CN109385895A - A kind of abrasion resistant fire blocking antistatic ribbon - Google Patents
A kind of abrasion resistant fire blocking antistatic ribbon Download PDFInfo
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- CN109385895A CN109385895A CN201811136898.XA CN201811136898A CN109385895A CN 109385895 A CN109385895 A CN 109385895A CN 201811136898 A CN201811136898 A CN 201811136898A CN 109385895 A CN109385895 A CN 109385895A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/13—Alginic acid or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
Abstract
This hair belongs to textile technology field, and in particular to a kind of abrasion resistant fire blocking antistatic ribbon, preparation method include raw material preparation, prepare fire-retardant filler, surface treatment filler, and mixing is woven into ribbon.The present invention has the advantage that the processing including organic modified clay compared with prior art, improve aluminium hydroxide and high density polyethylene (HDPE) molecule compatibility, to improve the binding force between high density polyethylene (HDPE) and filler, anti-flammability is improved while reducing aluminium hydroxide usage amount, avoid due to aluminium hydroxide additive amount excessively caused by agglomeration, make gained ribbon tensile strength and comprehensive mechanical property kept, poison gas is not discharged after burning, it is highly-safe, it is applied widely.
Description
Technical field
The invention belongs to textile technology fields, and in particular to a kind of abrasion resistant fire blocking antistatic ribbon.
Background technique
In addition to safety belt or elastic band, ribbon actually further includes polythene material, the letter band for mentioning word letter, for rolling
Banding, ridge belts, luggage ribbon, suede band, the ribbon on side etc., ribbon be widely used in climb the mountain packet, tent, gift box, handbag,
The decoration of craftwork.
Ribbon is made up using various yarns by raw material of different knitting skills, by different printed decoration modes, then
It is cut and various finished products is just made, on clothes, suspender belt is made in some for some sewings, more as clothes
Important component.One special operation protective garment is typically limited to the period of special operation, such as high voltage brake-pulling, livewire work, stokehold
The periods such as operation.Universal fire-resistant antistatic protective garment is advocated herein is primarily referred to as post or area protection clothes.
The application field of ribbon product is constantly widened in recent years, and use scope is also constantly expanding.This is just to ribbon product
Functionality propose very special quality requirement.In daily life, we, which would ordinarily be encountered, shocks by electricity and is produced because of caused by electrostatic
It lights a fire phenomena such as colored, causes meeting to shake hands, handle of pulling, door opening, shock phenomenon occurs whens turning on the tap etc..Subdue fabric not
Antistatic, will cause following problems electrostatic can adsorb clothes or skirt physically, and influence the image on dressing electrostatic of employee
Clothes dust suction phenomenon can be brought to verify through authoritative institution: the electrostatic interference that human body generates can change the normal current potential of body surface
Difference.As art technology, it would be highly desirable to develop novel abrasion resistant fire blocking antistatic ribbon.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of abrasion resistant fire blocking antistatic ribbon is provided.
The invention is realized by the following technical scheme:
A kind of abrasion resistant fire blocking antistatic ribbon, is made by following raw materials in part by weight: 100 parts of high density polyethylene (HDPE), DPPM22 ~ 28
Part, N, 3 ~ 5 parts of N (dibenzylidene phosphonic acid base) ethylenediamine, 32 ~ 36 parts of aluminium hydroxide, 10 ~ 15 parts of organic modified clay, zinc borate 6
~ 10 parts, EBS4 ~ 7 part, 2 ~ 8 parts of wollastonite in powder, 1 ~ 2 part of coupling agent.
A kind of abrasion resistant fire blocking antistatic ribbon, preparation method includes the following steps:
(1) raw material preparation: weighing each component raw material, spare；
(2) take zinc borate dry, it is 60 ~ 80 DEG C that DPPM, which is then added, and is heated to temperature, stirring 5 ~ EBS is added after ten minutes and has
Machine modified clay is stirred for 20 ~ 30 minutes under conditions of temperature is 95 ~ 105 DEG C, and cooling obtains fire-retardant filler；
(3) coupling agent is dissolved in water and prepares the solution that mass concentration is 4 ~ 6%, aluminium hydroxide, ultrasonic disperse 10 ~ 15 is then added
After minute, wollastonite in powder is added, stirring is to being completely dissolved, heated-air drying under conditions of revolving speed is 3500 ~ 4500 revs/min,
Surface treatment filler is obtained after screening；
(4) by fire-retardant filler, surface treatment filler and high density polyethylene (HDPE), N, N (dibenzylidene phosphonic acid base) ethylenediamine is mixed, so
Afterwards in extruding machine it is cooling after extrusion film, cut, heat orientation stretching, preheated processing is formed, yarn through doubling, twist thread,
Ribbon produced by cylinder Weaving-machine after warping volume, ribbon is after soaking is formed, using secondary dipping through to drawing
The abrasion resistant fire blocking antistatic ribbon after impregnation is formed after stretching sizing；Wherein: described twisting thread is divided into positive twirl or the reverse lay, latitude of warp
The positive twirl of line or reverse lay；Soaking uses the parts by weight being formulated are as follows: 0.5 ~ 2 part of polyvinyl alcohol, 98 ~ 99.5 parts of water, it will be upper
It is 7 ~ 8 formation soaking liquid that polyvinyl alcohol, which is stated, with adjustment pH value after water weighing mixture；Secondary dipping uses the parts by weight being formulated
Number are as follows: 5 parts of butadiene-styrene latex, 20 parts of acrylic based emulsion, 10 parts of water, 15 parts of 6.5% treatment fluid will be formed after said components mixture
Secondary dipping liquid；The parts by weight of 6.5% treatment fluid are as follows: 3 parts of resorcinol, 0.5 part of sodium alginate, 1.2 parts of formaldehyde, food
With 1 part of alkali, 95 parts of water, 5.5% treatment fluid will be formed after said components mixture.
Further, the aluminium hydroxide is surface-treated active nano aluminium hydroxide, specially by nanometer
Aluminium hydroxide powder mashing, carries out high speed dispersion in high-shear emulsion machine, regulates and is separately added into after revolving speed and temperature point
Powder, modifying agent filter after modified a period of time, wash, dry, crush, being ground up, sieved to obtain active aluminium hydroxide powder
End obtains organic modified clay；The dispersing agent is polyacrylamide, Sodium Polyacrylate, sodium tripolyphosphate, one in sodium metasilicate
Kind or a variety of modifying agent are aliphatic acid polyethenoxy ether, polyethylene glycol Octyl Ether, fatty diglycollic amide, alkylbenzene
Phenol polyethenoxy ether, polyoxyethylene carboxylate, alkylolamides, alkyl benzene sulfonate mixture.
Further, the coupling agent is one of chromium complex coupling agent, silane coupling agent and titanate coupling agent
Or it is a variety of.
Beneficial effects of the present invention:
The sizes of modified aluminum hydroxide particles increases, unmodified aluminum hydroxide particles since the surface of particle can be very high,
The specific surface area for reuniting to reduce particle has occurred in dry process, and modified aluminum hydroxide particles are due to surface
It has coated organic matter and has reduced surface energy, the dispersibility of the generation of agglomeration when preventing dry, aluminum hydroxide particles is big
Big to improve, aluminum hydroxide particles moisture content is lower, illustrates that modified effect is preferable, by unmodified nano-aluminum hydroxide and modification
After aluminium hydroxide later is separately added into polypropylene plastics, the modified aluminium hydroxide of flame retardant property has than unmodified aluminium hydroxide
It is improved, most of aluminum hydroxide particles before modified exist with aggregating state, and speed is inhomogenous when Plastics Combustion, flame retardant property
It is unstable.And modified aluminum hydroxide particles dispersion performance is preferable, aluminum hydroxide particles are substantially more equal with nano shape
Even is dispersed in resin, and burning velocity is uniform, improves so that oxygen index (OI) improves flame retardant of plastic performance.
The blending and modifying of DPPM and organic modified clay is handled in the present invention, changes aluminium hydroxide and high density polyethylene (HDPE) point
Sub- compatibility improves the binding force between high density polyethylene (HDPE) and middle material A, and obtained composite density is uniform, avoid by
The difference caused by density is different, improves processing performance；Fire retardant has the characteristics that low halogen, low cigarette, nitrogenated flame retardant have nothing
The features such as malicious, environmentally friendly, the tensile strength and comprehensive mechanical property of enhancing gained ribbon do not discharge poison gas, pacify after burning
Quan Xinggao, it is applied widely.
The present invention has the advantage that compared with prior art
Thermal property is largely inhaled when giving full play to it in conjunction with water vapour, improves the fire retardancy of itself；The thermal capacitance for improving fiber, has
Effect absorbs and reduces comburant surface emissivity heat, and the chance for making decomposition that free radical occur is reduced；Obstruct covering effect, shape after charing
At residue it is indeformable, can sufficiently obstruct flame diffusion and heat and oxygen conduction, keep fiber self-extinguishment good；It decomposes and produces
Raw nitrogenous gas and other non-flammable compressive gases can generate smothering action with starvation.
Specific embodiment
Illustrate the present invention with specific embodiment below, but is not limitation of the present invention.
Embodiment 1
A kind of abrasion resistant fire blocking antistatic ribbon, is made by following raw materials in part by weight: 100 parts of high density polyethylene (HDPE), DPPM23 parts, N,
4 parts of N (dibenzylidene phosphonic acid base) ethylenediamine, 35 parts of aluminium hydroxide, 14 parts of organic modified clay, 9 parts of zinc borate, EBS4 ~ 7 part,
6 parts of wollastonite in powder, 2 parts of coupling agent.
A kind of abrasion resistant fire blocking antistatic ribbon, preparation method includes the following steps:
(1) raw material preparation: weighing each component raw material, spare；
(2) take zinc borate dry, it is 60 ~ 80 DEG C that DPPM, which is then added, and is heated to temperature, stirring 5 ~ EBS is added after ten minutes and has
Machine modified clay is stirred for 20 ~ 30 minutes under conditions of temperature is 95 ~ 105 DEG C, and cooling obtains fire-retardant filler；
(3) coupling agent is dissolved in water and prepares the solution that mass concentration is 4 ~ 6%, aluminium hydroxide, ultrasonic disperse 10 ~ 15 is then added
After minute, wollastonite in powder is added, stirring is to being completely dissolved, heated-air drying under conditions of revolving speed is 3500 ~ 4500 revs/min,
Surface treatment filler is obtained after screening；
(4) by fire-retardant filler, surface treatment filler and high density polyethylene (HDPE), N, N (dibenzylidene phosphonic acid base) ethylenediamine is mixed, so
Afterwards in extruding machine it is cooling after extrusion film, cut, heat orientation stretching, preheated processing is formed, yarn through doubling, twist thread,
Ribbon produced by cylinder Weaving-machine after warping volume, ribbon is after soaking is formed, using secondary dipping through to drawing
The abrasion resistant fire blocking antistatic ribbon after impregnation is formed after stretching sizing；Wherein: described twisting thread is divided into positive twirl or the reverse lay, latitude of warp
The positive twirl of line or reverse lay；Soaking uses the parts by weight being formulated are as follows: 0.5 ~ 2 part of polyvinyl alcohol, 98 ~ 99.5 parts of water, it will be upper
It is 7 ~ 8 formation soaking liquid that polyvinyl alcohol, which is stated, with adjustment pH value after water weighing mixture；Secondary dipping uses the parts by weight being formulated
Number are as follows: 5 parts of butadiene-styrene latex, 20 parts of acrylic based emulsion, 10 parts of water, 15 parts of 6.5% treatment fluid will be formed after said components mixture
Secondary dipping liquid；The parts by weight of 6.5% treatment fluid are as follows: 3 parts of resorcinol, 0.5 part of sodium alginate, 1.2 parts of formaldehyde, food
With 1 part of alkali, 95 parts of water, 5.5% treatment fluid will be formed after said components mixture.
Further, the aluminium hydroxide is surface-treated active nano aluminium hydroxide, specially by nanometer
Aluminium hydroxide powder mashing, carries out high speed dispersion in high-shear emulsion machine, regulates and is separately added into after revolving speed and temperature point
Powder, modifying agent filter after modified a period of time, wash, dry, crush, being ground up, sieved to obtain active aluminium hydroxide powder
End obtains organic modified clay；The dispersing agent is polyacrylamide, Sodium Polyacrylate, sodium tripolyphosphate, one in sodium metasilicate
Kind or a variety of modifying agent are aliphatic acid polyethenoxy ether, polyethylene glycol Octyl Ether, fatty diglycollic amide, alkylbenzene
Phenol polyethenoxy ether, polyoxyethylene carboxylate, alkylolamides, alkyl benzene sulfonate mixture.
Further, the coupling agent is one of chromium complex coupling agent, silane coupling agent and titanate coupling agent
Or it is a variety of.
Embodiment 2
A kind of abrasion resistant fire blocking antistatic ribbon, is made by following raw materials in part by weight: 100 parts of high density polyethylene (HDPE), DPPM26 parts, N,
4 parts of N (dibenzylidene phosphonic acid base) ethylenediamine, 33 parts of aluminium hydroxide, 13 parts of organic modified clay, 7 parts of zinc borate, EBS5 parts, silicon
5 parts of limestone flour, 2 parts of coupling agent.
A kind of abrasion resistant fire blocking antistatic ribbon, preparation method includes the following steps:
(1) raw material preparation: weighing each component raw material, spare；
(2) take zinc borate dry, it is 60 ~ 80 DEG C that DPPM, which is then added, and is heated to temperature, stirring 5 ~ EBS is added after ten minutes and has
Machine modified clay is stirred for 20 ~ 30 minutes under conditions of temperature is 95 ~ 105 DEG C, and cooling obtains fire-retardant filler；
(3) coupling agent is dissolved in water and prepares the solution that mass concentration is 4 ~ 6%, aluminium hydroxide, ultrasonic disperse 10 ~ 15 is then added
After minute, wollastonite in powder is added, stirring is to being completely dissolved, heated-air drying under conditions of revolving speed is 3500 ~ 4500 revs/min,
Surface treatment filler is obtained after screening；
(4) by fire-retardant filler, surface treatment filler and high density polyethylene (HDPE), N, N (dibenzylidene phosphonic acid base) ethylenediamine is mixed, so
Afterwards in extruding machine it is cooling after extrusion film, cut, heat orientation stretching, preheated processing is formed, yarn through doubling, twist thread,
Ribbon produced by cylinder Weaving-machine after warping volume, ribbon is after soaking is formed, using secondary dipping through to drawing
The abrasion resistant fire blocking antistatic ribbon after impregnation is formed after stretching sizing；Wherein: described twisting thread is divided into positive twirl or the reverse lay, latitude of warp
The positive twirl of line or reverse lay；Soaking uses the parts by weight being formulated are as follows: 0.5 ~ 2 part of polyvinyl alcohol, 98 ~ 99.5 parts of water, it will be upper
It is 7 ~ 8 formation soaking liquid that polyvinyl alcohol, which is stated, with adjustment pH value after water weighing mixture；Secondary dipping uses the parts by weight being formulated
Number are as follows: 5 parts of butadiene-styrene latex, 20 parts of acrylic based emulsion, 10 parts of water, 15 parts of 6.5% treatment fluid will be formed after said components mixture
Secondary dipping liquid；The parts by weight of 6.5% treatment fluid are as follows: 3 parts of resorcinol, 0.5 part of sodium alginate, 1.2 parts of formaldehyde, food
With 1 part of alkali, 95 parts of water, 5.5% treatment fluid will be formed after said components mixture.
Further, the aluminium hydroxide is surface-treated active nano aluminium hydroxide, specially by nanometer
Aluminium hydroxide powder mashing, carries out high speed dispersion in high-shear emulsion machine, regulates and is separately added into after revolving speed and temperature point
Powder, modifying agent filter after modified a period of time, wash, dry, crush, being ground up, sieved to obtain active aluminium hydroxide powder
End obtains organic modified clay；The dispersing agent is polyacrylamide, Sodium Polyacrylate, sodium tripolyphosphate, one in sodium metasilicate
Kind or a variety of modifying agent are aliphatic acid polyethenoxy ether, polyethylene glycol Octyl Ether, fatty diglycollic amide, alkylbenzene
Phenol polyethenoxy ether, polyoxyethylene carboxylate, alkylolamides, alkyl benzene sulfonate mixture.
Further, the coupling agent is one of chromium complex coupling agent, silane coupling agent and titanate coupling agent
Or it is a variety of.
Comparative example 1
This comparative example compared with Example 2, weighs in step in raw material, saves aluminium hydroxide ingredient, method and step in addition to this
It is all the same.
Comparative example 2
This comparative example compared with Example 2, weighs in step in raw material, saves DPPM ingredient, and method and step in addition to this is homogeneous
Together.
Comparative example 3
This comparative example compared with Example 2, weighs in step in raw material, saves zinc borate ingredient, and method and step in addition to this is equal
It is identical.
Comparative example 4
This comparative example compared with Example 2, weighs in step in raw material, saves organic modified clay ingredient, method in addition to this
Step is all the same.Comparative example 5
This comparative example compared with Example 2, weighs in step in raw material, saves N, N (dibenzylidene phosphonic acid base) ethylenediamine ingredient,
Method and step in addition to this is all the same.
The performance test of abrasion resistant fire blocking antistatic ribbon prepared by each embodiment and comparative example of table 1
Note: You Shangbiao 1 is as can be seen that the anti-flammability of the heat-resisting ribbon of high-strength anti-flaming disclosed by the invention has obtained significantly mentioning
Height, while the control of its tensile strength is preferably, it can be very nearly the same with originality.The heat-resisting ribbon of high-strength anti-flaming disclosed by the invention has anti-
The good advantage of folding, pull resistance, and cost performance is high, it is cheap, antistatic, it is suitable for being widely popularized.
Claims (4)
1. a kind of abrasion resistant fire blocking antistatic ribbon, which is characterized in that be made by following raw materials in part by weight: high density polyethylene (HDPE) 100
Part, DPPM22 ~ 28 part, N, 3 ~ 5 parts of N (dibenzylidene phosphonic acid base) ethylenediamine, 32 ~ 36 parts of aluminium hydroxide, organic modified clay 10 ~
15 parts, 6 ~ 10 parts of zinc borate, EBS4 ~ 7 part, 2 ~ 8 parts of wollastonite in powder, 1 ~ 2 part of coupling agent.
2. abrasion resistant fire blocking antistatic ribbon as described in claim 1, which is characterized in that preparation method includes the following steps:
(1) raw material preparation: weighing each component raw material, spare；
(2) take zinc borate dry, it is 60 ~ 80 DEG C that DPPM, which is then added, and is heated to temperature, stirring 5 ~ EBS is added after ten minutes and has
Machine modified clay is stirred for 20 ~ 30 minutes under conditions of temperature is 95 ~ 105 DEG C, and cooling obtains fire-retardant filler；
(3) coupling agent is dissolved in water and prepares the solution that mass concentration is 4 ~ 6%, aluminium hydroxide, ultrasonic disperse 10 ~ 15 is then added
After minute, wollastonite in powder is added, stirring is to being completely dissolved, heated-air drying under conditions of revolving speed is 3500 ~ 4500 revs/min,
Surface treatment filler is obtained after screening；
(4) by fire-retardant filler, surface treatment filler and high density polyethylene (HDPE), N, N (dibenzylidene phosphonic acid base) ethylenediamine is mixed, so
Afterwards in extruding machine it is cooling after extrusion film, cut, heat orientation stretching, preheated processing is formed, yarn through doubling, twist thread,
Ribbon produced by cylinder Weaving-machine after warping volume, ribbon is after soaking is formed, using secondary dipping through to drawing
The abrasion resistant fire blocking antistatic ribbon after impregnation is formed after stretching sizing；Wherein: described twisting thread is divided into positive twirl or the reverse lay, latitude of warp
The positive twirl of line or reverse lay；Soaking uses the parts by weight being formulated are as follows: 0.5 ~ 2 part of polyvinyl alcohol, 98 ~ 99.5 parts of water, it will be upper
It is 7 ~ 8 formation soaking liquid that polyvinyl alcohol, which is stated, with adjustment pH value after water weighing mixture；Secondary dipping uses the parts by weight being formulated
Number are as follows: 5 parts of butadiene-styrene latex, 20 parts of acrylic based emulsion, 10 parts of water, 15 parts of 6.5% treatment fluid will be formed after said components mixture
Secondary dipping liquid；The parts by weight of 6.5% treatment fluid are as follows: 3 parts of resorcinol, 0.5 part of sodium alginate, 1.2 parts of formaldehyde, food
With 1 part of alkali, 95 parts of water, 5.5% treatment fluid will be formed after said components mixture.
3. abrasion resistant fire blocking antistatic ribbon as described in claim 1, which is characterized in that the aluminium hydroxide is at surface
Nano-aluminum hydroxide powder, is specially beaten by the active nano aluminium hydroxide managed, and high speed is carried out in high-shear emulsion machine
Dispersion is separately added into dispersing agent, modifying agent after regulating revolving speed and temperature, filter, wash after modified a period of time, is dry,
It crushes, be ground up, sieved to obtain active aluminium hydroxide powder, obtain organic modified clay；The dispersing agent is polyacrylamide, gathers
One of sodium acrylate, sodium tripolyphosphate, sodium metasilicate or a variety of modifying agent are aliphatic acid polyethenoxy ether, poly- second two
Alcohol Octyl Ether, fatty diglycollic amide, polyoxyethylene alkylphenol ether, polyoxyethylene carboxylate, alkylolamides, alkyl
The mixture of benzenesulfonates.
4. the preparation method of abrasion resistant fire blocking antistatic ribbon as described in claim 1, which is characterized in that the coupling agent is chromium
One of compound coupling agent, silane coupling agent and titanate coupling agent or a variety of is complexed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811136898.XA CN109385895A (en) | 2018-09-28 | 2018-09-28 | A kind of abrasion resistant fire blocking antistatic ribbon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811136898.XA CN109385895A (en) | 2018-09-28 | 2018-09-28 | A kind of abrasion resistant fire blocking antistatic ribbon |
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