CN109322148A - 毛纺织物用纳米抗皱整理工艺 - Google Patents
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Abstract
本发明公开了一种毛纺织物用纳米抗皱整理工艺,采用纳米SiO2、纳米ZnO的复合粉体和氨基硅酮弹性体JXC‑1,将纳米SiO2、纳米ZnO的复合粉体分散在吐温‑80溶液中,并采用聚丙烯酸钠、六偏磷酸钠来进行纳米SiO2、纳米ZnO的复合粉体的乳化和分散,制成纳米整理液,将毛纺织物净洗后浸泡在整理液中30min,再二浸二轧,轧余率85%,以80℃预烘,然后制备氨基硅酮弹性体JXC‑1整理液,并将织物浸泡在JXC‑1氨基硅酮弹性体整理液中30min,二浸二轧,轧余率75%,以75℃预烘,最后焙烘定型,焙烘温度120℃,焙烘时间2min。本发明利用纳米SiO2和纳米ZnO相复合的技术和纳米材料分散技术开发出针对毛纺织物的纳米抗皱整理剂,其不含甲醛等有害物质,是绿色环保、抗皱效果优良的纳米抗皱整理剂。
Description
技术领域
本发明属于纺织技术领域,特别涉及一种毛纺织物用纳米抗皱整理工艺。
背景技术
早在上个世纪70年代,国内外就针对毛纺织物易皱(其折皱回复角只有 100°—135°)这一弊端做出了一系列的研究,开发出了含甲醛的整理剂,用其整理毛纺织物能得到一定的抗皱功能(其制品的折皱回复角提高在26°以下)。80年代中后期,随着环保和绿色生态浪潮的日益高涨,国内、外均提出了从根本上消除甲醛的要求,无甲醛的环氧树脂抗皱整理剂被开发出来,但其整理的毛纺织物的抗皱效果不好(其制品的折皱回复角提高在23°以下),且手感粗硬,破坏了羊毛织物手感柔软、滑爽、弹性好的优良手感风格。90年代中后期,为了改善环氧树脂抗皱整理剂的缺点,开发出了水性聚氨酯抗皱整理剂,其整理的毛纺织物的手感有所改善,抗皱效果有所提高(其织物的折皱回复角提高在25°以下),但其抗皱效果不稳定,水洗50次后抗皱效果大幅降低(其织物的折皱回复角提高在19°以下),不能较好地满足国内外对抗皱毛纺织物的要求。开发出抗皱性能好、手感风格优良且绿色、环保、生产成本低的抗皱毛纺织物便成了国内外毛纺织行业急需解决的“共性技术问题”。
公告号CN 101575805纳米真丝抗皱针织服装的生产工艺中,其是采用纳米 SiO2和氨基硅酮弹性体JXC-1,将粒度为20nm至30nm的纳米SiO2分散在吐温-80溶剂中,并采用聚丙烯酸钠、六偏磷酸钠来进行纳米SiO2的乳化和分散,制成纳米整理液,将针织服装浸泡在纳米整理液中,后脱水烘干,使纳米SiO2牢固地吸附到织物内,然后制备氨基硅酮弹性体JXC-1整理液,并将针织服装浸泡在氨基硅酮弹性体JXC-1整理液中,再脱水烘干针织服装,使氨基硅酮弹性体JXC-1与针织服装充分反应并在针织服装表面形成稳定的弹性膜。该发明整理的真丝针织服装具有良好的抗皱效果,原真丝针织物的折皱回复角为 168°,按本发明整理后,其真丝针织物的折皱回复角为242°,提高了74°;水洗50次后的折皱回复角为236°,提高了68°,同时保持了织物的原有风格。但其只适用于真丝针织物,对毛纺针织物的抗皱效果不佳。
发明内容
本发明的目的是在纳米真丝抗皱针织服装的生产工艺的基础上,研发适合毛纺织物用纳米抗皱整理工艺,采用此工艺能够生产出具有优良抗皱性能(其折皱回复角提高在37°以上)、手感风格优良、不含对人体有害的物质、卫生、环保的抗皱毛纺织制品。
为了实现本发明的目的,采用的技术方案是:
一种毛纺织物用纳米抗皱整理工艺,采用粒径为100nm以内的纳米SiO2、纳米ZnO的复合粉体和氨基硅酮弹性体JXC-1,将纳米SiO2、纳米ZnO的复合粉体分散在吐温-80溶液中,并采用聚丙烯酸钠、六偏磷酸钠来进行纳米SiO2、纳米ZnO的复合粉体的乳化和分散,制成纳米整理液,将毛纺织物净洗后浸泡在整理液中30min,再在整理浸轧机上进行二浸二轧地浸泡纳米抗皱整理液,轧余率85%,以80℃预烘,使纳米SiO2、纳米ZnO牢固地吸附到毛纺织物内,然后制备氨基硅酮弹性体JXC-1整理液,并将织物浸泡在JXC-1氨基硅酮弹性体整理液中30min,二浸二轧,速度为1.5m/s,轧余率75%,以75℃预烘,最后焙烘定型,焙烘温度120℃,焙烘时间2min。
进一步,所述纳米抗皱粉体中的纳米SiO2与纳米ZnO的质量比为0—10:0 —10。
进一步,所述纳米抗皱粉体中的纳米SiO2与纳米ZnO的质量比优选为8:2。
进一步,所述纳米SiO2和纳米ZnO复合粉体的用量(o.w.f)为0.7%,JXC-1 氨基硅酮弹性体用量(o.w.f)为12%。
进一步,聚丙烯酸钠、六偏磷酸钠、吐温-80与纳米SiO2、纳米ZnO复合粉体的用量之比为2:1:1:1。
本发明采用纳米复合技术,生产出了粒径为100nm以内,颗粒均匀、球体状、分散性好、团聚少,以纳米SiO2与纳米ZnO相复合的纳米抗皱粉体,此纳米抗皱粉体材料具有优良的抗皱性能;在此纳米抗皱粉体中加入吐温-80、聚丙烯酸钠、六偏磷酸钠等将其制成了纳米抗皱粉体分散均匀、体系稳定的纳米抗皱整理剂,此整理剂可用于各类毛纺织面料的抗皱整理。
在羊毛纺织物的抗皱整理方面,纳米SiO2与纳米ZnO的有效复合能很好地形成“二元协同纳米界面”,其有效的利用分子以上层次的化学键力和利用外场(光场、磁场、电场等等)诱导下的非平衡态的协同效应为前提,在材料的宏观表面建造二元协同纳米界面结构,从而创造出二元协同纳米界面超双亲、超双疏技术,在织物表面会形成纳米尺寸效应,形成一层稳定的、纳米级的空气层。使羊毛织物中的羊毛蛋白质大分子之间的盐式键、氢键、范德华力等分子间作用力不易被破坏,从而提高羊毛织物的大分子链段间的作用力,提高其抗皱性能。超双疏技术的最大优势在于能在织物表面形成犹如荷叶的疏水功能,不仅能保持原织物的特性与特征,如透气、透湿等,更不会在加工成衣的过程中出现任何的改变与损害。
另一方面,纳米SiO2与纳米ZnO的有效复合具有很强的催化作用,纳米粉体在织物抗皱整理方面的催化为多相催化反应,反应在纳米微粒表面进行,其反应速率取决于纳米材料的比表面积、表面缺陷和电子结构。纳米微粒催化特性与其表面效应有关:粒径减小,比表面积骤增,表面原子数增多,表面原子周围缺少配位的相邻原子,造成表面缺陷留有大量悬空键,容易与其它原子结合,会形成活泼的自由基,这就是其化学活性的源头。这些自由基会与羊毛纤维的—NH2、—COOH发生交联反应,从而可以提高织物的折皱回复性。在羊毛纳米抗皱整理过程中,一般是在上述两个方面的共同作用下进行的。
毛纺织面料抗皱整理工艺中,纳米SiO2和纳米ZnO复合粉体的最佳分散工艺为:聚丙烯酸钠、六偏磷酸钠、吐温-80用量与纳米SiO2和纳米ZnO复合粉体用量之比为2:1:1:1;分散方法为剪切乳化分散法和超声波分散法,剪切乳化时间30min,转速3000rpm,超声时间5min,功率1000W。
本发明具有的有益效果:
1、本发明利用纳米SiO2和纳米ZnO相复合的技术和纳米材料分散技术开发出针对毛纺织物的纳米抗皱整理剂,其不含甲醛等有害物质,是绿色环保、抗皱效果优良的纳米抗皱整理剂。
2、本发明具有优良的抗皱性能,其折皱回复角提高在37°以上,其克服了国内外传统抗皱毛纺织物抗皱性能差(其折皱回复角提高在26°以下)并具有释放出游离的甲醛、织物手感粗硬、生产成本高等缺陷。
附图说明
图1为本发明的织物表面的纳米形貌示意图;
图2为本发明的纤维表面的纳米形貌示意图。
具体实施方式
下面结合实施例对本发明作进一步描述,但本发明的保护范围不仅仅局限于实施例。
1、配制纳米整理剂
1)将称好的纳米SiO2、纳米ZnO复合粉体倒入容器中;
2)向容器中加水后,搅拌,制成稀溶液;
3)向容器中加吐温-80、聚丙烯酸钠、六偏磷酸钠并不停地搅拌;
4)再加入适量的水,稀释溶液后,放在乳化机上以备充分乳化;
5)分散乳化,方法为剪切乳化分散法或超声波分散法,剪切乳化时间30min,转速3000rpm,超声时间5min,功率1000W。
2、毛纺织面料的制备
根据制备的面料为毛精纺面料、毛半精纺面料、毛粗纺面料或毛针织面料来进行毛纤维的选配,然后在对毛纤维按照工艺要求进行染色,染色后的毛纤维在充分分梳的基础上,按照适宜的制条工艺制备毛条,然后由毛条进行粗纱和细纱的纺纱工作,接着在织机(机织机和针织机)上将细纱织造成毛织品坯布,然后对毛织品坯布进行后整理,得到成品毛纺织面料。
3、物理吸附
将乳化好的纳米整理液倒入较大容器中,按1∶10(织物重量∶整理液重量)配成整理液,并保持水温30±2℃,搅拌均匀,加入需要整理的服装,要求所有服装都没入浸泡液中,浸泡30min,再在整理浸轧机上进行二浸二轧地浸泡纳米抗皱整理液,轧余率85%,以80℃预烘,按正常的烘干工艺进行。
4、配制氨基硅酮弹性体JXC-1整理剂
(1)量取规定体积的氨基硅酮弹性体JXC-1,并倒入容器中;
(2)向容器中加水后,搅拌,制成稀溶液;
(3)将氨基硅酮弹性体JXC-1稀溶液倒入较大容器中,按1∶10(织物重量∶整理液重量)配成整理液并搅拌均匀。
5、浸泡氨基硅酮弹性体JXC-1整理剂
将需要整理的服装全部没入浸泡液中,搅拌均匀,浴比1:10,保持水温30 ±2℃,浸泡30min,再在整理浸轧机上进行二浸二轧地浸泡纳米抗皱整理液,轧余率75%,以75℃预烘,最后焙烘定型,焙烘温度120℃,焙烘时间2min,按正常的烘干工艺进行。
其中,纳米SiO2和纳米ZnO复合粉体的用量(o.w.f)为0.7%,JXC-1氨基硅酮弹性体用量(o.w.f)为12%。它们对毛织物折皱回复性能的显著性影响顺序为:纳米SiO2用量>JXC-1氨基硅酮弹性体用量>焙烘温度>焙烘时间。
通过系统研究,采用纳米复合技术,选择纳米SiO2和纳米ZnO的质量比分别为10:0、8:2、6:4、5:5、3:7和0:10进行复合,然后对毛纺织面料进行抗皱整理。结果表明,织物折皱回复角提高度数分别为32.44°、37.11°、28.77°、 30.11°、25.16°和23.49°。可以看出,纳米SiO2和纳米ZnO按照8:2的复合比例,其织物的折皱回复角提高度数(37.11°)最大,其是最佳的毛织物抗皱整理纳米材料。
在批量生产出高质量的毛精纺面料和毛半精纺面料的基础上,采用本发明的纳米抗皱整理工艺,生产出的抗皱性能优良的纳米抗皱的毛精纺面料和毛半精纺面料制品,其成品折皱回复角提高前者在37°以上,后者在38°以上;洗涤50次后,折皱回复角提高在35°以上。
在批量生产出高质量的毛粗纺面料和毛针织面料的基础上,采用本发明的纳米抗皱整理工艺,生产出抗皱性能优良的纳米抗皱毛粗纺面料和毛针织面料制品,其成品折皱回复角提高前者在39°以上,后者在40°以上;洗涤50次后,折皱回复角提高在36°以上。
对纳米抗皱整理后的毛精纺制品进行电镜拍照,图1所示为将纳米抗皱整理后织物的表面放大3000倍后的照片,图2所示为将某一根纤维放大到5420 倍后得到的照片。由图1和图2可知,纳米抗皱粉体在毛精纺面料和毛纤维上均分布较均匀,团聚较少,其能充分发挥纳米抗皱粉体的抗皱功能。
此抗皱整理后的毛精纺面料制品经陕西省纺织产品质量检验测试中心按照国家标准(GB/T3819-1997、GB/T3923.1-2013、GB/T3917.2-2009等)对抗皱整理后的毛精纺制品和未进行抗皱整理的毛精纺制品(原样)进行了性能测试,测试得到抗皱整理后织物与原样的折皱回复角分别为166°和128°,抗皱整理后织物与原样水洗50次后的折皱回复角分别为150°和113°;抗皱整理后织物的折皱回复角相对于原样提高为38°,经50次水洗后,其折皱回复角相对于原样仍可提高37°;抗皱整理后织物的断裂强力、撕破强力、色牢度等指标与原样基本相同,均不含甲醛等有害物质,达到了预期的效果。
本发明开发出的纳米抗皱毛精纺面料取得了优良的抗皱效果,其制成的服装产品进行了试穿工作,试穿人员对此纳米抗皱服装产品给予了很好的肯定,此纳米抗皱毛精纺面料制成的服装抗皱性能与传统毛精纺面料的服装相比抗皱性能大幅提高,并且保持了手感柔顺、滑爽的优良风格,纳米抗皱毛精纺制品的可靠性、耐久性、安全性均符合国家要求。
本发明克服了国内外传统抗皱毛纺织制品抗皱性能差、释放出游离的甲醛、织物手感粗硬、生产成本高等缺陷,其成果是国际上羊毛纺织制品抗皱技术的重大突破,将使我国在抗皱毛纺织制品的生产技术上处于国际先进水平,使我国毛纺织制品在国际市场上具有很强的核心竞争力。
最后应说明的是:以上实施例仅用以说明本发明而并非限制本发明所描述的技术方案;因此,尽管本说明书参照上述的各个实施例对本发明已进行了详细的说明,但是,本领域的普通技术人员应当理解,仍然可以对本发明进行修改或等同替换;而一切不脱离本发明的精神和范围的技术方案的改进,其均应涵盖在本发明的权利要求范围中。
Claims (5)
1.一种毛纺织物用纳米抗皱整理工艺,其特征在于,采用粒径为100nm 以内的纳米SiO2、纳米ZnO的复合粉体和氨基硅酮弹性体JXC-1,将纳米SiO2、纳米ZnO的复合粉体分散在吐温-80溶液中,并采用聚丙烯酸钠、六偏磷酸钠来进行纳米SiO2、纳米ZnO的复合粉体的乳化和分散,制成纳米整理液,将毛纺织物净洗后浸泡在整理液中30min,再二浸二轧,轧余率85%,以80℃预烘,使纳米SiO2、纳米ZnO牢固地吸附到毛纺织物内,然后制备氨基硅酮弹性体JXC-1整理液,并将织物浸泡在JXC-1氨基硅酮弹性体整理液中30min,二浸二轧,轧余率75%,以75℃预烘,最后焙烘定型,焙烘温度120℃,焙烘时间 2min。
2.根据权利要求1所述的毛纺织物用纳米抗皱整理工艺,其特征在于,所述纳米抗皱粉体中的纳米SiO2 与纳米ZnO 的质量比为0—10:0—10。
3.根据权利要求2所述的毛纺织物用纳米抗皱整理工艺,其特征在于,所述纳米抗皱粉体中的纳米SiO2 与纳米ZnO 的质量比优选为8:2。
4.根据权利要求1所述的毛纺织物用纳米抗皱整理工艺,其特征在于,所述纳米SiO2和纳米ZnO复合粉体的用量(o.w.f)为0.7%,JXC-1氨基硅酮弹性体用量(o.w.f)为12%。
5.根据权利要求1所述的毛纺织物用纳米抗皱整理工艺,其特征在于,聚丙烯酸钠、六偏磷酸钠、吐温-80与纳米SiO2、纳米ZnO复合粉体的用量之比为2:1:1:1。
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110924145A (zh) * | 2019-12-11 | 2020-03-27 | 苏州经贸职业技术学院 | 一种棉麻织物环保防皱功能剂的制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08209538A (ja) * | 1995-01-27 | 1996-08-13 | Nobutaka Ono | セルロース繊維布帛の防皺処理法 |
CN1558020A (zh) * | 2004-01-19 | 2004-12-29 | 品德羊毛(太原)有限公司 | 毛绒表面钠米处理工艺 |
CN101575805A (zh) * | 2009-03-05 | 2009-11-11 | 浙江新阳服饰股份有限公司 | 一种纳米真丝抗皱针织服装的生产工艺 |
CN103572588A (zh) * | 2013-10-30 | 2014-02-12 | 东华大学 | 一种纳米材料增强棉织物抗皱整理液及其应用 |
CN103668941A (zh) * | 2013-11-06 | 2014-03-26 | 天津工业大学 | 一种兔毛纺织品抗静电纳米整理剂及整理工艺 |
-
2018
- 2018-09-11 CN CN201811057512.6A patent/CN109322148B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08209538A (ja) * | 1995-01-27 | 1996-08-13 | Nobutaka Ono | セルロース繊維布帛の防皺処理法 |
CN1558020A (zh) * | 2004-01-19 | 2004-12-29 | 品德羊毛(太原)有限公司 | 毛绒表面钠米处理工艺 |
CN101575805A (zh) * | 2009-03-05 | 2009-11-11 | 浙江新阳服饰股份有限公司 | 一种纳米真丝抗皱针织服装的生产工艺 |
CN103572588A (zh) * | 2013-10-30 | 2014-02-12 | 东华大学 | 一种纳米材料增强棉织物抗皱整理液及其应用 |
CN103668941A (zh) * | 2013-11-06 | 2014-03-26 | 天津工业大学 | 一种兔毛纺织品抗静电纳米整理剂及整理工艺 |
Non-Patent Citations (2)
Title |
---|
周瑞发等: "《纳米材料技术》", 31 July 2003 * |
王花会等: "纯棉针织物纳米氧化锌抗皱整理研究", 《针织工业》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110924145A (zh) * | 2019-12-11 | 2020-03-27 | 苏州经贸职业技术学院 | 一种棉麻织物环保防皱功能剂的制备方法 |
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