CN109364513A - A kind of VOC gas recyclable device - Google Patents

A kind of VOC gas recyclable device Download PDF

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Publication number
CN109364513A
CN109364513A CN201811494852.5A CN201811494852A CN109364513A CN 109364513 A CN109364513 A CN 109364513A CN 201811494852 A CN201811494852 A CN 201811494852A CN 109364513 A CN109364513 A CN 109364513A
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CN
China
Prior art keywords
gas
voc
liquid
heating tank
voc gas
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Pending
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CN201811494852.5A
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Chinese (zh)
Inventor
杨希贤
蔡霓
陈楚彬
钟志辉
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Foshan University
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Foshan University
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Priority to CN201811494852.5A priority Critical patent/CN109364513A/en
Publication of CN109364513A publication Critical patent/CN109364513A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/30Accessories for evaporators ; Constructional details thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0003Condensation of vapours; Recovering volatile solvents by condensation by using heat-exchange surfaces for indirect contact between gases or vapours and the cooling medium
    • B01D5/0006Coils or serpentines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of VOC gas recyclable devices.It is related to VOC gas recovery technology field.The present invention includes: VOC gas drainer, the first heating tank, the second heating tank, the first gas-liquid separator, the second gas-liquid separator.The present invention condenses VOC gas by the condenser pipe in VOC gas drainer and collects;VOC gas enter the first heating tank after being condensed into liquid, and condensate liquid enters the first gas-liquid separator after heating in the first heating tank and liquid is separated in liquid-collecting bottle;After the gas separated in first gas-liquid separator enters the heated pipe heating of the second heating tank, then through the second gas-liquid separator liquid is separated in liquid-collecting bottle, realizes to classify to VOC gas according to VOC gas different boiling and recycle;VOC gas concentration detector is installed in the second gas-liquid separator gas outlet simultaneously, facilitates and judges whether VOC gas collect sufficiently, improve VOC gas collection rate, reduce environmental pollution.

Description

A kind of VOC gas recyclable device
Technical field
The invention belongs to VOC gas recovery technology fields, more particularly to a kind of VOC gas recyclable device.
Background technique
Volatile organic gases compound (Volatile Organic Compounds abbreviation VOC) is more normal in atmosphere See and generally existing atmosphere pollution.Common component has hydrocarbon, benzene homologues, alcohols, ketone, phenols, aldehydes, ester Class, amine, nitrile (cyanogen) class etc..VOC issues third contact of a total solar or lunar eclipse chemical reaction in illumination effect, will lead to photochemical fog, Secondary Organic gas The raising of colloidal sol and atmosphere organic acid can destroy ozone layer, be the major reason that haze weather (PM2.5) is formed, can also show Certain toxicity, irritation, carcinogenicity out cause large effect to human health.
Mainly there are stationary source and two kinds of moving source in the source of VOC.Moving source mainly has automobile, steamer and aircraft etc. with petroleum Product is the discharge gas of the vehicles of fuel;There are many type of stationary source, and predominantly petrochemical process process and storage is set Standby equal effluent and the various occasions using organic solvent, such as spray painting, printing, metal degreasing and degreasing, adhesive, pharmacy, Plastics and rubber processing etc..Therefore the recycling and processing of VOC has a very important significance above-mentioned industry.
There are two major classes, that is, physical method and chemical methodes for the major technique recycled currently used for VOC.Physical method is main It is by changing temperature, pressure or using the methods of selective absorbent and permoselective membrane come concentration and separation VOC;Chemically Method has direct burning, thermal oxide, catalysis burning, biological oxidation, plasma method, ultraviolet catalytic oxidation method and its integrated skill It is nontoxic to be transformed into CO2 and water etc. with heat, light, catalyst or microorganism mainly by chemistry or biochemical reaction by art by VOC Harmful inorganic molecules compound.Traditionally the exhaust-gas treatment of VOC frequently with absorption or absorbs the methods of removal, burning removal, Although conventional method principle is simple, implement to be easy, all tool has certain defects and limitations.As absorption method has adsorbent There are biggish selectivity and dependence, and most of adsorbents can gradually lose activity after multiple long-time use, therefore must It must replace within every 3 to five years primary.Although combustion method can convert most of organic matter in VOC to environmentally friendly H2O and CO2, but due to VOC complicated component and ignition temperature is different, being passed through air capacity excessively causes fuel consumption big, drops simultaneously Low furnace temperature causes to burn insufficient, easily causes secondary pollution to environment.Although other methods are relatively new, technology ten is not divided into still It is ripe.
This invention address that a kind of VOC gas recyclable device is researched and developed, it is inconvenient for solving existing VOC gas recycling And the unfavorable caused problem of environmental pollution of recycling.
Summary of the invention
The purpose of the present invention is to provide a kind of VOC gas recyclable devices, pass through the condenser pipe pair in VOC gas drainer VOC gas condensation, and by the different heating that VOC gas are carried out with different temperatures in the first heating tank, the second heating tank, together When it is corresponding by the first gas-liquid separator, the second gas-liquid separator by VOC gas gas-liquid separation, realize the classification to VOC gas Recycling solves existing VOC gas recycling inconvenience and the unfavorable caused problem of environmental pollution of recycling.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions:
The present invention be a kind of VOC gas recyclable device, comprising: VOC gas drainer, the first heating tank, the second heating tank, First gas-liquid separator, the second gas-liquid separator;
Several gas delivery boards being parallel to each other uniformly are installed between the VOC gas drainer internal upper part two sidewalls, are used for VOC gas are evenly supplied in VOC gas drainer;VOC gas drainer side is installed by condenser;The condenser Condenser pipe protrude into VOC gas drainer lower part;VOC gas drainer top is equipped with VOC gas air inlet and condensate liquid Liquid outlet;
The liquid outlet of the VOC gas drainer is connected to by pipeline with the air inlet of the first heating tank;Described first adds Primary heater is installed on the outside of hot tank;The heating tube of the primary heater protrudes into the first heating tank;First heating tank Gas outlet be connected to the air inlet of the first gas-liquid separator by pipeline;The liquid outlet of first gas-liquid separator passes through pipe Road is connected to the first liquid-collecting bottle;
The gas outlet of first gas-liquid separator is connected to by pipeline with the air inlet of the second heating tank;Described second adds Secondary heater is installed on the outside of hot tank;The heating tube of the secondary heater protrudes into the second heating tank;Second heating tank Gas outlet be connected to with the air inlet of the second gas-liquid separator by pipeline;The liquid outlet of second gas-liquid separator and The connection of two liquid-collecting bottles;The gas outlet of second gas-liquid separator condenses the circulation that pot sidewall opens up by pipeline and VOC gas Inlet communication.
Preferably, first temperature probe is also installed in the VOC gas drainer;Is also installed in first heating tank Two temp probes;Third temp probe is also installed in second heating tank.
Preferably, it connects and installs first on the pipeline of the VOC gas drainer liquid outlet and the first heating tank air inlet Solenoid valve.
Preferably, second is installed on the pipeline of connection first heating tank gas outlet and the first gas-liquid separator air inlet Solenoid valve.
Preferably, third is installed on the pipeline of connection first gas-liquid separator gas outlet and the second heating tank air inlet Solenoid valve.
Preferably, the 4th is installed on the pipeline of connection second heating tank gas outlet and the second gas-liquid separator air inlet Solenoid valve;Second gas-liquid separator gas outlet is installed by VOC gas concentration detector.
The Pipe installing three for connecting the circulation import of second gas-liquid separator gas outlet and VOC gas drainer is powered Magnet valve;Described three-way magnetic valve one end is connected to going out gas branch pipe.
The invention has the following advantages:
1, the present invention condenses VOC gas by the condenser pipe in VOC gas drainer and collects;VOC gas are condensed into liquid Enter the first heating tank after body, condensate liquid enters the first gas-liquid separator after heating in the first heating tank and liquid is separated to collection In liquid bottle;After the gas separated in first gas-liquid separator enters the heated pipe heating of the second heating tank, then through second Liquid is separated in liquid-collecting bottle by gas-liquid separator, is realized to classify to VOC gas according to VOC gas different boiling and be recycled.
2, the present invention is connected by the circulation import that the second gas-liquid separator gas outlet and VOC gas drainer side open up It is logical, and install in VOC gas drainer first temperature probe, install in the first heating tank second temperature probe, second plus Third temp probe is installed in hot tank, control VOC gas is facilitated to collect the temperature control for being;Go out simultaneously in the second gas-liquid separator Port installs VOC gas concentration detector, facilitates and judges whether VOC gas collect sufficiently, improve VOC gas collection rate, reduces Environmental pollution.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Detailed description of the invention
In order to illustrate the technical solution of the embodiments of the present invention more clearly, will be described below to embodiment required Attached drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for ability For the those of ordinary skill of domain, without creative efforts, it can also be obtained according to these attached drawings other attached Figure.
Fig. 1 is a kind of structural schematic diagram of VOC gas recyclable device of the present invention;
Fig. 2 is the enlarged drawing of A in Fig. 1.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts all other Embodiment shall fall within the protection scope of the present invention.
In the description of the present invention, it is to be understood that, term " on ", "lower", " in ", indicating positions or the position such as "inner" Relationship is merely for convenience of description of the present invention and simplification of the description, rather than the component or element of indication or suggestion meaning must have There is specific orientation, be constructed and operated in a specific orientation, therefore is not considered as limiting the invention.
It please refers to shown in Fig. 1-2, the present invention is a kind of VOC gas recyclable device, comprising: VOC gas drainer 1, first Heating tank 2, the second heating tank 3, the first gas-liquid separator 4, the second gas-liquid separator 5;
Several gas delivery boards 11 being parallel to each other uniformly are installed, being used for will between 1 internal upper part two sidewalls of VOC gas drainer VOC gas are evenly supplied in VOC gas drainer 1;1 side of VOC gas drainer is installed by condenser 12;Condenser 12 it is cold Solidifying pipe 121 protrudes into 1 lower part of VOC gas drainer;1 top of VOC gas drainer is equipped with VOC gas air inlet and condensate liquid goes out liquid Mouthful;
The liquid outlet of VOC gas drainer 1 is connected to by pipeline 6 with the air inlet of the first heating tank 2;First heating tank 2 Outside is installed by primary heater 21;The heating tube of primary heater 21 protrudes into the first heating tank 2;The outlet of first heating tank 2 Mouth is connected to the air inlet of the first gas-liquid separator 4 by pipeline 6;The liquid outlet of first gas-liquid separator 4 passes through pipeline 6 and the The connection of one liquid-collecting bottle 41;
The gas outlet of first gas-liquid separator 4 is connected to by pipeline 6 with the air inlet of the second heating tank 3;Second heating tank 3 Outside is installed by secondary heater 31;The heating tube of secondary heater 31 protrudes into the second heating tank 3;The outlet of second heating tank 3 Mouth is connected to by pipeline 6 with the air inlet of the second gas-liquid separator 5;The liquid outlet of second gas-liquid separator 5 and the second liquid collecting Bottle 51 is connected to;The gas outlet of second gas-liquid separator 5 is connected by the circulation import that pipeline 6 and 1 side wall of VOC gas drainer open up It is logical.
Wherein, first temperature probe 13 is also installed in VOC gas drainer 1;Second temperature is also installed in first heating tank 2 Probe 22;Third temp probe 32 is also installed in second heating tank 2.
Wherein, it connects and the first electromagnetism is installed on the pipeline 6 of 1 liquid outlet of VOC gas drainer and 2 air inlet of the first heating tank Valve 14.
Wherein, the second electricity of installation on the pipeline 6 of connection 2 gas outlet of the first heating tank and 4 air inlet of the first gas-liquid separator Magnet valve 42.
Wherein, installation third electricity on the pipeline 6 of connection 4 gas outlet of the first gas-liquid separator and 3 air inlet of the second heating tank Magnet valve 33.
Wherein, the 4th electricity of installation on the pipeline 6 of connection 3 gas outlet of the second heating tank and 5 air inlet of the second gas-liquid separator Magnet valve 52;Second gas-liquid separator, 5 gas outlet is installed by VOC gas concentration detector 53.
Wherein, the installation of pipeline 6 three of the circulation import of connection 5 gas outlet of the second gas-liquid separator and VOC gas drainer 1 Three-way electromagnetic valve 54;54 one end of three-way magnetic valve is connected to going out gas branch pipe 55.
The present invention in actual use, when from the mouth of entering of VOC gas drainer 1 to enter VOC gas cold for VOC gas Solidifying tank 1, VOC gas pass through the gas delivery board 11 being parallel to each other and enter the bottom in VOC gas drainer 1;VOC gas condensation Condenser pipe 121 in tank 1 is condensed into liquid to VOC gas, and first temperature probe 13 monitors the temperature of VOC gas drainer 1 Reach and opens the first solenoid valve 14 after desired temperature value range and enter the first heating tank 2.
It is condensed into formation VOC gas-liquid mixture of the VOC gas of liquid after the heating tube heating in the first heating tank 2, After second temperature probe 22 monitors that the temperature value in the first heating tank 2 reaches the temperature value in preset range, the second electricity is opened Magnet valve 41 makes VOC gas-liquid mixture enter the first gas-liquid separator 4;VOC gas-liquid mixture is separated in the first gas-liquid separator 4 After enter in liquid-collecting bottle, remaining VOC gas enter the second heating tank 3, and in the second heating tank 3 heating tube heating, when The temperature value that third temp probe 32 monitors in the second heating tank 3 reaches preset temperature values;The 4th solenoid valve 51 is opened, Enter remaining VOC gas in the second gas-liquid separator 5;Remaining VOC gas are through the 5 separate rear part liquid separation of the second gas-liquid separator Body enters liquid-collecting bottle, at this point, VOC gas concentration detector 53 monitors whether VOC gas concentration reaches discharge standard, if so, It then controls three-way magnetic valve 54 and purified VOC gas is discharged from going out gas branch pipe 55;If it is not, then controlling three-way magnetic valve 54 Purified VOC gas are entered in VOC gas drainer 1 from pipeline 6 and circulation import, carry out circulating purification recycling, VOC gas purifying rate is improved, it is convenient and efficient.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the invention In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example. Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification, It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only It is limited by claims and its full scope and equivalent.

Claims (7)

1. a kind of VOC gas recyclable device characterized by comprising VOC gas drainer (1), the first heating tank (2), second Heating tank (3), the first gas-liquid separator (4), the second gas-liquid separator (5);
Several gas delivery boards (11) being parallel to each other uniformly are installed between VOC gas drainer (1) the internal upper part two sidewalls, are used It is interior in VOC gas are evenly supplied to VOC gas drainer (1);VOC gas drainer (1) side is installed by condenser (12);The condenser pipe (121) of the condenser (12) protrudes into VOC gas drainer (1) lower part;The VOC gas drainer (1) Top is equipped with VOC gas air inlet and condensate liquid liquid outlet;
The liquid outlet of the VOC gas drainer (1) is connected to by pipeline (6) with the air inlet of the first heating tank (2);Described Primary heater (21) are installed on the outside of one heating tank (2);The heating tube of the primary heater (21) protrudes into the first heating tank (2) It is interior;The gas outlet of first heating tank (2) is connected to the air inlet of the first gas-liquid separator (4) by pipeline (6);Described The liquid outlet of one gas-liquid separator (4) is connected to by pipeline (6) with the first liquid-collecting bottle (41);
The gas outlet of first gas-liquid separator (4) is connected to by pipeline (6) with the air inlet of the second heating tank (3);It is described Secondary heater (31) are installed on the outside of second heating tank (3);The heating tube of the secondary heater (31) protrudes into the second heating tank (3) in;The gas outlet of second heating tank (3) is connected to by pipeline (6) with the air inlet of the second gas-liquid separator (5); The liquid outlet of second gas-liquid separator (5) is connected to the second liquid-collecting bottle (51);The outlet of second gas-liquid separator (5) The circulation inlet communication that mouth is opened up by pipeline (6) and VOC gas drainer (1) side wall.
2. a kind of VOC gas recyclable device according to claim 1, which is characterized in that the VOC gas drainer (1) First temperature probe (13) also inside are installed;Second temperature probe (22) also are installed in first heating tank (2);Described second adds Third temp probe (32) also are installed in hot tank (2).
3. a kind of VOC gas recyclable device according to claim 1, which is characterized in that connect the VOC gas drainer (1) the first solenoid valve (14) are installed on the pipeline (6) of liquid outlet and the first heating tank (2) air inlet.
4. a kind of VOC gas recyclable device according to claim 1, which is characterized in that connection first heating tank (2) Second solenoid valve (42) are installed on the pipeline (6) of gas outlet and the first gas-liquid separator (4) air inlet.
5. a kind of VOC gas recyclable device according to claim 1, which is characterized in that connection first gas-liquid separation Third solenoid valve (33) are installed on the pipeline (6) of device (4) gas outlet and the second heating tank (3) air inlet.
6. a kind of VOC gas recyclable device according to claim 1, which is characterized in that connection second heating tank (3) 4th solenoid valve (52) is installed on the pipeline (6) of gas outlet and the second gas-liquid separator (5) air inlet;Second gas-liquid separation Device (5) gas outlet is installed by VOC gas concentration detector (53).
7. a kind of VOC gas recyclable device according to claim 1, which is characterized in that connection second gas-liquid separation The pipeline (6) of the circulation import of device (5) gas outlet and VOC gas drainer (1) installs three-way magnetic valve (54);Described three are powered Magnet valve (54) one end is connected to going out gas branch pipe (55).
CN201811494852.5A 2018-12-07 2018-12-07 A kind of VOC gas recyclable device Pending CN109364513A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811494852.5A CN109364513A (en) 2018-12-07 2018-12-07 A kind of VOC gas recyclable device

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Application Number Priority Date Filing Date Title
CN201811494852.5A CN109364513A (en) 2018-12-07 2018-12-07 A kind of VOC gas recyclable device

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110639352A (en) * 2019-11-02 2020-01-03 孙发喜 Vertical multi-stage absorption tower
CN113996154A (en) * 2021-11-17 2022-02-01 烟台杰瑞石油装备技术有限公司 Combustible gas circulation treatment equipment and combustible gas circulation treatment method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995028998A1 (en) * 1994-04-22 1995-11-02 S Seetharaman Ab A method for purifying combustion-generated gases and flue gases
CN1272096A (en) * 1998-05-14 2000-11-01 阿卡纯风险投资公司 Mechanical vapour recompression separation process
CN1561252A (en) * 2001-07-31 2005-01-05 哈姆沃西Kse瓦斯系统公司 Method for recovery of VOC-gas and an apparatus for recovery of VOC-gas
CN101554559A (en) * 2008-04-10 2009-10-14 陈锚 Adsorption method for purifying low-boiling-point organic compound
CN107497131A (en) * 2017-09-04 2017-12-22 合肥天翔环境工程有限公司 A kind of VOC gas recovery system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995028998A1 (en) * 1994-04-22 1995-11-02 S Seetharaman Ab A method for purifying combustion-generated gases and flue gases
CN1272096A (en) * 1998-05-14 2000-11-01 阿卡纯风险投资公司 Mechanical vapour recompression separation process
CN1561252A (en) * 2001-07-31 2005-01-05 哈姆沃西Kse瓦斯系统公司 Method for recovery of VOC-gas and an apparatus for recovery of VOC-gas
CN101554559A (en) * 2008-04-10 2009-10-14 陈锚 Adsorption method for purifying low-boiling-point organic compound
CN107497131A (en) * 2017-09-04 2017-12-22 合肥天翔环境工程有限公司 A kind of VOC gas recovery system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110639352A (en) * 2019-11-02 2020-01-03 孙发喜 Vertical multi-stage absorption tower
CN110639352B (en) * 2019-11-02 2023-10-20 孙发喜 Vertical multistage absorption tower
CN113996154A (en) * 2021-11-17 2022-02-01 烟台杰瑞石油装备技术有限公司 Combustible gas circulation treatment equipment and combustible gas circulation treatment method

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