CN109291549B - A kind of foamed ceramic decorative integrated board of high-strength light high-ductility and preparation method thereof - Google Patents
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility and preparation method thereof Download PDFInfo
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- CN109291549B CN109291549B CN201811123978.1A CN201811123978A CN109291549B CN 109291549 B CN109291549 B CN 109291549B CN 201811123978 A CN201811123978 A CN 201811123978A CN 109291549 B CN109291549 B CN 109291549B
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
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- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/002—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising natural stone or artificial stone
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- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
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Abstract
The invention discloses a kind of foamed ceramic decorative integrated boards of high-strength light high-ductility, including foamed light material layer, high-ductility architectural surface and wear-resistant coating；Foamed light material layer includes: stone material tailing, graphene, zirconium oxide, high temperature fluxing agent, clay, stabilizer and degumming agent；High-ductility architectural surface includes: AC foaming agent, stabilizer, calcium carbonate, high-intensity resin, processing aid, lubricant.The wear-resistant coating includes: graphene, silicon carbide whisker, schmigel, vermiculite, kaolin, fire retardant, nano-titanium dioxide, sodium phosphate, sodium metasilicate, hydroxyethyl cellulose, silicone acrylic emulsion and silica solution.The foamed ceramic decorative integrated board, the high-ductility architectural surface that porcelain tendre makes is bonded together with foamed light material layer by pressing mold, then in high-ductility architectural surface surface wear-resistant coating, have the effect of good toughness, high-strength light, fire-retardant, heat preservation, water proof anti-seepage and anti-aging.
Description
Technical field
The present invention relates to decoration material field, in particular to the foamed ceramic decorative integrated board of a kind of high-strength light high-ductility and
Preparation method.
Background technique
Existing Discussion on architecture surface of wall interior decorative coat is main currently on the market are as follows: ceramic tile, granite, marble,
Polyethylene kind extrusion molding heat insulating decorative board and exterior coating, wherein ceramic tile, granite and marble are in process of production, a large amount of to fire
Coal resource is burnt, environmental pollution destroys seriously, and ceramic tile dead weight is big, does not have self-insurance temperature function, during construction and installation
Using a large amount of cement mortar wet processes paste, complex procedures service life is short, easy to crack easy to fall off, caused by security risk it is larger；
Granite and marble itself belong to non-renewable mineral resources, in city increasingly development & construction demand, a large amount of recovery process
In seriously destroy ecological environment, yield rate utilization rate is extremely low, causes tailing rubbish to be difficult to the processing that is utilized effectively, be easy to cause
Geological disaster.Because material itself limits, service life easy to aging is short, weatherability is poor, fire line for polyethylene kind extrusion molding heat insulating decorative board
Can be poor, and once a large amount of poison gas of generation fire generation, cause environmental pollution to destroy very big；In exterior coating, elasticity is applied
Material, gloss paint, aqueous metallic paint and and flower king's coating be generally able to satisfy the requirement of water absorption and impermeability, some coating
Will be with certain primary coats with the use of can be only achieved requirement, elastic coating is difficult to reach requirement for gas permeability.Therefore, it studies
A kind of light, resistance to fire-retardant, water proof anti-seepage, non-aging and good mechanical performance the decoration applied to Discussion on architecture surface of wall
Material is extremely urgent.
Porcelain tendre is a kind of novel energy-saving low-carbon ornament materials, is used as decorative material for wall surface, have it is light, flexible,
The features such as appearance and modeling multiplicity, good weatherability；It is used as floor decorative material, has the characteristics that wear-resisting, anti-skidding, comfortable foot feeling；
Simple and quick construction is shortened the construction period than traditional material, saving space, save the cost, and not easily to fall off.Suitable for exterior wall, interior
The building decorations such as wall, ground change especially suitable for skyscraper exterior finish engineering, facade decorative engineering, Old City city
Make the surface-veneer engineered of the anisotropic building such as exterior wall plane materiel, the finish coat of external insulation system and curved wall, arch column.
In addition, with the accelerating process of industrialization and urbanization, the consumed resource of China's industrial circle will further expand
Greatly, it becomes increasingly conspicuous because of resource exploitation and using bring environmental problem, simultaneously because the utilization rate of resource is not high, produces a large amount of
Stone material tailing.Stone material tailing is typically all that the method for using nature to stack is handled.Farmland is not only occupied, and to nature
Ecological environment causes greatly to destroy.Rationally realize stone material tailing comprehensive utilization, can effective supplemental resources, improve Domestic Resources
Guarantee dynamics.
Application No. is the patents of invention of CN201610265638.7 to disclose a kind of porcelain tendre polyurethane thermal insulation and decoration composite plate
Preparation method by carrying out the preparation of flexible porcelain tendre directly on polyurethane thermal insulation board composite plate is once closed
At.The wind composite plate has had both the effect of heat preservation and decoration, but intensity is not high, and adaptation range is relatively limited.Application No. is
The patent of invention of CN201610959101.0 discloses a kind of heat preservation decoration integrative tapestry brick and preparation method thereof, by porcelain tendre
Finish coat and heat preservation interlayer connect into an entirety, have decoration and heat insulation function.But the tapestry brick is bonded by grout material
Porcelain tendre finish coat and insulating layer are easy to produce crack, and the tapestry brick still needs to improve in terms of intensity, toughness.
Summary of the invention
Goal of the invention of the invention first is that, in view of the above-mentioned problems, providing a kind of foamed ceramic dress of high-strength light high-ductility
Integrated board is adornd, the high-ductility architectural surface that porcelain tendre makes is bonded together with foamed light material layer by pressing mold, then in height
Tough architectural surface surface wear-resistant coating has good toughness, high-strength light, fire-retardant, heat preservation, water proof anti-seepage and anti-aging effect
Fruit.
In order to achieve the above objectives, the technical scheme adopted by the invention is that:
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility, including foamed light material layer, high-ductility architectural surface
And wear-resistant coating；The high-ductility architectural surface is made by porcelain tendre, is bonded with the foamed light material layer by pressing mold
Together, the wear-resistant coating is coated in high-ductility architectural surface surface.
The foamed light material layer by weight percentage, including following raw material: stone material tailing 65~85%, graphene
0.05~10%, zirconium oxide 0.05~10%, high temperature fluxing agent 0.05~10%, clay 0.05~8%, stabilizer 0.05~
5% and degumming agent 0.05~5%.
The porcelain tendre by weight percentage, including following raw material: calcium carbonate 30~50%, graphene 0.05~
10%, silicon carbide whisker 0.05~5%, clay 0.05~10%, AC foaming agent 0.05~5%, stabilizer 0.05~10%, plus
Work auxiliary agent 0.05~5%, lubricant 0.05~10%, high-intensity resin 30~60%, mica 1~10%, schmigel 0.05~
10% and colorant 0.05~5%.
The wear-resistant coating by weight percentage, including following raw material: graphene 1~10%, silicon carbide whisker 0.05
~5%, schmigel 3~10%, vermiculite 5~20%, kaolin 5~20%, fire retardant 3~10%, nano-titanium dioxide 1~
10%, sodium phosphate 5~15%, sodium metasilicate 10~20%, hydroxyethyl cellulose 0.05~5%, silicone acrylic emulsion 3~6% and silicon are molten
Glue 5~10%.
Preferably, the high-intensity resin is one of polyvinyl resin, epoxy resin, Corvic or more
Kind is formed by modification, specific method of modifying are as follows: chooses one kind or more of polyvinyl resin, epoxy resin, Corvic
Kind be mixed to get hybrid resin, be then added into the hybrid resin account for carbon nanotubes that its mass percent is 5~15%,
Silicon powder and zinc oxide, are then uniformly mixed, and extruding pelletization obtains high-intensity resin.
Preferably, the mass ratio of the carbon nanotubes, silicon powder and zinc oxide is 1~5:3~10:1~5.
Preferably, the stone material tailing is granite, feldspar, quartz, sandstone, basalt, diabase, shale, lime
One of rock and griotte are a variety of.
Preferably, the stone material tailing first passes through pretreatment, the preprocessing process are as follows: stone material tailing is crushed, grinding,
Then citrate is added and sodium sulfanilate carries out secondary grinding；The citrate and sodium sulfanilate of addition point
Not Wei stone material tailing quality 0.5~1% and 0.1~1%
Preferably, the high temperature fluxing agent is one of calcination of talc, raw talcum, diopside and fluorite or a variety of.
Preferably, the stabilizer is that liquid barium zinc compound stabilizer, liquid calcium zinc complex stabilizer, lead salt are compound steady
Determine one of agent, liquid barium cadmium and liquid barum cadmium zinc compound stabilizer or a variety of.
Preferably, the degumming agent is polybasic carboxylic acid water solubility organic-based material.
Another goal of the invention of the invention is to provide a kind of preparation of the foamed ceramic decorative integrated board of high-strength light high-ductility
Method has high tenacity, lightweight, high-strength, sound-insulating and heat-insulating heat preservation, resistance using being made by prefabricated, the secondary molding bonded of substep
Combustion, water proof anti-seepage, foamed ceramic decorative integrated board that is anti-aging, installing light high-strength light high tenacity.
In order to achieve the above objectives, the technical scheme adopted by the invention is that:
A kind of preparation method of the foamed ceramic decorative integrated board of high-strength light high-ductility, comprising the following steps:
The preparation of S1, foamed light material: graphene and stone material tailing are weighed according to the formula, mixing crushes simultaneously powder
Mill, is then added other raw materials, and mixing 0.5~4h of homogenizing is handled by mist projection granulating, dried, obtain foamed light powder.
The preparation of S2, high-ductility architectural surface: weighing calcium carbonate and graphene according to the formula, and mixing crushes simultaneously grinding,
Then other raw materials in formula are added, 0.5~3h of homogenizing are mixed subsequently into high speed rotation mixing machine, at mist projection granulating
Reason, drying is spare into savings storehouse, obtains high-ductility architectural surface raw material.
S3, it forms by a firing: the foamed light powder being burnt into 0.5~5h under 900~1300 DEG C of high temperature, is taken after cooling
Out, excision forming obtains foamed light material layer.
S4, secondary molding bonded: by the high-ductility architectural surface raw material pressure be 2~6MPa, heating temperature be 180~
250 DEG C, rate of extrusion be 45~100r/min under conditions of press mold, fretting map, extrusion, and immediately the foamed light layer whole
Surface pressure is that bonding cooling is carried out under 0.5~1.0MPa state, forms high-ductility architectural surface；Through polishing, polishing, cutting forming,
Obtain foamed ceramic decorative integrated board crude product.
S5, coating: weighing raw material according to the formula and prepare wear-resisting coating liquid, and is coated uniformly on the foamed ceramic dress
The surface of the high-ductility architectural surface of integrated board crude product is adornd, wear-resistant coating is formed, obtains foamed ceramic decorative one board finished product.
Preferably, in step S5, sodium phosphate and sodium metasilicate are first poured into Hybrid Heating in container, temperature is controlled 50~70
℃；And ceaselessly stir, and silica solution, it mixes them thoroughly, obtains binder；Then in proportion by graphene, silicon carbide whisker,
Schmigel, vermiculite, kaolin, fire retardant, nano-titanium dioxide and hydroxyethyl cellulose mixing, are added silicone acrylic emulsion, and stirring is mixed
1~2h is closed, mixture is obtained；Finally binder and mixture are added in blender, 1~5h is mixed, is uniformly mixed it,
Obtain wear-resisting coating liquid.
The invention has the following advantages:
1. the foamed ceramic decorative integrated board of high-strength light high-ductility of the invention, including foamed light material layer, high-ductility dress
Finish coat and wear-resistant coating；The high-ductility architectural surface that porcelain tendre makes is bonded together with foamed light material layer by pressing mold,
Then in high-ductility architectural surface surface wear-resistant coating, there is good toughness, high-strength light, fire-retardant, heat preservation, water proof anti-seepage and resist
The effect of aging.
Foamed light material layer, high-ductility architectural surface and wear-resistant coating contain graphene, pass through graphene high-ratio surface
The effect of long-pending, high adsorption capacity, makes graphene uniform be dispersed in other materials surface, and the physical property of material is made to tend towards stability, with
Each raw material mutually assists playing anti-aging, anticorrosive, heat-insulation and heat-preservation, sound insulation, water proof anti-seepage, fireproof, light in formula
The high-strength effect of matter.Zirconium oxide, clay, stabilizer and degumming agent, the toughening machine of zirconium oxide are added in foamed light material layer
It is formed with stress-induced phase transformation toughening and microcrack evolution equation.By the two-dimensional slice structure of graphene, reinforce graphene and degumming agent
Between interaction, adsorbed a large amount of zirconium oxide, clay and stabilizer, formed fine and close physical layer, improve the resistance of material
Combustion property, waterproofness, heat insulating ability and mechanical property.
In high-ductility architectural surface in addition to graphene and calcium carbonate, mica, schmigel and silicon carbide whisker also added, lead to
The two-dimensional slice structure of graphene is crossed, uniformly the interspersed mechanical property and waterproofness for improving decorative cover material in the structure.Carbonization
Silicon wafer must have very high breaking strength and elasticity modulus, can flexibly bear biggish strain without permanent deformation, utilize carbon
The stability that the mechanism of SiClx toughening has whiosker pullout, bridging and crack deflection to improve material.The two synergistic effect, improves
Compression strength and flexibility.
High-intensity resin improves the intensity and toughness of resin by addition carbon nanotubes, silicon powder and modified zinc oxide, from
And improve the mechanical property of high-ductility architectural surface.Carbon nanotubes, silicon powder, zinc oxide and resin respectively play independent effect,
Interdependence again simultaneously, the mechanical property of resin is poor, and only they are combined, and forms an entirety, could effectively
The effect of their own is played, mechanical strength of resin is improved.Carbon nanotubes, silicon powder and zinc oxide suitably increase as skeleton, content
Add the intensity that resin can be improved, but as content increases, makes resin structure relaxation instead, cause strength reduction, therefore answer
Strict control content.
Graphene and vermiculite is added in wear-resistant coating, is cooperated using vermiculite, graphene and nano-titanium dioxide, silicon carbide whisker
Effect, can greatly improve wear-resisting coating liquid in the adhesive force of tough architectural surface.Meanwhile under the high temperature conditions, coating is not blistering, no
Cracking, do not peel off, play waterproof, fire prevention, heat-insulation and heat-preservation, it is antiseptic and rustproof, anti-aging, insulation the effects of, extend foamed ceramic dress
Adorn integrated board service life.
2. the foamed ceramic decorative integrated board of high-strength light high-ductility of the invention, stone material tailing activity is lower, with other materials
The compatibility of material is poor, therefore first passes through pretreatment modification.Stone material tailing compatibility modified and activity improve, to change
Adhesive property between kind material, assigns microcrystalline jade high-temperature stability and cracking resistance.
It is prefabricated by substep, two 3. the preparation method of the foamed ceramic decorative integrated board of high-strength light high-ductility of the invention
Secondary molding bonded is made with high tenacity, high-strength light, good mechanical performance, sound-insulating and heat-insulating heat preservation, fire-retardant, water proof anti-seepage, resists
Aging, anticorrosive, installation light, low-carbon energy-saving and environmentally protective high-strength light high-ductility foamed ceramic decorative integrated board.
Specific embodiment
Embodiment 1:
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Including foamed light material layer, high-ductility architectural surface and wear-resistant coating；The high-ductility architectural surface is by porcelain tendre system
It forms, is bonded together with the foamed light material layer by pressing mold, the wear-resistant coating is coated in high-ductility architectural surface
Surface.
The foamed light material layer by weight percentage, including following raw material: stone material tailing 75%, graphene 5%,
Zirconium oxide 5%, high temperature fluxing agent 5%, clay 5%, stabilizer 2% and degumming agent 3%.
The porcelain tendre by weight percentage, including following raw material: calcium carbonate 35%, graphene 5%, silicon carbide whisker
2%, clay 3%, AC foaming agent 2%, stabilizer 3%, processing aid 1%, lubricant 2%, high-intensity resin 40%, mica
3%, schmigel 2% and colorant 2%.
The wear-resistant coating by weight percentage, including following raw material: graphene 5%, silicon carbide whisker 2%, corundum
Powder 5%, vermiculite 20%, kaolin 10%, fire retardant 5%, nano-titanium dioxide 8%, sodium phosphate 10%, sodium metasilicate 15%, hydroxyl
Ethyl cellulose 5%, silicone acrylic emulsion 5% and silica solution 10%.
The high-intensity resin is that polyvinyl resin modification forms, specific method of modifying are as follows: add into polyvinyl resin
Enter to account for carbon nanotubes, silicon powder and zinc oxide that its mass percent is 10%, is then uniformly mixed, extruding pelletization, obtains high-strength
Spend resin.The mass ratio of the carbon nanotubes, silicon powder and zinc oxide is 2:5:2.The stone material tailing is granite.
The stone material tailing first passes through pretreatment, the preprocessing process are as follows: by stone material tailing crush, grinding, then plus
Enter citrate and sodium sulfanilate carries out secondary grinding；The citrate and sodium sulfanilate of addition are respectively stone
The 1% and 0.5% of material tailing quality.The high temperature fluxing agent is calcination of talc.The stabilizer is that liquid barium zinc is compound
Stabilizer.The degumming agent is polybasic carboxylic acid water solubility organic-based material.
Preparation method, comprising the following steps:
The preparation of S1, foamed light material: graphene and stone material tailing are weighed according to the formula, mixing crushes simultaneously powder
Mill, is then added other raw materials, and mixing homogenizing 2h is handled by mist projection granulating, dried, obtain foamed light powder.
The preparation of S2, high-ductility architectural surface: weighing calcium carbonate and graphene according to the formula, and mixing crushes simultaneously grinding,
Then other raw materials in formula are added, mixes homogenizing 2h subsequently into high speed rotation mixing machine, handles, dry by mist projection granulating
It is dry, it is spare into savings storehouse, obtain high-ductility architectural surface raw material.
S3, it forms by a firing: the foamed light powder being burnt into 2h under 1200 DEG C of high temperature, takes out, is cut into after cooling
Type obtains foamed light material layer.
S4, secondary molding bonded: by the high-ductility architectural surface raw material pressure is 5MPa, heating temperature is 200 DEG C, is squeezed
Rate is press mold, fretting map, extrusion under conditions of 60r/min out, and the foamed light layer in whole face pressure is immediately
Bonding cooling is carried out under 1.0MPa state, forms high-ductility architectural surface；Through polishing, polishing, cutting forming, foamed ceramic dress is obtained
Adorn integrated board crude product.
S5, coating: weighing raw material according to the formula and prepare wear-resisting coating liquid, and is coated uniformly on the foamed ceramic dress
The surface of the high-ductility architectural surface of integrated board crude product is adornd, wear-resistant coating is formed, obtains foamed ceramic decorative one board finished product.
Wear-resisting coating liquid the preparation method comprises the following steps: sodium phosphate and sodium metasilicate are first poured into Hybrid Heating in container, temperature control
At 60 DEG C；And ceaselessly stir, and silica solution, it mixes them thoroughly, obtains binder；Then in proportion by graphene, silicon carbide
Whisker, schmigel, vermiculite, kaolin, fire retardant, nano-titanium dioxide and hydroxyethyl cellulose mixing, are added silicone acrylic emulsion, stir
Mixing 1.5h is mixed, mixture is obtained；Finally binder and mixture are added in blender, 3h is mixed, is uniformly mixed it,
Obtain wear-resisting coating liquid.
Embodiment 2:
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Including foamed light material layer, high-ductility architectural surface and wear-resistant coating；The high-ductility architectural surface is by porcelain tendre system
It forms, is bonded together with the foamed light material layer by pressing mold, the wear-resistant coating is coated in high-ductility architectural surface
Surface.
The foamed light material layer by weight percentage, including following raw material: stone material tailing 85%, graphene 5%,
Zirconium oxide 3%, high temperature fluxing agent 2%, clay 3%, stabilizer 1% and degumming agent 1%.
The porcelain tendre by weight percentage, including following raw material: calcium carbonate 40%, graphene 5%, silicon carbide whisker
2%, clay 3%, AC foaming agent 2%, stabilizer 3%, processing aid 2%, lubricant 5%, high-intensity resin 30%, mica
5%, schmigel 2% and colorant 1%.
The wear-resistant coating by weight percentage, including following raw material: graphene 5%, silicon carbide whisker 3%, corundum
Powder 8%, vermiculite 15%, kaolin 15%, fire retardant 5%, nano-titanium dioxide 10%, sodium phosphate 15%, sodium metasilicate 15%, hydroxyl
Ethyl cellulose 4%, silicone acrylic emulsion 4% and silica solution 6%.
The high-intensity resin is that polyvinyl resin modification forms, specific method of modifying are as follows: add into polyvinyl resin
Enter to account for carbon nanotubes, silicon powder and zinc oxide that its mass percent is 5%, is then uniformly mixed, extruding pelletization, obtains high-intensitive
Resin.The mass ratio of the carbon nanotubes, silicon powder and zinc oxide is 3:6:2.
The stone material tailing is feldspar, quartz and shale.The stone material tailing first passes through pretreatment, described pretreated
Journey are as follows: stone material tailing is crushed, grinding, citrate is then added and sodium sulfanilate carries out secondary grinding；It is added
Citrate and sodium sulfanilate are respectively the 0.6% and 0.2% of stone material tailing quality.
The high temperature fluxing agent is in diopside and fluorite.The stabilizer is liquid calcium zinc complex stabilizer and liquid
Body barium cadmium zinc composite stabilizer.
Preparation method, comprising the following steps:
The preparation of S1, foamed light material: graphene and stone material tailing are weighed according to the formula, mixing crushes simultaneously powder
Mill, is then added other raw materials, and mixing homogenizing 3h is handled by mist projection granulating, dried, obtain foamed light powder.
The preparation of S2, high-ductility architectural surface: weighing calcium carbonate and graphene according to the formula, and mixing crushes simultaneously grinding,
Then other raw materials in formula are added, mixes homogenizing 3h subsequently into high speed rotation mixing machine, handles, dry by mist projection granulating
It is dry, it is spare into savings storehouse, obtain high-ductility architectural surface raw material.
S3, it forms by a firing: the foamed light powder being burnt into 0.5h under 1300 DEG C of high temperature, takes out, cuts after cooling
Molding, obtains foamed light material layer.
S4, secondary molding bonded: by the high-ductility architectural surface raw material pressure is 6MPa, heating temperature is 250 DEG C, is squeezed
Rate is press mold, fretting map, extrusion under conditions of 100r/min out, and the foamed light layer in whole face pressure is immediately
Bonding cooling is carried out under 0.5MPa state, forms high-ductility architectural surface；Through polishing, polishing, cutting forming, foamed ceramic dress is obtained
Adorn integrated board crude product.
S5, coating: weighing raw material according to the formula and prepare wear-resisting coating liquid, and is coated uniformly on the foamed ceramic dress
The surface of the high-ductility architectural surface of integrated board crude product is adornd, wear-resistant coating is formed, obtains foamed ceramic decorative one board finished product.
Wear-resisting coating liquid the preparation method comprises the following steps: sodium phosphate and sodium metasilicate are first poured into Hybrid Heating in container, temperature control
At 70 DEG C；And ceaselessly stir, and silica solution, it mixes them thoroughly, obtains binder；Then in proportion by graphene, silicon carbide
Whisker, schmigel, vermiculite, kaolin, fire retardant, nano-titanium dioxide and hydroxyethyl cellulose mixing, are added silicone acrylic emulsion, stir
Mixing 1h is mixed, mixture is obtained；Finally binder and mixture are added in blender, 4h is mixed, is uniformly mixed it, i.e.,
Obtain wear-resisting coating liquid.
Embodiment 3:
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Including foamed light material layer, high-ductility architectural surface and wear-resistant coating；The high-ductility architectural surface is by porcelain tendre system
It forms, is bonded together with the foamed light material layer by pressing mold, the wear-resistant coating is coated in high-ductility architectural surface
Surface.
The foamed light material layer by weight percentage, including following raw material: stone material tailing 65%, graphene
10%, zirconium oxide 10%, high temperature fluxing agent 4%, clay 8%, stabilizer 2% and degumming agent 1%.
The porcelain tendre by weight percentage, including following raw material: calcium carbonate 50%, graphene 2%, silicon carbide whisker
1%, clay 1%, AC foaming agent 1.5%, stabilizer 1%, processing aid 0.5%, lubricant 0.5%, high-intensity resin 40%,
Mica 1%, schmigel 1% and colorant 0.5%.
The wear-resistant coating by weight percentage, including following raw material: graphene 1%, silicon carbide whisker 5%, corundum
Powder 4%, vermiculite 5%, kaolin 20%, fire retardant 10%, nano-titanium dioxide 5%, sodium phosphate 15%, sodium metasilicate 20%, hydroxyl
Ethyl cellulose 5%, silicone acrylic emulsion 3% and silica solution 7%.
The high-intensity resin is that polyvinyl resin modification forms, specific method of modifying are as follows: add into polyvinyl resin
Enter to account for carbon nanotubes, silicon powder and zinc oxide that its mass percent is 8%, is then uniformly mixed, extruding pelletization, obtains high-intensitive
Resin.The mass ratio of the carbon nanotubes, silicon powder and zinc oxide is 4:8:3.
The stone material tailing is granite and griotte.The stone material tailing first passes through pretreatment, described pretreated
Journey are as follows: stone material tailing is crushed, grinding, citrate is then added and sodium sulfanilate carries out secondary grinding；It is added
Citrate and sodium sulfanilate are respectively the 0.5% and 0.5% of stone material tailing quality
The high temperature fluxing agent is in calcination of talc, diopside and fluorite.The stabilizer is lead salt stable composition
Agent and liquid barium cadmium.
The preparation method is the same as that of Example 1.
Embodiment 4
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Compared with Example 1, the stone material tailing in the foamed light material layer is without pretreatment.
Embodiment 5
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Compared with Example 1, the high-intensity resin in the foamed light material layer is without modification.
Embodiment 6
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Compared with Example 1, the high-intensity resin in the foamed light material layer accounts for its mass percent by being added
It is modified for 12% carbon nanotubes, silicon powder and zinc oxide.
Embodiment 7
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Compared with Example 1, the high-intensity resin in the foamed light material layer accounts for its mass percent by being added
It is modified for 15% carbon nanotubes, silicon powder and zinc oxide.
Comparative example 1
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Compared with Example 1, the high-intensity resin in the foamed light material layer accounts for its mass percent by being added
It is modified for 18% carbon nanotubes, silicon powder and zinc oxide.
Comparative example 2:
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Compared with Example 1, it is not coated by wear-resistant coating.
Comparative example 3:
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Compared with Example 1, graphene is not contained in the foamed light material layer, porcelain tendre and wear-resistant coating.
Comparative example 4:
A kind of foamed ceramic decorative integrated board of high-strength light high-ductility
Compared with Example 1, silicon carbide whisker is not contained in the porcelain tendre and wear-resistant coating.
Performance test: foamed light decorative integrated plate sample is respectively prepared by the preparation method of embodiment 1-7 and comparative example 1-4
30mm × 20mm × 20mm style is made in product, detects the compression strength of style, flexural strength, combustion rating, oise insulation factor and leads
Hot coefficient, specific steps the results are shown in Table 1 referring to GB/T 17657-2013.
1 embodiment 1-5 of table and comparative example 1-3 the performance test results
Embodiment 1-5 and table 1 can be seen that the foamed ceramic decorative integrated board of high-strength light high-ductility of the invention, have
Higher compression strength, flexural strength and combustion rating, lower thermal coefficient and wearability test revolution illustrate that the present invention will
The high-ductility architectural surface of porcelain tendre production is bonded together with foamed light material layer by pressing mold, then in high-ductility architectural surface table
Face wear-resistant coating has the effect of good toughness, high-strength light, fire-retardant, heat preservation, water proof anti-seepage and anti-aging.
Embodiment 4-5, which can be seen that, can preferably improve decoration by pretreated stone material tailing and high-intensity resin
The intensity, toughness and wearability of integrated board.
As can be seen that carbon nanotubes, silicon powder and zinc oxide are as skeleton, content is suitable for embodiment 1,6-7 and comparative example 1
The intensity of resin can be improved when increasing, but as content increases, make resin structure relaxation instead, cause strength reduction, because
This answers strict control content, and 15% is optimum addition.
Embodiment 1 and comparative example 2-4 can be seen that wear-resistant coating and can reduce thermal coefficient, so as to improve heat insulation effect.
Graphene and silicon carbide whisker can preferably improve the intensity, toughness and wearability of decorative integrated plate.
Radionuclide limitation test: with the External Exposure Index and Outreach services of gamma ray spectrometer systematic survey test sample,
Testing result is shown in Table 2.
2 radionuclide of table limitation test data
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| External Exposure Index | 0.01 | 0.01 | 0.01 | 0.01 | 0.01 |
| Outreach services | 0.02 | 0.02 | 0.02 | 0.02 | 0.02 |
Known to table 2: External Exposure Index and Outreach services are lower, illustrate that the amount of radiation of sample is small, the spoke generated to human body
The effect of penetrating is also smaller.The External Exposure Index and Outreach services of embodiment 1-5 is relatively low, illustrates lightweight prepared by the present invention
The amount of radiation of the foamed ceramic decorative integrated board of high-strength and high ductility is relatively low, meets the market demand, and use is safer.
Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair
Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to
In the covered the scope of the patents of the present invention.
Claims (9)
1. a kind of foamed ceramic decorative integrated board of high-strength light high-ductility, it is characterised in that: including foamed light material layer, high-ductility
Architectural surface and wear-resistant coating；The high-ductility architectural surface is made by porcelain tendre, is passed through with the foamed light material layer
Pressing mold is bonded together, and the wear-resistant coating is coated in high-ductility architectural surface surface；
The foamed light material layer by weight percentage, including following raw material: stone material tailing 65~85%, graphene 0.05
~10%, zirconium oxide 0.05~10%, high temperature fluxing agent 0.05~10%, clay 0.05~8%, 0.05~5% and of stabilizer
Degumming agent 0.05~5%；
The porcelain tendre by weight percentage, including following raw material: calcium carbonate 30~50%, graphene 0.05~10%, carbon
SiClx whisker 0.05~5%, clay 0.05~10%, AC foaming agent 0.05~5%, stabilizer 0.05~10%, processing aid
0.05~5%, lubricant 0.05~10%, high-intensity resin 30~60%, mica 1~10%, 0.05~10% and of schmigel
Colorant 0.05~5%；
The high-intensity resin is that one of polyvinyl resin, epoxy resin, Corvic or a variety of processes are modified
It forms, specific method of modifying are as follows: selection polyvinyl resin, epoxy resin, the one or more of Corvic are mixed to get
Then hybrid resin is added into the hybrid resin and accounts for carbon nanotubes, silicon powder and oxygen that its mass percent is 5~15%
Change zinc, is then uniformly mixed, extruding pelletization obtains high-intensity resin；
The wear-resistant coating by weight percentage, including following raw material: graphene 1~10%, silicon carbide whisker 0.05~
5%, schmigel 3~10%, vermiculite 5~20%, kaolin 5~20%, fire retardant 3~10%, nano-titanium dioxide 1~
10%, sodium phosphate 5~15%, sodium metasilicate 10~20%, hydroxyethyl cellulose 0.05~5%, silicone acrylic emulsion 3~6% and silicon are molten
Glue 5~10%.
2. the foamed ceramic decorative integrated board of high-strength light high-ductility according to claim 1, it is characterised in that: the nanometer
The mass ratio of carbon pipe, silicon powder and zinc oxide is 1~5:3~10:1~5.
3. the foamed ceramic decorative integrated board of high-strength light high-ductility according to claim 1, it is characterised in that: the stone
Material tailing is one of granite, feldspar, quartz, sandstone, basalt, diabase, shale, limestone and griotte or more
Kind.
4. the foamed ceramic decorative integrated board of high-strength light high-ductility according to claim 1, it is characterised in that: the stone material
Tailing first passes through pretreatment, the preprocessing process are as follows: crushes stone material tailing, grinding, citrate is then added and to ammonia
Base benzene sulfonic acid sodium salt carries out secondary grinding；The citrate and sodium sulfanilate of addition are respectively the 0.5 of stone material tailing quality
~1% and 0.1~1%.
5. the foamed ceramic decorative integrated board of high-strength light high-ductility according to claim 1, it is characterised in that: the height
Warm fluxing agent is one of calcination of talc, raw talcum, diopside and fluorite or a variety of.
6. the foamed ceramic decorative integrated board of high-strength light high-ductility according to claim 1, it is characterised in that: described is steady
Determining agent is liquid barium zinc compound stabilizer, liquid calcium zinc complex stabilizer, lead salt compound stabilizer, liquid barium cadmium and liquid barium cadmium
One of zinc composite stabilizer is a variety of.
7. the foamed ceramic decorative integrated board of high-strength light high-ductility according to claim 1, it is characterised in that: the solution
Jelly is polybasic carboxylic acid water solubility organic-based material.
8. a kind of preparation of the foamed ceramic decorative integrated board of high-strength light high-ductility described in -7 any one according to claim 1
Method, it is characterised in that: the following steps are included:
The preparation of S1, foamed light material: graphene and stone material tailing are weighed according to the formula, mixing crushes simultaneously grinding, so
After be added other raw materials, mixing 0.5~4h of homogenizing is handled by mist projection granulating, is dried, obtain foamed light powder；
The preparation of S2, high-ductility architectural surface: calcium carbonate and graphene are weighed according to the formula, mixing crushes simultaneously grinding, then
Other raw materials in formula are added, mixes 0.5~3h of homogenizing subsequently into high speed rotation mixing machine, is handled by mist projection granulating,
Drying, it is spare into savings storehouse, obtain high-ductility architectural surface raw material；
S3, it forms by a firing: the foamed light powder being burnt into 0.5~5h under 900~1300 DEG C of high temperature, is taken out after cooling,
Excision forming obtains foamed light material layer；
S4, secondary molding bonded: the high-ductility architectural surface raw material is passed through into press mold, fretting map, extrusion, and the foaming immediately
Light layer carries out bonding cooling in the case where whole face pressure is 0.5~1.0MPa state, forms high-ductility architectural surface；Through polishing, polishing,
Cutting forming, obtains foamed ceramic decorative integrated board crude product；
S5, coating: raw material is weighed according to the formula and prepares wear-resisting coating liquid, and is coated uniformly on the foamed ceramic decorative one
The surface of the high-ductility architectural surface of body plate crude product forms wear-resistant coating, obtains foamed ceramic decorative one board finished product.
9. the preparation method of the foamed ceramic decorative integrated board of high-strength light high-ductility according to claim 8, feature
It is: in step S5, sodium phosphate and sodium metasilicate is first poured into Hybrid Heating in container, temperature is controlled at 50~70 DEG C；Do not stop
Stirring, and silica solution mixes them thoroughly, obtains binder；Then in proportion by graphene, silicon carbide whisker, schmigel, leech
Stone, kaolin, fire retardant, nano-titanium dioxide and hydroxyethyl cellulose mixing, are added silicone acrylic emulsion, are stirred 1~2h, obtain
Mixture；Finally binder and mixture are added in blender, 1~5h is mixed, is uniformly mixed it wear-resisting to get arriving
Coating liquid.
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| PCT/CN2019/101846 WO2020063205A1 (en) | 2018-09-26 | 2019-08-21 | Light-weight high-strength high-toughness foamed ceramic decorative integrated board and preparation method therefor |
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| CN109291549B (en) * | 2018-09-26 | 2019-09-24 | 广西旭腾实业集团有限公司 | A kind of foamed ceramic decorative integrated board of high-strength light high-ductility and preparation method thereof |
| CN110372411A (en) * | 2019-08-07 | 2019-10-25 | 淄博金卡陶瓷有限公司 | Honeycomb high-strength light ceramic wafer |
| CN110655392A (en) * | 2019-10-24 | 2020-01-07 | 信阳师范学院 | Microcrystalline surface porous heat-insulating ceramic composite material taking low-grade potassium feldspar as raw material and preparation method thereof |
| CN110627494A (en) * | 2019-10-28 | 2019-12-31 | 深圳市玉瓷科技有限公司 | Graphene ceramic material and preparation method thereof |
| CN110981413B (en) * | 2019-12-23 | 2022-03-22 | 佛山欧神诺陶瓷有限公司 | High-performance foamed ceramic and preparation method and application thereof |
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| CN109291549A (en) | 2019-02-01 |
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