CN109354828A - A kind of encapsulating material for light emitting diode - Google Patents

A kind of encapsulating material for light emitting diode Download PDF

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Publication number
CN109354828A
CN109354828A CN201811276584.XA CN201811276584A CN109354828A CN 109354828 A CN109354828 A CN 109354828A CN 201811276584 A CN201811276584 A CN 201811276584A CN 109354828 A CN109354828 A CN 109354828A
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CN
China
Prior art keywords
parts
light emitting
emitting diode
resin
silicone resin
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811276584.XA
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Chinese (zh)
Inventor
任向华
于家正
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Xuzhou Jing Di Electronics Co Ltd
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Xuzhou Jing Di Electronics Co Ltd
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Priority to CN201811276584.XA priority Critical patent/CN109354828A/en
Publication of CN109354828A publication Critical patent/CN109354828A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/52Encapsulations
    • H01L33/56Materials, e.g. epoxy or silicone resin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/206Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Power Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of encapsulating materials for light emitting diode, it include following component according to weight point meter: 30~50 parts of bisphenol A type epoxy resin, 15~25 parts of epoxy modified silicone resin, 10~20 parts of methyl MQ silicone resin, 5~15 parts of polyamide, 5~10 parts of m-phenylene diamine (MPD), 10~20 parts of vinyl silicone oil, 3~8 parts of containing hydrogen silicone oil, 2~5 parts of platinum complex catalyst, 8~12 parts of modified nano silicon dioxide particles, 1~3 part of tackifier, 0.5~1.5 part of fire retardant, 1~3 part of curing agent, 1~2 part of antioxidant, 2~5 parts of silane coupling agent, wherein, the weight ratio of the bisphenol A type epoxy resin and the epoxy modified silicone resin is 1.5~2.5:1.Encapsulating material hardness in the present invention is high, and good mechanical protection can be provided for light emitting diode, steam can be effectively prevent to enter device inside, is conducive to the long-time service stability of light emitting diode, and does not influence the service life of light emitting diode.

Description

A kind of encapsulating material for light emitting diode
Technical field
The present invention relates to LED technology fields, more particularly to a kind of encapsulating material for light emitting diode.
Background technique
Light emitting diode is to belong to electroluminescent device, and structure is mainly made of PN junction chip, electrode and optical system. With operating current is small, energy consumption is very low, structure is simple, small in size, light compared with the light sources such as traditional incandescent lamp, fluorescent lamp Just, the advantages that service life is long.In recent years, the technology development of LED is swift and violent, with LED light cause and brightness be gradually increased, it is photochromic constantly Abundant, application field also gradually expands to lighting area from display field.The luminescence chip of LED is smaller, typical to shine Area is 0125mm2, it is encapsulated in host material, is connected by lead with external electrode.Transparent material is encapsulated on LED light-emitting surface Material, effect is the spatial distribution state for exporting the luminous flux of chip to the maximum extent, while controlling output light, plays light Learn the effect of lens.
GaN base power-type White LED is the emphasis developed at present, have heat big, junction temperature or chip part junction temperature it is excessively high, The features such as emission wavelength is short.The encapsulating materials such as traditional transparent epoxy resin, acrylic resin, polycarbonate, in short-wavelength light Permeability, light fastness aging etc. have been unable to meet requirement.
For this reason, it is necessary to be able to solve existing in view of the above-mentioned problems, propose a kind of encapsulating material for light emitting diode There is the problem of technology.
Summary of the invention
The purpose of the present invention is to provide a kind of encapsulating material for light emitting diode, with overcome it is in the prior art not Foot.
To achieve the above object, the invention provides the following technical scheme:
A kind of encapsulating material for light emitting diode includes following component: bisphenol A type epoxy resin according to weight point meter 30~50 parts, 15~25 parts of epoxy modified silicone resin, 10~20 parts of methyl MQ silicone resin, 5~15 parts of polyamide, isophthalic two 5~10 parts of amine, 10~20 parts of vinyl silicone oil, 3~8 parts of containing hydrogen silicone oil, 2~5 parts of platinum complex catalyst, modified nano-silica 8~12 parts of silicon carbide particle, 1~3 part of tackifier, 0.5~1.5 part of fire retardant, 1~3 part of curing agent, 1~2 part of antioxidant, silane 2~5 parts of coupling agent, wherein the weight ratio of the bisphenol A type epoxy resin and the epoxy modified silicone resin is 1.5 ~2.5:1.
Preferably, the platinum complex catalyst is selected from platinumMethyl vinyl silicone complex compound, platinumPhthalic acid The mixing of one or more of platinum complex of diethylester complex compound, dicyclopentadiene platinous chloride, dichloro bis- (triphenylphosphines) Object.
Preferably, the tackifier are the mixture of alkyl naphthalene resin, polyborosiloxane, diphenyl silanediol.
Preferably, the weight ratio of the bisphenol A type epoxy resin and the epoxy modified silicone resin is 2:1.
It preferably, include following component according to weight point meter: 35~45 parts of bisphenol A type epoxy resin, epoxy-modified organic 17.5~22.5 parts of silicone resin, 12.5~17.5 parts of methyl MQ silicone resin, 7.5~12.5 parts of polyamide, 6~9 parts of m-phenylene diamine (MPD), 12~18 parts of vinyl silicone oil, 4~6 parts of containing hydrogen silicone oil, 2.75~4.25 parts of platinum complex catalyst, modified manometer silicon dioxide 9~11 parts of particle, 1.5~2.5 parts of tackifier, 0.75~1.25 part of fire retardant, 1.5~2.5 parts of curing agent, antioxidant 1.2~ 1.8 parts, 2.75~4.25 parts of silane coupling agent.
Preferably, include following component according to weight point meter: 40 parts of bisphenol A type epoxy resin, epoxy modified silicone tree 20 parts of rouge, 15 parts of methyl MQ silicone resin, 10 parts of polyamide, 7.5 parts of m-phenylene diamine (MPD), 15 parts of vinyl silicone oil, 5 parts of containing hydrogen silicone oil, 3 parts of platinum complex catalyst, 10 parts of modified nano silicon dioxide particles, 2 parts of tackifier, 1 part of fire retardant, 2 parts of curing agent, antioxygen 1.5 parts of agent, 3.5 parts of silane coupling agent.
Compared with the prior art, the advantages of the present invention are as follows: the encapsulating material hardness in the present invention is high, can be luminous two Pole pipe provides good mechanical protection, steam can be effectively prevent to enter device inside, is conducive to making for a long time for light emitting diode With stability, and the service life of light emitting diode is not influenced.
Specific embodiment
The present invention is described further by the following example: according to following embodiments, the present invention may be better understood. However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of encapsulating material for light emitting diode, includes following component: bisphenol-A according to weight point meter 30~50 parts of type epoxy resin, 15~25 parts of epoxy modified silicone resin, 10~20 parts of methyl MQ silicone resin, polyamide 5~ 15 parts, 5~10 parts of m-phenylene diamine (MPD), 10~20 parts of vinyl silicone oil, 3~8 parts of containing hydrogen silicone oil, 2~5 parts of platinum complex catalyst, 8~12 parts of modified nano silicon dioxide particles, 1~3 part of tackifier, 0.5~1.5 part of fire retardant, 1~3 part of curing agent, antioxidant 1~2 part, 2~5 parts of silane coupling agent, wherein the weight of the bisphenol A type epoxy resin and the epoxy modified silicone resin The ratio between amount is 1.5~2.5:1.
Wherein, the platinum complex catalyst is selected from platinumMethyl vinyl silicone complex compound, platinumPhthalic acid two One or more of the platinum complex of ethyl ester complex compound, dicyclopentadiene platinous chloride, dichloro bis- (triphenylphosphines) mixture; The tackifier are the mixture of alkyl naphthalene resin, polyborosiloxane, diphenyl silanediol;Further, the bisphenol A-type The weight ratio of epoxy resin and the epoxy modified silicone resin is 2:1.
The encapsulating material that light emitting diode is used in the present invention is illustrated with specific embodiment below.
Embodiment 1
Include following component according to weight point meter: 30 parts of bisphenol A type epoxy resin, 15 parts of epoxy modified silicone resin, 10 parts of methyl MQ silicone resin, 5 parts of polyamide, 5 parts of m-phenylene diamine (MPD), 10 parts of vinyl silicone oil, 3 parts of containing hydrogen silicone oil, platinum complex is urged 2 parts of agent, 8 parts of modified nano silicon dioxide particles, 1 part of tackifier, 0.5 part of fire retardant, 1 part of curing agent, 1 part of antioxidant, silicon 2 parts of alkane coupling agent.
Embodiment 2
Include following component according to weight point meter: 35 parts of bisphenol A type epoxy resin, epoxy modified silicone resin 17.5 Part, 12.5 parts of methyl MQ silicone resin, 7.5 parts of polyamide, 6 parts of m-phenylene diamine (MPD), 12 parts of vinyl silicone oil, 4 parts of containing hydrogen silicone oil, platinum network 2.75 parts of mixture catalyst, 9 parts of modified nano silicon dioxide particles, 1.5 parts of tackifier, 0.75 part of fire retardant, curing agent 1.5 Part, 1.2 parts of antioxidant, 2.75 parts of silane coupling agent.
Embodiment 3
Include following component according to weight point meter: 40 parts of bisphenol A type epoxy resin, 20 parts of epoxy modified silicone resin, 15 parts of methyl MQ silicone resin, 10 parts of polyamide, 7.5 parts of m-phenylene diamine (MPD), 15 parts of vinyl silicone oil, 5 parts of containing hydrogen silicone oil, platinum complex 3 parts of catalyst, 10 parts of modified nano silicon dioxide particles, 2 parts of tackifier, 1 part of fire retardant, 2 parts of curing agent, 1.5 parts of antioxidant, 3.5 parts of silane coupling agent.
Embodiment 4
Include following component according to weight point meter: 45 parts of bisphenol A type epoxy resin, epoxy modified silicone resin 22.5 Part, 17.5 parts of methyl MQ silicone resin, 12.5 parts of polyamide, 9 parts of m-phenylene diamine (MPD), 18 parts of vinyl silicone oil, 6 parts of containing hydrogen silicone oil, platinum 4.25 parts of complex compound catalyst, 11 parts of modified nano silicon dioxide particles, 2.5 parts of tackifier, 1.25 parts of fire retardant, curing agent 2.5 parts, 1.8 parts of antioxidant, 4.25 parts of silane coupling agent.
Embodiment 5
Include following component according to weight point meter: 50 parts of bisphenol A type epoxy resin, 25 parts of epoxy modified silicone resin, 20 parts of methyl MQ silicone resin, 15 parts of polyamide, 10 parts of m-phenylene diamine (MPD), 20 parts of vinyl silicone oil, 8 parts of containing hydrogen silicone oil, platinum complex 5 parts of catalyst, 12 parts of modified nano silicon dioxide particles, 3 parts of tackifier, 1.5 parts of fire retardant, 3 parts of curing agent, 2 parts of antioxidant, 5 parts of silane coupling agent.
In encapsulating material of the invention, by be added vinyl silicone oil, containing hydrogen silicone oil, modified nano silicon dioxide particles and Silane coupling agent enables modified nano silicon dioxide particles relatively evenly to disperse in encapsulating material, seals obtained from The surface of package material hardness with higher, Rockwell hardness can provide very well up to 98~106 for light emitting diode Mechanical protection, steam can be effectively prevent to enter device inside, be conducive to the long-time service stability of light emitting diode, and The service life of light emitting diode is not influenced.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive Property include so that include a series of elements process, method, article or equipment not only include those elements, but also Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic Element.

Claims (6)

1. a kind of encapsulating material for light emitting diode, which is characterized in that include following component: bisphenol-A according to weight point meter 30~50 parts of type epoxy resin, 15~25 parts of epoxy modified silicone resin, 10~20 parts of methyl MQ silicone resin, polyamide 5~ 15 parts, 5~10 parts of m-phenylene diamine (MPD), 10~20 parts of vinyl silicone oil, 3~8 parts of containing hydrogen silicone oil, 2~5 parts of platinum complex catalyst, 8~12 parts of modified nano silicon dioxide particles, 1~3 part of tackifier, 0.5~1.5 part of fire retardant, 1~3 part of curing agent, antioxidant 1~2 part, 2~5 parts of silane coupling agent, wherein the weight of the bisphenol A type epoxy resin and the epoxy modified silicone resin The ratio between amount is 1.5~2.5:1.
2. the encapsulating material according to claim 1 for light emitting diode, which is characterized in that the platinum complex catalysis Agent is selected from platinumMethyl vinyl silicone complex compound, platinumDiethyl phthalate complex compound, dicyclopentadiene dichloride One or more of the platinum complex of platinum, dichloro bis- (triphenylphosphines) mixture.
3. the encapsulating material according to claim 1 for light emitting diode, which is characterized in that the tackifier are alkyl Naphthalene resin, polyborosiloxane, diphenyl silanediol mixture.
4. the encapsulating material according to claim 1 for light emitting diode, which is characterized in that the bisphenol type epoxy The weight ratio of resin and the epoxy modified silicone resin is 2:1.
5. the encapsulating material according to claim 1 for light emitting diode, which is characterized in that include according to weight point meter Following component: 35~45 parts of bisphenol A type epoxy resin, 17.5~22.5 parts of epoxy modified silicone resin, methyl MQ silicone resin 12.5~17.5 parts, 7.5~12.5 parts of polyamide, 6~9 parts of m-phenylene diamine (MPD), 12~18 parts of vinyl silicone oil, containing hydrogen silicone oil 4~6 Part, 2.75~4.25 parts of platinum complex catalyst, 9~11 parts of modified nano silicon dioxide particles, 1.5~2.5 parts of tackifier, resistance 0.75~1.25 part of agent, 1.5~2.5 parts of curing agent, 1.2~1.8 parts of antioxidant, 2.75~4.25 parts of silane coupling agent of combustion.
6. the encapsulating material according to claim 1 for light emitting diode, which is characterized in that include according to weight point meter Following component: 40 parts of bisphenol A type epoxy resin, 20 parts of epoxy modified silicone resin, 15 parts of methyl MQ silicone resin, polyamide 10 Part, 7.5 parts of m-phenylene diamine (MPD), 15 parts of vinyl silicone oil, 5 parts of containing hydrogen silicone oil, 3 parts of platinum complex catalyst, modified nano-silica 10 parts of silicon particle, 2 parts of tackifier, 1 part of fire retardant, 2 parts of curing agent, 1.5 parts of antioxidant, 3.5 parts of silane coupling agent.
CN201811276584.XA 2018-10-30 2018-10-30 A kind of encapsulating material for light emitting diode Withdrawn CN109354828A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102977553A (en) * 2012-11-06 2013-03-20 中科院广州化学有限公司 Epoxy/silicone polymer composite material, and preparation method and application thereof
CN107266864A (en) * 2017-07-26 2017-10-20 合肥同佑电子科技有限公司 It is a kind of for insulating materials of LED package and preparation method thereof
CN108102601A (en) * 2017-12-20 2018-06-01 烟台德邦先进硅材料有限公司 A kind of organic silicon adhesive for UV LED chip encapsulation
CN108511584A (en) * 2018-03-12 2018-09-07 合肥同佑电子科技有限公司 A kind of special encapsulating material of light emitting diode and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102977553A (en) * 2012-11-06 2013-03-20 中科院广州化学有限公司 Epoxy/silicone polymer composite material, and preparation method and application thereof
CN107266864A (en) * 2017-07-26 2017-10-20 合肥同佑电子科技有限公司 It is a kind of for insulating materials of LED package and preparation method thereof
CN108102601A (en) * 2017-12-20 2018-06-01 烟台德邦先进硅材料有限公司 A kind of organic silicon adhesive for UV LED chip encapsulation
CN108511584A (en) * 2018-03-12 2018-09-07 合肥同佑电子科技有限公司 A kind of special encapsulating material of light emitting diode and preparation method thereof

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Application publication date: 20190219

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