CN109370419A - A kind of weather-proof magnetic coating for exterior wall - Google Patents

A kind of weather-proof magnetic coating for exterior wall Download PDF

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Publication number
CN109370419A
CN109370419A CN201811161457.5A CN201811161457A CN109370419A CN 109370419 A CN109370419 A CN 109370419A CN 201811161457 A CN201811161457 A CN 201811161457A CN 109370419 A CN109370419 A CN 109370419A
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CN
China
Prior art keywords
weather
coating
proof
powder
exterior wall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811161457.5A
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Chinese (zh)
Inventor
唐家玉
李锋利
魏学高
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI SGTECH COATING TECHNOLOGY Co Ltd
Original Assignee
ANHUI SGTECH COATING TECHNOLOGY Co Ltd
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Priority to CN201811161457.5A priority Critical patent/CN109370419A/en
Publication of CN109370419A publication Critical patent/CN109370419A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/23Magnetisable or magnetic paints or lacquers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/327Aluminium phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of weather-proof magnetic coating for exterior wall, and constituent and each ingredient percentage are respectively as follows: weather-proof substrate: 34~50%, coating filler: 20~40%, glue: 17~32%, magnetic micro-powder: 5~15% and coating additive: 4~10%;Weather-proof substrate includes organic siliconresin, ASA resin, lubricating oil and substrate auxiliary agent;Coating filler includes weather-proof fiber, crystalline flake graphite and powder filler;Coating additive includes expanding material, stabilizer, thickener, dispersing agent, levelling agent and defoaming agent.The present invention provides one kind and is easier to obtain preparation, the lower recipe ingredient of cost while obtaining stable magnetic function after guaranteeing coating;There is outstanding stickiness, waterproofness and weatherability with exterior wall, significantly reduce exterior coating fills up frequency, suitable for being widely popularized.

Description

A kind of weather-proof magnetic coating for exterior wall
Technical field
The invention belongs to functional paint technical fields, and in particular to a kind of weather-proof magnetic coating for exterior wall.
Background technique
With the continuous development of science and technology, the type of wall covering is also being constantly updated, wall finiss originally based on dicoration, By now, people increasingly value the functionality of wall finiss for development." functionality " of so-called wall finiss refers to that wall finiss is no longer only Only decoration functions, but the function of some convenience and functional is increased, such as the magnetic paint to grow up in recent years.
Magnetic coating is exactly that coating is mixed to magnetic powder, is coated on metope, increases metope by the function of adsorption magnet Energy;Magnetism paint has a wide range of application, and can be used in the metope in parlor, dining room and bedroom, can be used for cultivating the creativity of child, Simultaneously because having blended a large amount of magnetic core powders, certain electromagnetic shielding performance is made it have, it may also be used for electromagnetic shielding.But magnetic There is also following disadvantages for property paint:
1, price is higher, and the price of magnetism paint is about within one liter about 1000~2000 yuan, so general to applying in interior Wall is not suitable for applying in exterior wall.
2, in order to which magnetism keeps persistently, needing to coat four layers or more, the construction time is long, at high cost.
3, coating thickness is difficult to be affectedly bashful, it is not easy to uniform ground, and its durability is lower, be easy to produce bulging, slight crack, Generate clast.
Therefore, developing one kind in view of the above problems can apply in exterior wall, and moderate cost, long-lived magnetic painting Material is those skilled in the art institute urgent need to solve the problem.
Summary of the invention
To solve the above problems, the invention discloses a kind of weather-proof magnetic coatings for exterior wall.
In order to achieve the above object, the invention provides the following technical scheme:
A kind of weather-proof magnetic coating for exterior wall, constituent and each ingredient percentage are respectively as follows: weather-proof Substrate: 34~50%, coating filler: 20~40%, glue: 17~32%, magnetic micro-powder: 5~15% and coating additive: 4~ 10%;Mass percent shared by the constituent of weather-proof substrate and each ingredient is respectively as follows: organic siliconresin: 55~78%, ASA Resin: 10~25%, lubricating oil: 8~15% and substrate auxiliary agent: 4~10%;The constituent of coating filler and each ingredient Shared mass percent is respectively as follows: weather-proof fiber: 45~58%, crystalline flake graphite: 33~45% and powder filler: 9~14%; Mass percent shared by the constituent of coating additive and each ingredient is respectively as follows: expanding material: 22~30%, stabilizer: 10~ 16%, thickener: 15~23%, dispersing agent: 11~22%, levelling agent: 16~20% and defoaming agent: 5~10%.
Further, organic siliconresin is poly- methyl silicon resin, poly- ethyl silicone resin and polyoxyethylene alkyl aryl Ji Youjiguishu Any one in rouge.
Further, the percentage difference of substrate auxiliary agent gross mass shared by the constituent of substrate auxiliary agent and each ingredient Are as follows: plasticizer: 34~55%, phosphoric acid aluminium liquid: 22~33% and ethyl orthosilicate acidic aqueous solution: 22~33%.
Further, the weather-proof fiber in coating filler is Fypro, the weather-proof fiber of polyacrylonitrile and poly- third Any one in alkene staple fiber.
Further, powder filler is bentonite powder, agate stone powder, talcum powder, calcite powder and receives Any one in rice carbon or any several combination.
Further, glue is any one in emulsion paint for building, epoxy resin glue and acrylic size.
Further, magnetic micro-powder is the soft magnetism micro mist of 1000~2000 mesh.
Compared with prior art, the present invention providing one kind more while obtaining stable magnetic function after guaranteeing coating Easily obtain preparation, the lower recipe ingredient of cost;There is outstanding stickiness, waterproofness and weatherability with exterior wall, it is significant to drop Low exterior coating fills up frequency, suitable for being widely popularized.
Specific embodiment
Technical solution provided by the invention is described in detail below with reference to specific embodiment, it should be understood that following specific Embodiment is only illustrative of the invention and is not intended to limit the scope of the invention.
Embodiment 1:
The present invention provides a kind of weather-proof magnetic coating for exterior wall, constituent and each ingredient percentage point Not are as follows: weather-proof substrate: 34%, coating filler: 40%, glue: 17%, magnetic micro-powder: 5% and coating additive: 4%;It is magnetic micro- Powder is the soft magnetism micro mist of 1000 mesh.
Mass percent shared by the constituent of weather-proof substrate and each ingredient is respectively as follows: organic siliconresin: 55%, ASA Resin: 25%, lubricating oil: 10% and substrate auxiliary agent: 10%;Organic siliconresin is poly- methyl silicon resin;The composition of substrate auxiliary agent at Point and each ingredient shared by the percentage of substrate auxiliary agent gross mass be respectively as follows: plasticizer: 55%, phosphoric acid aluminium liquid: 22% and positive silicon The acidic aqueous solution of acetoacetic ester: 23%.
Mass percent shared by the constituent of coating filler and each ingredient is respectively as follows: weather-proof fiber: 45%, scale Graphite: 45% and powder filler: 10%;Weather-proof fiber is Fypro;Powder filler is bentonite powder.
Glue is emulsion paint for building.
Mass percent shared by the constituent of coating additive and each ingredient is respectively as follows: expanding material: 22%, stabilizer: 16%, thickener: 23%, dispersing agent: 11%, levelling agent: 20% and defoaming agent: 8%.
Embodiment 2:
The present invention provides a kind of weather-proof magnetic coating for exterior wall, constituent and each ingredient percentage point Not are as follows: weather-proof substrate: 50%, coating filler: 20%, glue: 17%, magnetic micro-powder: 9% and coating additive: 4%;It is magnetic micro- Powder is the soft magnetism micro mist of 2000 mesh.
Mass percent shared by the constituent of weather-proof substrate and each ingredient is respectively as follows: organic siliconresin: 78%, ASA Resin: 10%, lubricating oil: 8% and substrate auxiliary agent: 4%;Organic siliconresin is poly- ethyl silicone resin;The constituent of substrate auxiliary agent And the percentage of substrate auxiliary agent gross mass shared by each ingredient is respectively as follows: plasticizer: 34%, phosphoric acid aluminium liquid: 33% and positive silicic acid The acidic aqueous solution of ethyl ester: 33%.
Mass percent shared by the constituent of coating filler and each ingredient is respectively as follows: weather-proof fiber: 58%, scale Graphite: 33% and powder filler: 9%;Weather-proof fiber is polypropene staple;Powder filler is bentonite powder, agate The combination of stone powder, talcum powder.
Glue is epoxy resin glue.
Mass percent shared by the constituent of coating additive and each ingredient is respectively as follows: expanding material: 30%, stabilizer: 10%, thickener: 15%, dispersing agent: 22%, levelling agent: 16% and defoaming agent: 7%.
Embodiment 3:
The present invention provides a kind of weather-proof magnetic coating for exterior wall, constituent and each ingredient percentage point Not are as follows: weather-proof substrate: 42%, coating filler: 25%, glue: 20%, magnetic micro-powder: 9% and coating additive: 4%;It is magnetic micro- Powder is the soft magnetism micro mist of 2000 mesh.
Mass percent shared by the constituent of weather-proof substrate and each ingredient is respectively as follows: organic siliconresin: 66%, ASA Resin: 16%, lubricating oil: 8% and substrate auxiliary agent: 4%;Organic siliconresin is polyoxyethylene alkyl aryl base organic siliconresin;Substrate auxiliary agent The percentage of substrate auxiliary agent gross mass shared by constituent and each ingredient is respectively as follows: plasticizer: 44%, phosphoric acid aluminium liquid: 28% with And the acidic aqueous solution of ethyl orthosilicate: 28%.
Mass percent shared by the constituent of coating filler and each ingredient is respectively as follows: weather-proof fiber: 52%, scale Graphite: 38% and powder filler: 10%;Weather-proof fiber is polypropene staple;Powder filler is agate stone powder, talcum The combination of powder, calcite powder and nano-sized carbon.
Glue is any one in acrylic size.
Mass percent shared by the constituent of coating additive and each ingredient is respectively as follows: expanding material: 25%, stabilizer: 13%, thickener: 18%, dispersing agent: 18%, levelling agent: 18% and defoaming agent: 8%.
Exterior wall is respectively coated using the magnetic coating in three above embodiment, and carries out simulation weather resistant experiment, through implementing The wall that coating coats in example 3 while guaranteeing magnetic function, play the most, and integrity degree is optimal by color holding;Implement Example 1 is secondly, embodiment 2 is slightly worse, but is also significantly better than existing magnetic coating.
Finally, it should be noted that property technical side the above examples are only used to illustrate the technical scheme of the present invention and are not limiting Case, those skilled in the art should understand that, modification or equivalent replacement of the technical solution of the present invention are made for those, and The objective and range for not departing from the technical program, are intended to be within the scope of the claims of the invention.

Claims (7)

1. a kind of weather-proof magnetic coating for exterior wall, it is characterised in that: its constituent and each ingredient percentage Be respectively as follows: weather-proof substrate: 34~50%, coating filler: 20~40%, glue: 17~32%, magnetic micro-powder: 5~15% and Coating additive: 4~10%;Mass percent shared by the constituent of the weather-proof substrate and each ingredient is respectively as follows: organosilicon Resin: 55~78%, ASA resin: 10~25%, lubricating oil: 8~15% and substrate auxiliary agent: 4~10%;The coating filler Constituent and each ingredient shared by mass percent be respectively as follows: weather-proof fiber: 45~58%, crystalline flake graphite: 33~45% with And powder filler: 9~14%;Mass percent shared by the constituent of the coating additive and each ingredient is respectively as follows: increase-volume Agent: 22~30%, stabilizer: 10~16%, thickener: 15~23%, dispersing agent: 11~22%, levelling agent: 16~20% and disappear Infusion: 5~10%.
2. a kind of weather-proof magnetic coating for exterior wall according to claim 1, it is characterised in that: the organosilicon tree Rouge is any one in poly- methyl silicon resin, poly- ethyl silicone resin and polyoxyethylene alkyl aryl base organic siliconresin.
3. a kind of weather-proof magnetic coating for exterior wall according to claim 1, it is characterised in that: the substrate auxiliary agent Constituent and each ingredient shared by the percentage of substrate auxiliary agent gross mass be respectively as follows: plasticizer: 34~55%, phosphoric acid aluminium liquid: 22~33% and ethyl orthosilicate acidic aqueous solution: 22~33%.
4. a kind of weather-proof magnetic coating for exterior wall according to claim 1, it is characterised in that: the coating filling Weather-proof fiber in object is any one in Fypro, the weather-proof fiber of polyacrylonitrile and polypropene staple.
5. a kind of weather-proof magnetic coating for exterior wall according to claim 1, it is characterised in that: the powder filling Object be in bentonite powder, agate stone powder, talcum powder, calcite powder and nano-sized carbon any one or it is any several The combination of kind.
6. a kind of weather-proof magnetic coating for exterior wall according to claim 1, it is characterised in that: the glue is to build It builds with any one in emulsion paint, epoxy resin glue and acrylic size.
7. a kind of weather-proof magnetic coating for exterior wall according to claim 1, it is characterised in that: the magnetic micro-powder For the soft magnetism micro mist of 1000~2000 mesh.
CN201811161457.5A 2018-09-30 2018-09-30 A kind of weather-proof magnetic coating for exterior wall Pending CN109370419A (en)

Priority Applications (1)

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CN201811161457.5A CN109370419A (en) 2018-09-30 2018-09-30 A kind of weather-proof magnetic coating for exterior wall

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110079144A (en) * 2019-05-23 2019-08-02 温州市享通塑磁科技有限公司 A kind of magnetic paint of environmental protection and its manufacturing approach craft
CN110373111A (en) * 2019-06-27 2019-10-25 江苏亚一智能装备有限公司 A kind of restoration surface lacquer for extraordinary workpiece

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CN104694001A (en) * 2014-12-12 2015-06-10 杭州师范大学 Preparation method of superhydrophobic superparamagnetic silicone resin composite coating
CN104710919A (en) * 2015-04-02 2015-06-17 济南大学 Self-cleaning and environmental-friendly interior and exterior wall coating of buildings and preparation method thereof
CN106189388A (en) * 2016-07-19 2016-12-07 上海宜瓷龙新材料股份有限公司 There is porcelain plate and the double-coating preparation method thereof of the high glaze of 3D pattern effect

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
CN104694001A (en) * 2014-12-12 2015-06-10 杭州师范大学 Preparation method of superhydrophobic superparamagnetic silicone resin composite coating
CN104530964A (en) * 2014-12-21 2015-04-22 劳启绪 Preparation method of magnetic coating
CN104710919A (en) * 2015-04-02 2015-06-17 济南大学 Self-cleaning and environmental-friendly interior and exterior wall coating of buildings and preparation method thereof
CN106189388A (en) * 2016-07-19 2016-12-07 上海宜瓷龙新材料股份有限公司 There is porcelain plate and the double-coating preparation method thereof of the high glaze of 3D pattern effect

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110079144A (en) * 2019-05-23 2019-08-02 温州市享通塑磁科技有限公司 A kind of magnetic paint of environmental protection and its manufacturing approach craft
CN110373111A (en) * 2019-06-27 2019-10-25 江苏亚一智能装备有限公司 A kind of restoration surface lacquer for extraordinary workpiece

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Application publication date: 20190222