CN109371703A - Conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement and preparation method and application - Google Patents

Conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement and preparation method and application Download PDF

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Publication number
CN109371703A
CN109371703A CN201811289591.3A CN201811289591A CN109371703A CN 109371703 A CN109371703 A CN 109371703A CN 201811289591 A CN201811289591 A CN 201811289591A CN 109371703 A CN109371703 A CN 109371703A
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China
Prior art keywords
parts
aqueous
rubber cement
indsole
sheaing
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CN201811289591.3A
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Chinese (zh)
Inventor
张世林
陈松雄
侯文霞
晋齐怀
周川泉
杜江
田吉
王春桥
张华林
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Jihua 3537 Shoe Making Co Ltd
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Jihua 3537 Shoe Making Co Ltd
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Publication date
Application filed by Jihua 3537 Shoe Making Co Ltd filed Critical Jihua 3537 Shoe Making Co Ltd
Priority to CN201811289591.3A priority Critical patent/CN109371703A/en
Publication of CN109371703A publication Critical patent/CN109371703A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/04Properties of the materials having electrical or magnetic properties
    • D06N2209/041Conductive
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/10Clothing
    • D06N2211/106Footwear

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cements and preparation method and application, in parts by weight, including 167 parts of natural emulsions, 25 parts of titanium dioxides, 0.7 part of paregal O, 0.6 part of wetting agent JFC, 1.5 parts of aqueous defoamers, 75 parts of soft water, 5.0 parts of nano ATO dispersion liquids, 2.0 parts of mould inhibitor BCM, 0.9 part of anti-aging agent KY-405L, 4.0 parts of zinc oxide, 0.3 part of potassium hydroxide, 3.0 parts of sodium carboxymethylcelluloses, 1.5 parts of promotors, 3.0 parts of sulphur.The present invention screens the formula and preparation method of conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, optimizes, and makes it under the premise of adhesive strength is good, has excellent conducting function, and low in cost, asepsis environment-protecting can improve the quality of production.Simple production process of the invention, material source is extensive, is suitable for industrialized production.

Description

Conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement and preparation method and application
Technical field
The present invention relates to rubber processing, especially a kind of conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement and its system Preparation Method and application.
Background technique
Currently, for the electric conductivity for realizing base fabric sheaing rubber cement in shoes use, most of gasoline using filling metal powder Type rubber cement, adhesive property is good, and adhesive strength is high, but pollutes the disadvantage is that existing to environment, easy to cause fire, is good for operator Health harm is larger.And since organic solvent is volatile, storage and transport are also not easy, storage life is very short, about on a week left side The right side is not able to satisfy real production demand.And the rubber cement prepared using water as solvent, production technology are easy, it is not necessary to It employs powerful device and energy saving, can reach one existing for technique and technical requirement and Gasoline rubber paste A little disadvantages.However usually using the aqueous rubber cement of latex production since consistency is low, coated in being easy to produce seep through on rubber overshoes base fabric Phenomenon, influences rubber overshoes presentation quality, and base fabric generates adhesion deformation in blanking process and seriously brings very big be stranded to actual production It is difficult.And electrostatic charge cannot be exported successfully in vitro because conductive capability is limited, far can not eliminate particular surroundings by such rubber cement Under due to itself static electricity and bring harm and security risk.
Therefore, it is the market demand for meeting particular surroundings and special population, guarantees rubber overshoes quality, improves cloth and sponge rubber The bond properties and its electric conductivity of glue, it is ensured that cloth cover seep through and other issues will not be generated, shoes are eliminated with base fabric and scrape slurry process In Electrostatic Fire, and the electrostatic of human body institute band can be successfully exported, so that invention waterborne conductive sheaing rubber cement is conductive in production Have urgent reality unexpectedly adopted during rubber overshoes.
Summary of the invention
The technical problems to be solved by the present invention are: provide a kind of conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement and its Preparation method and application, it has excellent conducting function, and low in cost, asepsis environment-protecting can improve the quality of production, with gram Take the deficiencies in the prior art.
Of the invention is achieved in that conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, in parts by weight, packet Include 160~170 parts of natural emulsions, 20~30 parts of titanium dioxides, 0.5~0.9 part of paregal O, 0.5~0.7 part of wetting agent JFC, 1~ 2 parts of aqueous defoamers, 70~80 parts of soft water, 4~6 parts of nano ATO dispersion liquids, 1.5~2.5 parts of mould inhibitor BCM, 0.8~1.0 part Anti-aging agent KY-405L, 3~5 parts of zinc oxide, 0.2~0.4 part of potassium hydroxide, 2~4 parts of sodium carboxymethylcelluloses, 1~2 part of promotion Agent and 2.5~3.5 parts of sulphur.
Preferred mode is, in parts by weight, including 167 parts of natural emulsions, 25 parts of titanium dioxides, 0.7 part is average Add O, 0.6 part of wetting agent JFC, 1.5 parts of aqueous defoamers, 75 parts of soft water, 5.0 parts of nano ATO dispersion liquids, 2.0 parts of mould inhibitors BCM, 0.9 part of anti-aging agent KY-405L, 4.0 parts of zinc oxide, 0.3 part of potassium hydroxide, 3.0 parts of sodium carboxymethylcelluloses, 1.5 parts of rush Into agent and 3.0 parts of sulphur.
The preparation method of conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, takes each component by above-mentioned weight fraction;1) match CMC swelling body processed: 65 parts of soft water, sodium carboxymethylcellulose and mould inhibitor BCM mixing are added into blender, is slowly stirred and adds Enter potassium hydroxide, stir to sodium carboxymethylcellulose the thick shape liquid for no clustering phenomena that is uniformly dispersed, obtains CMC swelling body;
2) vulcanizing agent aqueous dispersions are prepared:
A) canned small ball weight is 8 kilograms, and wherein the small ball weight of diameter 20-40mm is 6.0 kilograms, diameter 10- The small ball weight of 15mm is 2.0 kilograms, is replenished in time after abrasion;
B) tinning sequence: 5 parts of soft water are added into tank, anti-aging agent KY-405L, zinc oxide, promotor, sulphur, aqueous disappear Infusion is eventually adding remaining soft water, and various compounding agents are stirred evenly, upper cover sealing → labelling, ball milling;
C) Ball-milling Time adds up whole for 10 hours, and tank cannot be washed with water when tank out, and tinning must use soft water;
D) ball milling liquid shows enchashment use, cannot go out tank and park deposit;
3) rubber cement manufactures: vulcanizing agent aqueous dispersions being added into CMC swelling body, nano ATO dispersion liquid, wetting agent JFC, put down Flat plus O and titanium dioxide, stirring to powder it is fully dispersed uniformly after, obtain mixing mother liquor;Under agitation, to mixing mother liquor in by Natural emulsion is gradually added, continues that it is fully dispersed to be stirred to each compounding agent to be uniform viscous body, pulp is got product, with imitative Baume Densimeter measures rubber cement concentration, and concentration is 13~18 seconds.
A kind of application of conduction rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, it is characterised in that: 48 prepared in rubber cement In hour, the glue that a layer thickness is 0.2~0.4mm is equably scraped on base fabric in the rubber overshoes sponge that resistance value tends to 0.000K Ω Pulp layer guarantees that the gap of fabric fibre is filled up completely by rubber cement, takes the middle base fabric for the sheaing rubber cement covering that length and width is 25cm or so Be put into vulcanizing tank, vulcanize under conditions of 130 DEG C × 40min it is primary, after parking one day, base fabric surface dirt and miscellaneous in cleaning Object, with resistance apparatus measure in base fabric resistance value.
Nano ATO dispersion liquid --- water fluid conductive material, resistivity 106-108(Ω.cm)
Natural emulsion --- it is bonded with measuring fiber.
Wetting agent JFC --- increase bonding rubber cement to the penetrating power of woven design, to improve bonding intensity.
Paregal O --- increase the stability of rubber cement system, improves the greasy property that sole cloth scrapes slurry, it is ensured that pulp layer is thick Degree.
Aqueous defoamer --- eliminate the insoluble gas in rubber cement.
Potassium hydroxide --- alkaline medium prevents from going bad.
Mould inhibitor BCM --- prevent mucilage layer and sole cloth from going mouldy.
Hydroxymethyl cellulose --- for the thickening stabilizing agent in rubber cement body, prevent rubber cement to the through performance of woven design.
Titanium dioxide --- woven design filler.
Nano ATO dispersion liquid performance parameter
Interconnection of the evenly dispersed nano ATO conducting particles in insulating body is to reach the effect of electrically conducting transparent Fruit, and stablize without easy to knot groups.
In order to further verify effect of the invention, following experiment has been carried out:
One, optimum proportion of materials research
Table 1
Table 1 is continuous
Table 1 continuous 2
Table 1 continuous 3
According to 1 test result of table, optimum formula are as follows: 167 parts of natural emulsions, 25 parts of titanium dioxides, 0.7 part of paregal O, 0.6 Part wetting agent JFC, 1.5 parts of aqueous defoamers, 75 parts of soft water, 5.0 parts of nano ATO dispersion liquids, 2.0 parts of mould inhibitor BCM, 0.9 part Anti-aging agent KY-405L, 4.0 parts of zinc oxide, 0.3 part of potassium hydroxide, 3.0 parts of sodium carboxymethylcelluloses, 1.5 parts of promotors, 3.0 parts Sulphur.
Two, pulping process is studied
Table 2
It show that optimum manufacturing process is by several comparison of process flow in table 2: first manufacturing CMC swelling body, vulcanizing agent Aqueous dispersions, then each compounding agent is added thereto and is fabricated to titanium dioxide mixing liquid, it is finally gradually added into natural emulsion again, prepares Sheaing rubber cement quality be just able to satisfy and scrape base fabric requirement.
By adopting the above-described technical solution, compared with prior art, the present invention is to rubber overshoes sponge indsole fabric aqueous sheaing The formula and preparation method of rubber cement are screened, are optimized, and make it under the premise of adhesive strength is good, have good conductive function Can, asepsis environment-protecting can improve the quality of production.Simple production process of the invention, material source is extensive, is suitable for industrial metaplasia It produces.The invention is simple and feasible, low in cost, and the using effect of product is good.
Specific embodiment
The embodiment of the present invention 1: conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, in parts by weight, including 167 Part natural emulsion, 25 parts of titanium dioxides, 0.7 part of paregal O, 0.6 part of wetting agent JFC, 1.5 parts of aqueous defoamers, 75 parts of soft water, 5.0 parts of nano ATO dispersion liquids, 2.0 parts of mould inhibitor BCM, 0.9 part of anti-aging agent KY-405L, 4.0 parts of zinc oxide, 0.3 part of hydroxide Potassium, 3.0 parts of sodium carboxymethylcelluloses, 1.5 parts of promotors, 3.0 parts of sulphur.
The preparation method of conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, takes each component by above-mentioned weight fraction;1) match CMC swelling body processed: 65 parts of soft water, 3 parts of sodium carboxymethylcelluloses and 2.0 parts of mould inhibitor BCM mixing are added into blender, slowly 0.3 part of potassium hydroxide is stirred and be added, the thick shape liquid for no clustering phenomena that is uniformly dispersed is stirred to sodium carboxymethylcellulose, is obtained CMC swelling body;2) prepare vulcanizing agent aqueous dispersions: a) canned small ball weight is 8 kilograms, wherein the bead weight of diameter 20-40mm Amount is 6.0 kilograms, and the small ball weight that diameter is 10-15mm is 2.0 kilograms, is replenished in time after abrasion.B) tinning sequence: into tank Be added 5 parts of soft water, 0.9 part of anti-aging agent KY-405L, 4.0 parts of zinc oxide, 1.5 parts of promotors, 3.0 parts of sulphur, 1.5 parts aqueous disappear Infusion is eventually adding 5.0 parts of soft water, various compounding agents is stirred evenly, upper cover sealing → labelling, ball milling.C) Ball-milling Time Add up whole for 10 hours, tank cannot be washed with water when tank out, tinning must use soft water.D) ball milling liquid shows enchashment use, forbids tank out Park deposit.3) rubber cement manufactures: vulcanizing agent aqueous dispersions, 5.0 parts of nano ATO dispersion liquids, 0.6 part being added into CMC swelling body Wetting agent JFC, 0.75 part of paregal O, 25 parts of titanium dioxides, stirring to powder it is fully dispersed uniformly after, obtain mixing mother liquor;It is stirring Under the conditions of, 167 parts of natural emulsions are gradually added into mixing mother liquor, continue that it is fully dispersed to be stirred to each compounding agent to be uniform viscous Thick body, pulp are got product, and measure rubber cement concentration with imitative Baumé areometer, it is qualification that concentration, which is 13~18 seconds,.
The application of conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, it is characterised in that: 48 hours prepared in rubber cement It is interior, the rubber cement that a layer thickness is 0.2~0.4mm is equably scraped on base fabric in the rubber overshoes sponge that resistance value tends to 0.000K Ω Layer, guarantees that the gap of fabric fibre is filled up completely by rubber cement, and the indsole for the sheaing rubber cement covering that length and width is 25cm or so is taken to lay Enter in vulcanizing tank, vulcanize under conditions of 130 DEG C × 40min it is primary, after parking one day, base fabric surface dirt and miscellaneous in cleaning Object, with resistance apparatus measure in base fabric resistance value.
The embodiment of the present invention 2: conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, in parts by weight, including 167 Part natural emulsion, 30 parts of titanium dioxides, 0.7 part of paregal O, 0.6 part of wetting agent JFC, 1.5 parts of aqueous defoamers, 75 parts of soft water, 8.0 parts of nano ATO dispersion liquids, 2.0 parts of mould inhibitor BCM, 0.9 part of anti-aging agent KY-405L, 4.0 parts of zinc oxide, 0.3 part of hydroxide Potassium, 3.0 parts of sodium carboxymethylcelluloses, 1.5 parts of promotors, 3.0 parts of sulphur.
Preparation method and application is the same as embodiment 1.
The embodiment of the present invention 3: conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, in parts by weight, including 167 Part natural emulsion, 25 parts of titanium dioxides, 0.7 part of paregal O, 0.6 part of wetting agent JFC, 1.5 parts of aqueous defoamers, 85 parts of soft water, 5.0 parts of nano ATO dispersion liquids, 2.0 parts of mould inhibitor BCM, 0.9 part of anti-aging agent KY-405L, 4.0 parts of zinc oxide, 0.3 part of hydroxide Potassium, 4.0 parts of sodium carboxymethylcelluloses, 1.5 parts of promotors, 3.0 parts of sulphur.Preparation method and application is the same as embodiment 1.

Claims (7)

1. a kind of conduction rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, it is characterised in that: in parts by weight, including 160~ 170 parts of natural emulsions, 20~30 parts of titanium dioxides, 0.5~0.9 part of paregal O, 0.5~0.7 part of wetting agent JFC, 1~2 part aqueous Defoaming agent, 70~80 parts of soft water, 4~6 parts of nano ATO dispersion liquids, 1.5~2.5 parts of mould inhibitor BCM, 0.8~1.0 part of anti-aging agent KY-405L, 3~5 parts of zinc oxide, 0.2~0.4 part of potassium hydroxide, 2~4 parts of sodium carboxymethylcelluloses, 1~2 part of promotor and 2.5~3.5 parts of sulphur.
2. base fabric sheaing rubber cement in antistatic rubber overshoes sponge according to claim 1, it is characterised in that: according to parts by weight It calculates, including 167 parts of natural emulsions, 25 parts of titanium dioxides, 0.7 part of paregal O, 0.6 part of wetting agent JFC, 1.5 parts of aqueous defoamers, 75 parts of soft water, 5.0 parts of nano ATO dispersion liquids, 2.0 parts of mould inhibitor BCM, 0.9 part of anti-aging agent KY-405L, 4.0 parts of zinc oxide, 0.3 Part potassium hydroxide, 3.0 parts of sodium carboxymethylcelluloses, 1.5 parts of promotors and 3.0 parts of sulphur.
3. conduction rubber overshoes sponge indsole fabric aqueous sheaing rubber cement according to claim 1 or 2, it is characterised in that: genuine milk Glue solid is content 60%.
4. conduction rubber overshoes sponge indsole fabric aqueous sheaing rubber cement according to claim 1 or 2, it is characterised in that: nano ATO Dispersion liquid is water fluid conductive material.
5. conduction rubber overshoes sponge indsole fabric aqueous sheaing rubber cement according to claim 1 or 2, it is characterised in that: 1.5 parts of rush It is 1.5 parts of promotor TT into agent.
6. a kind of preparation method of conduction rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, it is characterised in that: press above-mentioned weight fraction Take each component;
1) it prepares CMC swelling body: 65 parts of soft water, sodium carboxymethylcellulose and mould inhibitor BCM mixing being added into blender, slowly Potassium hydroxide is stirred and be added, the thick shape liquid for no clustering phenomena that is uniformly dispersed is stirred to sodium carboxymethylcellulose, obtains CMC swelling Body;
2) vulcanizing agent aqueous dispersions are prepared:
A) canned small ball weight is 8 kilograms, and wherein the small ball weight of diameter 20-40mm is 6.0 kilograms, and diameter is 10-15mm's Small ball weight is 2.0 kilograms, is replenished in time after abrasion;
B) tinning sequence: 5 parts of soft water, anti-aging agent KY-405L, zinc oxide, promotor, sulphur, aqueous defoamer being added into tank, It is eventually adding remaining soft water, various compounding agents are stirred evenly, upper cover sealing → labelling, ball milling;
C) Ball-milling Time adds up whole for 10 hours, and tank cannot be washed with water when tank out, and tinning must use soft water;
D) ball milling liquid shows enchashment use, cannot go out tank and park deposit;
3) rubber cement manufactures: vulcanizing agent aqueous dispersions, nano ATO dispersion liquid, wetting agent JFC, peregal being added into CMC swelling body O and titanium dioxide, stirring to powder it is fully dispersed uniformly after, obtain mixing mother liquor;Under agitation, gradually add into mixing mother liquor Enter natural emulsion, continues that it is fully dispersed to be stirred to each compounding agent to be uniform viscous body, pulp is got product, with imitative Baume degree Meter measurement rubber cement concentration, concentration are 13~18 seconds.
7. a kind of application of conduction rubber overshoes sponge indsole fabric aqueous sheaing rubber cement, it is characterised in that: prepared in rubber cement 48 small When it is interior, the rubber cement that a layer thickness is 0.2~0.4mm is equably scraped on base fabric in the rubber overshoes sponge that resistance value tends to 0.000K Ω Layer, guarantees that the gap of fabric fibre is filled up completely by rubber cement, and the indsole for the sheaing rubber cement covering that length and width is 25cm or so is taken to lay Enter in vulcanizing tank, vulcanize under conditions of 130 DEG C × 40min it is primary, after parking one day, base fabric surface dirt and miscellaneous in cleaning Object, with resistance apparatus measure in base fabric resistance value.
CN201811289591.3A 2018-10-31 2018-10-31 Conductive rubber overshoes sponge indsole fabric aqueous sheaing rubber cement and preparation method and application Pending CN109371703A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110628097A (en) * 2019-09-27 2019-12-31 际华三五三七有限责任公司 Middle-base fabric scratch latex slurry for shoes and preparation method and application thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103276599A (en) * 2013-06-18 2013-09-04 际华三五三七制鞋有限责任公司 Anti-static water-based cloth coating mucilage in base cloth in sponges in rubber shoes, and preparation method and application thereof
CN103340490A (en) * 2013-06-18 2013-10-09 际华三五三七制鞋有限责任公司 Environment-friendly non-metal puncture-proof antistatic one-time heat-vulcanization rubber shoe and manufacturing method thereof
CN106047208A (en) * 2016-07-26 2016-10-26 常熟市长江胶带有限公司 Antistatic shading tape
CN108300344A (en) * 2016-09-19 2018-07-20 东莞爵士先进电子应用材料有限公司 Conductive tape and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103276599A (en) * 2013-06-18 2013-09-04 际华三五三七制鞋有限责任公司 Anti-static water-based cloth coating mucilage in base cloth in sponges in rubber shoes, and preparation method and application thereof
CN103340490A (en) * 2013-06-18 2013-10-09 际华三五三七制鞋有限责任公司 Environment-friendly non-metal puncture-proof antistatic one-time heat-vulcanization rubber shoe and manufacturing method thereof
CN106047208A (en) * 2016-07-26 2016-10-26 常熟市长江胶带有限公司 Antistatic shading tape
CN108300344A (en) * 2016-09-19 2018-07-20 东莞爵士先进电子应用材料有限公司 Conductive tape and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110628097A (en) * 2019-09-27 2019-12-31 际华三五三七有限责任公司 Middle-base fabric scratch latex slurry for shoes and preparation method and application thereof

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Application publication date: 20190222