CN109321124A - A kind of flexible real stone paint - Google Patents

A kind of flexible real stone paint Download PDF

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Publication number
CN109321124A
CN109321124A CN201811039626.8A CN201811039626A CN109321124A CN 109321124 A CN109321124 A CN 109321124A CN 201811039626 A CN201811039626 A CN 201811039626A CN 109321124 A CN109321124 A CN 109321124A
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China
Prior art keywords
parts
agent
stone paint
real stone
cosolvent
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Pending
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CN201811039626.8A
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Chinese (zh)
Inventor
王四九
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Jiangsu Jiunuo Building Materials Polytron Technologies Inc
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Jiangsu Jiunuo Building Materials Polytron Technologies Inc
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Priority to CN201811039626.8A priority Critical patent/CN109321124A/en
Publication of CN109321124A publication Critical patent/CN109321124A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention relates to exterior wall surface decorative field of material technology, especially a kind of flexible real stone paint;70-80 parts of quartz sand, 15-20 parts of polyurethane-modified acrylic acid lotion, 0.08-0.15 parts of defoaming agent, 0.1-0.15 parts of wetting agent, 0.12-0.16 parts of sterilization antiseptic, 0.06-0.08 parts of auxiliary rheological agents, 0.38-0.42 parts of cosolvent, 2.4-2.8 parts of organosilicon moisture repellent, 20-40 parts of water;Outer wall flexible lacquer of the invention selects polyurethane-modified acrylic acid lotion, and it is equipped with auxiliary rheological agents and cosolvent, making lacquer of the invention not only has decorative effect and water resistance as excellent lithotome, also there is excellent weatherability and flexibility simultaneously, it can effectively ensure that it will not be because internal movement leads to coating cracking in construction, and quick dry agent is added in being formulated, it is easily dried lacquer, further improve the water resistance of lacquer, finally mixed with natural colour sand according to a certain amount of ratio, impart the adhesive force of product of the present invention brilliance, it is effectively improved the drop rate of lacquer.

Description

A kind of flexible real stone paint
Technical field
The present invention relates to exterior wall surface decorative field of material technology, especially a kind of flexible real stone paint.
Background technique
Lacquer is the coating that a kind of decorative effect exactly likes marble, granite.The main natural stone for using various colors Powder is formulated, applied to the imitation stone effect of external wall, therefore also known as liquid stone.
Building after lacquer finishing has natural true natural colour, gives graceful, harmonious, serious beauty Sense, is suitable for the indoor and outdoor decoration of all kinds of buildings.Especially decorated on curved-surface building object, it is vivid, there is a kind of recurrence Natural effect.Lacquer has fire prevention, waterproof, acid and alkali-resistance, anti-pollution.It is nontoxic, tasteless, bonding force is strong, will never fade equal spies Point, can effectively stop extraneous adverse circumstances to building corrode, extend the service life of building, due to lacquer have it is good Adhesive force and freeze-thaw resistance property, therefore be suitble to use in cold district.
Polymer emulsion used in lacquer general at present is mostly the styrene-acrylic emulsion of high glass transition temperature, film after film forming Under low temperature and with the passing of time intensity is high, but relative toughness is inadequate, has brittleness tendency after use, there is after by the impact of base's stress repetition The risk of freezing up cracking is especially embodied in cold region significant with the temperature difference.In addition, the compact in paint film of lacquer is poor, it is mechanical Hole is big, and flexible Glass Transition Temperature of Latex is low, and stain resistance is poor.Therefore it is good that a kind of flexible protrusion, splitting resistance are provided, while again Have both excellent flexible real stone paint of water-fast weather-proof contaminated resistance and preparation method thereof oneself become when business urgently.Summary of the invention
The object of the present invention is to provide a kind of toughness by force, paint film is not easy to crack, flexible real stone paint with long service life.
In order to solve the above technical problems, The technical solution adopted by the invention is as follows:
A kind of flexible real stone paint, mass parts composition are as follows: 70-80 parts of quartz sand, polyurethane-modified acrylic acid lotion 15-20 Part, 0.08-0.15 parts of defoaming agent, 0.1-0.15 parts of wetting agent, 0.12-0.16 parts of sterilization antiseptic, auxiliary rheological agents 0.06-0.08 Part, 0.38-0.42 parts of cosolvent, 2.4-2.8 parts of organosilicon moisture repellent, 20-40 parts of water.
Further, the mass parts composition of the defoaming agent is as follows: 10-15 parts of methyl silicone oil, sodium tripolyphosphate 10- 12 parts, 72-76 parts of salt, 6-8 parts of mannitol, 3-5 parts of silica, the defoaming agent the preparation method is as follows: (1) in room temperature It is lower to mix methyl silicone oil and silica, mixture is obtained, (2) are by the sodium tripolyphosphate, mannitol, salt etc. of crushing Then mixing stirs evenly in the mixture in step (1) points, obtains defoaming agent.
Further, the wetting agent is total to modified polyorganosiloxanes, polyoxyethylene alkylphenol using organic fluoro- polyethers Ether, polyoxyethylene aliphatic alcohol ether, one of polyoxyethylene polyoxypropylene block copolymer.
Further, the sterilization antiseptic selects l, 2- benzisothiazole-3-ketone, the different thiophene of 5- chloro-2-methyl -4- One of the mixture of-3 -one of oxazoline and 2- methyl 4- isothiazoline 3- ketone.
Further, the auxiliary rheological agents select polyamide wax powder auxiliary rheological agents, active castor oil organic derivative, castor One of sesame oil organic derivative.
Further, the cosolvent is ethylene glycol.
Further, mass parts composition it is as follows: 72-78 parts of quartz sand, 16-18 parts of polyurethane-modified acrylic acid lotion, 0.12-0.14 parts of defoaming agent, 0.12-0.14 parts of wetting agent, 0.13-0.15 parts of sterilization antiseptic, auxiliary rheological agents 0.06-0.08 Part, 0.38-0.4 parts of cosolvent, 2.5-2.6 parts of organosilicon moisture repellent, 24-36 parts of water.
Further, mass parts composition is as follows: 75 parts of quartz sand, 18 parts of polyurethane-modified acrylic acid lotion, defoaming agent 0.12 part, 0.14 part of wetting agent, 0.14 part of sterilization antiseptic, 0.07 part of auxiliary rheological agents, 0.4 part of cosolvent, organosilicon moisture repellent 2.5 parts, 30 parts of water.
It is using the beneficial effect of technical solution of the present invention:
Outer wall flexible lacquer of the invention selects polyurethane-modified acrylic acid lotion, and is equipped with auxiliary rheological agents and cosolvent, makes Lacquer of the invention not only has decorative effect and water resistance as excellent lithotome, also while having excellent weatherability And flexibility, it can effectively ensure that it will not lead to coating cracking in construction because of internal movement, and be added in formula fast Dry agent, is easily dried lacquer, further improves the water resistance of lacquer, finally and natural colour sand is according to a certain amount of ratio Example mixing, imparts the adhesive force of product of the present invention brilliance, is effectively improved the drop rate of lacquer.
Specific embodiment
The following examples can make those skilled in the art that the present invention be more fully understood, but these embodiments are not Limiting the scope of the invention." one embodiment " or " embodiment " referred to herein, which refers to, may be included in the present invention at least A particular feature, structure, or characteristic in one implementation.In the present specification different places occur " in one embodiment In " the same embodiment not is referred both to, nor the individual or selective embodiment mutually exclusive with other embodiments.
Embodiment 1
A kind of flexible real stone paint, mass parts composition are as follows: 70 parts of quartz sand, 15 parts of polyurethane-modified acrylic acid lotion, defoaming 0.08 part of agent, 0.1 part of wetting agent, 0.12 part of sterilization antiseptic, 0.06 part of auxiliary rheological agents, 0.38 part of cosolvent, organosilicon hydrophobic 2.4 parts of agent, 20 parts of water.
Wherein, defoaming agent mass parts composition it is as follows: 10 parts of methyl silicone oil, 10 parts of sodium tripolyphosphate, 72 parts of salt, 6 parts of mannitol, 3 parts of silica, defoaming agent the preparation method is as follows: (1) at room temperature by methyl silicone oil and titanium dioxide Silicon mixes, and obtains mixture, and (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then with it is mixed in step (1) It closes to divide in object and stir evenly, obtain defoaming agent.
Wherein, wetting agent is total to modified polyorganosiloxanes using organic fluoro- polyethers.
Wherein, sterilization antiseptic selects l, 2- benzisothiazole-3-ketone.
Wherein, auxiliary rheological agents select polyamide wax powder auxiliary rheological agents.
Wherein, cosolvent is ethylene glycol.
Embodiment 2
A kind of flexible real stone paint, mass parts composition are as follows: 72 parts of quartz sand, 16 parts of polyurethane-modified acrylic acid lotion, defoaming 0.12 part of agent, 0.12 part of wetting agent, 0.13 part of sterilization antiseptic, 0.06 part of auxiliary rheological agents, 0.38 part of cosolvent, organosilicon hydrophobic 2.5 parts of agent, 24 parts of water.
Wherein, defoaming agent mass parts composition it is as follows: 12 parts of methyl silicone oil, 11 parts of sodium tripolyphosphate, 74 parts of salt, 7 parts of mannitol, 4 parts of silica, the defoaming agent the preparation method is as follows: (1) at room temperature by methyl silicone oil and two Silica mixes, and obtains mixture, and (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then and in step (1) Mixture in point stir evenly, obtain defoaming agent.
Wherein, wetting agent uses polyoxyethylated alkyl phenol.
Wherein, sterilization antiseptic selects-3 -one of 5- chloro-2-methyl-4- isothiazoline and 2- methyl 4- isothiazoline 3- ketone The mixture of composition is mixed in any proportion.
Wherein, auxiliary rheological agents select active castor oil organic derivative.
Wherein, cosolvent is ethylene glycol.
Embodiment 3
A kind of flexible real stone paint, mass parts composition are as follows: 75 parts of quartz sand, 18 parts of polyurethane-modified acrylic acid lotion, defoaming 0.12 part of agent, 0.14 part of wetting agent, 0.14 part of sterilization antiseptic, 0.07 part of auxiliary rheological agents, 0.4 part of cosolvent, organosilicon hydrophobic 2.5 parts of agent, 30 parts of water.
Wherein, defoaming agent mass parts composition it is as follows: 12 parts of methyl silicone oil, 11 parts of sodium tripolyphosphate, 74 parts of salt, 7 parts of mannitol, 4 parts of silica, the defoaming agent the preparation method is as follows: (1) at room temperature by methyl silicone oil and two Silica mixes, and obtains mixture, and (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then and in step (1) Mixture in point stir evenly, obtain defoaming agent.
Wherein, wetting agent is total to modified polyorganosiloxanes, polyoxyethylated alkyl phenol, polyoxy second using organic fluoro- polyethers Alkene fatty alcohol ether, one of polyoxyethylene polyoxypropylene block copolymer.
Wherein, sterilization antiseptic selects l, 2- benzisothiazole-3-ketone.
Wherein, auxiliary rheological agents select castor oil organic derivative.
Wherein, cosolvent is ethylene glycol.
Embodiment 4
A kind of flexible real stone paint, mass parts composition are as follows: 78 parts of quartz sand, 18 parts of polyurethane-modified acrylic acid lotion, defoaming 0.14 part of agent, 0.14 part of wetting agent, 0.15 part of sterilization antiseptic, 0.08 part of auxiliary rheological agents, 0.4 part of cosolvent, organosilicon hydrophobic 2.6 parts of agent, 36 parts of water.
Wherein, defoaming agent mass parts composition it is as follows: 15 parts of methyl silicone oil, 12 parts of sodium tripolyphosphate, 76 parts of salt, 8 parts of mannitol, 5 parts of silica, the defoaming agent the preparation method is as follows: (1) at room temperature by methyl silicone oil and two Silica mixes, and obtains mixture, and (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then and in step (1) Mixture in point stir evenly, obtain defoaming agent.
Wherein, wetting agent, which uses, polyoxyethylene polyoxypropylene block copolymer.
Wherein, sterilization antiseptic selects l, 2- benzisothiazole-3-ketone.
Wherein, auxiliary rheological agents select polyamide wax powder auxiliary rheological agents.
Wherein, cosolvent is ethylene glycol.
Embodiment 5
A kind of flexible real stone paint, mass parts composition are as follows: 80 parts of quartz sand, 20 parts of polyurethane-modified acrylic acid lotion, defoaming 0.15 part of agent, 0.15 part of wetting agent, 0.16 part of sterilization antiseptic, 0.08 part of auxiliary rheological agents, 0.42 part of cosolvent, organosilicon hydrophobic 2.8 parts of agent, 40 parts of water.
Wherein, defoaming agent mass parts composition it is as follows: 15 parts of methyl silicone oil, 12 parts of sodium tripolyphosphate, 76 parts of salt, 8 parts of mannitol, 5 parts of silica, the defoaming agent the preparation method is as follows: (1) at room temperature by methyl silicone oil and two Silica mixes, and obtains mixture, and (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then and in step (1) Mixture in point stir evenly, obtain defoaming agent.
Wherein, wetting agent is total to modified polyorganosiloxanes using organic fluoro- polyethers.
Wherein, sterilization antiseptic selects l, 2- benzisothiazole-3-ketone.
Wherein, the mass parts composition of auxiliary rheological agents is as follows: polyamide wax powder auxiliary rheological agents.
Wherein, cosolvent is ethylene glycol.
Embodiment 6
Itself the difference from embodiment 1 is that: sterilization antiseptic is using common commercially available fungicide.
Embodiment 7
Itself the difference from example 2 is that: it does not include organosilicon moisture repellent.
Embodiment 8
The difference of itself and embodiment 3 is: its sterilization antiseptic used is common commercially available sterilization antiseptic.
Embodiment 9
The difference of itself and embodiment 4 is: it does not include organosilicon moisture repellent.
Embodiment 10
Prior art products.
Flexible real stone paint in embodiment 1-9 is made using the conventional method in industry.
The performance detection detection of embodiment 1-10 see the table below.
Detection project Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8 Embodiment 9 Embodiment 10
Initial dry cracking resistance Flawless Flawless Flawless Flawless Flawless There is crackle There is crackle There is crackle There is crackle Slight crackle
Flexible (diameter 50mm) Flawless Flawless Flawless Flawless Flawless There is crackle There is crackle There is crackle There is crackle Slight crackle
Weatherability (96h) It is excellent It is excellent It is excellent It is excellent It is excellent Generally Generally Generally Generally Generally
Alkali resistance (96h) It is without exception It is without exception It is without exception It is without exception It is without exception Generally Generally Generally Generally Generally
Water resistance (96h) It is without exception It is without exception It is without exception It is without exception It is without exception Generally Generally Generally Generally Generally
Standard state viscosity intensity (MPa) 1.21 1.16 1.20 1.25 1.18 0.72 0.75 0.39 0.73 0.8
Adhesion It is excellent It is excellent It is excellent It is excellent It is excellent Generally Generally Generally Generally Generally
Thermal storage stability It is without exception It is without exception It is without exception It is without exception It is without exception There is agglomeration There is agglomeration There is agglomeration There is agglomeration There is slight agglomeration
Low tempertaure storage stability It is without exception It is without exception It is without exception It is without exception It is without exception There is agglomeration There is agglomeration There is agglomeration There is agglomeration There is slight agglomeration
From the test result of above-described embodiment: a kind of flexible real stone paint prepared by the present invention has certain flexibility, It can effectively prevent cracking, but also have excellent water resistance, weatherability and excellent adhesive force.
Those skilled in the art it should be appreciated that, the purpose of the application is: outer wall flexible of the invention Lacquer selects polyurethane-modified acrylic acid lotion, and is equipped with auxiliary rheological agents and cosolvent, has lacquer of the invention not only There are decorative effect and water resistance as excellent lithotome, also while there is excellent weatherability and flexibility, can effectively ensure that It will not lead to coating cracking in construction because of internal movement, and be added to quick dry agent in formula, and lacquer is made to be easy to dry It is dry, the water resistance of lacquer is further improved, is finally mixed with natural colour sand according to a certain amount of ratio, imparts the present invention The adhesive force of product brilliance is effectively improved the drop rate of lacquer.
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.It is all in essence of the invention Within mind and principle, any modification, equivalent substitution, improvement and etc. done be should all be included in the protection scope of the present invention.This The technical scope of item invention is not limited to the contents of the specification, it is necessary to its technology is determined according to scope of the claims Property range.

Claims (8)

1. a kind of flexible real stone paint, it is characterised in that: its mass parts composition is as follows: 70-80 parts of quartz sand, polyurethane-modified propylene 15-20 parts of yogurt liquid, 0.08-0.15 parts of defoaming agent, 0.1-0.15 parts of wetting agent, 0.12-0.16 parts of sterilization antiseptic, rheology help 0.06-0.08 parts of agent, 0.38-0.42 parts of cosolvent, 2.4-2.8 parts of organosilicon moisture repellent, 20-40 parts of water.
2. a kind of flexible real stone paint according to claim 1, it is characterised in that: the mass parts composition of the defoaming agent is such as Under: 10-15 parts of methyl silicone oil, 10-12 parts of sodium tripolyphosphate, 72-76 parts of salt, 6-8 parts of mannitol, silica 3-5 Part, the defoaming agent the preparation method is as follows: (1) at room temperature mixes methyl silicone oil and silica, mixed Object, (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then stir evenly, obtain in the mixture in step (1) points To defoaming agent.
3. a kind of flexible real stone paint according to claim 1, it is characterised in that: the wetting agent uses organic fluoro- polyethers Modified polyorganosiloxanes, polyoxyethylated alkyl phenol altogether, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block copolymerization One of object.
4. a kind of flexible real stone paint according to claim 1, it is characterised in that: the sterilization antiseptic selects l, 2- benzene And in the mixture of isothiazoline-3- ketone ,-3 -one of 5- chloro-2-methyl-4- isothiazoline and 2- methyl 4- isothiazoline 3- ketone One kind.
5. a kind of flexible real stone paint according to claim 1, it is characterised in that: the auxiliary rheological agents select polyamide wax powder One of body auxiliary rheological agents, active castor oil organic derivative, castor oil organic derivative.
6. a kind of flexible real stone paint according to claim 1, it is characterised in that: the cosolvent is ethylene glycol.
7. a kind of flexible real stone paint according to claim 1, it is characterised in that: its mass parts composition is as follows: quartz sand 72- 78 parts, 16-18 parts of polyurethane-modified acrylic acid lotion, 0.12-0.14 parts of defoaming agent, 0.12-0.14 parts of wetting agent, sterilization and anticorrosion 0.13-0.15 parts of agent, 0.06-0.08 parts of auxiliary rheological agents, 0.38-0.4 parts of cosolvent, 2.5-2.6 parts of organosilicon moisture repellent, water 24-36 parts.
8. a kind of flexible real stone paint according to claim 7, it is characterised in that: its mass parts composition is as follows: quartz sand 75 Part, 18 parts of polyurethane-modified acrylic acid lotion, 0.12 part of defoaming agent, 0.14 part of wetting agent, 0.14 part of sterilization antiseptic, rheology help 0.07 part of agent, 0.4 part of cosolvent, 2.5 parts of organosilicon moisture repellent, 30 parts of water.
CN201811039626.8A 2018-09-06 2018-09-06 A kind of flexible real stone paint Pending CN109321124A (en)

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Application Number Priority Date Filing Date Title
CN201811039626.8A CN109321124A (en) 2018-09-06 2018-09-06 A kind of flexible real stone paint

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111234686A (en) * 2020-03-10 2020-06-05 浙江华德新材料有限公司 Self-crosslinking acrylic polyurethane dispersion stone-like paint and preparation method thereof
CN111892871A (en) * 2020-07-17 2020-11-06 广东福莱特建筑材料有限公司 High-toughness anti-crack rock slice paint and preparation method thereof
CN112608626A (en) * 2020-12-01 2021-04-06 安徽科创美涂料科技股份有限公司 Waterborne polyurethane-polyacrylic acid-based self-repairing real stone paint and preparation method thereof
CN113683948A (en) * 2021-07-30 2021-11-23 安徽众雁涂料有限公司 Production method of wind-crack-resistant and impact-resistant stone-like paint
CN115491096A (en) * 2022-09-21 2022-12-20 浙江建工装饰材料有限公司 Anti-cracking stone-like paint and construction process thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602197A (en) * 2013-11-29 2014-02-26 江门市华石涂料有限公司 Stone-like paint and preparation method thereof
CN105621959A (en) * 2015-12-18 2016-06-01 三棵树涂料股份有限公司 Flexible true stone paint and preparation method thereof
CN106669237A (en) * 2016-12-14 2017-05-17 东至绿洲环保化工有限公司 Organic silicon defoamer containing sodium tripolyphosphate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602197A (en) * 2013-11-29 2014-02-26 江门市华石涂料有限公司 Stone-like paint and preparation method thereof
CN105621959A (en) * 2015-12-18 2016-06-01 三棵树涂料股份有限公司 Flexible true stone paint and preparation method thereof
CN106669237A (en) * 2016-12-14 2017-05-17 东至绿洲环保化工有限公司 Organic silicon defoamer containing sodium tripolyphosphate

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111234686A (en) * 2020-03-10 2020-06-05 浙江华德新材料有限公司 Self-crosslinking acrylic polyurethane dispersion stone-like paint and preparation method thereof
CN111892871A (en) * 2020-07-17 2020-11-06 广东福莱特建筑材料有限公司 High-toughness anti-crack rock slice paint and preparation method thereof
CN112608626A (en) * 2020-12-01 2021-04-06 安徽科创美涂料科技股份有限公司 Waterborne polyurethane-polyacrylic acid-based self-repairing real stone paint and preparation method thereof
CN113683948A (en) * 2021-07-30 2021-11-23 安徽众雁涂料有限公司 Production method of wind-crack-resistant and impact-resistant stone-like paint
CN113683948B (en) * 2021-07-30 2022-10-11 安徽众雁涂料有限公司 Production method of anti-wind-crack impact-resistant real stone paint
CN115491096A (en) * 2022-09-21 2022-12-20 浙江建工装饰材料有限公司 Anti-cracking stone-like paint and construction process thereof

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Application publication date: 20190212