CN109321124A - A kind of flexible real stone paint - Google Patents
A kind of flexible real stone paint Download PDFInfo
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- CN109321124A CN109321124A CN201811039626.8A CN201811039626A CN109321124A CN 109321124 A CN109321124 A CN 109321124A CN 201811039626 A CN201811039626 A CN 201811039626A CN 109321124 A CN109321124 A CN 109321124A
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- stone paint
- real stone
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to exterior wall surface decorative field of material technology, especially a kind of flexible real stone paint;70-80 parts of quartz sand, 15-20 parts of polyurethane-modified acrylic acid lotion, 0.08-0.15 parts of defoaming agent, 0.1-0.15 parts of wetting agent, 0.12-0.16 parts of sterilization antiseptic, 0.06-0.08 parts of auxiliary rheological agents, 0.38-0.42 parts of cosolvent, 2.4-2.8 parts of organosilicon moisture repellent, 20-40 parts of water;Outer wall flexible lacquer of the invention selects polyurethane-modified acrylic acid lotion, and it is equipped with auxiliary rheological agents and cosolvent, making lacquer of the invention not only has decorative effect and water resistance as excellent lithotome, also there is excellent weatherability and flexibility simultaneously, it can effectively ensure that it will not be because internal movement leads to coating cracking in construction, and quick dry agent is added in being formulated, it is easily dried lacquer, further improve the water resistance of lacquer, finally mixed with natural colour sand according to a certain amount of ratio, impart the adhesive force of product of the present invention brilliance, it is effectively improved the drop rate of lacquer.
Description
Technical field
The present invention relates to exterior wall surface decorative field of material technology, especially a kind of flexible real stone paint.
Background technique
Lacquer is the coating that a kind of decorative effect exactly likes marble, granite.The main natural stone for using various colors
Powder is formulated, applied to the imitation stone effect of external wall, therefore also known as liquid stone.
Building after lacquer finishing has natural true natural colour, gives graceful, harmonious, serious beauty
Sense, is suitable for the indoor and outdoor decoration of all kinds of buildings.Especially decorated on curved-surface building object, it is vivid, there is a kind of recurrence
Natural effect.Lacquer has fire prevention, waterproof, acid and alkali-resistance, anti-pollution.It is nontoxic, tasteless, bonding force is strong, will never fade equal spies
Point, can effectively stop extraneous adverse circumstances to building corrode, extend the service life of building, due to lacquer have it is good
Adhesive force and freeze-thaw resistance property, therefore be suitble to use in cold district.
Polymer emulsion used in lacquer general at present is mostly the styrene-acrylic emulsion of high glass transition temperature, film after film forming
Under low temperature and with the passing of time intensity is high, but relative toughness is inadequate, has brittleness tendency after use, there is after by the impact of base's stress repetition
The risk of freezing up cracking is especially embodied in cold region significant with the temperature difference.In addition, the compact in paint film of lacquer is poor, it is mechanical
Hole is big, and flexible Glass Transition Temperature of Latex is low, and stain resistance is poor.Therefore it is good that a kind of flexible protrusion, splitting resistance are provided, while again
Have both excellent flexible real stone paint of water-fast weather-proof contaminated resistance and preparation method thereof oneself become when business urgently.Summary of the invention
The object of the present invention is to provide a kind of toughness by force, paint film is not easy to crack, flexible real stone paint with long service life.
In order to solve the above technical problems, The technical solution adopted by the invention is as follows:
A kind of flexible real stone paint, mass parts composition are as follows: 70-80 parts of quartz sand, polyurethane-modified acrylic acid lotion 15-20
Part, 0.08-0.15 parts of defoaming agent, 0.1-0.15 parts of wetting agent, 0.12-0.16 parts of sterilization antiseptic, auxiliary rheological agents 0.06-0.08
Part, 0.38-0.42 parts of cosolvent, 2.4-2.8 parts of organosilicon moisture repellent, 20-40 parts of water.
Further, the mass parts composition of the defoaming agent is as follows: 10-15 parts of methyl silicone oil, sodium tripolyphosphate 10-
12 parts, 72-76 parts of salt, 6-8 parts of mannitol, 3-5 parts of silica, the defoaming agent the preparation method is as follows: (1) in room temperature
It is lower to mix methyl silicone oil and silica, mixture is obtained, (2) are by the sodium tripolyphosphate, mannitol, salt etc. of crushing
Then mixing stirs evenly in the mixture in step (1) points, obtains defoaming agent.
Further, the wetting agent is total to modified polyorganosiloxanes, polyoxyethylene alkylphenol using organic fluoro- polyethers
Ether, polyoxyethylene aliphatic alcohol ether, one of polyoxyethylene polyoxypropylene block copolymer.
Further, the sterilization antiseptic selects l, 2- benzisothiazole-3-ketone, the different thiophene of 5- chloro-2-methyl -4-
One of the mixture of-3 -one of oxazoline and 2- methyl 4- isothiazoline 3- ketone.
Further, the auxiliary rheological agents select polyamide wax powder auxiliary rheological agents, active castor oil organic derivative, castor
One of sesame oil organic derivative.
Further, the cosolvent is ethylene glycol.
Further, mass parts composition it is as follows: 72-78 parts of quartz sand, 16-18 parts of polyurethane-modified acrylic acid lotion,
0.12-0.14 parts of defoaming agent, 0.12-0.14 parts of wetting agent, 0.13-0.15 parts of sterilization antiseptic, auxiliary rheological agents 0.06-0.08
Part, 0.38-0.4 parts of cosolvent, 2.5-2.6 parts of organosilicon moisture repellent, 24-36 parts of water.
Further, mass parts composition is as follows: 75 parts of quartz sand, 18 parts of polyurethane-modified acrylic acid lotion, defoaming agent
0.12 part, 0.14 part of wetting agent, 0.14 part of sterilization antiseptic, 0.07 part of auxiliary rheological agents, 0.4 part of cosolvent, organosilicon moisture repellent
2.5 parts, 30 parts of water.
It is using the beneficial effect of technical solution of the present invention:
Outer wall flexible lacquer of the invention selects polyurethane-modified acrylic acid lotion, and is equipped with auxiliary rheological agents and cosolvent, makes
Lacquer of the invention not only has decorative effect and water resistance as excellent lithotome, also while having excellent weatherability
And flexibility, it can effectively ensure that it will not lead to coating cracking in construction because of internal movement, and be added in formula fast
Dry agent, is easily dried lacquer, further improves the water resistance of lacquer, finally and natural colour sand is according to a certain amount of ratio
Example mixing, imparts the adhesive force of product of the present invention brilliance, is effectively improved the drop rate of lacquer.
Specific embodiment
The following examples can make those skilled in the art that the present invention be more fully understood, but these embodiments are not
Limiting the scope of the invention." one embodiment " or " embodiment " referred to herein, which refers to, may be included in the present invention at least
A particular feature, structure, or characteristic in one implementation.In the present specification different places occur " in one embodiment
In " the same embodiment not is referred both to, nor the individual or selective embodiment mutually exclusive with other embodiments.
Embodiment 1
A kind of flexible real stone paint, mass parts composition are as follows: 70 parts of quartz sand, 15 parts of polyurethane-modified acrylic acid lotion, defoaming
0.08 part of agent, 0.1 part of wetting agent, 0.12 part of sterilization antiseptic, 0.06 part of auxiliary rheological agents, 0.38 part of cosolvent, organosilicon hydrophobic
2.4 parts of agent, 20 parts of water.
Wherein, defoaming agent mass parts composition it is as follows: 10 parts of methyl silicone oil, 10 parts of sodium tripolyphosphate, 72 parts of salt,
6 parts of mannitol, 3 parts of silica, defoaming agent the preparation method is as follows: (1) at room temperature by methyl silicone oil and titanium dioxide
Silicon mixes, and obtains mixture, and (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then with it is mixed in step (1)
It closes to divide in object and stir evenly, obtain defoaming agent.
Wherein, wetting agent is total to modified polyorganosiloxanes using organic fluoro- polyethers.
Wherein, sterilization antiseptic selects l, 2- benzisothiazole-3-ketone.
Wherein, auxiliary rheological agents select polyamide wax powder auxiliary rheological agents.
Wherein, cosolvent is ethylene glycol.
Embodiment 2
A kind of flexible real stone paint, mass parts composition are as follows: 72 parts of quartz sand, 16 parts of polyurethane-modified acrylic acid lotion, defoaming
0.12 part of agent, 0.12 part of wetting agent, 0.13 part of sterilization antiseptic, 0.06 part of auxiliary rheological agents, 0.38 part of cosolvent, organosilicon hydrophobic
2.5 parts of agent, 24 parts of water.
Wherein, defoaming agent mass parts composition it is as follows: 12 parts of methyl silicone oil, 11 parts of sodium tripolyphosphate, 74 parts of salt,
7 parts of mannitol, 4 parts of silica, the defoaming agent the preparation method is as follows: (1) at room temperature by methyl silicone oil and two
Silica mixes, and obtains mixture, and (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then and in step (1)
Mixture in point stir evenly, obtain defoaming agent.
Wherein, wetting agent uses polyoxyethylated alkyl phenol.
Wherein, sterilization antiseptic selects-3 -one of 5- chloro-2-methyl-4- isothiazoline and 2- methyl 4- isothiazoline 3- ketone
The mixture of composition is mixed in any proportion.
Wherein, auxiliary rheological agents select active castor oil organic derivative.
Wherein, cosolvent is ethylene glycol.
Embodiment 3
A kind of flexible real stone paint, mass parts composition are as follows: 75 parts of quartz sand, 18 parts of polyurethane-modified acrylic acid lotion, defoaming
0.12 part of agent, 0.14 part of wetting agent, 0.14 part of sterilization antiseptic, 0.07 part of auxiliary rheological agents, 0.4 part of cosolvent, organosilicon hydrophobic
2.5 parts of agent, 30 parts of water.
Wherein, defoaming agent mass parts composition it is as follows: 12 parts of methyl silicone oil, 11 parts of sodium tripolyphosphate, 74 parts of salt,
7 parts of mannitol, 4 parts of silica, the defoaming agent the preparation method is as follows: (1) at room temperature by methyl silicone oil and two
Silica mixes, and obtains mixture, and (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then and in step (1)
Mixture in point stir evenly, obtain defoaming agent.
Wherein, wetting agent is total to modified polyorganosiloxanes, polyoxyethylated alkyl phenol, polyoxy second using organic fluoro- polyethers
Alkene fatty alcohol ether, one of polyoxyethylene polyoxypropylene block copolymer.
Wherein, sterilization antiseptic selects l, 2- benzisothiazole-3-ketone.
Wherein, auxiliary rheological agents select castor oil organic derivative.
Wherein, cosolvent is ethylene glycol.
Embodiment 4
A kind of flexible real stone paint, mass parts composition are as follows: 78 parts of quartz sand, 18 parts of polyurethane-modified acrylic acid lotion, defoaming
0.14 part of agent, 0.14 part of wetting agent, 0.15 part of sterilization antiseptic, 0.08 part of auxiliary rheological agents, 0.4 part of cosolvent, organosilicon hydrophobic
2.6 parts of agent, 36 parts of water.
Wherein, defoaming agent mass parts composition it is as follows: 15 parts of methyl silicone oil, 12 parts of sodium tripolyphosphate, 76 parts of salt,
8 parts of mannitol, 5 parts of silica, the defoaming agent the preparation method is as follows: (1) at room temperature by methyl silicone oil and two
Silica mixes, and obtains mixture, and (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then and in step (1)
Mixture in point stir evenly, obtain defoaming agent.
Wherein, wetting agent, which uses, polyoxyethylene polyoxypropylene block copolymer.
Wherein, sterilization antiseptic selects l, 2- benzisothiazole-3-ketone.
Wherein, auxiliary rheological agents select polyamide wax powder auxiliary rheological agents.
Wherein, cosolvent is ethylene glycol.
Embodiment 5
A kind of flexible real stone paint, mass parts composition are as follows: 80 parts of quartz sand, 20 parts of polyurethane-modified acrylic acid lotion, defoaming
0.15 part of agent, 0.15 part of wetting agent, 0.16 part of sterilization antiseptic, 0.08 part of auxiliary rheological agents, 0.42 part of cosolvent, organosilicon hydrophobic
2.8 parts of agent, 40 parts of water.
Wherein, defoaming agent mass parts composition it is as follows: 15 parts of methyl silicone oil, 12 parts of sodium tripolyphosphate, 76 parts of salt,
8 parts of mannitol, 5 parts of silica, the defoaming agent the preparation method is as follows: (1) at room temperature by methyl silicone oil and two
Silica mixes, and obtains mixture, and (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then and in step (1)
Mixture in point stir evenly, obtain defoaming agent.
Wherein, wetting agent is total to modified polyorganosiloxanes using organic fluoro- polyethers.
Wherein, sterilization antiseptic selects l, 2- benzisothiazole-3-ketone.
Wherein, the mass parts composition of auxiliary rheological agents is as follows: polyamide wax powder auxiliary rheological agents.
Wherein, cosolvent is ethylene glycol.
Embodiment 6
Itself the difference from embodiment 1 is that: sterilization antiseptic is using common commercially available fungicide.
Embodiment 7
Itself the difference from example 2 is that: it does not include organosilicon moisture repellent.
Embodiment 8
The difference of itself and embodiment 3 is: its sterilization antiseptic used is common commercially available sterilization antiseptic.
Embodiment 9
The difference of itself and embodiment 4 is: it does not include organosilicon moisture repellent.
Embodiment 10
Prior art products.
Flexible real stone paint in embodiment 1-9 is made using the conventional method in industry.
The performance detection detection of embodiment 1-10 see the table below.
Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 |
Initial dry cracking resistance | Flawless | Flawless | Flawless | Flawless | Flawless | There is crackle | There is crackle | There is crackle | There is crackle | Slight crackle |
Flexible (diameter 50mm) | Flawless | Flawless | Flawless | Flawless | Flawless | There is crackle | There is crackle | There is crackle | There is crackle | Slight crackle |
Weatherability (96h) | It is excellent | It is excellent | It is excellent | It is excellent | It is excellent | Generally | Generally | Generally | Generally | Generally |
Alkali resistance (96h) | It is without exception | It is without exception | It is without exception | It is without exception | It is without exception | Generally | Generally | Generally | Generally | Generally |
Water resistance (96h) | It is without exception | It is without exception | It is without exception | It is without exception | It is without exception | Generally | Generally | Generally | Generally | Generally |
Standard state viscosity intensity (MPa) | 1.21 | 1.16 | 1.20 | 1.25 | 1.18 | 0.72 | 0.75 | 0.39 | 0.73 | 0.8 |
Adhesion | It is excellent | It is excellent | It is excellent | It is excellent | It is excellent | Generally | Generally | Generally | Generally | Generally |
Thermal storage stability | It is without exception | It is without exception | It is without exception | It is without exception | It is without exception | There is agglomeration | There is agglomeration | There is agglomeration | There is agglomeration | There is slight agglomeration |
Low tempertaure storage stability | It is without exception | It is without exception | It is without exception | It is without exception | It is without exception | There is agglomeration | There is agglomeration | There is agglomeration | There is agglomeration | There is slight agglomeration |
From the test result of above-described embodiment: a kind of flexible real stone paint prepared by the present invention has certain flexibility,
It can effectively prevent cracking, but also have excellent water resistance, weatherability and excellent adhesive force.
Those skilled in the art it should be appreciated that, the purpose of the application is: outer wall flexible of the invention
Lacquer selects polyurethane-modified acrylic acid lotion, and is equipped with auxiliary rheological agents and cosolvent, has lacquer of the invention not only
There are decorative effect and water resistance as excellent lithotome, also while there is excellent weatherability and flexibility, can effectively ensure that
It will not lead to coating cracking in construction because of internal movement, and be added to quick dry agent in formula, and lacquer is made to be easy to dry
It is dry, the water resistance of lacquer is further improved, is finally mixed with natural colour sand according to a certain amount of ratio, imparts the present invention
The adhesive force of product brilliance is effectively improved the drop rate of lacquer.
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.It is all in essence of the invention
Within mind and principle, any modification, equivalent substitution, improvement and etc. done be should all be included in the protection scope of the present invention.This
The technical scope of item invention is not limited to the contents of the specification, it is necessary to its technology is determined according to scope of the claims
Property range.
Claims (8)
1. a kind of flexible real stone paint, it is characterised in that: its mass parts composition is as follows: 70-80 parts of quartz sand, polyurethane-modified propylene
15-20 parts of yogurt liquid, 0.08-0.15 parts of defoaming agent, 0.1-0.15 parts of wetting agent, 0.12-0.16 parts of sterilization antiseptic, rheology help
0.06-0.08 parts of agent, 0.38-0.42 parts of cosolvent, 2.4-2.8 parts of organosilicon moisture repellent, 20-40 parts of water.
2. a kind of flexible real stone paint according to claim 1, it is characterised in that: the mass parts composition of the defoaming agent is such as
Under: 10-15 parts of methyl silicone oil, 10-12 parts of sodium tripolyphosphate, 72-76 parts of salt, 6-8 parts of mannitol, silica 3-5
Part, the defoaming agent the preparation method is as follows: (1) at room temperature mixes methyl silicone oil and silica, mixed
Object, (2) mix sodium tripolyphosphate, mannitol, salt of crushing etc., then stir evenly, obtain in the mixture in step (1) points
To defoaming agent.
3. a kind of flexible real stone paint according to claim 1, it is characterised in that: the wetting agent uses organic fluoro- polyethers
Modified polyorganosiloxanes, polyoxyethylated alkyl phenol altogether, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block copolymerization
One of object.
4. a kind of flexible real stone paint according to claim 1, it is characterised in that: the sterilization antiseptic selects l, 2- benzene
And in the mixture of isothiazoline-3- ketone ,-3 -one of 5- chloro-2-methyl-4- isothiazoline and 2- methyl 4- isothiazoline 3- ketone
One kind.
5. a kind of flexible real stone paint according to claim 1, it is characterised in that: the auxiliary rheological agents select polyamide wax powder
One of body auxiliary rheological agents, active castor oil organic derivative, castor oil organic derivative.
6. a kind of flexible real stone paint according to claim 1, it is characterised in that: the cosolvent is ethylene glycol.
7. a kind of flexible real stone paint according to claim 1, it is characterised in that: its mass parts composition is as follows: quartz sand 72-
78 parts, 16-18 parts of polyurethane-modified acrylic acid lotion, 0.12-0.14 parts of defoaming agent, 0.12-0.14 parts of wetting agent, sterilization and anticorrosion
0.13-0.15 parts of agent, 0.06-0.08 parts of auxiliary rheological agents, 0.38-0.4 parts of cosolvent, 2.5-2.6 parts of organosilicon moisture repellent, water
24-36 parts.
8. a kind of flexible real stone paint according to claim 7, it is characterised in that: its mass parts composition is as follows: quartz sand 75
Part, 18 parts of polyurethane-modified acrylic acid lotion, 0.12 part of defoaming agent, 0.14 part of wetting agent, 0.14 part of sterilization antiseptic, rheology help
0.07 part of agent, 0.4 part of cosolvent, 2.5 parts of organosilicon moisture repellent, 30 parts of water.
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CN201811039626.8A CN109321124A (en) | 2018-09-06 | 2018-09-06 | A kind of flexible real stone paint |
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CN111234686A (en) * | 2020-03-10 | 2020-06-05 | 浙江华德新材料有限公司 | Self-crosslinking acrylic polyurethane dispersion stone-like paint and preparation method thereof |
CN111892871A (en) * | 2020-07-17 | 2020-11-06 | 广东福莱特建筑材料有限公司 | High-toughness anti-crack rock slice paint and preparation method thereof |
CN112608626A (en) * | 2020-12-01 | 2021-04-06 | 安徽科创美涂料科技股份有限公司 | Waterborne polyurethane-polyacrylic acid-based self-repairing real stone paint and preparation method thereof |
CN113683948A (en) * | 2021-07-30 | 2021-11-23 | 安徽众雁涂料有限公司 | Production method of wind-crack-resistant and impact-resistant stone-like paint |
CN115491096A (en) * | 2022-09-21 | 2022-12-20 | 浙江建工装饰材料有限公司 | Anti-cracking stone-like paint and construction process thereof |
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CN106669237A (en) * | 2016-12-14 | 2017-05-17 | 东至绿洲环保化工有限公司 | Organic silicon defoamer containing sodium tripolyphosphate |
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CN103602197A (en) * | 2013-11-29 | 2014-02-26 | 江门市华石涂料有限公司 | Stone-like paint and preparation method thereof |
CN105621959A (en) * | 2015-12-18 | 2016-06-01 | 三棵树涂料股份有限公司 | Flexible true stone paint and preparation method thereof |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111234686A (en) * | 2020-03-10 | 2020-06-05 | 浙江华德新材料有限公司 | Self-crosslinking acrylic polyurethane dispersion stone-like paint and preparation method thereof |
CN111892871A (en) * | 2020-07-17 | 2020-11-06 | 广东福莱特建筑材料有限公司 | High-toughness anti-crack rock slice paint and preparation method thereof |
CN112608626A (en) * | 2020-12-01 | 2021-04-06 | 安徽科创美涂料科技股份有限公司 | Waterborne polyurethane-polyacrylic acid-based self-repairing real stone paint and preparation method thereof |
CN113683948A (en) * | 2021-07-30 | 2021-11-23 | 安徽众雁涂料有限公司 | Production method of wind-crack-resistant and impact-resistant stone-like paint |
CN113683948B (en) * | 2021-07-30 | 2022-10-11 | 安徽众雁涂料有限公司 | Production method of anti-wind-crack impact-resistant real stone paint |
CN115491096A (en) * | 2022-09-21 | 2022-12-20 | 浙江建工装饰材料有限公司 | Anti-cracking stone-like paint and construction process thereof |
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Address after: 213200 No. 168, Zhidong Road, Zhixi industrial concentration zone, Jintan District, Changzhou City, Jiangsu Province Applicant after: Jiangsu Jiunuo New Material Technology Co.,Ltd. Address before: 213200 No. 168, Zhidong Road, Zhixi industrial concentration zone, Jintan District, Changzhou City, Jiangsu Province Applicant before: JIANGSU JIUNUO BUILDING MATERIAL TECHNOLOGY Co.,Ltd. |
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Application publication date: 20190212 |