CN109336714A - One kind composite microbe fertilizer containing humic acid and preparation method - Google Patents

One kind composite microbe fertilizer containing humic acid and preparation method Download PDF

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Publication number
CN109336714A
CN109336714A CN201811241913.7A CN201811241913A CN109336714A CN 109336714 A CN109336714 A CN 109336714A CN 201811241913 A CN201811241913 A CN 201811241913A CN 109336714 A CN109336714 A CN 109336714A
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CN
China
Prior art keywords
parts
humic acid
composite microbe
microbe fertilizer
microbial
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Pending
Application number
CN201811241913.7A
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Chinese (zh)
Inventor
高立志
黄祥川
吕新春
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Shandong Province Liaocheng City Luxi Nitrocompound Fertilizer Co Ltd
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Shandong Province Liaocheng City Luxi Nitrocompound Fertilizer Co Ltd
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Application filed by Shandong Province Liaocheng City Luxi Nitrocompound Fertilizer Co Ltd filed Critical Shandong Province Liaocheng City Luxi Nitrocompound Fertilizer Co Ltd
Priority to CN201811241913.7A priority Critical patent/CN109336714A/en
Publication of CN109336714A publication Critical patent/CN109336714A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates

Abstract

The invention discloses a kind of composite microbe fertilizer containing humic acid and preparation methods; a kind of composite microbe fertilizer containing humic acid; it is characterized in that; raw material is in terms of 100 parts of mass parts; 10~30 parts of ammonium nitrate, 5~15 parts of monoammonium phosphate, 5~15 parts of potassium nitrate, 1~3 part of zinc nitrate, 0~2 part of boric acid, 37~50 parts of humic acid, 0.4~4 part of microbial germ powder, 2~10 parts of protective agent; wherein, the boric acid additive amount is not 0.Preparation method is to be inoculated with required microbial bacterial agent, and carry out three grade fermemtation, obtains microbial inoculum;Use 300~500 mesh vermiculite powers as adsorbent, is added in mentioned microorganism bacterium solution product, is spray-dried to get microbial germ powder;After the completion of ammonium nitrate, monoammonium phosphate, potassium nitrate, zinc nitrate and boric acid are mixed in proportion, then humic acid, protective agent and microbial germ powder are added, after mixing up to composite microbe fertilizer containing humic acid.The fertilizer preparation rationally, A wide selection of colours and designs, full of nutrition, inorganic nutrients needed for plant growth can be provided and organic substance, and can anti-soil-borne disease, improve crop resistance, promote plant growth.

Description

One kind composite microbe fertilizer containing humic acid and preparation method
Technical field
The present invention relates to agro-ecology fertilizer fields, and in particular to one kind composite microbe fertilizer containing humic acid and preparation side Method.
Background technique
Now, fertilizer application amount in China's increases year by year, and the utilization rate and effect of increasing production of chemical fertilizer constantly decline, while big quantization The application for learning fertilizer, not only causes soil hardening, salinization of soil serious, and soil fertility decline causes soil degradation, and also result in Serious water body and environmental pollution.From 2015, country pointed out in plain text, to widely popularize microbial manure, carried out " organic fertilizer Substitute inorganic fertilizer " action.
Humic acid is the organic substance of a kind of high bioactivity, in improvement soil, promotes soil nutrient validation, raising fertilizer Material utilization rate etc. has obvious effects on;When microbial bacterial agent is used for crop pouring root, also there is directly or indirectly improvement soil Tiny ecosystem restores the effects of soil fertility and prevention soil-borne disease, and the two compounding application answers cocoa to mutually promote, jointly to soil, work Object works.But at present on the market, there has been no the composite microbiological fertilizer containing humic acid, tracing it to its cause should be humic acid characteristic and exists Alkalinity is stabilized, and microorganism then likes neutral meta-acid environment existence.
Meanwhile the microbial manure generally existing shelf-life is short, situations such as microorganism easy mortality, and there has been no have at present Effect ground Protective substances.
Summary of the invention
In order to solve the deficiencies in the prior art, an object of the present invention is to provide a kind of complex microorganism containing humic acid Fertilizer, the fertilizer preparation rationally, A wide selection of colours and designs, full of nutrition, inorganic nutrients needed for plant growth can be provided and organic substance, Again can anti-soil-borne disease, improve crop resistance, promote plant growth.
To achieve the goals above, the technical solution of the present invention is as follows:
A kind of composite microbe fertilizer containing humic acid, raw material is in terms of 100 parts of mass parts, 10~30 parts of ammonium nitrate, monoammonium phosphate 5 ~15 parts, 5~15 parts of potassium nitrate, 1~3 part of zinc nitrate, 0~2 part of boric acid, 37~50 parts of humic acid, microbial germ powder 0.4~4 Part, 2~10 parts of protective agent, wherein the monoammonium phosphate contains N-P2O5Amount is 11-44, and the boric acid is not 0, and the humic acid contains You machine matter Han Liang≤55%, the microbial bacterial agent are plant growth-promoting rhizobacteria class, and You imitates Jun Shuo≤5,000,000,000/g living.
Firstly, selecting the natural humic acid of high activity as organic matter in the present invention, in improvement soil, promote soil nutrient Validation, raising utilization rate of fertilizer etc. have obvious effects on.Secondly, the present invention uses plant growth-promoting rhizobacteria class gemma bar Bacterium, compared with the strain of the acquisitions such as other animal intestinal tracts, adaptability with higher, energy mass propagation inhibit soil in the soil The generation of disease is passed, plant growth is promoted.Third, the present invention comprehensively consider needed for plant growth big, middle and trace element and organic Matter demand is arranged in pairs or groups reasonable, full of nutrition.
The second object of the present invention is to provide a kind of preparation method of above-mentioned fertilizer,
(1) required microbial bacterial agent is inoculated with, and carries out three grade fermemtation, obtain microbial inoculum.
(2) it uses 300~500 mesh vermiculite powers as adsorbent, is added in mentioned microorganism bacterium solution product, is sprayed Drying is to get microbial germ powder.
(3) after the completion of mixing ammonium nitrate, monoammonium phosphate, potassium nitrate, zinc nitrate and boric acid in proportion, then rotten plant is added Acid, protective agent and microbial germ powder, after mixing up to composite microbe fertilizer containing humic acid.
Protective agent is to mix citric acid, sucrose, ammonium sulfate in the ratio of 0~1:0~1:1.5~3 in the step (3) It closes, protectant effect are as follows: the stability for effectively improving the microorganism shelf-life, guaranteeing humic acid.
The beneficial effects of the present invention are:
1. inorganic nutritive element, humic acid, microorganism are bound organically in one, body by composite microbiological fertilizer of the invention Fertilizer benefit can be improved in quick-acting, the long-term effect of humic acid, the disease resistance of plant growth-promoting rhizobacteria and the growth-promoting of existing inorganic fertilizer With 20% or more rate, also there are the multi-efficiencies such as anti-soil-borne disease, anti-continuous cropping, activating soil, upgrading volume increase.
2. composite microbiological fertilizer protective agent provided by the present invention, not only has certain pooling feature, together to humic acid When also have certain protective effect to the growth of microorganism, can be by the shelf-life of microorganism by improving for 6~December to 12~24 months.
3. composite microbiological fertilizer of the invention is water-soluble good, water-insoluble≤0.5% is far below requirements of the national standard ≤ 5%, it is suitable for the modes such as drip irrigation and spray irrigation.
Specific embodiment
It is noted that following detailed description is all illustrative, it is intended to provide further instruction to the application.Unless another It indicates, all technical and scientific terms used herein has usual with the application person of an ordinary skill in the technical field The identical meanings of understanding.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singular Also it is intended to include plural form, additionally, it should be understood that, when in the present specification using term "comprising" and/or " packet Include " when, indicate existing characteristics, step, operation, device, component and/or their combination.
As background technique is introduced, an object of the present invention is to provide a kind of composite microbe fertilizer containing humic acid, The fertilizer preparation rationally, A wide selection of colours and designs, full of nutrition, inorganic nutrients needed for plant growth can be provided and organic substance, again Can anti-soil-borne disease, improve crop resistance, promote plant growth.
To achieve the goals above, the technical solution of the present invention is as follows:
A kind of composite microbe fertilizer containing humic acid, raw material is in terms of 100 parts of mass parts, 10~30 parts of ammonium nitrate, monoammonium phosphate 5 ~15 parts, 5~15 parts of potassium nitrate, 1~3 part of zinc nitrate, 0~2 part of boric acid, 37~50 parts of humic acid, microbial germ powder 0.4~4 Part, 2~10 parts of protective agent, wherein the monoammonium phosphate contains N-P2O5Amount is 11-44, and the boric acid is not 0, and the humic acid contains You machine matter Han Liang≤55%, the microbial bacterial agent are plant growth-promoting rhizobacteria class, and You imitates Jun Shuo≤5,000,000,000/g living.
Firstly, selecting the natural humic acid of high activity as organic matter in the present invention, in improvement soil, promote soil nutrient Validation, raising utilization rate of fertilizer etc. have obvious effects on.Secondly, the present invention uses plant growth-promoting rhizobacteria class gemma bar Bacterium, compared with the strain of the acquisitions such as other animal intestinal tracts, adaptability with higher, energy mass propagation inhibit soil in the soil The generation of disease is passed, plant growth is promoted.Third, the present invention comprehensively consider needed for plant growth big, middle and trace element and organic Matter demand is arranged in pairs or groups reasonable, full of nutrition.
In order to increase fertilizer available phosphorus nutrient content, it is preferred that the monoammonium phosphate contains N-P2O5Amount is 11-44.Both advantageous In control production cost, and it can guarantee that fertilizer quickly dissolves when application.
Fertilizer organic matter nutrient content in order to further increase, it is preferred that the humic acid be containing the content of organic matter≤ 55%, it is water-soluble good.
Zinc nitrate is divided into anhydrous nitric acid zinc and seven water zinc nitrates, if the combination water in seven water zinc nitrates is removed, needs pair It is heat-treated, so that the expense of anhydrous nitric acid zinc is higher than seven water zinc nitrates, and in order to reduce the cost of production fertilizer, this Shen Please be preferred, the zinc nitrate is seven water zinc nitrates.
In order to effectively improve the shelf-life of microorganism and the stability of humic acid, the application is preferred, and the protective agent is One of citric acid, sucrose, ammonium sulfate are a variety of.
The present invention also provides a kind of preparation method of above-mentioned fertilizer,
(1) required microbial bacterial agent is inoculated with, and carries out three grade fermemtation, obtain microbial inoculum.
(2) it uses 300~500 mesh vermiculite powers as adsorbent, is added in mentioned microorganism bacterium solution product, is sprayed Drying is to get microbial germ powder.
(3) after the completion of mixing ammonium nitrate, monoammonium phosphate, potassium nitrate, zinc nitrate and boric acid in proportion, then rotten plant is added Acid, protective agent and microbial germ powder, after mixing up to composite microbe fertilizer containing humic acid.
Present invention also provides a kind of application methods of above-mentioned composite microbiological fertilizer, by above-mentioned fertilizer and water with mass ratio The ratio of 1:50~80 is mixed, and is then applied to mixed fertilizer in the crop fields with water punching.
Preferably, 9 points of 4 points to second day of the morning of the afternoon that the time that fertilizer punching is applied is first day.
In order to enable those skilled in the art can clearly understand the technical solution of the application, below with reference to tool The technical solution of the application is described in detail in the embodiment and comparative example of body.
Embodiment 1:
Raw material proportioning are as follows: in terms of 100 parts of mass parts, 30 parts of ammonium nitrate, 15 parts of monoammonium phosphate, 5 parts of potassium nitrate, seven water nitric acid 2 parts of zinc, 0.6 part of boric acid, 38.4 parts of humic acid, 4 parts of microbial germ powder, 5 parts of protective agent.
Composite microbe fertilizer the preparation method is as follows:
(1) required microbial bacterial agent is inoculated with, and carries out three grade fermemtation, obtain microbial inoculum.
(2) it uses 300~500 mesh vermiculite powers as adsorbent, is added in mentioned microorganism bacterium solution product, is sprayed Drying is to get microbial germ powder.
(3) after the completion of mixing ammonium nitrate, monoammonium phosphate, potassium nitrate, zinc nitrate and boric acid in proportion, then rotten plant is added Acid, protective agent and microbial germ powder, after mixing up to composite microbe fertilizer containing humic acid.
In the fertilizer prepared:
A great number of elements content: nitrogen element content 12.52%, P elements (P2O5) content 6.6%, potassium element (K2O) content 2.3%;
Micronutrient levels: (zinc+boron) 0.86%;
The content of organic matter: 21.12%;
Content of microorganisms: 200,000,000/g.
The application method of the fertilizer are as follows:
Extension rate: it is diluted with water by 1:50~80 times (mass ratio);Punching apply the time: preferably in the morning 9 when before or afternoon 4 When applied with backlash.
Embodiment 2:
Raw material proportioning are as follows: in terms of 100 parts of mass parts, 25 parts of ammonium nitrate, 10 parts of monoammonium phosphate, 5 parts of potassium nitrate, seven water nitric acid 2 parts of zinc, 0.6 part of boric acid, 48.4 parts of humic acid, 4 parts of microbial germ powder, 5 parts of protective agent.
Composite microbe fertilizer the preparation method is as follows:
(1) required microbial bacterial agent is inoculated with, and carries out three grade fermemtation, obtain microbial inoculum.
(2) it uses 300~500 mesh vermiculite powers as adsorbent, is added in mentioned microorganism bacterium solution product, is sprayed Drying is to get microbial germ powder.
(3) after the completion of mixing ammonium nitrate, monoammonium phosphate, potassium nitrate, zinc nitrate and boric acid in proportion, then rotten plant is added Acid, protective agent and microbial germ powder, after mixing up to composite microbe fertilizer containing humic acid.
In the fertilizer prepared,
A great number of elements content: nitrogen element content 10.28%, P elements (P2O5) content 4.4%, potassium element (K2O) content 2.3%;
Micronutrient levels: (zinc+boron) 0.86%;
The content of organic matter: 26.62%;
Content of microorganisms: 200,000,000/g.
The application method of the fertilizer are as follows:
Extension rate: it is diluted with water by 1:50~80 times (mass ratio);Punching apply the time: preferably in the morning 9 when before or afternoon 4 When applied with backlash.
Embodiment 3:
Raw material proportioning are as follows: in terms of 100 parts of mass parts, 30 parts of ammonium nitrate, 15 parts of monoammonium phosphate, 5 parts of potassium nitrate, seven water nitric acid 2 parts of zinc, 0.6 part of boric acid, 38.4 parts of humic acid, 0.4 part of microbial germ powder, 8.6 parts of protective agent.
Composite microbe fertilizer the preparation method is as follows:
(1) required microbial bacterial agent is inoculated with, and carries out three grade fermemtation, obtain microbial inoculum.
(2) it uses 300~500 mesh vermiculite powers as adsorbent, is added in mentioned microorganism bacterium solution product, is sprayed Drying is to get microbial germ powder.
(3) after the completion of mixing ammonium nitrate, monoammonium phosphate, potassium nitrate, zinc nitrate and boric acid in proportion, then rotten plant is added Acid, protective agent and microbial germ powder, after mixing up to composite microbe fertilizer containing humic acid.
In the fertilizer prepared:
A great number of elements content: nitrogen element content 12.52%, P elements (P2O5) content 6.6%, potassium element (K2O) content 2.3%;
Micronutrient levels: (zinc+boron) 0.86%;
The content of organic matter: 21.12%;
Content of microorganisms: 0.2 hundred million/g.
The application method of the fertilizer are as follows:
Extension rate: it is diluted with water by 1:50~80 times (mass ratio);Punching apply the time: preferably in the morning 9 when before or afternoon 4 When applied with backlash.
Comparative example:
The comparative example is identical as the formula of embodiment 1 and preparation method, and a large amount of members in the fertilizer of comparative example preparation Cellulose content, the content of organic matter and content of microorganisms are same as Example 1, the difference is that, the humic acid in embodiment 1 is with phase The organic fertilizer of commonly using in the market of equimolar amounts replaces.
Manure trial is as follows:
1 test material
For trying soil: it is location-appropriate, unobscured, avoid the ground such as the edge of a field, the woods, draining is good, fertile soil, and topography is flat Smooth, water flowing, water project situation are preferable;For studying object: cucumber;Test method: cell method of comparison is used, is not provided with repeating, each place Manage area 200m2(0.4 mu).
2 test process
Test sets 4 processing altogether, wherein processing 1 is control group: conventional fertilizer application does not do other processing;Processing 2 is implementation Example 1: conventional fertilizer application, and rush the fertilizer for applying embodiment 1;Processing 3 is embodiment 2: conventional fertilizer application, and rushes the fertilizer for applying embodiment 2 Material;Processing 4 is embodiment 3: conventional fertilizer application, and rushes the fertilizer for applying embodiment 3;Processing 5 is comparative example: conventional fertilizer application, and rushes and apply The fertilizer of comparative example.Rushed accordingly according to embodiment applying method carry out punching apply.
3 test results
As seen from the above table, applying fertilizer of the invention has apparent production-increasing function to cucumber.Experimental group and control group phase Than average mu rate of growth is respectively 21.6%, 25.4% and 16.4%, and the quality of cucumber is also significantly improved, appearance Quality significantly improves, and color is preferable, and mouthfeel is also more preferable.And compared by contrast groups, experimental group and control group, it can be seen that right Although the fertilizer of ratio also can per mu yield increase, its increase production much not as good as the volume increase of experimental group.
The foregoing is merely preferred embodiment of the present application, are not intended to limit this application, for the skill of this field For art personnel, various changes and changes are possible in this application.Within the spirit and principles of this application, made any to repair Change, equivalent replacement, improvement etc., should be included within the scope of protection of this application.

Claims (7)

1. a kind of composite microbe fertilizer containing humic acid, characterized in that raw material is in terms of 100 parts of mass parts, 10~30 parts of ammonium nitrate, phosphorus 5~15 parts of sour monoammonium, 5~15 parts of potassium nitrate, 1~3 part of zinc nitrate, 0~2 part of boric acid, 37~50 parts of humic acid, microbial germ powder 0.4~4 part, 2~10 parts of protective agent, wherein the boric acid additive amount is not 0.
2. composite microbe fertilizer as described in claim 1, characterized in that the monoammonium phosphate contains N-P2O5Amount is 11-44.
3. composite microbe fertilizer as described in claim 1, characterized in that the zinc nitrate is seven water zinc nitrates.
4. composite microbe fertilizer as described in claim 1, characterized in that the humic acid contains the content of organic matter≤55%.
5. composite microbe fertilizer as described in claim 1, characterized in that the microbial bacterial agent is plant growth-promoting rhizobacteria Class, You imitate Jun Shuo≤5,000,000,000/g living.
6. composite microbe fertilizer as described in claim 1, characterized in that the protective agent is citric acid, in sucrose, ammonium sulfate It is one or more.
7. a kind of preparation method of any composite microbe fertilizer of Claims 1 to 5, characterized in that the steps include:
(1) required microbial bacterial agent is inoculated with, and carries out three grade fermemtation, obtain microbial inoculum;
(2) it uses 300~500 mesh vermiculite powers as adsorbent, is added in mentioned microorganism bacterium solution product, is done by spraying It is dry to get microbial germ powder;
(3) it after the completion of mixing ammonium nitrate, monoammonium phosphate, potassium nitrate, zinc nitrate and boric acid in proportion, then adds humic acid, protect Agent and microbial germ powder are protected, after mixing up to composite microbe fertilizer containing humic acid.
CN201811241913.7A 2018-10-24 2018-10-24 One kind composite microbe fertilizer containing humic acid and preparation method Pending CN109336714A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110055077A (en) * 2019-05-21 2019-07-26 王海斌 A kind of controllable plant growth saves artificial microbial bacterial agent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757292A (en) * 2012-05-17 2012-10-31 新疆农垦科学院农业新技术推广服务中心 Water-soluble microbial multi-element solid fertilizer
CN106966834A (en) * 2017-04-13 2017-07-21 河南骏化发展股份有限公司 A kind of complex microorganism granular fertilizer and preparation method thereof
CN107056513A (en) * 2017-06-27 2017-08-18 山东昆仲知识产权代理有限公司 Microbial bacteria agent and process for producing same
CN108358712A (en) * 2018-05-11 2018-08-03 侯淑璐 A kind of vegetables Water soluble fertilizer and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757292A (en) * 2012-05-17 2012-10-31 新疆农垦科学院农业新技术推广服务中心 Water-soluble microbial multi-element solid fertilizer
CN106966834A (en) * 2017-04-13 2017-07-21 河南骏化发展股份有限公司 A kind of complex microorganism granular fertilizer and preparation method thereof
CN107056513A (en) * 2017-06-27 2017-08-18 山东昆仲知识产权代理有限公司 Microbial bacteria agent and process for producing same
CN108358712A (en) * 2018-05-11 2018-08-03 侯淑璐 A kind of vegetables Water soluble fertilizer and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110055077A (en) * 2019-05-21 2019-07-26 王海斌 A kind of controllable plant growth saves artificial microbial bacterial agent

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