CN108728934A - A kind of heat-resisting ribbon of high-strength anti-flaming - Google Patents
A kind of heat-resisting ribbon of high-strength anti-flaming Download PDFInfo
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- CN108728934A CN108728934A CN201810772970.1A CN201810772970A CN108728934A CN 108728934 A CN108728934 A CN 108728934A CN 201810772970 A CN201810772970 A CN 201810772970A CN 108728934 A CN108728934 A CN 108728934A
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- parts
- heat
- flaming
- agent
- strength anti
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000007822 coupling agent Substances 0.000 claims abstract description 23
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 12
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 10
- 239000013078 crystal Substances 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 5
- 239000004734 Polyphenylene sulfide Substances 0.000 claims abstract description 5
- 239000002216 antistatic agent Substances 0.000 claims abstract description 5
- 239000004917 carbon fiber Substances 0.000 claims abstract description 5
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 5
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 5
- 239000004927 clay Substances 0.000 claims abstract description 5
- 150000002500 ions Chemical class 0.000 claims abstract description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000004048 modification Effects 0.000 claims abstract description 5
- 238000012986 modification Methods 0.000 claims abstract description 5
- 229920000728 polyester Polymers 0.000 claims abstract description 5
- 229920000570 polyether Polymers 0.000 claims abstract description 5
- 229920000069 polyphenylene sulfide Polymers 0.000 claims abstract description 5
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 5
- 150000003457 sulfones Chemical class 0.000 claims abstract description 5
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 16
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000003963 antioxidant agent Substances 0.000 claims description 12
- 230000003078 antioxidant effect Effects 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical group NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 5
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 150000004645 aluminates Chemical group 0.000 claims description 4
- 238000000498 ball milling Methods 0.000 claims description 4
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 claims description 4
- 229910001632 barium fluoride Inorganic materials 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000011858 nanopowder Substances 0.000 claims description 4
- 150000001451 organic peroxides Chemical class 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- 238000004513 sizing Methods 0.000 claims description 4
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 claims description 3
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 claims description 3
- -1 polytetrafluoroethylene Polymers 0.000 claims description 3
- 230000008878 coupling Effects 0.000 claims description 2
- 238000010168 coupling process Methods 0.000 claims description 2
- 238000005859 coupling reaction Methods 0.000 claims description 2
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 2
- 229910001635 magnesium fluoride Inorganic materials 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 15
- 239000003921 oil Substances 0.000 abstract description 13
- 230000002940 repellent Effects 0.000 abstract description 12
- 239000005871 repellent Substances 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 8
- 239000002994 raw material Substances 0.000 abstract description 8
- 239000004519 grease Substances 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 2
- 238000002485 combustion reaction Methods 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- YESRULSVSWLZLT-UHFFFAOYSA-N C(C)O[SiH](OCC)OCC.[Ru].[F] Chemical class C(C)O[SiH](OCC)OCC.[Ru].[F] YESRULSVSWLZLT-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical class CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 3
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 230000002742 anti-folding effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04D—TRIMMINGS; RIBBONS, TAPES OR BANDS, NOT OTHERWISE PROVIDED FOR
- D04D9/00—Ribbons, tapes, welts, bands, beadings, or other decorative or ornamental strips, not otherwise provided for
Abstract
The invention discloses a kind of heat-resisting ribbons of high-strength anti-flaming, are made of the raw material of following parts by weight：50 ~ 80 parts of polyphenylene sulfide sulfone, 50 ~ 100 parts of soluble poly tetrafluoroethene, 10 ~ 20 parts of modified poly ester, 2 ~ 5 parts of carbon nanotube, 20 ~ 30 parts of chlorinated polyether, 5 ~ 10 parts of carbon fiber, silicon carbide is fine 1 ~ 3 part short, 0.5 ~ 1 part of calcium sulfate crystal whiskers, 1 ~ 2 part of ion modification clay, 1 ~ 2 part of coupling agent, 2 ~ 5 parts of antistatic agent, 2 ~ 5 parts of antiaging agent.The heat-resisting ribbon of high-strength anti-flaming made from treatment process of the present invention has the advantages of heat-proof combustion-resistant, and cost-effective, cheap, antistatic, water repellent is grease proofing, avoids oil pollution and water stain bonding, stable chemical performance, usage time long.
Description
Technical field
The invention belongs to ribbon production technical fields, and in particular to a kind of heat-resisting ribbon of high-strength anti-flaming.
Background technology
Ribbon is that narrow web fabric or tubing is made by raw material of various yarns.Narrow fabrics are various in style, use extensively
In dress ornament, footwear material, luggage, industry, agricultural, military supplies, communications and transportation Deng Ge branchs of industry.In the past, ribbon was all handicraft workshop life
Production, raw material are cotton thread, linen thread.After founding of New, ribbon gradually developed to raw material polyamide fibre, polyvinyl, terylene, polypropylene fibre, spandex,
Viscose glue etc., forms woven, woollen yarn knitting, knitting three categories technology, and fabric construction has plain weave, twill, satin weave, jacquard weave, bilayer, more
Layer, tubulose and united organization.
Existing ribbon intensity is relatively low, and wear-resisting property is poor.Although some ribbons have flame retardant effect, flame retardant rating compared with
It is low, be unable to reach specific environment requirement be especially existing ribbon because itself material property determine by
Elongation percentage is bigger when pulling force.
Because the application scenario of ribbon is very extensive, but ribbon is after all the fabric of raw material by yarn as a kind of, it
Poor flame retardant properties, the buffer zone especially used in fire-fighting and rescue or the conveyer belt in production field, the environment used
Open fire may be touched, ribbon is then easy to be ignited at this time, threatens to the life of personnel, is damaged to equipment；?
In family, general ribbon once encounters burning things which may cause a fire disaster and is unable to reach fire-retardant effect or even can accelerate the sprawling of burning things which may cause a fire disaster, increases fire
Harm.
Invention content
The purpose of the present invention is for existing problem, provide a kind of heat-resisting ribbon of high-strength anti-flaming.
The invention is realized by the following technical scheme：
A kind of heat-resisting ribbon of high-strength anti-flaming, includes component below：50 ~ 80 parts of polyphenylene sulfide sulfone, soluble polytetrafluoroethyl-ne
50 ~ 100 parts of alkene, 10 ~ 20 parts of modified poly ester, 2 ~ 5 parts of carbon nanotube, 20 ~ 30 parts of chlorinated polyether, 5 ~ 10 parts of carbon fiber, silicon carbide
Short fine 1 ~ 3 part, it is 0.5 ~ 1 part of calcium sulfate crystal whiskers, 1 ~ 2 part of ion modification clay, 1 ~ 2 part of coupling agent, 2 ~ 5 parts of antistatic agent, anti-old
2 ~ 5 parts of agent, 0.5 ~ 1 part of water repellent oil resistance agent, 0.5 ~ 1 part of cleaning additive.
Further, water repellent oil resistance agent is by fluorochemical and alcohol 1：80~1：60 weight ratio are uniformly mixed,
Middle fluorochemical is lH, lH, 2H, 2H- perfluors dodecyl mercaptans, 17 fluorine ruthenium triethoxysilanes, ten trifluoro octyls three
It is one or more in Ethoxysilane.
Further, cleaning additive is by 1 ~ 2 part of nano-inorganic substance, 20 ~ 30 parts of solvent, 0.5 ~ 1 part of coupling agent, solubility
13 ~ 15 parts of polytetrafluoroethylene (PTFE), mixing, disperse ball milling, and wherein nano-powder is mesoporous silicon oxide, ice crystal, fluorination
One or more of aluminium, barium fluoride, magnesium fluoride are constituted, and grain size is 50 ~ 100nm, and solvent is by acetone, dichloroethanes, dichloromethane
One or more compositions in alkane, toluene, coupling agent are aluminate coupling agent, titanate coupling agent, organic peroxide coupling
One or more compositions in agent, each substance is placed in ball mill be fully ground to get.
Further, the antiaging agent is the mixture of p phenylenediamine type antioxidant and quinoline type antioxidant, and to benzene
The mass ratio of Diamines anti-aging agent and quinoline type antioxidant is 1 ~ 3：1~2.
Further, above-mentioned each group is placed in high-speed mixer, blending while must heat 320 ~ 370 DEG C, wait for
It is completely dried rear can be taken off, is granulated cold cut using double screw extruder, then by double screw extruder melting extrusion and pass through
Manifold spinneret spinneret, cooling, sizing obtains twine；By twine knitmesh to get to the heat-resisting ribbon of high-strength anti-flaming.
Beneficial effects of the present invention：
The heat-resisting ribbon of a kind of high-strength anti-flaming provided by the invention, the present invention have the following advantages compared to existing art：The present invention adopts
The heat-resisting ribbon of antistatic high-strength anti-flaming of uniform water repellent oil resistant is made with solid-liquid hybrid process blending method, using fluorine system polymer
Material soluble poly tetrafluoroethene ensure that double thin effects of material, while compared with face coat method, have rub resistance, resistance to
Washing, etc. advantages.This method has broken the heat-resisting ribbon water repellent oil resistant effect of existing high-strength anti-flaming, can only make face coat
Form has self-cleaning surface to possess good rub resistance, washing resistance performance, can be in oil content height, high-water content height
The field of the harshness high request such as producer gas, electric furnace, converter, carbon black, cement, oil oven, waste incinerator, asphalt mixing uses, and
All have good application prospect.
Specific implementation mode
Illustrate the present invention with specific embodiment below, but is not limitation of the present invention.
Embodiment 1
A kind of heat-resisting ribbon of high-strength anti-flaming, includes component below：80 parts of polyphenylene sulfide sulfone, soluble poly tetrafluoroethene
100 parts, 20 parts of modified poly ester, 2 parts of carbon nanotube, 30 parts of chlorinated polyether, 5 parts of carbon fiber, silicon carbide are fine 3 parts short, calcium sulfate is brilliant
1 part of palpus, 2 parts of ion modification clay, 1 part of coupling agent, 2 parts of antistatic agent, 2 parts of antiaging agent, 1 part of water repellent oil resistance agent, cleaning add
Add 1 part of agent.
Further, water repellent oil resistance agent is by fluorochemical and alcohol 1：80~1：60 weight ratio are uniformly mixed,
Middle fluorochemical is lH, lH, 2H, 2H- perfluors dodecyl mercaptans, 17 fluorine ruthenium triethoxysilanes, ten trifluoro octyls three
It is one or more in Ethoxysilane.
Further, cleaning additive is by 1 part of nano-inorganic substance, 30 parts of solvent, 1 part of coupling agent, soluble polytetrafluoroethyl-ne
15 parts of alkene, mixing, disperse ball milling, and wherein nano-powder is mesoporous silicon oxide, ice crystal, aluminum fluoride, barium fluoride, fluorine
Change one or more of magnesium to constitute, grain size is 50 ~ 100nm, and solvent is by one in acetone, dichloroethanes, dichloromethane, toluene
Kind or a variety of compositions, coupling agent are aluminate coupling agent, titanate coupling agent, one kind in organic peroxide coupling agent or more
Kind constitute, each substance is placed in ball mill be fully ground to get.
Further, the antiaging agent is the mixture of p phenylenediamine type antioxidant and quinoline type antioxidant, and to benzene
The mass ratio of Diamines anti-aging agent and quinoline type antioxidant is 1 ~ 3：1~2.
Further, above-mentioned each group is placed in high-speed mixer, blending while must heat 320 ~ 370 DEG C, wait for
It is completely dried rear can be taken off, is granulated cold cut using double screw extruder, then by double screw extruder melting extrusion and pass through
Manifold spinneret spinneret, cooling, sizing obtains twine；By twine knitmesh to get to the heat-resisting ribbon of high-strength anti-flaming.
Embodiment 2
A kind of heat-resisting ribbon of high-strength anti-flaming, includes component below：80 parts of polyphenylene sulfide sulfone, soluble poly tetrafluoroethene 50
Part, 20 parts of modified poly ester, 2 parts of carbon nanotube, 20 parts of chlorinated polyether, 5 parts of carbon fiber, silicon carbide is fine 3 parts short, calcium sulfate crystal whiskers 1
Part, 2 parts of ion modification clay, 1 part of coupling agent, 2 parts of antistatic agent, 2 parts of antiaging agent, 1 part of water repellent oil resistance agent, cleaning additive
1 part.
Further, water repellent oil resistance agent is by fluorochemical and alcohol 1：80~1：60 weight ratio are uniformly mixed,
Middle fluorochemical is lH, lH, 2H, 2H- perfluors dodecyl mercaptans, 17 fluorine ruthenium triethoxysilanes, ten trifluoro octyls three
It is one or more in Ethoxysilane.
Further, cleaning additive is by 2 parts of nano-inorganic substance, 30 parts of solvent, 1 part of coupling agent, soluble polytetrafluoroethyl-ne
15 parts of alkene, mixing, disperse ball milling, and wherein nano-powder is mesoporous silicon oxide, ice crystal, aluminum fluoride, barium fluoride, fluorine
Change one or more of magnesium to constitute, grain size is 50 ~ 100nm, and solvent is by one in acetone, dichloroethanes, dichloromethane, toluene
Kind or a variety of compositions, coupling agent are aluminate coupling agent, titanate coupling agent, one kind in organic peroxide coupling agent or more
Kind constitute, each substance is placed in ball mill be fully ground to get.
Further, the antiaging agent is the mixture of p phenylenediamine type antioxidant and quinoline type antioxidant, and to benzene
The mass ratio of Diamines anti-aging agent and quinoline type antioxidant is 1 ~ 3：1~2.
Further, above-mentioned each group is placed in high-speed mixer, blending while must heat 320 ~ 370 DEG C, wait for
It is completely dried rear can be taken off, is granulated cold cut using double screw extruder, then by double screw extruder melting extrusion and pass through
Manifold spinneret spinneret, cooling, sizing obtains twine；By twine knitmesh to get to the heat-resisting ribbon of high-strength anti-flaming.
Comparative example 1
This comparative example compared with Example 2, in raw material weighs step, saves water repellent oil resistance agent ingredient, method step in addition to this
Rapid all same.
Comparative example 2
This comparative example compared with Example 2, in raw material weighs step, saves cleaning additive ingredient, method step in addition to this
Rapid all same.
Comparative example 3
This comparative example compared with Example 2, in raw material weighs step, saves soluble poly tetrafluoroethene ingredient, in addition to this
Method and step all same.
The mechanical property of the heat-resisting ribbon of high-strength anti-flaming prepared by 1 each embodiment and comparative example of table
Note：The intensity of the heat-resisting ribbon of high-strength anti-flaming disclosed by the invention is significantly improved it can be seen from upper table 1,
Its elongation at break control simultaneously is preferable, can be very nearly the same with originality.Water repellent is grease proofing, with obvious effects.It is disclosed by the invention high-strength
Degree flame-proof heat-resistant ribbon has the advantages that anti-folding, pull resistance are good and cost-effective, cheap, antistatic, water repellent is grease proofing, avoids
Oil pollution and water stain bonding, stable chemical performance, usage time are long.It is the heat-resisting ribbon of the high-strength anti-flaming has, heatproof, resistance to
The physical characteristics such as corrosion.
Claims (4)
1. a kind of heat-resisting ribbon of high-strength anti-flaming, which is characterized in that include component below：50 ~ 80 parts of polyphenylene sulfide sulfone, can
50 ~ 100 parts of dissolubility polytetrafluoroethylene (PTFE), 10 ~ 20 parts of modified poly ester, 2 ~ 5 parts of carbon nanotube, 20 ~ 30 parts of chlorinated polyether, carbon fiber 5 ~
10 parts, silicon carbide is fine 1 ~ 3 part short, 0.5 ~ 1 part of calcium sulfate crystal whiskers, 1 ~ 2 part of ion modification clay, 1 ~ 2 part of coupling agent, antistatic agent
2 ~ 5 parts, 2 ~ 5 parts of antiaging agent.
2. the heat-resisting ribbon of a kind of high-strength anti-flaming as described in right 1, which is characterized in that cleaning additive by nano-inorganic substance 1 ~
2 parts, 20 ~ 30 parts of solvent, 0.5 ~ 1 part of coupling agent, 13 ~ 15 parts of soluble poly tetrafluoroethene, mixing ball milling, disperses, wherein
Nano-powder is that one or more of mesoporous silicon oxide, ice crystal, aluminum fluoride, barium fluoride, magnesium fluoride are constituted, grain size 50
~ 100nm, solvent are made of one or more in acetone, dichloroethanes, dichloromethane, toluene, and coupling agent is Aluminate coupling
Each substance is placed in ball mill fully by one or more compositions in agent, titanate coupling agent, organic peroxide coupling agent
Grinding to get.
3. the heat-resisting ribbon of a kind of high-strength anti-flaming as described in right 1, which is characterized in that the antiaging agent is p-phenylenediamine class
The mixture of anti-aging agent and quinoline type antioxidant, and the mass ratio of p phenylenediamine type antioxidant and quinoline type antioxidant is 1 ~ 3：1~
2。
4. the heat-resisting ribbon of a kind of high-strength anti-flaming as described in right 1, which is characterized in that above-mentioned each group is placed in mixed at high speed
In machine, blending while, must heat 320 ~ 370 DEG C, and rear to be completely dried can be taken off, and is granulated using double screw extruder cold
It cuts, then by double screw extruder melting extrusion and by manifold spinneret spinneret, cooling, sizing obtains twine；By twine
Knitmesh is to get to the heat-resisting ribbon of high-strength anti-flaming.
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