CN109378391A - A kind of solar battery mask plate for spin coating proceeding - Google Patents

A kind of solar battery mask plate for spin coating proceeding Download PDF

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Publication number
CN109378391A
CN109378391A CN201811469584.1A CN201811469584A CN109378391A CN 109378391 A CN109378391 A CN 109378391A CN 201811469584 A CN201811469584 A CN 201811469584A CN 109378391 A CN109378391 A CN 109378391A
Authority
CN
China
Prior art keywords
solar battery
grid
plate
spin coating
mask plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811469584.1A
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Chinese (zh)
Inventor
董超
熊继光
秦校军
赵志国
邬俊波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huaneng Clean Energy Research Institute
China Huaneng Group Co Ltd
Original Assignee
Huaneng Clean Energy Research Institute
China Huaneng Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huaneng Clean Energy Research Institute, China Huaneng Group Co Ltd filed Critical Huaneng Clean Energy Research Institute
Priority to CN201811469584.1A priority Critical patent/CN109378391A/en
Publication of CN109378391A publication Critical patent/CN109378391A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10Deposition of organic active material
    • H10K71/12Deposition of organic active material using liquid deposition, e.g. spin coating
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/80Constructional details
    • H10K30/81Electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

Abstract

The present invention provides a kind of solar battery mask plates for spin coating proceeding, including peripheral frame skeleton and the electrode domain thin plate being fixed on peripheral frame skeleton;Peripheral frame skeleton is equipped with several grid, each quadrille four edges;Several grid also are provided on electrode domain thin plate;The grid of electrode domain thin plate and the grid of peripheral frame skeleton are correspondingly arranged;Coating film area is equipped on each grid of electrode domain thin plate, coating film area is made of several ring structures and rectangular configuration.The invention solar battery mask plate uses the coating film area of several ring structures and rectangular configuration, the specific region with same battery structure distribution can be selected with frame, it is possible thereby to determine the optimal region of battery efficiency, and then the region specific structural features are studied, adjusts technological parameter;Can also a plurality of ring structure cell area in this way, judge the uniformity of technique preparation.

Description

A kind of solar battery mask plate for spin coating proceeding
Technical field
The invention belongs to mask plate technical field, in particular to a kind of mask that solar battery is prepared for spin coating proceeding Plate.
Background technique
Perovskite solar battery is very fast as a kind of novel solar battery development that photovoltaic industry occurs, at present There are the projects such as associated subject study, such as high efficiency, stability, large area direction in domestic many colleges and universities.Perovskite Solar battery since 2009 discovery since its photoelectric conversion efficiency from 3.8% promoted by now 22% or more, Improved efficiency speed is that various solar batteries are promoted fastest in the market, and its photoelectric conversion efficiency has been approached or surpasses Cross conventional crystalline silicon, copper indium gallium selenide and cadmium telluride cells on the market.Another big advantage of perovskite solar battery is exactly to make Process flow, which is compared, greatly shortens simplification with conventional crystalline silicon battery, and cost of manufacture is also greatly reduced.Perovskite solar-electricity Pond is usually made of the material film of multilayer different function, and the preparation of film can use solwution method, i.e. spin coating proceeding system It is standby.Metal material as electrode generally uses the techniques such as vacuum evaporation, magnetron sputtering to prepare.
In general, metal electrode (such as gold, silver, aluminium as electrode etc.) generallys use vapour deposition process plated film.Gas Required electrode pattern is generally deposited in phase sedimentation using the mask plate for designing special pattern, and mask plate is by certain amount of phase It is formed with cage, each grid accommodates, fixes glass substrate;Coating film area in grid is the figure of electrode evaporation, with one Determine the rectangle that mode arranges to constitute.The corresponding electrode of each rectangle, electrode have a differentiation of positive and negative electrode, one of electrode with Other polarity of electrode are opposite.Other parts are masked plate and block, no plating film pattern.The cage of mask plate and glass substrate Size matches, and generally slightly expands compared with the size of glass substrate, with allow glass substrate cutting, hand break during caused by The presence of size slight change phenomenon.
Perovskite solar battery in the production process, the functions such as electron transfer layer, perovskite active layer, hole transmission layer Thin layer mostly uses spin coating proceeding to be prepared.And spin coating proceeding is weaker in the control of the thickness uniformity of thin layer, preparation Thickness of thin layer is in by center radial change of gradient around.In the prior art, as shown in fig. 6, using rectangular graph mask plate Electrode battery is prepared, is unfavorable for distinguishing the corresponding battery efficiency in different cell thickness regions, simultaneously in final test battery efficiency Electrical property difference caused by this difference in thickness cannot be embodied;As shown in fig. 7, the grid size of mask plate and the size of substrate Match, substrate is possible to be stuck in inside grid when being put into taking-up, is not easy to the adjustment and movement of glass substrate.
Summary of the invention
The purpose of the present invention is to provide a kind of solar battery mask plates suitable for spin coating proceeding, to solve above-mentioned skill Art problem.The annular slab graph structure of mask plate of the invention can select the specific region with same battery structure distribution with frame, It is possible thereby to determine the optimal region of battery efficiency.
To achieve the goals above, the technical solution adopted by the present invention is that:
A kind of solar battery mask plate for spin coating proceeding, including peripheral frame skeleton and the electricity being fixed on peripheral frame skeleton Pole domain thin plate;Peripheral frame skeleton is equipped with several grid, each quadrille four edges;It also is provided on electrode domain thin plate several A grid;The grid of electrode domain thin plate and the grid of peripheral frame skeleton are correspondingly arranged;On each grid of electrode domain thin plate Equipped with coating film area, coating film area is made of several ring structures and rectangular configuration.
Further, at least one vertex is equipped with recess in each grid of peripheral frame skeleton.
Further, the circular recess that recess is 3/4ths.
Further, peripheral frame skeleton includes outline border and several demarcation plates in outline border, between the grid of peripheral frame skeleton Pass through divides.
Further, with peripheral frame skeleton using being welded and fixed, welding junction polishes electrode domain thin plate.
Further, peripheral frame skeleton is made of steel plate, steel plate thickness 1.25mm.
Further, electrode domain thin plate is made of steel plate, steel plate thickness 0.2mm.
Further, mask plate is separated into 8 × 8 evenly arranged 64 square lattices by outline border and demarcation plate, 2.5mm is spaced between the grid of peripheral frame skeleton.
Further, coating film area is hollowed out area in electrode domain thin plate, and other parts are masked plate and block.
Further, the solar battery mask plate for spin coating proceeding preparation method the following steps are included:
1) production obtains the peripheral frame skeleton of solar battery mask plate;
2) production obtains the electrode domain thin plate equipped with coating film area;
3) the electrode domain thin plate in step 2) is fixed on the peripheral frame skeleton in step 1) using welding manner, is obtained Solar battery mask plate for spin coating proceeding.
Compared with prior art, the beneficial effects of the present invention are as follows:
A kind of solar battery mask plate for spin coating proceeding, using the plated film area for having several annulars and rectangular configuration Domain can select the specific region of the distribution with same battery structure with frame, it is possible thereby to determine the optimal region of battery efficiency, And then study the region specific structural features, adjust technological parameter, it can also be judged by several ring structure cell areas Spin coating proceeding prepares the uniformity of solar battery.Recess is arranged using grid vertex, the tools such as tweezers can be accommodated, is convenient for glass Being put into of glass substrate is taken out and the adjustment of the position of glass substrate.
Detailed description of the invention
Fig. 1 is one of the mask plate of the present invention example schematic with 8 × 8 totally 64 grid peripheral frame skeletons.
Fig. 2 is one of the mask plate of the present invention example schematic with 8 × 8 totally 64 electrode domain thin plates.
Fig. 3 is the electrode domain thin plate partial schematic diagram of mask plate of the present invention.
Fig. 4 is the peripheral frame skeleton partial schematic diagram of mask plate of the present invention.
Fig. 5 is the electrode domain thin plate coating film area structural schematic diagram of mask plate of the present invention.
Fig. 6 is the plated film graphic structure schematic diagram of traditional mask board.
Fig. 7 is the coating film area structural schematic diagram of traditional mask board.
Specific embodiment
The embodiment that the present invention will be described in detail with reference to the accompanying drawings and examples.
As shown in Fig. 1,4, the present invention provides a kind of solar battery mask plate for spin coating proceeding, including peripheral frame skeleton 1;Peripheral frame skeleton 1 includes outline border 11 and demarcation plate 12;Mask plate is separated into several grid 3 by outline border 11 and demarcation plate 12, is used for Fixed glass substrate;Each grid 3 has four edges;The square lattice plays a part of to accommodate, fixes glass substrate;Each grid 3 vertex are equipped with 3/4ths cylindrical recess 31, can accommodate the tools such as tweezers, convenient for being put into of glass substrate, take out and Position adjustment.
As shown in Fig. 2,3,5, a kind of solar battery mask plate for spin coating proceeding further includes electrode domain thin plate 2, Several grid also are provided on electrode domain thin plate 2;The grid of electrode domain thin plate 2 and the grid 3 one of peripheral frame skeleton 1 are a pair of It answers;Each grid of electrode domain thin plate 2 is equipped with coating film area 21;Coating film area 21 is by ring structure 221 and rectangular configuration 222 are constituted;On electrode domain thin plate 2 in addition to 21 region of coating film area, other parts are by mask plate shielding.
It as shown in Figure 6,7, is solar battery mask plate traditional in the prior art, traditional mask plate peripheral frame skeleton The square lattice of formation is not provided with notch, is not easy to the position adjustment and movement of glass substrate;Traditional electrode domain is thin Coating film area on plate is rectangular configuration;The coating film area of rectangular configuration is unfavorable for distinguishing different cell thickness regions corresponding Battery efficiency.
A kind of production method of the solar battery mask plate for spin coating proceeding of the present invention, comprising the following steps:
1) production obtains the peripheral frame skeleton 1 of solar battery mask plate;
2) production obtains the electrode domain thin plate 2 equipped with coating film area 21;
3) the electrode domain thin plate 2 in step 2) is fixed on the peripheral frame skeleton 1 in step 1) using welding manner, is obtained To the solar energy mask plate for spin coating proceeding.
Embodiment
A kind of solar battery mask plate for spin coating proceeding, outline border skeleton 1 are constituted using steel plate, with a thickness of 1.25mm, identical as experimental glass substrate thickness, mask plate is separated into 8 × 8 by the outline border 11 and demarcation plate 12 of outline border skeleton 1 Totally 64 square lattices 3, between grid 3 between be divided into 2.5mm.The grid of electrode domain thin plate 2 and the grid 3 one of outline border skeleton 1 One is correspondingly arranged, and is welded and fixed with peripheral frame skeleton 1;Electrode domain thin plate 2 is constituted using steel plate, with a thickness of 0.2mm;Electrode version Coating film area 21 is set on figure thin plate 2, and coating film area is made of ring structure 221 and rectangular configuration 222;Electrode domain thin plate 2 On in addition to 21 region of coating film area, other parts are by mask plate shielding.
Other structures form of the invention can change the size and quantity of domain annular region on the basis of the present invention To adapt to the required region tested, rectangular area electrode can also be changed and draw position and the spacing of section to adapt to different batteries surveys Try fixture.
The foregoing is merely an example of the present invention, are not intended to restrict the invention.For the professional technique of this field For personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, that is done any repairs Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of solar battery mask plate for spin coating proceeding, which is characterized in that including peripheral frame skeleton (1) and be fixed on side Electrode domain thin plate (2) on frame skeleton (1);Peripheral frame skeleton (1) is equipped with several grid (3), and each grid (3) has four Side;Several grid also are provided on electrode domain thin plate (2);The grid of electrode domain thin plate (2) and the grid of peripheral frame skeleton (1) It is correspondingly arranged;It is equipped on each grid of electrode domain thin plate (2) coating film area (21), coating film area (21) is by several annulars Structure (221) and rectangular configuration (222) are constituted.
2. a kind of solar battery mask plate for spin coating proceeding according to claim 1, which is characterized in that frame bone At least one vertex is equipped with recess (31) in each grid (3) of frame (1).
3. a kind of solar battery mask plate for spin coating proceeding according to claim 2, which is characterized in that recess (31) circular recess for being 3/4ths.
4. a kind of solar battery mask plate for spin coating proceeding according to claim 1, which is characterized in that frame bone Frame (1) includes outline border (11) and several demarcation plates (12) in outline border, passes through between the grid (3) of peripheral frame skeleton (1) and divides Partition (12) separates.
5. a kind of solar battery mask plate for spin coating proceeding according to claim 1, which is characterized in that electrode version With peripheral frame skeleton (1) using being welded and fixed, welding junction polishes figure thin plate (2).
6. a kind of solar battery mask plate suitable for spin coating proceeding according to claim 1, which is characterized in that frame Skeleton (1) is made of steel plate, steel plate thickness 1.25mm.
7. a kind of solar battery mask plate for spin coating proceeding according to claim 1, which is characterized in that electrode version Figure thin plate (2) is made of steel plate, steel plate thickness 0.2mm.
8. a kind of solar battery mask plate for spin coating proceeding according to claim 4, which is characterized in that outline border (11) and mask plate is separated into 8 × 8 evenly arranged 64 square lattices (3), peripheral frame skeleton (1) by demarcation plate (12) Grid (3) between be spaced 2.5mm.
9. a kind of solar battery mask plate for spin coating proceeding according to claim 1, which is characterized in that electrode version Coating film area (21) is hollowed out area in figure thin plate (2), and other parts are masked plate and block.
10. a kind of solar battery mask plate for spin coating proceeding according to any one of claim 1 to 9, special Sign is, the preparation method of the solar battery mask plate for spin coating proceeding the following steps are included:
1) production obtains the peripheral frame skeleton (1) of solar battery mask plate;
2) production obtains the electrode domain thin plate (2) equipped with coating film area (21);
3) it on the peripheral frame skeleton (1) for using welding manner to be fixed in step 1) the electrode domain thin plate (2) in step 2), obtains To the solar battery mask plate for spin coating proceeding.
CN201811469584.1A 2018-11-28 2018-11-28 A kind of solar battery mask plate for spin coating proceeding Pending CN109378391A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
CN109378391A true CN109378391A (en) 2019-02-22

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1908665A (en) * 2005-08-02 2007-02-07 中国科学院电子学研究所 Blended self-assembly membrane based micro ampere immunity sensor and preparation thereof
US20110259392A1 (en) * 2010-11-04 2011-10-27 Sungeun Lee Thin film solar cell and method of manufacturing the same
CN105045032A (en) * 2015-08-27 2015-11-11 京东方科技集团股份有限公司 Mask plate, spacer and display device
CN206432282U (en) * 2017-01-22 2017-08-22 苏州阿特斯阳光电力科技有限公司 A kind of PERC batteries plated film mask structure
CN208939013U (en) * 2018-11-28 2019-06-04 中国华能集团有限公司 A kind of solar battery mask plate for spin coating proceeding

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1908665A (en) * 2005-08-02 2007-02-07 中国科学院电子学研究所 Blended self-assembly membrane based micro ampere immunity sensor and preparation thereof
US20110259392A1 (en) * 2010-11-04 2011-10-27 Sungeun Lee Thin film solar cell and method of manufacturing the same
CN105045032A (en) * 2015-08-27 2015-11-11 京东方科技集团股份有限公司 Mask plate, spacer and display device
CN206432282U (en) * 2017-01-22 2017-08-22 苏州阿特斯阳光电力科技有限公司 A kind of PERC batteries plated film mask structure
CN208939013U (en) * 2018-11-28 2019-06-04 中国华能集团有限公司 A kind of solar battery mask plate for spin coating proceeding

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