
9. production technique according to claim 8, is characterized in that: described partial solvent is that parts by weight are the toluene of 1～3 part, and described residual solvent is that parts by weight are 3～5 parts of vinyl acetic monomers.
10. the construction technology of the unsaturated polyester coatings for furniture of the anti-greening of a quick-drying as claimed in claim 1, it is characterized in that: when construction, by A part: B part: C part=100:2:2 is deployed to stir, add appropriate thinner and be transferred to working viscosity, adopt spraying method construction.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210530976.0A CN103788840A (en) | 2012-12-11 | 2012-12-11 | Quick-drying and greening-proof unsaturated polyester furniture coating as well as production and construction processes thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210530976.0A CN103788840A (en) | 2012-12-11 | 2012-12-11 | Quick-drying and greening-proof unsaturated polyester furniture coating as well as production and construction processes thereof |
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| CN103788840A true CN103788840A (en) | 2014-05-14 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104312393A (en) * | 2014-11-04 | 2015-01-28 | 刘星 | Unsaturated polyester paint coated on furniture and preparation method thereof |
| CN104497813A (en) * | 2014-12-11 | 2015-04-08 | 三棵树涂料股份有限公司 | Nitrocellulose-modified low-temperature quick-drying unsaturated polyester primer and preparation method thereof |
| CN105062333A (en) * | 2015-08-26 | 2015-11-18 | 成都展辰涂料有限公司 | Glossy unsaturated polyester finish paint |
| CN105946319A (en) * | 2016-04-27 | 2016-09-21 | 河南省亿丰塑业有限公司 | Method for producing sheet material |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312393A (en) * | 2014-11-04 | 2015-01-28 | 刘星 | Unsaturated polyester paint coated on furniture and preparation method thereof |
| CN104497813A (en) * | 2014-12-11 | 2015-04-08 | 三棵树涂料股份有限公司 | Nitrocellulose-modified low-temperature quick-drying unsaturated polyester primer and preparation method thereof |
| CN104497813B (en) * | 2014-12-11 | 2017-10-03 | 三棵树涂料股份有限公司 | Nitrocotton is modified low-temperature quick-dry unsaturated polyester (UP) priming paint and preparation method thereof |
| CN105062333A (en) * | 2015-08-26 | 2015-11-18 | 成都展辰涂料有限公司 | Glossy unsaturated polyester finish paint |
| CN105946319A (en) * | 2016-04-27 | 2016-09-21 | 河南省亿丰塑业有限公司 | Method for producing sheet material |
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Application publication date: 20140514 |