CN109385112A - A kind of wear-resistant plastic formula - Google Patents

A kind of wear-resistant plastic formula Download PDF

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Publication number
CN109385112A
CN109385112A CN201811416616.1A CN201811416616A CN109385112A CN 109385112 A CN109385112 A CN 109385112A CN 201811416616 A CN201811416616 A CN 201811416616A CN 109385112 A CN109385112 A CN 109385112A
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China
Prior art keywords
parts
wear
resistant plastic
plasticizer
benzotriazole
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CN201811416616.1A
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Chinese (zh)
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陈冰玉
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Individual
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Individual
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Priority to CN201811416616.1A priority Critical patent/CN109385112A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009Sulfides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of wear-resistant plastic formula, the raw material including following parts by weight: 35-39 parts of thermoplastic resin masterbatch, 24-28 parts of polyamide, 11-15 parts of polypropylene, 2-6 parts of plasticizer, 4-8 parts of polyvinyl chloride resin, 8-12 parts of diamond dust, 15-19 parts of triethylamine, 12-16 parts of tungsten disulfide, 16-20 parts of white fused alumina micro mist, 8-12 parts of benzene sulfonic acid, 3-7 parts of polyimides, 17-21 parts of benzotriazole, 4-8 parts of titanium dioxide, 9-13 parts of aluminium oxide and suitable water.On the basis of original thermoplastic resin masterbatch, polyamide, polypropylene, plasticizer and polyvinyl chloride resin, diamond dust, triethylamine, tungsten disulfide, white fused alumina micro mist, benzene sulfonic acid, polyimides, benzotriazole, titanium dioxide and aluminium oxide are increased newly, the service life of plastics is improved, so that the wear-resisting property of plastics is greatly improved.

Description

A kind of wear-resistant plastic formula
Technical field
The present invention relates to the technical field of plastic production more particularly to a kind of wear-resistant plastic formulas.
Background technique
The Plastics Industry of China has formed the more industry body of class by long-term struggle and the opening towards the whole world System becomes the basic material industry run neck and neck with steel, cement, timber.As a kind of new material, using field Remote super above-mentioned three kinds of basic materials, Chinese Plastics Industry make remarkable achievements, and realize historic leap, but It is that existing plastic wear-resisting is poor, therefore proposes a kind of wear-resistant plastic formula.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of wear-resistant plastic formulas.
A kind of wear-resistant plastic formula proposed by the present invention, the raw material including following parts by weight: thermoplastic resin masterbatch 35-39 Part, 24-28 parts of polyamide, 11-15 parts of polypropylene, 2-6 parts of plasticizer, 4-8 parts of polyvinyl chloride resin, 8-12 parts of diamond dust, triethylamine 15-19 parts, 12-16 parts of tungsten disulfide, 16-20 parts of white fused alumina micro mist, 8-12 parts of benzene sulfonic acid, 3-7 parts of polyimides, benzotriazole 17-21 parts, 4-8 parts of titanium dioxide, 9-13 parts of aluminium oxide and suitable water.
Preferably, the raw material including following parts by weight: 36-38 parts of thermoplastic resin masterbatch, 25-27 parts of polyamide, poly- third 12-14 parts of alkene, 3-5 parts of plasticizer, 5-7 parts of polyvinyl chloride resin, 9-11 parts of diamond dust, 16-18 parts of triethylamine, tungsten disulfide 13-15 Part, 17-19 parts of white fused alumina micro mist, 9-11 parts of benzene sulfonic acid, 4-6 parts of polyimides, 18-20 parts of benzotriazole, 5-7 parts of titanium dioxide, 10-12 parts of aluminium oxide and suitable water.
Preferably, the raw material including following parts by weight: the raw material including following parts by weight: 37 parts of thermoplastic resin masterbatch, 26 parts of polyamide, 13 parts of polypropylene, 4 parts of plasticizer, 6 parts of polyvinyl chloride resin, 10 parts of diamond dust, 17 parts of triethylamine, tungsten disulfide 14 Part, 18 parts of white fused alumina micro mist, 10 parts of benzene sulfonic acid, 5 parts of polyimides, 19 parts of benzotriazole, 6 parts of titanium dioxide, 11 parts of aluminium oxide and Suitable water.
Preferably, the plasticizer is made of polyvinyl chloride, dipentaerythritol, polyethylene glycol and polyvinyl alcohol of acetalization.
Preferably, preparation method includes the following steps:
S1: by diamond dust, triethylamine, tungsten disulfide, white fused alumina micro mist, benzene sulfonic acid, polyimides, benzotriazole, titanium dioxide, oxygen Change aluminium and suitable water is poured into mixing and blending machine and stirred evenly;
S2: thermoplastic resin masterbatch, polyamide, polypropylene, plasticizer and PVC tree are poured into mixing and blending machine described in S1 Rouge continues to stir;
After the completion of being stirred in S3:S2, gains are put into heater box and are heated;
S4: pouring into gains in mold after the completion of heating, is put into molding machine and carries out extrusion forming;
S5: being cooled to room temperature after extrusion forming, finally obtains the plastics with wear-resisting property.
Preferably, in the S1, the temperature setting of mixing and blending machine is 70-75 DEG C, and mixing time is set as 25-35min, Mixing speed is set as 200-250r/min.
Preferably, in the S2, mixing time is set as 25-35min, and mixing speed is set as 200-250r/min.
Preferably, in the S3, heating temperature is set as 100-120 DEG C, keeps the temperature 15-20min.
Beneficial effects of the present invention: in original thermoplastic resin masterbatch, polyamide, polypropylene, plasticizer and polyvinyl chloride resin On the basis of, increase diamond dust, triethylamine, tungsten disulfide, white fused alumina micro mist, benzene sulfonic acid, polyimides, benzotriazole, titanium white newly Powder and aluminium oxide improve the service life of plastics, so that the wear-resisting property of plastics is greatly improved.
Specific embodiment
Combined with specific embodiments below the present invention is made further to explain.
Embodiment one
A kind of wear-resistant plastic formula is proposed in the present embodiment, the raw material including following parts by weight: thermoplastic resin masterbatch 35-39 Part, 24-28 parts of polyamide, 11-15 parts of polypropylene, 2-6 parts of plasticizer, 4-8 parts of polyvinyl chloride resin, 8-12 parts of diamond dust, triethylamine 15-19 parts, 12-16 parts of tungsten disulfide, 16-20 parts of white fused alumina micro mist, 8-12 parts of benzene sulfonic acid, 3-7 parts of polyimides, benzotriazole 17-21 parts, 4-8 parts of titanium dioxide, 9-13 parts of aluminium oxide and suitable water;
Preparation method includes the following steps:
S1: by diamond dust, triethylamine, tungsten disulfide, white fused alumina micro mist, benzene sulfonic acid, polyimides, benzotriazole, titanium dioxide, oxygen Change aluminium and suitable water is poured into mixing and blending machine and stirred evenly;
S2: thermoplastic resin masterbatch, polyamide, polypropylene, plasticizer and PVC tree are poured into mixing and blending machine described in S1 Rouge continues to stir;
After the completion of being stirred in S3:S2, gains are put into heater box and are heated;
S4: pouring into gains in mold after the completion of heating, is put into molding machine and carries out extrusion forming;
S5: being cooled to room temperature after extrusion forming, finally obtains the plastics with wear-resisting property.
Embodiment two
A kind of wear-resistant plastic formula is proposed in the present embodiment, the raw material including following parts by weight: thermoplastic resin masterbatch 35-39 Part, 24-28 parts of polyamide, 11-15 parts of polypropylene, 2-6 parts of plasticizer, 4-8 parts of polyvinyl chloride resin, 8-12 parts of diamond dust, triethylamine 15-19 parts, 12-16 parts of tungsten disulfide, 16-20 parts of white fused alumina micro mist, 8-12 parts of benzene sulfonic acid, 3-7 parts of polyimides, benzotriazole 17-21 parts, 4-8 parts of titanium dioxide, 9-13 parts of aluminium oxide and suitable water;
Preparation method includes the following steps:
S1: by diamond dust, triethylamine, tungsten disulfide, white fused alumina micro mist, benzene sulfonic acid, polyimides, benzotriazole, titanium dioxide, oxygen Change aluminium and suitable water is poured into mixing and blending machine and stirred evenly;
S2: thermoplastic resin masterbatch, polyamide, polypropylene, plasticizer and PVC tree are poured into mixing and blending machine described in S1 Rouge continues to stir;
After the completion of being stirred in S3:S2, gains are put into heater box and are heated;
S4: pouring into gains in mold after the completion of heating, is put into molding machine and carries out extrusion forming;
S5: being cooled to room temperature after extrusion forming, finally obtains the plastics with wear-resisting property.
Embodiment three
A kind of wear-resistant plastic formula is proposed in the present embodiment, the raw material including following parts by weight: thermoplastic resin masterbatch 35-39 Part, 24-28 parts of polyamide, 11-15 parts of polypropylene, 2-6 parts of plasticizer, 4-8 parts of polyvinyl chloride resin, 8-12 parts of diamond dust, triethylamine 15-19 parts, 12-16 parts of tungsten disulfide, 16-20 parts of white fused alumina micro mist, 8-12 parts of benzene sulfonic acid, 3-7 parts of polyimides, benzotriazole 17-21 parts, 4-8 parts of titanium dioxide, 9-13 parts of aluminium oxide and suitable water;
Preparation method includes the following steps:
S1: by diamond dust, triethylamine, tungsten disulfide, white fused alumina micro mist, benzene sulfonic acid, polyimides, benzotriazole, titanium dioxide, oxygen Change aluminium and suitable water is poured into mixing and blending machine and stirred evenly;
S2: thermoplastic resin masterbatch, polyamide, polypropylene, plasticizer and PVC tree are poured into mixing and blending machine described in S1 Rouge continues to stir;
After the completion of being stirred in S3:S2, gains are put into heater box and are heated;
S4: pouring into gains in mold after the completion of heating, is put into molding machine and carries out extrusion forming;
S5: being cooled to room temperature after extrusion forming, finally obtains the plastics with wear-resisting property.
Example IV
A kind of wear-resistant plastic formula is proposed in the present embodiment, the raw material including following parts by weight: thermoplastic resin masterbatch 35-39 Part, 24-28 parts of polyamide, 11-15 parts of polypropylene, 2-6 parts of plasticizer, 4-8 parts of polyvinyl chloride resin, 8-12 parts of diamond dust, triethylamine 15-19 parts, 12-16 parts of tungsten disulfide, 16-20 parts of white fused alumina micro mist, 8-12 parts of benzene sulfonic acid, 3-7 parts of polyimides, benzotriazole 17-21 parts, 4-8 parts of titanium dioxide, 9-13 parts of aluminium oxide and suitable water;
Preparation method includes the following steps:
S1: by diamond dust, triethylamine, tungsten disulfide, white fused alumina micro mist, benzene sulfonic acid, polyimides, benzotriazole, titanium dioxide, oxygen Change aluminium and suitable water is poured into mixing and blending machine and stirred evenly;
S2: thermoplastic resin masterbatch, polyamide, polypropylene, plasticizer and PVC tree are poured into mixing and blending machine described in S1 Rouge continues to stir;
After the completion of being stirred in S3:S2, gains are put into heater box and are heated;
S4: pouring into gains in mold after the completion of heating, is put into molding machine and carries out extrusion forming;
S5: being cooled to room temperature after extrusion forming, finally obtains the plastics with wear-resisting property.
Embodiment five
A kind of wear-resistant plastic formula is proposed in the present embodiment, the raw material including following parts by weight: thermoplastic resin masterbatch 35-39 Part, 24-28 parts of polyamide, 11-15 parts of polypropylene, 2-6 parts of plasticizer, 4-8 parts of polyvinyl chloride resin, 8-12 parts of diamond dust, triethylamine 15-19 parts, 12-16 parts of tungsten disulfide, 16-20 parts of white fused alumina micro mist, 8-12 parts of benzene sulfonic acid, 3-7 parts of polyimides, benzotriazole 17-21 parts, 4-8 parts of titanium dioxide, 9-13 parts of aluminium oxide and suitable water;
Preparation method includes the following steps:
S1: by diamond dust, triethylamine, tungsten disulfide, white fused alumina micro mist, benzene sulfonic acid, polyimides, benzotriazole, titanium dioxide, oxygen Change aluminium and suitable water is poured into mixing and blending machine and stirred evenly;
S2: thermoplastic resin masterbatch, polyamide, polypropylene, plasticizer and PVC tree are poured into mixing and blending machine described in S1 Rouge continues to stir;
After the completion of being stirred in S3:S2, gains are put into heater box and are heated;
S4: pouring into gains in mold after the completion of heating, is put into molding machine and carries out extrusion forming;
S5: being cooled to room temperature after extrusion forming, finally obtains the plastics with wear-resisting property.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (8)

1. a kind of wear-resistant plastic formula, which is characterized in that the raw material including following parts by weight: 35-39 parts of thermoplastic resin masterbatch, 24-28 parts of polyamide, 11-15 parts of polypropylene, 2-6 parts of plasticizer, 4-8 parts of polyvinyl chloride resin, 8-12 parts of diamond dust, triethylamine 15-19 Part, 12-16 parts of tungsten disulfide, 16-20 parts of white fused alumina micro mist, 8-12 parts of benzene sulfonic acid, 3-7 parts of polyimides, benzotriazole 17-21 Part, 4-8 parts of titanium dioxide, 9-13 parts of aluminium oxide and suitable water.
2. a kind of wear-resistant plastic formula according to claim 1, which is characterized in that the raw material including following parts by weight: heat 36-38 parts of plastic resin masterbatch, 25-27 parts of polyamide, 12-14 parts of polypropylene, 3-5 parts of plasticizer, 5-7 parts of polyvinyl chloride resin, Buddha's warrior attendant 9-11 parts of sand, 16-18 parts of triethylamine, 13-15 parts of tungsten disulfide, 17-19 parts of white fused alumina micro mist, 9-11 parts of benzene sulfonic acid, polyamides are sub- 4-6 parts of amine, 18-20 parts of benzotriazole, 5-7 parts of titanium dioxide, 10-12 parts of aluminium oxide and suitable water.
3. a kind of wear-resistant plastic formula according to claim 1, which is characterized in that the raw material including following parts by weight: heat 37 parts of plastic resin masterbatch, 26 parts of polyamide, 13 parts of polypropylene, 4 parts of plasticizer, 6 parts of polyvinyl chloride resin, 10 parts of diamond dust, triethylamine 17 parts, 14 parts of tungsten disulfide, 18 parts of white fused alumina micro mist, 10 parts of benzene sulfonic acid, 5 parts of polyimides, 19 parts of benzotriazole, titanium dioxide 6 Part, 11 parts of aluminium oxide and suitable water.
4. a kind of wear-resistant plastic formula according to claim 1, which is characterized in that the plasticizer is by polyvinyl chloride, two Pentaerythrite, polyethylene glycol and polyvinyl alcohol of acetalization composition.
5. a kind of wear-resistant plastic formula according to claim 1, which is characterized in that preparation method includes the following steps:
S1: by diamond dust, triethylamine, tungsten disulfide, white fused alumina micro mist, benzene sulfonic acid, polyimides, benzotriazole, titanium dioxide, oxygen Change aluminium and suitable water is poured into mixing and blending machine and stirred evenly;
S2: thermoplastic resin masterbatch, polyamide, polypropylene, plasticizer and PVC tree are poured into mixing and blending machine described in S1 Rouge continues to stir;
After the completion of being stirred in S3:S2, gains are put into heater box and are heated;
S4: pouring into gains in mold after the completion of heating, is put into molding machine and carries out extrusion forming;
S5: being cooled to room temperature after extrusion forming, finally obtains the plastics with wear-resisting property.
6. a kind of wear-resistant plastic formula according to claim 5, which is characterized in that in the S1, the temperature of mixing and blending machine Degree is set as 70-75 DEG C, and mixing time is set as 25-35min, and mixing speed is set as 200-250r/min.
7. a kind of wear-resistant plastic formula according to claim 5, which is characterized in that in the S2, mixing time is set as 25-35min, mixing speed are set as 200-250r/min.
8. a kind of wear-resistant plastic formula according to claim 5, which is characterized in that in the S3, heating temperature is set as 100-120 DEG C, keep the temperature 15-20min.
CN201811416616.1A 2018-11-26 2018-11-26 A kind of wear-resistant plastic formula Withdrawn CN109385112A (en)

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CN201811416616.1A CN109385112A (en) 2018-11-26 2018-11-26 A kind of wear-resistant plastic formula

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Application Number Priority Date Filing Date Title
CN201811416616.1A CN109385112A (en) 2018-11-26 2018-11-26 A kind of wear-resistant plastic formula

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102101922A (en) * 2009-12-22 2011-06-22 上海新上化高分子材料有限公司 Wear-resistance halogen-free low-smoke expansion flame-retarding polyolefin sheath plastic and preparation method thereof
CN103524863A (en) * 2013-09-25 2014-01-22 吴江市天源塑胶有限公司 Heat-conducting wear-resistant plastic
CN103665683A (en) * 2013-11-19 2014-03-26 青岛汇而通商贸有限公司 High-strength wear-resistant engineering plastic
CN107163359A (en) * 2017-07-18 2017-09-15 合肥万之景门窗有限公司 A kind of antibacterial wear-resistant plastic and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102101922A (en) * 2009-12-22 2011-06-22 上海新上化高分子材料有限公司 Wear-resistance halogen-free low-smoke expansion flame-retarding polyolefin sheath plastic and preparation method thereof
CN103524863A (en) * 2013-09-25 2014-01-22 吴江市天源塑胶有限公司 Heat-conducting wear-resistant plastic
CN103665683A (en) * 2013-11-19 2014-03-26 青岛汇而通商贸有限公司 High-strength wear-resistant engineering plastic
CN107163359A (en) * 2017-07-18 2017-09-15 合肥万之景门窗有限公司 A kind of antibacterial wear-resistant plastic and preparation method thereof

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Application publication date: 20190226

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