CN109384473A - A kind of high tenacity ceramic glaze - Google Patents
A kind of high tenacity ceramic glaze Download PDFInfo
- Publication number
- CN109384473A CN109384473A CN201811516303.3A CN201811516303A CN109384473A CN 109384473 A CN109384473 A CN 109384473A CN 201811516303 A CN201811516303 A CN 201811516303A CN 109384473 A CN109384473 A CN 109384473A
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- parts
- oxide
- high tenacity
- ceramic glaze
- glaze
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The present invention relates to a kind of high tenacity ceramic glazes, it is prepared from the following raw materials in parts by weight: 5-10 parts of calcite, 40-50 parts of silica, 7-12 parts of titanium dioxide, 2-8 parts of potassium oxide, 2-8 parts of sodium oxide molybdena, 5-20 parts of ceria, 5-10 parts of cerous fluoride, 1-5 parts of calcium oxide, 15-25 parts of aluminium oxide, 4-10 parts of diboron trioxide, FeO3-7 parts；Total, the present invention has the advantages that toughness is high, hardness is high, adherence is good.
Description
Technical field
The invention belongs to porcelain manufacturing technology fields, and in particular to a kind of high tenacity ceramic glaze.
Background technique
Roasting of the ceramic glaze through certain temperature and melt, when the temperature drops, formed ceramic surface glassy thin layer, it makes
Ware increases mechanical strength, thermal stability, dielectric strength and the erosion for preventing liquid, gas, and glaze is beautiful there are also porcelain is increased
With convenient for washing the effects of wiping, not being sticky with by dust, various decorations are can be used also with the artistic effect of enhanced article in glaze, but existing
Common glaze formula composition be difficult to meet performance requirement, the performances such as the toughness and adherence of overglaze glaze are relatively poor；Therefore,
There is provided the high tenacity ceramic glaze that a kind of toughness is high, hardness is high, adherence is good is very important.
Summary of the invention
The purpose of the invention is to overcome the deficiencies in the prior art, and it is good to provide a kind of high toughness, hardness height, adherence
High tenacity ceramic glaze.
The object of the present invention is achieved like this: a kind of high tenacity ceramic glaze, by the raw material system of following parts by weight
At: 5-10 parts of calcite, 40-50 parts of silica, 7-12 parts of titanium dioxide, 2-8 parts of potassium oxide, 2-8 parts of sodium oxide molybdena, titanium dioxide
5-20 parts of cerium, 5-10 parts of cerous fluoride, 1-5 parts of calcium oxide, 15-25 parts of aluminium oxide, 4-10 parts of diboron trioxide, FeO3-7 parts.
A kind of high tenacity ceramic glaze, is prepared from the following raw materials in parts by weight: 5 parts of calcite, 40 parts of silica,
7 parts of titanium dioxide, 2 parts of potassium oxide, 2 parts of sodium oxide molybdena, 5 parts of ceria, 5 parts of cerous fluoride, 1 part of calcium oxide, 15 parts of aluminium oxide,
4 parts of diboron trioxide, FeO3 parts.
A kind of high tenacity ceramic glaze, is prepared from the following raw materials in parts by weight: 7 parts of calcite, 45 parts of silica,
10 parts of titanium dioxide, 5 parts of potassium oxide, 5 parts of sodium oxide molybdena, 12 parts of ceria, 7 parts of cerous fluoride, 3 parts of calcium oxide, aluminium oxide 20
Part, 7 parts of diboron trioxide, FeO5 parts.
A kind of high tenacity ceramic glaze, is prepared from the following raw materials in parts by weight: 10 parts of calcite, silica 50
Part, 12 parts of titanium dioxide, 8 parts of potassium oxide, 8 parts of sodium oxide molybdena, 20 parts of ceria, 10 parts of cerous fluoride, 5 parts of calcium oxide, oxidation
25 parts of aluminium, 10 parts of diboron trioxide, FeO7 parts.
Beneficial effects of the present invention: in the present invention, calcite is also known as calcium stone, mainly plays the effect of cosolvent, energy
Hardness, wear resistance and the corrosion resistance for enough increasing glaze, reduce the melting temperature of glaze, increase the glossiness and transparency of glaze colours,
Prevent and treat glaze cracking and accumulation；Silica is base stock, is capable of forming the skeleton of enamel；Titanium dioxide fusing point is very high, can quilt
For manufacturing fireproof glass, glaze, enamel, clay, experimental ware resistant to high temperature etc., property is stablized, a large amount of to be used as in paint
White pigment, it has persistence of the good covering power as zinc white, is also used as the delustering agent of enamel, can be with
Generate a kind of very bright, hard and acidproof vitreous enamel cover；Potassium oxide, sodium oxide molybdena are alkali metal oxide, are extremely strong help
Solvent；The presence of ceria and cerous fluoride substantially increases FeO in the dissolution of base layer, becomes the catalysis of interfacial reaction
Agent accelerates interfacial reaction, and silicate reaction in FeO and enamel layer is promoted to generate silicic acid iron compound, silicic acid iron compound shape
At anchor-shaped, glaze is tightly held on matrix, increases the adherence of glaze and matrix, and ceria three
The hardness of enamel layer can be provided significantly by being added while cerium fluoride；Calcium oxide and silica form glass, can improve base
The combination of body and glaze improves the elasticity, hardness and gloss of glaze；Aluminum oxide glues frit for porcelain enamel under firing temperature
Degree increases, and nucleus is formed smoothly, and crystal, which is grown up, to be obstructed, and forms a large amount of microstructure, improves the hardness of enamel layer；Three oxidations two
Boron has lesser surface tension and low modulus of elasticity, thus may advantageously facilitate the mobility of melt, improves the gloss of enamel
Degree, sophistication and elasticity also have the function of that fusing point is low, plays cosolvent；Ceramic glaze of the invention can be greatly improved and be warded off
The toughness of glaze and its adherence with base layer, and the hardness of glaze, glossiness and elasticity are preferable.
Specific embodiment
Embodiment 1
A kind of high tenacity ceramic glaze, is prepared from the following raw materials in parts by weight: 5 parts of calcite, 40 parts of silica, and dioxy
7 parts of titanium of change, 2 parts of potassium oxide, 2 parts of sodium oxide molybdena, 5 parts of ceria, 5 parts of cerous fluoride, 1 part of calcium oxide, 15 parts of aluminium oxide, three oxygen
Change 4 parts, FeO3 parts of two boron.
Ceramic glaze of the invention can greatly improve the toughness of frit for porcelain enamel and its adherence with base layer, and glaze
Hardness, glossiness and elasticity it is preferable.
Embodiment 2
A kind of high tenacity ceramic glaze, is prepared from the following raw materials in parts by weight: 10 parts of calcite, 50 parts of silica, and two
12 parts of titanium oxide, 8 parts of potassium oxide, 8 parts of sodium oxide molybdena, 20 parts of ceria, 10 parts of cerous fluoride, 5 parts of calcium oxide, aluminium oxide 25
Part, 10 parts of diboron trioxide, FeO7 parts.
Ceramic glaze of the invention can greatly improve the toughness of frit for porcelain enamel and its adherence with base layer, and glaze
Hardness, glossiness and elasticity it is preferable.
Claims (4)
1. a kind of high tenacity ceramic glaze, which is characterized in that it is prepared from the following raw materials in parts by weight: 5-10 parts of calcite,
It is 40-50 parts of silica, 7-12 parts of titanium dioxide, 2-8 parts of potassium oxide, 2-8 parts of sodium oxide molybdena, 5-20 parts of ceria, borontrifluoride
5-10 parts of cerium, 1-5 parts of calcium oxide, 15-25 parts of aluminium oxide, 4-10 parts of diboron trioxide, FeO3-7 parts.
2. a kind of high tenacity ceramic glaze according to claim 1, which is characterized in that its by following parts by weight raw material
It is made: 5 parts of calcite, 40 parts of silica, 7 parts of titanium dioxide, 2 parts of potassium oxide, 2 parts of sodium oxide molybdena, 5 parts of ceria, trifluoro
Change 5 parts of cerium, 1 part of calcium oxide, 15 parts of aluminium oxide, 4 parts of diboron trioxide, FeO3 parts.
3. a kind of high tenacity ceramic glaze according to claim 1, which is characterized in that its by following parts by weight raw material
It is made: 7 parts of calcite, 45 parts of silica, 10 parts of titanium dioxide, 5 parts of potassium oxide, 5 parts of sodium oxide molybdena, 12 parts of ceria, three
7 parts of cerium fluoride, 3 parts of calcium oxide, 20 parts of aluminium oxide, 7 parts of diboron trioxide, FeO5 parts.
4. a kind of high tenacity ceramic glaze according to claim 1, which is characterized in that its by following parts by weight raw material
It is made: 10 parts of calcite, 50 parts of silica, 12 parts of titanium dioxide, 8 parts of potassium oxide, 8 parts of sodium oxide molybdena, 20 parts of ceria, three
10 parts of cerium fluoride, 5 parts of calcium oxide, 25 parts of aluminium oxide, 10 parts of diboron trioxide, FeO7 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811516303.3A CN109384473A (en) | 2018-12-12 | 2018-12-12 | A kind of high tenacity ceramic glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811516303.3A CN109384473A (en) | 2018-12-12 | 2018-12-12 | A kind of high tenacity ceramic glaze |
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| Publication Number | Publication Date |
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| CN109384473A true CN109384473A (en) | 2019-02-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201811516303.3A Pending CN109384473A (en) | 2018-12-12 | 2018-12-12 | A kind of high tenacity ceramic glaze |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111635134A (en) * | 2020-05-06 | 2020-09-08 | 佛山科学技术学院 | High-toughness foamed ceramic glaze |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129153A (en) * | 2017-05-04 | 2017-09-05 | 钦州学院 | Enamel internal container of water-heater glaze |
| CN108640508A (en) * | 2018-05-29 | 2018-10-12 | 禹州市土魂钧瓷有限公司 | A kind of preparation method of feather glaze |
-
2018
- 2018-12-12 CN CN201811516303.3A patent/CN109384473A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129153A (en) * | 2017-05-04 | 2017-09-05 | 钦州学院 | Enamel internal container of water-heater glaze |
| CN108640508A (en) * | 2018-05-29 | 2018-10-12 | 禹州市土魂钧瓷有限公司 | A kind of preparation method of feather glaze |
Non-Patent Citations (2)
| Title |
|---|
| 应礼文: "《中学化学百科全书》", 30 November 1992, 科学技术文献出版社 * |
| 陈虹: "《中国陶瓷古典釉颜料配方及工艺研究》", 30 November 2016, 江西高校出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111635134A (en) * | 2020-05-06 | 2020-09-08 | 佛山科学技术学院 | High-toughness foamed ceramic glaze |
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Application publication date: 20190226 |