CN108148510A - A kind of normal temperature self-drying type inorganic nano material adhesive - Google Patents
A kind of normal temperature self-drying type inorganic nano material adhesive Download PDFInfo
- Publication number
- CN108148510A CN108148510A CN201711467082.0A CN201711467082A CN108148510A CN 108148510 A CN108148510 A CN 108148510A CN 201711467082 A CN201711467082 A CN 201711467082A CN 108148510 A CN108148510 A CN 108148510A
- Authority
- CN
- China
- Prior art keywords
- nano material
- inorganic nano
- material adhesive
- normal temperature
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
- C09J1/02—Adhesives based on inorganic constituents containing water-soluble alkali silicates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Abstract
The present invention relates to a kind of normal temperature self-drying type inorganic nano material adhesives, the inorganic nano material adhesive is that Nano silica sol is modified using silane coupler modified Ludox and the low modulus silicic acid nak response of oneself synthesis, inorganic nano material adhesive is made, the inorganic nano material adhesive can be used as adhesive after thickener and use by adding in, there is very strong cementability to zinc, steel, timber, glass etc., new type bonding agent acid-alkali-corrosive-resisting of the present invention, water resistance are relatively strong, brittleness is smaller, impact resistance, and being capable of self-curing under room temperature.
Description
Technical field
The present invention relates to technical field of adhesive, specially a kind of normal temperature self-drying type inorganic nano material adhesive.
Background technology
Adhesive is one of most important auxiliary material, using extremely wide in packaging operation.Adhesive is that have to glue
Property substance, by its viscosity can by two kinds separation material link together.The many adhesives of type of adhesive are really
The various stress material general names that identical or different material is made to connect or be bonded, mainly there is liquid, paste and solid-state three types.
Inorganic nano material adhesive is a kind of new type bonding agent.The high temperature that general organic bond can be born is usually all
Below 100 DEG C.Such as latex at 60 DEG C hereinafter, epoxy resin is at 100 DEG C or so, phenolic resin is at 220 DEG C or so.And it inorganic receives
The high temperature that rice material adhesive can be born reaches 600-900 DEG C.It can high temperature resistant again low-temperature-resistant, it is at low cost, it is non-aging, it is right
Zinc, steel, timber, glass, paper etc. have very strong cementability.At present inorganic bond on the market be primarily present intolerant to
The problems such as acid and alkali corrosion, water resistance are poor, brittleness is larger, not impact resistance, and can not self-curing under room temperature.
For the problems of inorganic bond at present on the market, it is inorganic that the present invention is prepared for a kind of normal temperature self-drying type
Nano material adhesive, inorganic nano material adhesive overcome inorganic bond not acid-alkali-corrosive-resisting, poor water resistance the problem of,
The flexibility of adhesive is strengthened simultaneously, is reduced because brittleness generates the risk of cracking.Meanwhile the inorganic nano material be can be with
Normal temperature self-drying type inorganic nano material adhesive.
Invention content
The purpose of the present invention is to solve exist in the prior art not acid-alkali-corrosive-resisting, water resistance are poor, brittleness is larger,
The problems such as not impact resistance, and under room temperature can not self-curing, practical performance is not strong, and propose a kind of normal temperature self-drying type it is inorganic
Nano material adhesive.
To achieve the above object, the present invention provides following technical solution：The inorganic nano material adhesive is to utilize
Silane coupler modified Ludox and the low modulus silicic acid nak response of oneself synthesis to be modified Nano silica sol, are made inorganic and receive
Rice material adhesive, the inorganic nano material adhesive can be used as adhesive after thickener and use by adding in, to zinc, steel,
Timber, glass etc. have very strong cementability.
Preferably, described in homemade potassium silicate solution, addition silane resin, Ludox and coalescents are eventually adding
Thickener.
Preferably, the composition ratio of the inorganic nano material adhesive is the potassium silicate of homemade 0.5-3 moduluses
Solution 20%-80%, silane resin 0.1%-5%, Ludox 79.8%-14.0%, coalescents 0.1%-1%.
Preferably, the thickener is selected from hydroxymethyl cellulose, hydroxyethyl cellulose, inorganic bentonite, attapulgite, illiteracy
One or more of de- soil.
Preferably, the silane resin can be KH550, KH560, KH570, KH578, MTMS, the silane resins such as MTES
Two kinds or three kinds.
Preferably, the coalescents can be PVA PVB PEG.
Compared with prior art, the beneficial effects of the invention are as follows：Solvent of the present invention is water, meets present environmental requirement.
There is no toxic action to human body, ensured that construction personnel's is healthy and safe, it is low that inorganic structure imparts its excellent high temperature resistant
Warm nature energy compensates for organic bond high temperature resistant poor performance at low temperatures, the shortcomings that weatherability is poor, substantially increases the use of adhesive
Range and service life, nano inorganic material adhesive possess the water resistance and acid and alkali-resistance that common inorganic adhesive does not have on the market
Property, therefore can be applied to the mal-conditions such as outdoor and soda acid.Nano inorganic material adhesive also improves inorganic bond
The shortcomings that brittleness and poor impact resistance, the inorganic nano material can be with normal temperature self-dryings.
Specific embodiment
The technical solution in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's all other embodiments obtained without making creative work belong to the model that the present invention protects
It encloses.
Inorganic nano material of the present invention bonds agent compounding method：The potassium silicate solution 20%- of homemade 0.5-3 moduluses
80%, add in the silane resin of 0.1%-5%, silane resin can be (KH550, KH560, KH570, KH578, MTMS,
Two kinds of the silane resins such as MTES or three kinds), the Ludox (thickness of silica gel 25%) of 79.8%-14% is added,
60-100 degree is stirred to react 1-2 hours, is eventually adding the coalescents of 0.1%-1%, coalescents can be PVA PVB
Inorganic nano material adhesive is made in PEG etc., selects suitable thickener (hydroxymethyl cellulose, hydroxyethyl cellulose, inorganic
One or more of bentonite, attapulgite, montmorillonite) and water be mixed and made into 0.1%-5% pregels, according to (1%-
10%) ratio is added in inorganic nano material adhesive, is stirred evenly, is sealed up for safekeeping.
It prepares embodiment with different below the present invention is further explained.
Embodiment 1：
In the potassium silicate solution 50% of homemade 1 modulus, 1.5% silane resin containing KH570 and KH578 is added in, then
50% Ludox is added in, is stirred to react 1-2 hours in 60-100 degree, is eventually adding 0.7% PVA coalescents, nothing is made
Machine nano material adhesive selects inorganic bentonite and attapulgite and water to be mixed and made into 2% pregel, according to 1.5% ratio
Example add in inorganic nano material adhesive in, stir evenly, seal up for safekeeping to get to the present invention adhesive.
Embodiment 2：
In the potassium silicate solution 30% of homemade 2 modulus, 3% silane resin containing KH550 and KH560 is added in, then add
Enter 25% Ludox, be stirred to react 1-2 hours in 60-100 degree, be eventually adding 0.5% PVA coalescents, be made inorganic
Nano material adhesive selects hydroxyethyl cellulose and water to be mixed and made into 3% pregel, and inorganic receive is added according to 5% ratio
Rice material adhesive in, stir evenly, seal up for safekeeping to get to the present invention adhesive.
Embodiment 3：
In the potassium silicate solution 60% of homemade 0.5 modulus, 4% silane resin containing MTMS and MTES is added in, then add
Enter 60% Ludox, be stirred to react 1-2 hours in 60-100 degree, be eventually adding 0.8% PVA coalescents, be made inorganic
Nano material adhesive selects hydroxyethyl cellulose and water to be mixed and made into 3% pregel, and inorganic receive is added according to 6% ratio
Rice material adhesive in, stir evenly, seal up for safekeeping to get to the present invention adhesive.
Embodiment 4：
In the potassium silicate solution 30% of homemade 3 modulus, add in 2% containing KH560, KH570 and KH578 silane trees
Fat adds 25% Ludox, is stirred to react 1-2 hours in 60-100 degree, is eventually adding 0.6% PVB coalescents,
Inorganic nano material adhesive is made, hydroxyl montmorillonite and water is selected to be mixed and made into 3% pregel, nothing is added according to 7% ratio
In machine nano material adhesive, stir evenly, seal up for safekeeping to get to the present invention adhesive.
The application method of the present invention：Inorganic nano material adhesive, which is applied to, needs the place that bonds, needing to bond
Material (steel, glass, paper etc.) be bonded together, place etc. it is to be dried；Or inorganic nano material adhesive, with
Zinc powder, aluminium powder, silica flour, sawdust are mixed in a certain ratio, and are applied to the place for needing to smear, can also be brushed wallpaper.
It is obvious to a person skilled in the art that the present invention is not limited to the details of above-mentioned exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requirement rather than above description limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
Claims (5)
1. a kind of normal temperature self-drying type inorganic nano material adhesive according to claim 1, it is characterised in that：The self-control
Potassium silicate solution, add in silane resin, Ludox and coalescents, be eventually adding thickener.
2. a kind of normal temperature self-drying type inorganic nano material adhesive according to claim 1, it is characterised in that：The described nothing
The composition ratio of machine nano material adhesive is potassium silicate solution 20%-80%, the silane resin of homemade 0.5-3 moduluses
0.1%-5%, Ludox 79.8%-14.0%, coalescents 0.1%-1%.
3. a kind of normal temperature self-drying type inorganic nano material adhesive according to claim 1, it is characterised in that：The thickening
Agent is selected from one or more of hydroxymethyl cellulose, hydroxyethyl cellulose, inorganic bentonite, attapulgite, montmorillonite.
4. a kind of normal temperature self-drying type inorganic nano material adhesive according to claim 1, it is characterised in that：The silane
Resin can be KH550, KH560, KH570, KH578, MTMS, two kinds or three kinds of the silane resins such as MTES.
5. a kind of normal temperature self-drying type inorganic nano material adhesive according to claim 1, it is characterised in that：The film forming
Auxiliary agent can be PVA PVB PEG.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711467082.0A CN108148510A (en) | 2017-12-28 | 2017-12-28 | A kind of normal temperature self-drying type inorganic nano material adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711467082.0A CN108148510A (en) | 2017-12-28 | 2017-12-28 | A kind of normal temperature self-drying type inorganic nano material adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108148510A true CN108148510A (en) | 2018-06-12 |
Family
ID=62463687
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711467082.0A Pending CN108148510A (en) | 2017-12-28 | 2017-12-28 | A kind of normal temperature self-drying type inorganic nano material adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108148510A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115584212A (en) * | 2022-10-27 | 2023-01-10 | 盛吉盛(宁波)半导体科技有限公司 | Silicon material adhesive and preparation method and use method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0413304A1 (en) * | 1989-08-14 | 1991-02-20 | Nissan Chemical Industries Ltd. | Inorganic adhesive composition |
| US5015677A (en) * | 1986-04-25 | 1991-05-14 | Bio-Polymers, Inc. | Adhesives derived from bioadhesive polyphenolic proteins |
| CN1468924A (en) * | 2003-06-02 | 2004-01-21 | 海洋化工研究院 | Synthesis of high-molar ratio potassium silicate adhesive and aqueous anticorrosive paint composition |
| CN105731977A (en) * | 2016-01-27 | 2016-07-06 | 广东施彩涂料有限公司 | Water-tolerant inorganic coating and preparation method thereof |
| CN107151466A (en) * | 2017-06-16 | 2017-09-12 | 杭州惟翔科技有限公司 | Inorganic bond and its manufacture method |
-
2017
- 2017-12-28 CN CN201711467082.0A patent/CN108148510A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5015677A (en) * | 1986-04-25 | 1991-05-14 | Bio-Polymers, Inc. | Adhesives derived from bioadhesive polyphenolic proteins |
| EP0413304A1 (en) * | 1989-08-14 | 1991-02-20 | Nissan Chemical Industries Ltd. | Inorganic adhesive composition |
| CN1468924A (en) * | 2003-06-02 | 2004-01-21 | 海洋化工研究院 | Synthesis of high-molar ratio potassium silicate adhesive and aqueous anticorrosive paint composition |
| CN105731977A (en) * | 2016-01-27 | 2016-07-06 | 广东施彩涂料有限公司 | Water-tolerant inorganic coating and preparation method thereof |
| CN107151466A (en) * | 2017-06-16 | 2017-09-12 | 杭州惟翔科技有限公司 | Inorganic bond and its manufacture method |
Non-Patent Citations (4)
| Title |
|---|
| 于守武，等: "《高分子材料改性-原理及技术》", 31 May 2015, 北京：知识产权出版社 * |
| 余志伟编: "《矿物材料与工程》", 31 December 2012, 中南大学出版社 * |
| 唐玉林编: "《圣泉铸工手册》", 31 October 1999, 东北大学出版社 * |
| 罗明生，等: "《药剂辅料大全》", 31 January 2006, 成都：四川科学技术出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115584212A (en) * | 2022-10-27 | 2023-01-10 | 盛吉盛(宁波)半导体科技有限公司 | Silicon material adhesive and preparation method and use method thereof |
| CN115584212B (en) * | 2022-10-27 | 2023-11-03 | 盛吉盛(宁波)半导体科技有限公司 | Silicon material adhesive and preparation method and application method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100506929C (en) | Aqueous self-bonding coating for electrical steel | |
| CN103666293B (en) | Heat resistance instant dry adhesive and preparation method thereof | |
| CN103773253B (en) | A kind of fire-resistant waterproof silicate based Wood Adhesives and preparation method thereof | |
| CN102115655A (en) | Single component flexible epoxy sealant | |
| CN107641489A (en) | Water process column-type film components epoxy resin embedding adhesive and preparation method thereof | |
| CN108148510A (en) | A kind of normal temperature self-drying type inorganic nano material adhesive | |
| CN105131864A (en) | Resin adhesive and preparation method thereof | |
| CN111073570B (en) | Medium-temperature curing high-toughness epoxy adhesive and preparation method thereof | |
| CN106190011A (en) | A kind of glass cement | |
| CN105315941A (en) | Heatproof and fireproof SMT adhesive and preparing method thereof | |
| CN105315933B (en) | A kind of antistripping instant drying adhesive and preparation method thereof | |
| CN107043601A (en) | A kind of High-strength double-component high temperature resistant inorganic fluid sealant | |
| CN101880376A (en) | Ageing-resistant epoxy resin curing agent | |
| CN105400458A (en) | Environmentally friendly glue for food packaging, and preparation method thereof | |
| CN104119807B (en) | A kind of gluing hot melt adhesive special of notebook of the gluing hot melt adhesive special of notebook containing multiple fiber | |
| CN104194673A (en) | Formula and preparation process of hydroxypropyl-polysiloxane sealant | |
| CN105925216A (en) | Solid adhesive | |
| CN104962044A (en) | Corrosion resistance composite release film | |
| CN113416508B (en) | Hot-melt pressure-sensitive adhesive and preparation method thereof | |
| CN104327760A (en) | Fold-resistant environmentally-friendly adhesive and preparation method thereof | |
| CN102994014B (en) | High-sealing bonding resin for glass and metal | |
| CN101338153A (en) | High temperature resistant foam glue and method for preparing same | |
| CN104893637A (en) | Flame-retardant high-air-permeability carton adhesive and preparation method thereof | |
| CN106634689A (en) | Metal bonding agent | |
| CN103725207B (en) | Anticorrosive acid-resistant epoxy resin adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180612 |
|
| RJ01 | Rejection of invention patent application after publication |