CN109370450A - A kind of adhesive applied to medical packaging bottle - Google Patents
A kind of adhesive applied to medical packaging bottle Download PDFInfo
- Publication number
- CN109370450A CN109370450A CN201811220825.9A CN201811220825A CN109370450A CN 109370450 A CN109370450 A CN 109370450A CN 201811220825 A CN201811220825 A CN 201811220825A CN 109370450 A CN109370450 A CN 109370450A
- Authority
- CN
- China
- Prior art keywords
- parts
- packaging bottle
- medical packaging
- adhesive applied
- bottle according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Medical Preparation Storing Or Oral Administration Devices (AREA)
Abstract
The present invention relates to a kind of adhesive applied to medical packaging bottle, the raw material including following parts by weight: organosilicon -10-30 parts of acrylic resin, 1-10 parts of esters of silicon acis, 1-5 parts of silica solution, 1-10 parts of silane coupling agent, 0.1-10 parts of gluing auxiliary agent, appropriate solvent.Its adhesive property, thermal stability, volume stability are stablized.
Description
Technical field
The present invention relates to field of packaging material, and in particular to a kind of adhesive applied to medical packaging bottle.
Background technique
Medicine is the substance or preparation of prevention or treatment or diagnosing human and livestock disease.Medical also preventable disease, is controlled
Disease is treated, pain is reduced, improves health, or enhancing body is to the resistance of disease or the substance of assisted diagnosis disease.For doctor
Pack bottling, has one is what must be fully sealed when leaving the factory, needs in use, patient or doctor cut use immediately again,
The Packaging Bottle of Liquid pharmaceutical is such as housed, Liquid pharmaceutical occurs in transport or to the used time breaking or hitting the problem of splitting in order to prevent,
Its body generallys use rubber, and leakproofness and stability in order to guarantee bottleneck, and bottleneck is closed using aluminium alloy or copper aluminium
Metal type material, and just need to use medical packaging bottle between rubber body and aluminium alloy or the bottle cap of albronze profile
Adhesive is packaged.
Summary of the invention
The purpose of the present invention is to provide the excellent one kind of a kind of adhesive property, thermal stability, volume stability to answer
Adhesive for medical packaging bottle.
In order to solve the above technical problems, the technical solution used in the present invention is: a kind of glue applied to medical packaging bottle
Stick, the raw material including following parts by weight: organosilicon -10-30 parts of acrylic resin, 1-10 parts of esters of silicon acis, silica solution 1-5
Part, 1-10 parts of silane coupling agent, 0.1-10 parts of gluing auxiliary agent, appropriate solvent.
Preferably, the raw material including following parts by weight: organosilicon -15-25 parts of acrylic resin, 2-5 parts of esters of silicon acis, silicon
1-3 parts of colloidal sol, 1-5 parts of silane coupling agent, 1-5 parts of gluing auxiliary agent, appropriate solvent.
Preferably, the raw material including following parts by weight: 20 parts of organosilicon-acrylic resin, 5 parts of esters of silicon acis, silica solution 3
Part, 5 parts of silane coupling agent, 5 parts of gluing auxiliary agent, appropriate solvent.
Preferably, the esters of silicon acis is selected from ethyl orthosilicate, methyl orthosilicate, butyl silicate, trimethylsiloxy group silicon
At least one of acid esters, methacrylic acid trimethylsilyl group.
Preferably, the silane coupling agent is selected from vinyltriethoxysilane, vinyltrimethoxysilane, vinyl
Any one in three (beta-methoxy ethyoxyl) silane.
Preferably, the gluing auxiliary agent includes anti-aging agent, stabilizer, fire retardant.
Preferably, the anti-aging agent is styrenated phenol, and stabilizer is zinc stearate, and fire retardant is cyclooctane.
Preferably, any one of the solvent in methanol, ethyl alcohol, ethyl acetate.
The beneficial effects of the present invention are: the adhesive of medical packaging bottle of the invention is with organosilicon-acrylic resin etc.
Composite material is base-material, is mutually bonded composition three-dimensional space net structure, improves interface bond strength and cohesive force, while can mend
Volume contraction is repaid, flexibility is improved；Silane coupling agent is crosslinking agent, after gluing, under the diffusion of molecule, and silane coupling agent
It can migrate to generation coupled action at bonding interface, be condensed with the aluminium alloy or albronze profiled metal oxide of bottle cap,
And be coupled with the organic principle hinge in adhesive, make the aluminium alloy or albronze profiled metal matrix of adhesive and bottle cap
Adsorbed close；Silica solution and compositing organic material generate suction-operated, improve the crosslinking inside adhesive, while can form bridging
Key increases the whole mechanical strength of adhesive.The polarity of product and silicon rubber obtained is adapted, the adhesive property with silicon rubber
It is good, and the wettability and cementability of the aluminium alloy or albronze profiled metal to bottle cap are good, it can as one-coat adhesive
Realize the aluminium alloy of polar rubber and bottle cap or the bonding hot vulcanization of albronze profiled metal, comprehensive mechanical property performance is excellent
It is different.
Specific embodiment
1-5 is with reference to embodiments with the present invention is further illustrated.
Embodiment 1:
A kind of adhesive applied to medical packaging bottle, the raw material including following parts by weight: organosilicon-acrylic resin
10 parts, esters of silicon acis be selected from 10 parts of ethyl orthosilicate, 1 part of silica solution, 10 parts of vinyltriethoxysilane, styrenated phenol 2
Part, 1 part of zinc stearate, 1 part of cyclooctane, 100 parts of methanol.
Embodiment 2:
A kind of adhesive applied to medical packaging bottle, the raw material including following parts by weight: organosilicon-acrylic resin
30 parts, 1 part of methyl orthosilicate, 5 parts of silica solution, 1 part of vinyltrimethoxysilane, 2 parts of styrenated phenol, zinc stearate 2
Part, 2 parts of cyclooctane, 100 parts of ethyl alcohol.
Embodiment 3:
A kind of adhesive applied to medical packaging bottle, the raw material including following parts by weight: organosilicon-acrylic resin
15 parts, 5 parts of butyl silicate, 1 part of silica solution, 5 parts of vinyltriethoxysilane, 0.5 part of styrenated phenol, zinc stearate
0.5 part, 0.5 part of cyclooctane, 100 parts of methanol.
Embodiment 4:
A kind of adhesive applied to medical packaging bottle, the raw material including following parts by weight: organosilicon-acrylic resin
25 parts, 2 parts of trimethylsiloxysilicates, 1-3 parts of silica solution, 1 part of vinyltrimethoxysilane, 5 parts of gluing auxiliary agent, ethyl alcohol
100 parts.
Embodiment 5:
A kind of adhesive applied to medical packaging bottle, the raw material including following parts by weight: organosilicon-acrylic resin
20 parts, 5 parts of methacrylic acid trimethylsilyl group, 3 parts of silica solution, 5 parts of silane of vinyl three (beta-methoxy ethyoxyl), styrol
1 part of phenol, 1 part of zinc stearate, 3 parts of cyclooctane, 100 parts of ethyl acetate.
Above-described embodiment uses aluminium alloy or albronze and the vinylsiloxane rubber of body use at room temperature in body
Pull-off strength (Mpa):
Above-described embodiment is that typical several embodiments, essence of the invention are not limited by above embodiments in the present invention,
Although referring to above-described embodiment, invention is explained in detail, for those skilled in the art, still may be used
To modify to technical solution illustrated in the above embodiments or equivalent replacement of some of the technical features.It is all
Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in guarantor of the invention
Within the scope of shield.
Claims (8)
1. a kind of adhesive applied to medical packaging bottle, it is characterised in that: the raw material including following parts by weight: organosilicon-
10-30 parts of acrylic resin, 1-10 parts of esters of silicon acis, 1-5 parts of silica solution, 1-10 parts of silane coupling agent, 0.1-10 parts of gluing auxiliary agent,
Appropriate solvent.
2. a kind of adhesive applied to medical packaging bottle according to claim 1, it is characterised in that: including following weight
The raw material of number: organosilicon -15-25 parts of acrylic resin, 2-5 parts of esters of silicon acis, 1-3 parts of silica solution, 1-5 parts of silane coupling agent,
1-5 parts of gluing auxiliary agent, appropriate solvent.
3. a kind of adhesive applied to medical packaging bottle according to claim 1, it is characterised in that: including following weight
The raw material of number: 20 parts of organosilicon-acrylic resin, 5 parts of esters of silicon acis, 3 parts of silica solution, 5 parts of silane coupling agent, gluing auxiliary agent 5
Part, appropriate solvent.
4. a kind of adhesive applied to medical packaging bottle according to claim 1, it is characterised in that: the esters of silicon acis choosing
From in ethyl orthosilicate, methyl orthosilicate, butyl silicate, trimethylsiloxysilicates, methacrylic acid trimethylsilyl group
At least one.
5. a kind of adhesive applied to medical packaging bottle according to claim 1 or 4, it is characterised in that: the silane
Coupling agent is in vinyltriethoxysilane, vinyltrimethoxysilane, vinyl three (beta-methoxy ethyoxyl) silane
Any one.
6. a kind of adhesive applied to medical packaging bottle according to claim 1, it is characterised in that: the gluing auxiliary agent
Including anti-aging agent, stabilizer, fire retardant.
7. a kind of adhesive applied to medical packaging bottle according to claim 6, it is characterised in that: the anti-aging agent is
Styrenated phenol, stabilizer are zinc stearate, and fire retardant is cyclooctane.
8. a kind of adhesive applied to medical packaging bottle according to claim 1, it is characterised in that: the solvent is selected from
Methanol, ethyl alcohol, any one in ethyl acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811220825.9A CN109370450A (en) | 2018-10-19 | 2018-10-19 | A kind of adhesive applied to medical packaging bottle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811220825.9A CN109370450A (en) | 2018-10-19 | 2018-10-19 | A kind of adhesive applied to medical packaging bottle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109370450A true CN109370450A (en) | 2019-02-22 |
Family
ID=65400393
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811220825.9A Pending CN109370450A (en) | 2018-10-19 | 2018-10-19 | A kind of adhesive applied to medical packaging bottle |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109370450A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005281528A (en) * | 2004-03-30 | 2005-10-13 | Yokohama Rubber Co Ltd:The | Adhesive composition for optical material |
| CN104892942A (en) * | 2015-06-04 | 2015-09-09 | 成都拓利化工实业有限公司 | Tackifier for addition-type organic silicon rubber and preparation method thereof |
| CN105505084A (en) * | 2014-09-24 | 2016-04-20 | 比亚迪股份有限公司 | Addition-type silicon rubber primer and preparation method thereof |
| CN109096956A (en) * | 2018-07-11 | 2018-12-28 | 合肥德济新材料科技有限公司 | Addition-type silicon rubber single-coating-type Heat vulcanization adhesive |
-
2018
- 2018-10-19 CN CN201811220825.9A patent/CN109370450A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005281528A (en) * | 2004-03-30 | 2005-10-13 | Yokohama Rubber Co Ltd:The | Adhesive composition for optical material |
| CN105505084A (en) * | 2014-09-24 | 2016-04-20 | 比亚迪股份有限公司 | Addition-type silicon rubber primer and preparation method thereof |
| CN104892942A (en) * | 2015-06-04 | 2015-09-09 | 成都拓利化工实业有限公司 | Tackifier for addition-type organic silicon rubber and preparation method thereof |
| CN109096956A (en) * | 2018-07-11 | 2018-12-28 | 合肥德济新材料科技有限公司 | Addition-type silicon rubber single-coating-type Heat vulcanization adhesive |
Non-Patent Citations (2)
| Title |
|---|
| 李子东等: "《高校实验室安全管理与技术》", 30 June 2009, 中国计量出版社 * |
| 陈昭琼等: "《精细化工产品配方、合成及应用》", 31 October 1999, 国防工业出版社 * |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20190222 |