CN110358225A - A kind of processing technology of hard PVC material - Google Patents
A kind of processing technology of hard PVC material Download PDFInfo
- Publication number
- CN110358225A CN110358225A CN201910767739.8A CN201910767739A CN110358225A CN 110358225 A CN110358225 A CN 110358225A CN 201910767739 A CN201910767739 A CN 201910767739A CN 110358225 A CN110358225 A CN 110358225A
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- CN
- China
- Prior art keywords
- pvc
- pvc material
- preparation
- hard
- processing technology
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of processing technologys of hard PVC material, comprising the following steps: A, preparation: get out hard PVC material prepares raw material;B, melt: the PVC production basic material of preparation is melted according to preparation flow;C, it adds reagent: will successively add various reagents in raw material that melted PVC material produces;D, it produces: the raw material prepared is used for the preparation of PVC material;E, the PVC finished-product material of preparation is handled, the present invention uses perfect preparation process, and the PVC material produced not only has good toughness, while hardness is high, has the advantages that scratch resistance.
Description
Technical field
The present invention relates to the processing technique field of PVC material, specially a kind of processing technology of hard PVC material.
Background technique
PVC material, that is, polyvinyl chloride, it is one of maximum plastic product of yield in the world, cheap, is widely used,
Corvic is white or buff powder, cannot individually be used, it is necessary to by being modified.PVC is the white of amorphous structure
Color powder, the degree of branching is smaller, poor to the stability of light and heat.Different additives, polychlorostyrene can be added according to different purposes
Different physical property and mechanical property can be presented in vinyl plastics.Suitable plasticizer is added in Corvic, can make
At a variety of hard, soft and transparent article.
PVC was most had found early in 1835 by the famous scientist (Henri Victor Regnault) of France.Then exist
German another one scientist (Eugen Baumann) has also discovered this new material within 1872.It is white in PVC material at that time
The solid of color, great fragility, there is no actual applications.In Russia chemist (Ivan early 20th century
Ostromislensky) and the chemical personage of a batch such as Fritz Klatte once attempts to change the fragility of pvc, becomes
Commercial product still has failed and comes to an end.
Currently, PVC material in our life using very universal, but many PVC material quality are softer, hardness
It is not high, usually scratch can be scraped by sharp thing during use.
Summary of the invention
The purpose of the present invention is to provide a kind of good toughness, while hardness is high, the processing of the hard PVC material with scratch resistance
Technique, to solve the problems mentioned in the above background technology.
To achieve the above object, the invention provides the following technical scheme: a kind of processing technology of hard PVC material, including
Following steps:
A, prepare: get out hard PVC material prepares raw material;
B, melt: the PVC production basic material of preparation is melted according to preparation flow;
C, it adds reagent: will successively add various reagents in raw material that melted PVC material produces;
D, it produces: the raw material prepared is used for the preparation of PVC material;
E, the PVC finished-product material of preparation is handled.
Preferably, the raw material melamine for preparing PVC production according to step A, hard vinyl chloride resin, nanometer two
Titanium dioxide powder, nano silica, nanometer titanium dioxide iron, epoxy resin, antioxidant, compound stabilizer, levelling agent, ring
Oxygen reinforcing agent, defoaming agent, fire retardant, plasticizer, toughener.
Preferably, described according to step B
A, first by melamine, epoxy resin is weaved with Corvic and is blended in pulverizer;
B, the melamine that will be blended, epoxy resin and hard vinyl chloride resin are placed in thawing vat, and being heated to 150 DEG C makes three
Poly cyanamid, epoxy resin and hard vinyl chloride resin are melted in 5min at 150 DEG C, using blender to the melamine of thawing,
Epoxy resin is stirred with hard vinyl chloride resin, mixing speed 60r/min.
Preferably, described according to step C
A, by nano titanium dioxide powder, nano silica, nanometer titanium dioxide iron, antioxidant, compound stabilizer, epoxy
Reinforcing agent, fire retardant, plasticizer, toughener are added, and stir 8-10min;
B, 5min is stirred after being subsequently added into defoaming agent, is then allowed to stand 8min, temperature is dropped to 120 DEG C.
Preferably, the PVC that will be prepared according to step D prepares the equipment or mould that raw material pours into PVC material preparation
In tool, and increase levelling agent on the surface of the material, is solidified using water-cooled cooling.
Preferably, described to be carried out the edge for preparing molding PVC material according to step E to cut finishing.
Compared with prior art, the beneficial effects of the present invention are:
The present invention uses perfect preparation process, and the PVC material produced not only has good toughness, while hardness is high, has
The advantages of scratch resistance.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The invention provides the following technical scheme: a kind of processing technology of hard PVC material, the following steps are included:
A, prepare: get out hard PVC material prepares raw material;
B, melt: the PVC production basic material of preparation is melted according to preparation flow;
C, it adds reagent: will successively add various reagents in raw material that melted PVC material produces;
D, it produces: the raw material prepared is used for the preparation of PVC material;
E, the PVC finished-product material of preparation is handled.
A prepares the raw material melamine of PVC production, hard vinyl chloride resin, nano titanium dioxide powder, nano-silica
SiClx, nanometer titanium dioxide iron, epoxy resin, antioxidant, compound stabilizer, levelling agent, epoxy reinforcing agent, defoaming agent are fire-retardant
Agent, plasticizer, toughener.
20 parts of melamine, 50 parts of hard vinyl chloride resin, 15 parts of nano titanium dioxide powder, nano silica 12
Part, 5 parts of nanometer titanium dioxide iron, 35 parts of epoxy resin, 4 parts of antioxidant, 3 parts of compound stabilizer, 10 parts of levelling agent, epoxy increases
Gu 15 parts of agent, 5 parts of defoaming agent, 8 parts of fire retardant, 4 parts of plasticizer, 6 parts of toughener.
Compound stabilizer used in the PVC material is Methyltin stabiliser, and calcium zinc stabilizer, barium zinc stabilizer is therein
One kind, defoaming agent are silicone emulsion, the fatty acid ester compounded object of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxy second
Alkene polyoxy propyl alcohol amidogen ether is one such.
First by melamine, epoxy resin is weaved with Corvic and is blended in pulverizer, the melamine that will be blended
Amine, epoxy resin and hard vinyl chloride resin are placed in thawing vat, and being heated to 150 DEG C makes melamine, epoxy resin and hard
Corvic is melted in 5min at 150 DEG C, using blender to the melamine of thawing, epoxy resin and hard polyvinyl chloride
Resin is stirred, mixing speed 60r/min, and it is with high hardness excellent that hard vinyl chloride resin has the material of the PVC of production
Point.
Again by nano titanium dioxide powder, nano silica, nanometer titanium dioxide iron, antioxidant, compound stabilizer,
Epoxy reinforcing agent, fire retardant, plasticizer, toughener are added, and stir 8-10min, stir 5min after being subsequently added into defoaming agent, then
8min is stood, temperature is dropped to 120 DEG C, the PVC prepared is prepared into the equipment or mold that raw material pours into PVC material preparation
In, and increase levelling agent on the surface of the material, make the smooth surface of the PVC material of production, is solidified using water-cooled cooling.
The edge for preparing molding PVC material is carried out to cut finishing, the PVC material that shearing trims is rolled up first,
And the PVC material volume outer surface that retracting is got up is wrapped up using packaging film.
The present invention uses perfect preparation process, and the PVC material produced not only has good toughness, while hardness is high,
Has the advantages that scratch resistance.
In conclusion of the invention
The present invention uses perfect preparation process, and the PVC material produced not only has good toughness, while hardness is high, has
The advantages of scratch resistance.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (6)
1. a kind of processing technology of hard PVC material, it is characterised in that: the following steps are included:
A, prepare: get out hard PVC material prepares raw material;
B, melt: the PVC production basic material of preparation is melted according to preparation flow;
C, it adds reagent: will successively add various reagents in raw material that melted PVC material produces;
D, it produces: the raw material prepared is used for the preparation of PVC material;
E, the PVC finished-product material of preparation is handled.
2. a kind of processing technology of hard PVC material according to claim 1, it is characterised in that: it is described quasi- according to step A
The raw material melamine of standby PVC production, hard vinyl chloride resin, nano titanium dioxide powder, nano silica, nanometer two
Iron oxide, epoxy resin, antioxidant, compound stabilizer, levelling agent, epoxy reinforcing agent, defoaming agent, fire retardant, plasticizer,
Toughener.
3. a kind of processing technology of hard PVC material according to claim 1, it is characterised in that: it is described according to step B
First by melamine, epoxy resin is weaved with Corvic and is blended in pulverizer;
The melamine that will be blended, epoxy resin and hard vinyl chloride resin are placed in thawing vat, and being heated to 150 DEG C makes trimerization
Cyanamide, epoxy resin and hard vinyl chloride resin are melted in 5min at 150 DEG C, using blender to the melamine of thawing, ring
Oxygen resin is stirred with hard vinyl chloride resin, mixing speed 60r/min.
4. a kind of processing technology of hard PVC material according to claim 1, it is characterised in that: it is described according to step C
A, by nano titanium dioxide powder, nano silica, nanometer titanium dioxide iron, antioxidant, compound stabilizer, epoxy
Reinforcing agent, fire retardant, plasticizer, toughener are added, and stir 8-10min;
B, 5min is stirred after being subsequently added into defoaming agent, is then allowed to stand 8min, temperature is dropped to 120 DEG C.
5. a kind of processing technology of hard PVC material according to claim 1, it is characterised in that: it is described to be incited somebody to action according to step D
The PVC prepared prepares raw material and pours into equipment or the mold of PVC material preparation, and increases levelling agent on the surface of the material, most
Solidified afterwards using water-cooled cooling.
6. a kind of processing technology of hard PVC material according to claim 1, it is characterised in that: it is described to be incited somebody to action according to step E
The edge for preparing molding PVC material carries out cutting finishing.
Priority Applications (1)
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CN201910767739.8A CN110358225A (en) | 2019-08-20 | 2019-08-20 | A kind of processing technology of hard PVC material |
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CN201910767739.8A CN110358225A (en) | 2019-08-20 | 2019-08-20 | A kind of processing technology of hard PVC material |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104059310A (en) * | 2013-03-18 | 2014-09-24 | 中国石油化工股份有限公司 | Modified hard polyvinyl chloride composition and preparation method thereof |
CN106084575A (en) * | 2016-08-29 | 2016-11-09 | 芜湖市天雄新材料科技有限公司 | A kind of Environment-friendlywear-resistant wear-resistant type PVC decorative material |
CN109897310A (en) * | 2019-04-08 | 2019-06-18 | 安徽律正科技信息服务有限公司 | A kind of retardant polymer material and preparation method thereof |
-
2019
- 2019-08-20 CN CN201910767739.8A patent/CN110358225A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104059310A (en) * | 2013-03-18 | 2014-09-24 | 中国石油化工股份有限公司 | Modified hard polyvinyl chloride composition and preparation method thereof |
CN106084575A (en) * | 2016-08-29 | 2016-11-09 | 芜湖市天雄新材料科技有限公司 | A kind of Environment-friendlywear-resistant wear-resistant type PVC decorative material |
CN109897310A (en) * | 2019-04-08 | 2019-06-18 | 安徽律正科技信息服务有限公司 | A kind of retardant polymer material and preparation method thereof |
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Application publication date: 20191022 |
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