CN109401455A - Phenylpropyl alcohol expanding fire-proof paint - Google Patents
Phenylpropyl alcohol expanding fire-proof paint Download PDFInfo
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- CN109401455A CN109401455A CN201811232345.4A CN201811232345A CN109401455A CN 109401455 A CN109401455 A CN 109401455A CN 201811232345 A CN201811232345 A CN 201811232345A CN 109401455 A CN109401455 A CN 109401455A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
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- Nanotechnology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Biochemistry (AREA)
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention proposes a kind of phenylpropyl alcohol expanding fire-proof paints, according to parts by weight, including following components: 50~70 parts of styrene-acrylic emulsion, 4~8 parts of ammonium polyphosphate, 2~6 parts of dipentaerythritol, 8~16 parts of expanded perlite, 5~10 parts of hydroxyethyl cellulose, 0.4~0.8 part of wetting dispersing agent, 0.3~0.6 part of levelling agent, 2~6 parts of coalescing agent and 6~12 parts of modified Nano carborundum；Wherein, the modified Nano carborundum is mainly prepared by nanometer silicon carbide, starch and silane coupling agent.Not only coating expansion multiplying power is high for the fireproof coating, also improves its heat-insulated and refractory ability.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of phenylpropyl alcohol expanding fire-proof paint.
Background technique
Fireproof coating is exactly by that on the surface of those combustible materials, can improve the refractory ability of material, subtract paint brush
Slow propagation of flame spread speed, or can prevent to burn within a certain period of time, this kind of coating are known as fireproof coating, or are called fire-retardant
Coating.Fireproof coating is to reduce by the combustibility of painting material surface for flammable substrates surface, block the rapid climing of fire
Prolong, to improve by a kind of sapecial coating of painting material fire endurance.It is applied to flammable substrates surface, to change material table
Face combustion characteristics, retardance fire are spread rapidly；Or be applied on building element, the extraordinary of fire endurance to improve component applies
Material claims fireproof coating.
Although steel do not have combustibility, its thermal coefficient is big, and fire resistance is poor, in the case where flameproof protection is not added,
Generally there was only the fire endurance of 15min under the direct calcination of thermal-flame.More than 15min, steel construction intensity is reduced rapidly and very
Bearing capacity is lost fastly.When the temperature of structure reaches 350,500,600 DEG C, intensity declines 1/3,1/2,2/3 respectively, works as knot
When structure temperature reaches 600 DEG C or more, steel construction will lose bearing capacity completely.Just because of this, effective guarantor is taken to steel member
Shield measure protects it from the direct calcination of thermal-flame, delays the time of collapsing, providing valuable time for fire control just seems
It is particularly significant.Fireproof coating is coated on steel surface, in addition to there is decoration and protective effect, due to the noninflammability of coating itself
And flame retardancy, the sprawling of flame when fire can be prevented to occur delay the extension of the intensity of a fire.
Summary of the invention
The present invention proposes a kind of phenylpropyl alcohol expanding fire-proof paint, and not only coating expansion multiplying power is high for the fireproof coating, also improves
Its heat-insulated and refractory ability.
The technical scheme of the present invention is realized as follows:
A kind of phenylpropyl alcohol expanding fire-proof paint, according to parts by weight, including following components:
50~70 parts of styrene-acrylic emulsion, 4~8 parts of ammonium polyphosphate, 2~6 parts of dipentaerythritol, 8~16 parts of expanded perlite, hydroxyl
5~10 parts of ethyl cellulose, 0.4~0.8 part of wetting dispersing agent, 0.3~0.6 part of levelling agent, 2~6 parts of coalescing agent and modification
6~12 parts of nanometer silicon carbide；Wherein, the modified Nano carborundum is mainly by nanometer silicon carbide, starch and silane coupling agent system
It is standby to obtain.
Preferably, the modified Nano carborundum the preparation method comprises the following steps:
1) starch is added to the water and is stirred dispersion, amylase is then added and is digested, heating is gone out after enzymatic hydrolysis
It is living, obtain enzymolysis liquid；
2) nanometer silicon carbide and silane coupling agent are added into the enzymolysis liquid of step 1) and is stirred dispersion, warm to 60 DEG C~
70 DEG C, be stirred to react 2~6h, after centrifugal vacuum it is dry.
Preferably, the mass ratio of the starch and the nanometer silicon carbide is 10~20:1, the nanometer silicon carbide with
The mass ratio of the silane coupling agent is 25~35:1.
Preferably, the silane coupling agent is aminopropyl triethoxysilane, glycidol fan's oxygroup propyl trimethoxy
Silane, methacryloxypropyl trimethoxy silane, vinyltriethoxysilane, vinyltriethoxysilane, mercapto
Propyl front three (second) one or more of oxysilane and ethylenediaminepropyltriethoxysilane.
Preferably, the wetting dispersing agent is calgon wetting agent；The levelling agent selects water-and acrylate total
Polymers, fluorine richness polyacrylate copolymer or Siloxane-Oxyalkylene Copolymers polymer are one such.
Preferably, the coalescing agent be propylene glycol phenylate, dipropylene glycol n-butyl ether, Lauryl Alcohol ester, methoxybutanol,
At least one of ethylene glycol monobutyl ether and dipropylene glycol propyl ether.
The preparation method of phenylpropyl alcohol expanding fire-proof paint of the invention:
After mixing the above components evenly according to the proportion.
Beneficial effects of the present invention:
Phenylpropyl alcohol expanding fire-proof paint of the invention, which is added to, mainly to be prepared by nanometer silicon carbide, starch and silane coupling agent
Obtained nanometer silicon carbide, it is high with matrix resin binding force, it is not easy to be precipitated, improves the water resistance and fire insulation of coating
Energy.
Specific embodiment
Embodiment 1
Modified Nano carborundum the preparation method comprises the following steps:
1) starch is added to the water and is stirred dispersion, amylase is then added and is digested, heating is gone out after enzymatic hydrolysis
It is living, obtain enzymolysis liquid；
2) nanometer silicon carbide is added into the enzymolysis liquid of step 1) and aminopropyl triethoxysilane is stirred dispersion, temperature
To 60 DEG C DEG C, be stirred to react 6h, after centrifugal vacuum it is dry.
The mass ratio of starch and nanometer silicon carbide is 20:1, the quality of nanometer silicon carbide and aminopropyl triethoxysilane
The ratio between be 25:1.
Embodiment 2
Modified Nano carborundum the preparation method comprises the following steps:
1) starch is added to the water and is stirred dispersion, amylase is then added and is digested, heating is gone out after enzymatic hydrolysis
It is living, obtain enzymolysis liquid；
2) be added into the enzymolysis liquid of step 1) nanometer silicon carbide and methacryloxypropyl trimethoxy silane into
Row is dispersed with stirring, and temperature is stirred to react 2h to 70 DEG C, after centrifugal vacuum it is dry.
Embodiment 3
A kind of phenylpropyl alcohol expanding fire-proof paint, according to parts by weight, including following components:
60 parts of styrene-acrylic emulsion, 6 parts of ammonium polyphosphate, 7 parts of dipentaerythritol, 12 parts of expanded perlite, hydroxyethyl cellulose 7
The modification of part, 0.6 part of calgon wetting agent, 0.5 part of water-borne acrylate copolymer, 4 parts of propylene glycol phenylate and embodiment 1
8 parts of nanometer silicon carbide.
Embodiment 4
A kind of phenylpropyl alcohol expanding fire-proof paint, according to parts by weight, including following components:
50 parts of styrene-acrylic emulsion, 4 parts of ammonium polyphosphate, 8 parts of dipentaerythritol, 8 parts of expanded perlite, 5 parts of hydroxyethyl cellulose,
0.4 part of calgon wetting agent, 0.3 part of Siloxane-Oxyalkylene Copolymers polymer, 3 parts of Lauryl Alcohol ester and embodiment 2 change
6 parts of nanometer silicon carbide of property.
Embodiment 5
A kind of phenylpropyl alcohol expanding fire-proof paint, according to parts by weight, including following components:
55 parts of styrene-acrylic emulsion, 8 parts of ammonium polyphosphate, 5 parts of dipentaerythritol, 16 parts of expanded perlite, hydroxyethyl cellulose 8
Part, 0.5 part of calgon wetting agent, 0.6 part of Siloxane-Oxyalkylene Copolymers polymer, 2 parts of ethylene glycol monobutyl ether and embodiment 1
10 parts of modified Nano carborundum.
Embodiment 6
A kind of phenylpropyl alcohol expanding fire-proof paint, according to parts by weight, including following components:
70 parts of styrene-acrylic emulsion, 5 parts of ammonium polyphosphate, 10 parts of dipentaerythritol, 14 parts of expanded perlite, hydroxyethyl cellulose 10
Part, 0.8 part of calgon wetting agent, 0.6 part of fluorine richness polyacrylate copolymer, 6 parts of dipropylene glycol propyl ether and embodiment 2
12 parts of modified Nano carborundum.
Test example
The phenylpropyl alcohol expanding fire-proof paint that embodiment 3~6 obtains is tested for the property according to GB14907-2002, as a result
It is shown in Table 1:
The performance test results of the phenylpropyl alcohol expanding fire-proof paint of the invention of table 1
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (6)
1. a kind of phenylpropyl alcohol expanding fire-proof paint, which is characterized in that according to parts by weight, including following components:
50~70 parts of styrene-acrylic emulsion, 4~8 parts of ammonium polyphosphate, 2~6 parts of dipentaerythritol, 8~16 parts of expanded perlite, ethoxy
5~10 parts of cellulose, 0.4~0.8 part of wetting dispersing agent, 0.3~0.6 part of levelling agent, 2~6 parts of coalescing agent and modified Nano
6~12 parts of silicon carbide；Wherein, the modified Nano carborundum is mainly prepared by nanometer silicon carbide, starch and silane coupling agent
It arrives.
2. phenylpropyl alcohol expanding fire-proof paint according to claim 1, which is characterized in that the system of the modified Nano carborundum
Preparation Method are as follows:
1) starch is added to the water and is stirred dispersion, amylase is then added and is digested, heat up inactivation after enzymatic hydrolysis, obtains
To enzymolysis liquid；
2) nanometer silicon carbide is added into the enzymolysis liquid of step 1) and silane coupling agent is stirred dispersion, temperature to 60 DEG C~70
DEG C, be stirred to react 2~6h, after centrifugal vacuum it is dry.
3. phenylpropyl alcohol expanding fire-proof paint according to claim 2, which is characterized in that the starch and the nano silicon carbide
The mass ratio of silicon is 10~20:1, and the mass ratio of the nanometer silicon carbide and the silane coupling agent is 25~35:1.
4. phenylpropyl alcohol expanding fire-proof paint according to claim 2, which is characterized in that the silane coupling agent is aminopropyl
Triethoxysilane, glycidyl ester oxy propyl trimethoxysilane, methacryloxypropyl trimethoxy silane, second
Alkenyl triethoxysilane, three ethoxy of vinyltriethoxysilane, mercapto propyl front three (second) oxysilane and ethylenediamine propyl
One or more of base silane.
5. phenylpropyl alcohol expanding fire-proof paint according to claim 1, which is characterized in that the wetting dispersing agent is six inclined phosphorus
Sour sodium wetting agent；The levelling agent selects water-borne acrylate copolymer, fluorine richness polyacrylate copolymer or polyether-modified
Polysiloxane polymer is one such.
6. phenylpropyl alcohol expanding fire-proof paint according to claim 1, which is characterized in that the coalescing agent is propylene glycol phenyl
At least one in ether, dipropylene glycol n-butyl ether, Lauryl Alcohol ester, methoxybutanol, ethylene glycol monobutyl ether and dipropylene glycol propyl ether
Kind.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811232345.4A CN109401455A (en) | 2018-10-22 | 2018-10-22 | Phenylpropyl alcohol expanding fire-proof paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811232345.4A CN109401455A (en) | 2018-10-22 | 2018-10-22 | Phenylpropyl alcohol expanding fire-proof paint |
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| Publication Number | Publication Date |
|---|---|
| CN109401455A true CN109401455A (en) | 2019-03-01 |
Family
ID=65468897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811232345.4A Pending CN109401455A (en) | 2018-10-22 | 2018-10-22 | Phenylpropyl alcohol expanding fire-proof paint |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102675992A (en) * | 2011-03-07 | 2012-09-19 | 嘉宝莉化工集团股份有限公司 | Expanded type aqueous facing fireproof coating and preparation method thereof |
| CN104449097A (en) * | 2014-12-11 | 2015-03-25 | 江门市绿茵环保科技有限公司 | Novel fireproof thermal insulation coating and preparation method thereof |
| CN106752429A (en) * | 2016-11-18 | 2017-05-31 | 公安部四川消防研究所 | Fireproof coating, its preparation method and the flame screen containing fireproof coating |
| CN108084805A (en) * | 2017-12-06 | 2018-05-29 | 田秋珍 | A kind of preparation method of water proof type diatom ooze coating |
| CN108467636A (en) * | 2018-04-17 | 2018-08-31 | 邹奇峰 | A kind of aqueous phenylpropyl alcohol antirusting paint with fire protecting performance |
-
2018
- 2018-10-22 CN CN201811232345.4A patent/CN109401455A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102675992A (en) * | 2011-03-07 | 2012-09-19 | 嘉宝莉化工集团股份有限公司 | Expanded type aqueous facing fireproof coating and preparation method thereof |
| CN104449097A (en) * | 2014-12-11 | 2015-03-25 | 江门市绿茵环保科技有限公司 | Novel fireproof thermal insulation coating and preparation method thereof |
| CN106752429A (en) * | 2016-11-18 | 2017-05-31 | 公安部四川消防研究所 | Fireproof coating, its preparation method and the flame screen containing fireproof coating |
| CN108084805A (en) * | 2017-12-06 | 2018-05-29 | 田秋珍 | A kind of preparation method of water proof type diatom ooze coating |
| CN108467636A (en) * | 2018-04-17 | 2018-08-31 | 邹奇峰 | A kind of aqueous phenylpropyl alcohol antirusting paint with fire protecting performance |
Non-Patent Citations (4)
| Title |
|---|
| 何小维: "《碳水化合物功能材料》", 31 January 2007, 中国轻工业出版社 * |
| 李干佐等: "《表面活性剂在能源和选矿工业中的应用》", 30 April 2002, 中国轻工业出版社 * |
| 翟庆洲: "《纳米技术》", 31 March 2006, 兵器工业出版社 * |
| 颜进华: "《造纸化学品》", 31 August 2015, 华南理工大学出版社 * |
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