CN112807962A - Chemical waste gas treatment system - Google Patents

Chemical waste gas treatment system Download PDF

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Publication number
CN112807962A
CN112807962A CN202110090688.7A CN202110090688A CN112807962A CN 112807962 A CN112807962 A CN 112807962A CN 202110090688 A CN202110090688 A CN 202110090688A CN 112807962 A CN112807962 A CN 112807962A
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China
Prior art keywords
waste gas
catalytic
treatment system
activated carbon
gas treatment
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Pending
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CN202110090688.7A
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Chinese (zh)
Inventor
江映萱
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Shanghai Yingshan Environmental Technology Co ltd
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Shanghai Yingshan Environmental Technology Co ltd
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Priority to CN202110090688.7A priority Critical patent/CN112807962A/en
Publication of CN112807962A publication Critical patent/CN112807962A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D45/00Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/12Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/806Microwaves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/818Employing electrical discharges or the generation of a plasma

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Toxicology (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses a chemical waste gas treatment system, which comprises a condensation separator, a catalytic absorber, acid and alkali washing equipment, a cyclone demister, microwave photoelectrocatalysis oxidation equipment, fan equipment and an activated carbon adsorber which are sequentially communicated through a waste gas pipeline; the condensation separator, the catalytic absorber, the acid and alkali washing device, the cyclone demister, the microwave photoelectrocatalysis oxidation device and the fan device are connected with a controller together. The system sequentially carries out processes of condensation separation, catalytic absorption, acid washing, alkali washing, cyclone demisting, microwave photoelectrocatalysis oxidation, activated carbon adsorption and the like on the waste gas, ensures that the waste gas meets the environmental protection requirement when being discharged, and has the advantages of small equipment volume, low operation cost and long service cycle.

Description

Chemical waste gas treatment system
Technical Field
The invention relates to the technical field of chemical waste gas treatment, in particular to a chemical waste gas treatment system.
Background
Chemical waste gas refers to toxic and harmful gas discharged from chemical plants in chemical production. Chemical waste gas often contains many kinds of pollutants, has complex physical and chemical properties and different toxicity, seriously pollutes the environment and influences human health.
The selection of the waste gas treatment process is directly related to whether the emission index of waste gas treatment can meet the treatment requirement and the stability of the emission index, whether the operation management is convenient and reliable, and the construction cost, the operation cost, the floor area size and the energy consumption are high and low.
Several methods are currently used and their disadvantages, in particular the following:
1. and (3) an activated carbon adsorption process. The process has the advantages of less equipment investment, simple and reliable process and capability of removing trace (ppm) substances, and is particularly suitable for treating small-gas-quantity organic waste gas. However, after a period of use, the adsorption capacity decreases, and thus the spent adsorbent is replaced. The replacement period of the activated carbon is determined according to the organic content of the discharged waste gas, and is generally three months according to the operation condition of similar waste gas treatment equipment.
2. A catalytic combustion method. The process is advanced, secondary pollution is not generated, one-time investment is large, and the in-place of process facilities is difficult to ensure for organic waste gas treatment facilities with large air quantity.
3. Diesel oil, engine oil and additive absorption method. The method for treating the organic waste gas has the advantages of mature process, simple equipment, low one-time investment and the like, the absorbent has wide sources and low price, and has great advantages for treating the organic waste gas with large air volume, but the organic solvent is flammable and explosive, and the safe operation is influenced if the anti-explosion measures are improper.
4. Chemical oxidation method. The method mainly comprises the steps of adding an oxidant, oxidizing organic matters into tasteless and nontoxic substances through the oxidation action of the oxidant, and discharging the substances, but the method still has limitation on some pollutants and cannot completely oxidize the pollutants.
5. Water spray absorption method and water bath method. The method has the advantages of simple process, low cost, large gas treatment amount, capability of effectively removing particulate matters, and low organic gas removal efficiency.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a chemical waste gas treatment system, which solves the defects of the prior art.
In order to achieve the purpose, the invention adopts the following technical scheme:
a chemical waste gas treatment system is characterized in that: the device comprises a condensation separator, a catalytic absorber, acid and alkali washing equipment, a cyclone demister, microwave photoelectrocatalysis oxidation equipment, fan equipment and an activated carbon adsorber which are sequentially communicated through an exhaust gas pipeline; the condensation separator, the catalytic absorber, the acid and alkali washing device, the cyclone demister, the microwave photoelectrocatalysis oxidation device and the fan device are connected with a controller together.
According to the optimized scheme, the condensation separator comprises a condensation shell, a heat exchanger is arranged in the condensation shell, and the heat exchanger is communicated with an external cold water source container; and a water pump is arranged on a pipeline between the heat exchanger and the cold water source container.
According to the optimized scheme, the catalytic absorber comprises a catalyst shell, a catalytic water tank is arranged in the catalyst shell, and water with a catalyst is contained in the catalytic water tank; the intake pipe of the exhaust gas line on the catalyst housing is inserted into the water.
According to the optimized scheme, the acid washing and alkali washing equipment comprises an acid washing tower and an alkali washing tower which are sequentially communicated.
According to the optimized scheme, the microwave photoelectrocatalysis oxidation equipment comprises a catalytic oxidation shell, wherein a photolysis area and a photocatalytic oxidation area are arranged in the catalytic oxidation shell according to the flowing direction of waste gas; an electrodeless lamp is arranged in the photolysis region; and a ceramic catalytic plate is arranged in the photocatalytic oxidation area.
According to the optimized scheme, the ceramic catalytic plate is formed by solidifying the nano photocatalyst on the honeycomb ceramic substrate in a sintering mode.
According to the optimized scheme, the fan device uses a centrifugal fan.
According to the optimized scheme, the activated carbon adsorber comprises an activated carbon adsorption box and an activated carbon filter screen arranged in the activated carbon adsorption box; the activated carbon adsorption box adopts a fixed bed type structure, and the diameter of the activated carbon adsorption box is 2000 mm.
In an optimized scheme, the controllers are all PLC.
Due to the adoption of the technology, compared with the prior art, the invention has the beneficial effects that:
the system sequentially carries out processes of condensation separation, catalytic absorption, acid washing, alkali washing, cyclone demisting, microwave photoelectrocatalysis oxidation, activated carbon adsorption and the like on the waste gas, ensures that the waste gas meets the environmental protection requirement when being discharged, and has the advantages of small equipment volume, low operation cost and long service cycle.
Drawings
FIG. 1 is a schematic block diagram of one embodiment of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
As shown in fig. 1, a chemical waste gas treatment system comprises a condensation separator, a catalytic absorber, an acid and alkali washing device, a cyclone demister, a microwave photoelectrocatalysis oxidation device, a fan device and an activated carbon adsorber which are sequentially communicated through a waste gas pipeline.
The condensation separator, the catalytic absorber, the acid and alkali washing device, the cyclone demister, the microwave photoelectrocatalysis oxidation device and the fan device are connected with a controller together. The controllers are all PLC. The purpose of PLC is to realize automated control, and PLC is the mature product in the market, and the purchase is convenient, and the technical staff also can easily master.
The condensation separator comprises a condensation shell, a heat exchanger is arranged in the condensation shell, and the heat exchanger is communicated with an external cold water source container; and a water pump is arranged on a pipeline between the heat exchanger and the cold water source container. The condensation separator is used for condensing and separating the high-concentration organic waste gas, and the load of a subsequent treatment process is reduced.
The catalytic absorber comprises a catalytic converter shell, a catalytic water tank is arranged in the catalytic converter shell, and water with a catalyst is contained in the catalytic water tank; the intake pipe of the exhaust gas line on the catalyst housing is inserted into the water. When the waste gas passes through the catalytic absorber, the catalyst catalyzes the hydration of ethylene oxide, thereby facilitating the absorption.
The acid washing and alkali washing equipment comprises an acid washing tower and an alkali washing tower which are communicated in sequence. The organic matters in the waste gas are further separated through acid washing and alkali washing. The ammonia waste gas in the waste gas can be removed by acid washing, and the hydrogen sulfide gas in the water can be removed by alkali washing, so that the concentration of pollutants in the waste gas is reduced.
Through the whirl defroster, get rid of the moisture in the waste gas, prevent that the moisture in the waste gas from being adsorbed by active carbon, influencing the adsorption efficiency of waste gas.
The microwave photoelectrocatalysis oxidation device comprises a catalytic oxidation shell, wherein a photolysis area and a photocatalytic oxidation area are arranged in the catalytic oxidation shell according to the flowing direction of waste gas. An electrodeless lamp is arranged in the photolysis area. And a ceramic catalytic plate is arranged in the photocatalytic oxidation area. The ceramic catalytic plate is prepared by solidifying a nano photocatalyst on a honeycomb ceramic substrate in a sintering mode. The microwave photoelectrocatalysis oxidation equipment mainly utilizes 'microwave plasma strong electromagnetic field, special light source and photocatalyst' to efficiently crack organic molecules in waste gas under the synergistic action of multiple effects, so that malodorous gas is instantly converted into colorless and odorless stable and harmless oxides such as carbon dioxide, water and the like, and the purposes of deodorization and purification are achieved. The principle of the technology is colloquially called energy time conversion, and most of the reaction can be completed within 1 s.
The fan device uses a centrifugal fan. The released organic waste gas is captured to the waste gas treatment system under the action of the fan. After the concentration of the waste gas is very low after the previous concentrated treatment process, the waste gas is conveyed to an activated carbon adsorber by a fan for further purification treatment.
The activated carbon adsorber comprises an activated carbon adsorption box and an activated carbon filter screen arranged in the activated carbon adsorption box; the activated carbon adsorption box adopts a fixed bed type structure, and the diameter of the activated carbon adsorption box is 2000 mm. After the activated carbon adsorption device operates for a period of time, the purification efficiency of the activated carbon adsorption device can be reduced to a certain limit value, and the exhaust emission does not reach the standard at the moment, so that the activated carbon of the adsorption bed needs to be replaced. The specific replacement period is determined according to the actual use condition, and the replacement period is six months under the general condition.
The system sequentially carries out processes of condensation separation, catalytic absorption, acid washing, alkali washing, cyclone demisting, microwave photoelectrocatalysis oxidation, activated carbon adsorption and the like on the waste gas, ensures that the waste gas meets the environmental protection requirement when being discharged, and has the advantages of small equipment volume, low operation cost and long service cycle.
In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", and the like, indicate orientations and positional relationships based on those shown in the drawings, and are used only for convenience of description and simplicity of description, and do not indicate or imply that the equipment or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be considered as limiting the present invention.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. In the description of the present invention, "a plurality" means two or more unless specifically defined otherwise.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (9)

1. A chemical waste gas treatment system is characterized in that: the device comprises a condensation separator, a catalytic absorber, acid and alkali washing equipment, a cyclone demister, microwave photoelectrocatalysis oxidation equipment, fan equipment and an activated carbon adsorber which are sequentially communicated through an exhaust gas pipeline;
the condensation separator, the catalytic absorber, the acid and alkali washing device, the cyclone demister, the microwave photoelectrocatalysis oxidation device and the fan device are connected with a controller together.
2. The chemical waste gas treatment system according to claim 1, wherein: the condensation separator comprises a condensation shell, a heat exchanger is arranged in the condensation shell, and the heat exchanger is communicated with an external cold water source container; and a water pump is arranged on a pipeline between the heat exchanger and the cold water source container.
3. The chemical waste gas treatment system according to claim 2, wherein: the catalytic absorber comprises a catalytic converter shell, a catalytic water tank is arranged in the catalytic converter shell, and water with a catalyst is contained in the catalytic water tank; the intake pipe of the exhaust gas line on the catalyst housing is inserted into the water.
4. A chemical waste gas treatment system according to claim 3, characterized in that: the acid washing and alkali washing equipment comprises an acid washing tower and an alkali washing tower which are communicated in sequence.
5. The chemical waste gas treatment system according to claim 4, wherein: the microwave photoelectrocatalysis oxidation equipment comprises a catalytic oxidation shell, wherein a photolysis area and a photocatalytic oxidation area are arranged in the catalytic oxidation shell according to the flowing direction of waste gas; an electrodeless lamp is arranged in the photolysis region; and a ceramic catalytic plate is arranged in the photocatalytic oxidation area.
6. The chemical waste gas treatment system according to claim 5, wherein: the ceramic catalytic plate is prepared by solidifying a nano photocatalyst on a honeycomb ceramic substrate in a sintering mode.
7. The chemical waste gas treatment system according to claim 6, wherein: the fan device uses a centrifugal fan.
8. The chemical waste gas treatment system according to claim 7, wherein: the activated carbon adsorber comprises an activated carbon adsorption box and an activated carbon filter screen arranged in the activated carbon adsorption box; the activated carbon adsorption box adopts a fixed bed type structure, and the diameter of the activated carbon adsorption box is 2000 mm.
9. The chemical waste gas treatment system according to claim 8, wherein: the controllers are all PLC.
CN202110090688.7A 2021-01-22 2021-01-22 Chemical waste gas treatment system Pending CN112807962A (en)

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CN202110090688.7A CN112807962A (en) 2021-01-22 2021-01-22 Chemical waste gas treatment system

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114225644A (en) * 2021-11-23 2022-03-25 安徽金禾实业股份有限公司 Device and method for treating trichloroethane tail gas in sucralose production
CN114904363A (en) * 2021-09-08 2022-08-16 惠州市宙邦化工有限公司 Method for treating waste gas containing ethylene oxide

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108939873A (en) * 2018-08-01 2018-12-07 安徽华星化工有限公司 A method of administering dimethyl tetrachloride house exhaust
CN110833754A (en) * 2019-09-24 2020-02-25 上海邦高化学有限公司 Device for absorbing ethylene oxide waste gas and method for treating ethylene oxide waste gas
CN211886052U (en) * 2020-02-18 2020-11-10 上海兰宝环保科技有限公司 Waste gas treatment system

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108939873A (en) * 2018-08-01 2018-12-07 安徽华星化工有限公司 A method of administering dimethyl tetrachloride house exhaust
CN110833754A (en) * 2019-09-24 2020-02-25 上海邦高化学有限公司 Device for absorbing ethylene oxide waste gas and method for treating ethylene oxide waste gas
CN211886052U (en) * 2020-02-18 2020-11-10 上海兰宝环保科技有限公司 Waste gas treatment system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114904363A (en) * 2021-09-08 2022-08-16 惠州市宙邦化工有限公司 Method for treating waste gas containing ethylene oxide
CN114225644A (en) * 2021-11-23 2022-03-25 安徽金禾实业股份有限公司 Device and method for treating trichloroethane tail gas in sucralose production
CN114225644B (en) * 2021-11-23 2024-05-03 安徽金禾实业股份有限公司 Trichloroethane tail gas treatment device and method in sucralose production

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