CN109281196A - The dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton - Google Patents
The dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton Download PDFInfo
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- CN109281196A CN109281196A CN201811028042.0A CN201811028042A CN109281196A CN 109281196 A CN109281196 A CN 109281196A CN 201811028042 A CN201811028042 A CN 201811028042A CN 109281196 A CN109281196 A CN 109281196A
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- Prior art keywords
- parts
- partly
- fabric
- dyeing
- agent
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- 239000004744 fabric Substances 0.000 title claims abstract description 172
- 238000004043 dyeing Methods 0.000 title claims abstract description 97
- 239000010977 jade Substances 0.000 title claims abstract description 74
- 229920000742 Cotton Polymers 0.000 title claims abstract description 72
- 238000003672 processing method Methods 0.000 title claims abstract description 38
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 65
- 238000009990 desizing Methods 0.000 claims abstract description 46
- 238000004513 sizing Methods 0.000 claims abstract description 39
- 239000000975 dye Substances 0.000 claims abstract description 37
- 239000000835 fiber Substances 0.000 claims abstract description 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004902 Softening Agent Substances 0.000 claims abstract description 8
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 8
- NNTWKXKLHMTGBU-UHFFFAOYSA-N 4,5-dihydroxyimidazolidin-2-one Chemical compound OC1NC(=O)NC1O NNTWKXKLHMTGBU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 6
- 229920001807 Urea-formaldehyde Polymers 0.000 claims abstract description 6
- 239000000675 fabric finishing Substances 0.000 claims abstract description 6
- 238000009962 finishing (textile) Methods 0.000 claims abstract description 6
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 6
- 125000002091 cationic group Chemical group 0.000 claims abstract description 5
- 239000003223 protective agent Substances 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 24
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 19
- 238000009991 scouring Methods 0.000 claims description 19
- 239000012752 auxiliary agent Substances 0.000 claims description 16
- 238000007670 refining Methods 0.000 claims description 15
- 229910052708 sodium Inorganic materials 0.000 claims description 15
- 239000011734 sodium Substances 0.000 claims description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 13
- 229920004933 Terylene® Polymers 0.000 claims description 12
- 239000002216 antistatic agent Substances 0.000 claims description 12
- 238000010792 warming Methods 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 10
- 239000007924 injection Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 229920004934 Dacron® Polymers 0.000 claims description 6
- 229920001410 Microfiber Polymers 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 6
- -1 poly- ammonia Ester Chemical class 0.000 claims description 5
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 125000005227 alkyl sulfonate group Chemical group 0.000 claims description 4
- 229910021389 graphene Inorganic materials 0.000 claims description 4
- 229950007687 macrogol ester Drugs 0.000 claims description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
- 235000017550 sodium carbonate Nutrition 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 4
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 4
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 4
- MHXFWEJMQVIWDH-UHFFFAOYSA-N 1-amino-4-hydroxy-2-phenoxyanthracene-9,10-dione Chemical compound C1=C(O)C=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C1OC1=CC=CC=C1 MHXFWEJMQVIWDH-UHFFFAOYSA-N 0.000 claims description 3
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 claims description 3
- 229920001732 Lignosulfonate Polymers 0.000 claims description 3
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 claims description 3
- 229920005610 lignin Polymers 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims 1
- 238000004321 preservation Methods 0.000 claims 1
- 230000008439 repair process Effects 0.000 claims 1
- 230000006386 memory function Effects 0.000 abstract description 12
- 238000011084 recovery Methods 0.000 abstract description 8
- 238000007639 printing Methods 0.000 abstract description 4
- 150000003961 organosilicon compounds Chemical class 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 44
- 238000012360 testing method Methods 0.000 description 16
- 239000002002 slurry Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 238000005259 measurement Methods 0.000 description 7
- 239000004753 textile Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000037303 wrinkles Effects 0.000 description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000005526 G1 to G0 transition Effects 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000009979 jig dyeing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 230000010148 water-pollination Effects 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 102100038123 Teneurin-4 Human genes 0.000 description 1
- 101710122302 Teneurin-4 Proteins 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 150000001735 carboxylic acids Chemical group 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000004879 dioscorea Nutrition 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 238000009527 percussion Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000012192 staining solution Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0032—Determining dye recipes and dyeing parameters; Colour matching or monitoring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/854—Textiles which contain different kinds of fibres containing modified or unmodified fibres, i.e. containing the same type of fibres having different characteristics, e.g. twisted and not-twisted fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of dyeing and finishing processing methods of precious jade imitation memory fabric of partly fluffing cotton, and are related to fabrics printing and dyeing technical field, its key points of the technical solution are that the following steps are included: (1) open-width desizing;(2) flat cylinder refines cloth;(3) it dyes;(4) preshrunk;(5) it is formed: fabric is subjected to soft sizing by forming machine, by, than being added in forming machine for the softening agent TF-404A and sizing aids of 20:1:1,165-185 DEG C of setting temperature, setting time 30-50s, the door width of forming machine is 153-155cm with fabric quality;The sizing aids include the substance of following parts by weight: 3-8 parts of hydroxymethyl-2 dihydroxy-ethylene urea resins, 4-8 parts of polyurethane-modified organosilicons, 3-6 portions of strong fiber protective agents LH-034,2-5 parts of cationic ammonia tomb silicone fabric finishing agents, 3-6 parts of melamine resins.The present invention solve the problems, such as partly to fluff cotton precious jade dyeing fabric shape memory function and shape-recovery capabilities it is not high.Using sizing aids, the shape memory function and shape-recovery capabilities of precious jade fabric of partly fluffing cotton can be improved.
Description
Technical field
The present invention relates to fabrics printing and dyeing technical fields, more specifically, it is related to a kind of precious jade imitation memory fabric of partly fluffing cotton
Dyeing and finishing processing method.
Background technique
Shape memory fabric be one kind by the material with shape memory function, be processed into the form weaved or arranged or
It is introduced into fabric, under specific external condition, has shape memory, high recovery deformation, good antidetonation and adaptability etc. excellent
The textile of anisotropic energy.In its face polymers molecule, by the stationary phase and amorphous phase of crystallization phase composition and generation crystallization and knot
Crystalline substance melting reversible change partially crystallizable structure composition can anti-phase collective effect, and then assign fabric form memory function.
It is all with stationary phase and can anti-phase polymer, all have shape memory function, such as terylene (PET) fabric.But
The glass transition temperature (Tg) of terylene differs more apparent with human body temperature and conventional environment, is not easy daily usually at 80 DEG C or so
Its shape memory is embodied in life.The memory function of fabric not only with the glass transition temperature of fiber, molecule modulus, crystallization
The supramolecular structures such as degree are related, and closely related with the factors such as textile technology such as yarn twist, line density.As on the market
The precious jade fabric of partly fluffing cotton of higher reputation is obtained, warp uses terylene 75D/72F network yarn, and weft uses 150D polyester low stretch
Silk with 40D spandex coat, weaved on rapier loom in plain weave, weft yams are acted on through twisting so that its in
Torque resilience performance it is violent, can express certain memory effect in use, and fabric is integrally well-pressed, it is flexible,
Cloth is fine and soft, and slim and graceful smooth, drapability is good, soft handle, therefore the derived product as memory class fabric, with its imitative memory characteristic
And relative to the lower price of memory class fabric, it is widely used in the fields such as housing, tooling, men and women's easy dress, family's decorations.
In the prior art, it can refer to the Chinese invention patent file that Authorization Notice No. is CN103243573B, it discloses
A kind of dyeing and printing process for imitation memory fabric, comprising: first time desizing refining step, second of desizing refining step and dyeing
Step.For 150D fabric, increase low alkali cold dome step before first time desizing refining step;For 50D fabric,
Increase the pre- alkali treatment of an open width.
The dyeing and printing process of existing this imitation memory fabric, due to using desizing refining step twice, although can make
The dyeing effect of fabric is more preferable, so that the color difference of finished product is smaller, improves the quality of finished product;But this method processing is partly fluffed cotton, and precious jade is imitative to be remembered
When recalling fabric, the time of concise desizing is longer twice, the shape memory function for precious jade imitation memory fabric of partly fluffing cotton and high recovery deformation
Ability is poor.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of dye of precious jade imitation memory fabric of partly fluffing cotton
Finishing processing method makes precious jade imitation memory fabric even dyeing of partly fluffing cotton by special dyeing and setting treatment, and has good
Shape memory function and dimensional stability.
To achieve the above object, the present invention provides the following technical scheme that a kind of dyeing and finishing for precious jade imitation memory fabric of partly fluffing cotton
Processing method, comprising the following steps: (1) open-width desizing;(2) flat cylinder refines cloth;(3) it dyes;(4) preshrunk;(5) it is formed;The step
Suddenly (3) are realized in accordance with the following methods: the complete fabric of cloth will be refined and be placed in overflow dyeing machine, the temperature of overflow dyeing machine is increased to 45 DEG C,
Dye liquor and auxiliary agent are injected, control bath raio is 1:8, starts to be warming up to 80 with the speed of 0.6-0.8 DEG C/min after the completion of dye liquor injection
DEG C, and 10-15min is kept the temperature, then be warming up to 105 DEG C with the speed of 0.6-0.8 DEG C/min, and keep the temperature 8-12min, then with 0.7-
The speed of 0.9 DEG C/min is warming up to 130 DEG C, keeps the temperature 55-65min, is finally cooled down with the speed of 1.0-1.4 DEG C/min, when
When temperature is down to 60 DEG C, it is rinsed with water 15-20min;
The formula of the dye liquor are as follows: disperse grey E-N0.085%owf, Disperse Red 3B 0.089%owf, disperse yellow E-
GL0.053owf;
The auxiliary agent comprises the following components in parts by weight: the sulphur ammonium that 20-30 parts of water, 3-8 parts of mass concentrations are 0.6-0.9g/L is molten
Dressing agent that levelling agent that liquid, 4-9 part mass concentration are 0.3-0.5g/L, 3-5 parts of mass concentrations are 0.3-0.5g/L, 4-8 parts
Mass concentration is the yarn agent of deoiling of 0.3-0.4g/L;Wherein levelling agent is dacron ultrafine fiber high temperature levelling agent TF-212K, is repaired
Toner is dressing agent S-8231, and yarn agent of deoiling is the yarn agent TF-106T that deoils;
The step (5) is to realize in accordance with the following methods: fabric is subjected to soft sizing by forming machine, it will be with fabric quality ratio
It is added in forming machine for the softening agent TF-404A and sizing aids of 20:1:1,165-185 DEG C of setting temperature, be formed speed 40-
45m/min, be formed overfeeding+4%-+6%, setting time 30-50s, and the door width of forming machine is 153-155cm;
Wherein the concentration of softening agent TF-404A is 20-30g/L;
The sizing aids include the substance of following parts by weight: 3-8 parts of hydroxymethyl-2 dihydroxy-ethylene urea resins, 4-8 parts of poly- ammonia
Ester modified organosilicon, 3-6 portions of strong fiber protective agents LH-034,2-5 parts of cationic ammonia tomb silicone fabric finishing agents, 3-
6 parts of melamine resins.
By using above-mentioned technical proposal, the slurry of fabric surface is removed first with open-width desizing, is convenient for subsequent dyeing
And sizing, then flat cylinder refining cloth is carried out, the friction between fiber and fiber can be adjusted, coefficient of friction is reduced, reduces the production of electrostatic
Raw, the fabric by flat cylinder refining cloth has good dyeability and feel;Partly fluff cotton precious jade fabric ingredient be terylene, glass
Change temperature and is generally 70-80 DEG C, when temperature is higher than its vitrification point, fiber macromolecular chain segment motion intense, intermolecular sky
Gap increases, and the dye liquor molecule and the lesser molecule of portion size for being dissolved in the dispersion in dye liquor can carry out fibrous inside, therefore
At 80 DEG C, dyeing rate is most fast, and dacron ultrafine fiber levelling agent TF-212K and dressing agent S-8231 can contaminate shallower fabric
When, it avoiding generating color difference, improves dyeing effect and level dyeing degree, after 120 DEG C of dyeing are kept the temperature, cooling rate is more slow,
It can prevent fabric from generating wrinkle and coarse feel;
For fabric in dyeing, the movement of strand can make a width have certain contraction, in desizing, refining cloth and dyeing course, knit
Object by various external force effect and generate deformation, there are internal stress, fabric plays pendulum, sizing when, use
165-185 DEG C, higher temperature can be such that terylene intramolecule energy is released, and internal stress is relaxed, and crystallinity and take
It is improved to degree, so that fabric system is in ability minimum state, and then obtain good dimensional stability, it is wherein strong in sizing aids
Power fiber protection agent can improve the tearing brute force of fabric itself, improve the wrinkle resistance and wearability of fabric, provide soft and rich
Full feel, hydroxymethyl-2 dihydroxy-ethylene urea resin can make fabric have good feel, and high resilience, raising are knitted
The washability and hydrolytic resistance of object;Polyurethane-modified organosilicon, fiber is in sizing, expanded by heating, while polyurethane-modified having
The arrangement of machine silicon is aggravated by thermal molecular motion, enters fibrous inside and fiber easily with Hydrogenbond, is conducive to the color jail for improving fabric
Degree, and polyurethane-modified organosilicon forms a film in fiber surface, keeps fiber surface flat and smooth, reducing fabric movement makes the resistance of fiber
Power, while the fibrous elasticity wrapped up that the introducing of polyurethane segment is increases, and reinforces the shape memory function of fabric;Sun from
Subtype ammonia tomb silicone fabric finishing agent can make fabric have good feel and elasticity, increase the washable and wear-resisting of fabric
Fastness;Melamine resin can increase shrinkproof, wrinkle resistant, the washable function of fabric;Therefore patterning process can make to knit
The good shape memory function of the acquisition of object, guarantees the dimensional stability of fabric.
The present invention is further arranged to: the warp and weft for partly fluffing cotton precious jade imitation memory fabric are 75D terylene, broadwise
Twisting, twist 22T/2S2Z.
By using above-mentioned technical proposal, radial line and weft are all made of 75D terylene, and weft is twisted, and the twist is 22
It twists, 2 is left, 2 right twisting, and due to using thinner 75D terylene, so that the elasticity of fabric is stronger, shape memory function is stronger.
The present invention is further arranged to: further include in the sizing aids with sizing aids mass ratio be 1:1 it is antistatic
Agent;The antistatic agent comprises the following components in parts by weight: Sodium Polyacrylate, the 3-7 that 2-5 parts of mass fractions are 0.1-1.0%
Macrogol ester, 1-3 parts of graphenes, 2-5 parts of zinc oxide, the 2-6 parts of sodium lignin sulfonates, 2-5 parts that part mass fraction is 1-3%
Conductive mica.
By using above-mentioned technical proposal, macrogol ester contains ehter bond, is easy through ehter bond in conjunction with moisture in air,
And conductive channel is formed, it is used in conjunction with Sodium Polyacrylate sodium, antistatic effect is more preferable, and graphene has good electron-transport
Performance can export electrostatic, carry out anti-static functional arrangement to fabric, fabric surface hydrophily can be improved, and then reduce
Sheet resistance reaches antistatic effect, and polyester segment is identical as terylene molecular structure in addition, and eutectic is formed after heat treatment, forms
Long-chain also greatly improves washability.
The present invention is further arranged to: the step (1) is realized in accordance with the following methods: the precious jade imitation memory fabric that will partly fluff cotton is put
Set fill desizing liquid pad padded in slot the temperature for keeping desizing liquid twice be 85-90 DEG C, pad every time 2-3 hours, it
It banks up at 60-80 DEG C 8-10 hours, is rinsed with clear water afterwards.
By using above-mentioned technical proposal, slurry therewith ingredient is mainly polyvinyl alcohol and gathers in precious jade weaving process of partly fluffing cotton
Acrylic acid sodium ester, the use of desizing liquid can make ester bond alcoholysis in slurry macromolecular, and the carboxylic acid side chain of amido bond becomes sodium salt, from
And macromolecular chain segment is set to break to form the degree of polymerization compared with small molecule and segment, and then be changed into have by gelling material by slurry and dissolve
The colloidal sol of property, under 85-90 DEG C of environment, the dissociation that high temperature established leftover slurry originally is broken, towards being conducive to starch
Expect the orienting response decomposed, keeps desizing complete, enter fibrous inside convenient for subsequent dye liquor, make even dyeing.
The present invention is further arranged to: the step (2) is realized in accordance with the following methods: water being added in flat cylinder, keeps water
Temperature be 50-60 DEG C, auxiliary scouring agent is being added into flat cylinder, the precious jade imitation memory fabric of partly fluffing cotton after desizing is placed on flat cylinder
In, control water-bath ratio is 1:10, then temperature is risen to 95-100 DEG C, is refined cloth 3-4 hours, is washed after refining cloth;
Wherein auxiliary scouring agent comprises the following components in parts by weight: 10-15 parts of mass concentrations be the liquid alkaline of 5-10g/L, 3-7 parts deoil
Spirit, 2-5 parts of mass concentrations be 2-5g/L soda ash, 3-5 parts of mass concentrations be 1-3g/L scouring agent;
Spirit deoil wherein as deoil clever TF-108A, scouring agent WT-N6.
By using above-mentioned technical proposal, in spinning weaving process, often need that different type is added according to process difference
Finish, if but finish remove and be not thorough in pretreatment process, easily cause cloth cover color spot, it is therefore desirable to flat cylinder refine cloth process
It is middle that the clever TF-108A that deoils is added, with excellent emulsification and dispersibility, it is ensured that fabric oil agent is effectively removed,
And it prevents from staiing fabric surface again;In 95-100 DEG C of high temperature and by under liquid alkaline and the alkaline environment of soda ash manufacture, fabric is fine
Dimension can sufficiently obtain moisture expantion, and in addition due to alkali denudation, surface hollow is obvious, and specific surface area increases, and not only make
Measurement of Quality in Unit Area of Fabric decline, and preferable dyeability and feel can be obtained.
The present invention is further arranged to: the desizing liquid comprises the following components in parts by weight: 10-15 parts of mass concentrations are
4-7 parts of 5-9 parts of sodium hydroxide, tripolyphosphate ammonium, the neopelex of 10-20g/L, 3-5 parts of sodium secondary alkyl sulfonate, alkali
3-6 parts of lignin, 20-30 parts of water.
By using above-mentioned technical proposal, sodium hydroxide makes desizing liquid keep alkalinity, and paste composition is mainly polyvinyl alcohol
With polyacrylic acid sodium ester, the decontamination of neopelex and sodium secondary alkyl sulfonate at high temperature is higher, can make to starch
Material dissolves in lye, and tripolyphosphate ammonium has good chelation to the metal ion in slurry after dissolution, not only can be with
Preventing from falling off, slurry is counter to stain, and can soften processing quality of water, in the flowing of desizing liquid, own physical gravity and water
Under percussion, slurry and finish etc. fall off from fabric to be separated.
The present invention is further arranged to: liquid alkaline is the sodium hydroxide and matter that mass fraction is 30-32% in the auxiliary scouring agent
Measure the mixed liquor for the vulcanized sodium that score is 14-18%.
By using above-mentioned technical proposal, sodium hydroxide and vulcanized sodium can be such that the slurry on fabric is swollen, after swelling
Slurry is washed away due to water, is fallen off from fabric, keeps fabric spreading mass desizing complete, avoids slurry remaining, causes dyeing uneven
It is even.
The present invention is further arranged to: heap is postponed in the step (1) is padded with the dilute sulfuric acid that mass concentration is 4-6g/L
Twice, it then banks up 3-6 hours.
By using above-mentioned technical proposal, lye remaining on fiber can be neutralized with dilute sulfuric acid, and is removed and inhaled on fiber
The coloring matters such as attached residue glue keep fiber loosely soft, further promote slurry hydrolysis, remove organic salt impurity on fabric,
Desizing rate is improved, even dyeing is made.
The present invention is further arranged to: dye liquor is uniformly injected into the form of ratio material feeding in the step (3), total injection time
For 15min.
Textile dyeing can be made uniform dye liquor uniform material feeding several times by using above-mentioned technical proposal, prevent because
Situations such as material feeding is too fast, causes uneven dyeing.
The present invention is further arranged to: the preshrunk temperature of step (4) preshrunk is 110-130 DEG C, speed 10-20m/
min。
By using above-mentioned technical proposal, shrinking processes can reduce fabric, and radially shrink and stable broadwise are shunk, and are reduced
Fabric washing shrinkage improves fabric flexibility.
In conclusion the present invention has the advantages that compared with the prior art
(1) by the present invention in that with specific sizing aids, make fabric that there is good shape memory function and height after sizing
Recovery capability increases the washable and wear resistance of fabric, guarantees the dimensional stability of fabric;
(2) present invention can carry out anti-static functional arrangement to fabric by adding specific antistatic agent in dye liquor, can
Fabric surface hydrophily is improved, and then reduces sheet resistance, reaches antistatic effect;
(3) present invention can make the dispersion being dissolved in dye liquor by specifically heating and cooling step in dyeing course
Dye liquor molecule and the lesser molecule of portion size can carry out fibrous inside, improve dyeing rate, can prevent fabric from generating folding
Wrinkle and coarse feel;
(4) present invention can be avoided by the way that dacron ultrafine fiber levelling agent TF-212K and dressing agent S-8231 is added in dyeing
Color difference is generated, dyeing effect and level dyeing degree are improved.
Specific embodiment
In following embodiment: step (1) open width is moved back middle using open-width desizing range, is the limited public affairs of the flourish dyeing and finishing machinery of Taiwan letter
Take charge of the OS-9V1200 open-width desizing range of manufacture, the flat cylinder of step (2) refines cloth using high-temperature high-pressure automatic jig dyeing, for Zhejiang Huahai
The ZHGR2200S type high-temperature high-pressure automatic jig dyeing of resultant force Science and Technology Co., Ltd. manufacture, overflow dyeing machine is Haining in step (3)
The CSF18020 high temperature and pressure liquid stream overflow dyeing machine of Yadong Machinery Co., Ltd. manufacture, forming machine is Micron Technology of South Korea machine in step (5)
The MEGATE forming machine of Xie Zhu formula Co., Ltd manufacture.
A kind of embodiment 1: dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, comprising the following steps:
(1) open-width desizing;Precious jade imitation memory fabric of partly fluffing cotton is placed on and fills padding for desizing liquid and is padded in slot twice, keeps moving back
The temperature of slurries is 85 DEG C, pads 2 hours, banks up at 60 DEG C later 8 hours every time, the dilute sulfuric acid for being 4g/L with mass concentration
It pads twice, then banks up 3 hours, rinsed with clear water;
The warp and weft for precious jade imitation memory fabric of wherein partly fluffing cotton are 75D terylene, broadwise twisting, twist 22T/2S2Z;
Desizing liquid comprises the following components in parts by weight: 10 parts of mass concentrations are 5 parts of sodium hydroxide, the tripolyphosphate ammonium of 10g/L, ten
4 parts of dialkyl benzene sulfonic acids sodium, 3 parts of sodium secondary alkyl sulfonate, 3 parts of alkali lignin, 20 parts of water;
(2) flat cylinder refines cloth: water is added in flat cylinder, keeping the temperature of water is 50 DEG C, auxiliary scouring agent is being added into flat cylinder, by desizing
Precious jade imitation memory fabric of partly fluffing cotton afterwards is placed in flat cylinder, and control water-bath ratio is 1:10, then temperature is risen to 95 DEG C, refines cloth 3
Hour, it is washed after refining cloth;
Wherein auxiliary scouring agent comprises the following components in parts by weight: 10 parts of mass concentrations are the liquid alkaline of 5g/L, 3 parts of deoil spirits, 2 parts of quality
The scouring agent that soda ash that concentration is 2g/L, 3 parts of mass concentrations are 1g/L;
Spirit deoil wherein as deoil clever TF-108A, scouring agent WT-N6;
Liquid alkaline is the mixed liquor of the sodium hydroxide that mass fraction is 30% and the vulcanized sodium that mass fraction is 14% in auxiliary scouring agent;
(3) dye: the complete fabric of cloth will be refined and be placed in overflow dyeing machine, the temperature of overflow dyeing machine is increased to 45 DEG C, injection dye liquor and
Auxiliary agent, control bath raio are 1:8, and dye liquor is uniformly injected into the form of ratio material feeding, and total injection time is 15min;Dye liquor injection is completed
Start to be warming up to 80 DEG C with the speed of 0.6 DEG C/min afterwards, and keep the temperature 10min, then be warming up to 105 DEG C with the speed of 0.6 DEG C/min,
And keep the temperature 8min, be then warming up to 130 DEG C with the speed of 0.7 DEG C/min, keep the temperature 55min, finally with the speed of 1.0 DEG C/min into
Row cooling, when temperature is down to 60 DEG C, is rinsed with water 15min;
The formula of the dye liquor are as follows: disperse grey E-N0.085%owf, Disperse Red 3B 0.089%owf, disperse yellow E-
GL0.053owf;
The auxiliary agent comprises the following components in parts by weight: 20 parts of water, 3 parts of mass concentrations are the ammonium sulfate solution of 0.6g/L, 4 parts of quality
The yarn that deoils that dressing agent that levelling agent that concentration is 0.3g/L, 3 parts of mass concentrations are 0.3g/L, 4 parts of mass concentrations are 0.3g/L
Agent;Wherein levelling agent is dacron ultrafine fiber high temperature levelling agent TF-212K, and dressing agent is dressing agent S-8231, and yarn agent of deoiling is
Deoil yarn agent TF-106T;
(4) preshrunk: preshrunk temperature is 110 DEG C, speed 10m/min;
(5) be formed: by fabric by forming machine carry out softness sizing, by with fabric quality than the softening agent TF- for 20:1:1:1
404A sizing aids and antistatic agent are added in forming machine, and 165 DEG C of setting temperature, be formed speed 40m/min, and sizing overfeeding+
4%, setting time 30s, the door width of forming machine are 153cm;
Wherein the concentration of softening agent TF-404A is 20g/L;
Sizing aids include the substance of following parts by weight: 3 parts of hydroxymethyl-2 dihydroxy-ethylene urea resins, 4-8 parts it is polyurethane-modified
Organosilicon, 3 parts of strong fiber protective agent LH-034,2 parts of cationic ammonia tomb silicone fabric finishing agents, 3 parts of melamines
Formaldehyde resin;
Antistatic agent comprises the following components in parts by weight: Sodium Polyacrylate that 2 parts of mass fractions are 0.1%, 3 parts of mass fractions are
1% macrogol ester, 1 part of graphene, 2 parts of zinc oxide, 2 parts of sodium lignin sulfonates, 2 parts of Conductive micas.
Embodiment 2-5: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, it is fixed
The corresponding parts by weight of component and each component that type auxiliary agent includes are as shown in table 1.
Component contained by sizing aids and the corresponding parts by weight of each component in 1 embodiment 2-5 of table
Embodiment 6-9: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, desizing liquid
Contained component and the corresponding parts by weight of each component are as shown in table 2.
Component contained by desizing liquid and the corresponding parts by weight of each component in 2 embodiment 6-9 of table
Embodiment 10-13: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, help refining
The corresponding parts by weight of component and each component contained by agent are as shown in table 3.
Component contained by auxiliary scouring agent and the corresponding parts by weight of each component in 3 embodiment 10-13 of table
Embodiment 14-17: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, resist quiet
Component contained by electric agent and the corresponding parts by weight of each component are as shown in table 4.
Component contained by antistatic agent and the corresponding parts by weight of each component in 4 embodiment 14-17 of table
Embodiment 18: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, each step
Technological parameter it is different, it is specific as follows:
(1) open-width desizing;Precious jade imitation memory fabric of partly fluffing cotton is placed on and fills padding for desizing liquid and is padded in slot twice, keeps moving back
The temperature of slurries is 90 DEG C, pads 3 hours, banks up at 80 DEG C later 10 hours every time, the dilute sulphur for being 6g/L with mass concentration
Acidleach is rolled twice, then is banked up 6 hours, is rinsed with clear water;
The warp and weft for precious jade imitation memory fabric of wherein partly fluffing cotton are 75D terylene, broadwise twisting, twist 22T/2S2Z;
(2) flat cylinder refines cloth: water is added in flat cylinder, keeping the temperature of water is 60 DEG C, auxiliary scouring agent is being added into flat cylinder, by desizing
Precious jade imitation memory fabric of partly fluffing cotton afterwards is placed in flat cylinder, and control water-bath ratio is 1:10, then temperature is risen to 100 DEG C, refines cloth 4
Hour, it is washed after refining cloth;
(3) dye: the complete fabric of cloth will be refined and be placed in overflow dyeing machine, the temperature of overflow dyeing machine is increased to 45 DEG C, injection dye liquor and
Auxiliary agent, control bath raio are 1:8, and dye liquor is uniformly injected into the form of ratio material feeding, and total injection time is 15min;Dye liquor injection is completed
Start to be warming up to 80 DEG C with the speed of 0.8 DEG C/min afterwards, and keep the temperature 15min, then be warming up to 105 DEG C with the speed of 0.8 DEG C/min,
And 12min is kept the temperature, 130 DEG C then are warming up to the speed of 0.9 DEG C/min, 65min is kept the temperature, finally with the speed of 1.4 DEG C/min
Cool down, when temperature is down to 60 DEG C, is rinsed with water 20min;
(4) preshrunk: preshrunk temperature is 130 DEG C, speed 20m/min;
(5) be formed: by fabric by forming machine carry out softness sizing, by with fabric quality than the softening agent TF- for 20:1:1:1
404A sizing aids and antistatic agent are added in forming machine, and 185 DEG C of setting temperature, be formed speed 45m/min, and sizing overfeeding+
6%, setting time 50s, the door width of forming machine are 155cm.
Comparative example 1: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
(1) desizing liquid is not used in.
Comparative example 2: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
(2) auxiliary scouring agent is not used in.
Comparative example 3: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
(3) auxiliary agent is not injected into.
Comparative example 4: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
(5) sizing aids are not used in.
Comparative example 5: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, it is described
Antistatic agent is not used in step (5).
Comparative example 6: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
(3) it is not injected into auxiliary agent in, does not use sizing aids in step (5).
Comparative example 7: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
(5) sizing aids are free of polyurethane-modified organosilicon in.
Comparative example 8: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
(5) sizing aids are free of strong fiber protective agent in.
Comparative example 9: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
(5) sizing aids are free of cationic ammonia tomb silicone fabric finishing agent in.
Comparative example 10: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
Suddenly sizing aids are free of melamine resin in (5).
Comparative example 11: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
Suddenly sizing aids are free of hydroxymethyl-2 dihydroxy-ethylene urea resin in (5).
Comparative example 12: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
Suddenly auxiliary agent is free of sulphur ammonium in (3).
Comparative example 13: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
Suddenly dacron ultrafine fiber high temperature levelling agent TF-212K is free of in (3).
Comparative example 14: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
Suddenly dressing agent S-8231 is free of in (3).
Comparative example 15: a kind of dyeing and finishing processing method for precious jade imitation memory fabric of partly fluffing cotton, the difference from embodiment 1 is that, step
Suddenly without the yarn agent TF-106T that deoils in (3).
By according to the precious jade imitation memory fabric of partly fluffing cotton after dyeing and finishing processing method dyeing and finishing in embodiment 1-18 and comparative example 1-15,
It is detected according to following detection method:
1, whiteness: measuring according to GB/T8245-1987 " the Instrument measuring method of textile whiteness ", and test result is as shown in table 5;
2, ultimate strength and tearing brute force: according to GB/T3923-1997, " textile fabric tensile property first part: fracture is strong
The measurement galley proof method of power and extension at break " it measures, test result is as shown in table 5;
3, it creasy recovery angle: according to GBT3819-1997 " horn cupping is replied in the measurement of textile fabric wrinkle recovery property " measurement, surveys
Test result is as shown in table 5;
4, it the performance measurements such as fastness to rubbing, washing fastness: is detected according to GB/T17253-2008 " synthetic fibers silk fabrics "
Standard test, test result are as shown in table 6;
5, elastic extension: detecting according to ASTM3107-75 " elastic fabric method of testing ", and test result is as shown in table 6;
6, desizing rate is tested: desizing rate=[fabric weight before (before desizing in fabric-desizing after fabric weight)/desizing] × 100% is surveyed
Test result is as shown in table 6;
7, the measurement of dyeing percentage: dyestuff is measured in the extinction of maximum absorption wave strong point using ultraviolet-visible spectrophotometer
Degree, and the dyeing percentage of dyestuff: E=(A0-A1)/A0 × 100% is calculated according to the following formula, in formula: E is dyeing percentage;A0
For blank dye liquor absorbance;A1 is staining solution absorbance, and test result is as shown in table 6.
Table 5 according to embodiment 1-18 and the precious jade imitation memory fabric of partly fluffing cotton of comparative example 1-15 dyeing and finishing test result
Respectively without using desizing liquid and auxiliary scouring agent in comparative example 1 and comparative example 2, so half bullet in comparative example 1 and comparative example 2
The whiteness of flower precious jade imitation memory fabric is smaller, without using sizing aids, therefore half bullet Jing Guo 4 dyeing and finishing of comparative example in comparative example 4
Spend the ultimate strength, tearing brute force and creasy recovery angle performance of precious jade imitation memory fabric poor;It is helped in comparative example 7-11 without sizing
Any one component in agent, by the inspection of the precious jade imitation memory fabric of partly fluffing cotton of comparative example 7-11 dyeing and finishing it can be seen from data in 5
Measured data result is poor.
Table 6 according to embodiment 1-18 and the precious jade imitation memory fabric of partly fluffing cotton of comparative example 1-15 dyeing and finishing method dyeing and finishing test number
According to
Desizing agent is used because no in comparative example 1, therefore desizing rate test result is lower, dyeing percentage numerical value is lower, comparison
Example 2 does not use auxiliary scouring agent, and in flat cylinder refining cloth, desizing is incomplete, causes desizing rate and dyeing percentage numerical value lower, right
Without using sizing aids, therefore the elastic extension of the precious jade imitation memory fabric of partly fluffing cotton Jing Guo 4 dyeing and finishing of comparative example in ratio 4
It is smaller, without using sizing aids and auxiliary agent, therefore the precious jade imitation memory fabric of partly fluffing cotton Jing Guo 6 dyeing and finishing of comparative example in comparative example 6
Elastic extension it is lower, and dyeing percentage is lower.
It will be according to comparative example 3, comparative example 6, comparative example 12-15, embodiment 2, embodiment 6, embodiment 10, embodiment 14
The test of dye uniformity is carried out with the precious jade imitation memory fabric of partly fluffing cotton of 18 dyeing and finishing of embodiment, test method is as follows:
10 different points are randomly selected on dye sample, test their K/S value respectively, then according to mathematical statistics principle, are divided
Average value, very poor and relative standard deviation (Sr) are not calculated, for characterizing the level-dyeing property of dyed fabric.Very poor, relative standard
Deviation is smaller, then level-dyeing property is better, and correlation formula is as follows:
In formula:Represent the k/s value of maximum absorption wave strong point i-th measurement;It represents i-th point of k/s value and puts down
The standard deviation of mean value;Sr represents the K/S value of each point and the standard deviation of average value, and test structure is as shown in table 7.
7 auxiliary agent of table is half-and-half fluffed cotton the influence test result of precious jade imitation memory fabric dye uniformity
As shown in Table 7, the precious jade of partly fluffing cotton according to embodiment 2, embodiment 6,18 dyeing and finishing of embodiment 10, embodiment 14 and embodiment is imitative
The standard deviation of memory face fabric is small, very poor also relatively small, illustrates according to embodiment 2, embodiment 6, embodiment 10, embodiment 14
It is higher with the dye uniformity of the precious jade imitation memory fabric of partly fluffing cotton of 18 dyeing and finishing of embodiment, according to comparative example 3 and comparative example 6 and
The standard deviation of the precious jade imitation memory fabric of partly fluffing cotton of comparative example 12-15 dyeing and finishing is larger, very poor also larger, comparative example 3 and comparative example 6
In without addition auxiliary agent, respectively without a component in addition auxiliary agent in comparative example 12-15, illustrate that auxiliary agent precious jade of half-and-half fluffing cotton is imitative
The dye uniformity of memory face fabric has preferable effect, according to the precious jade of partly fluffing cotton of comparative example 3, comparative example 6 and comparative example 12-15 dyeing and finishing
The dye uniformity of imitation memory fabric is poor.
By the imitative note of precious jade of partly fluffing cotton by comparative example 5 and embodiment 2, embodiment 6, embodiment 10, embodiment 14-18 dyeing and finishing
Recall the detection that fabric carries out antistatic property according to GB/T12703.2-2009 " textile antistatic property evaluates part 2 ", surveys
It is as shown in table 8 to try structure.
8 antistatic agent of table half-and-half fluff cotton precious jade imitation memory fabric antistatic property influence test result
Because without using antistatic agent, sheet resistance is larger, half-life in comparative example 5 it can be seen from the data in table 8
Longer, electrostatic pressure is larger, and resists according to embodiment 2, embodiment 6, embodiment 10, embodiment 14-18 dyeing and finishing method and process quiet
The sheet resistance of electric treatment is smaller, and half-life is short, and electrostatic pressure is smaller, and antistatic effect is obvious.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (10)
- The dyeing and finishing processing method of precious jade imitation memory fabric 1. one kind is partly fluffed cotton, comprising the following steps: (1) open-width desizing;(2) flat cylinder refining Cloth;(3) it dyes;(4) preshrunk;(5) it is formed;It is characterized by: the step (3) is realized in accordance with the following methods: complete by cloth is refined Fabric is placed in overflow dyeing machine, and the temperature of overflow dyeing machine is increased to 45 DEG C, injects dye liquor and auxiliary agent, and control bath raio is 1:8, dye liquor Start with the speed of 0.6-0.8 DEG C/min to be warming up to 80 DEG C after the completion of injection, and keep the temperature 10-15min, then with 0.6-0.8 DEG C/ The speed of min is warming up to 105 DEG C, and keeps the temperature 8-12min, is then warming up to 130 DEG C with the speed of 0.7-0.9 DEG C/min, heat preservation 55-65min is finally cooled down with the speed of 1.0-1.4 DEG C/min, when temperature is down to 60 DEG C, is rinsed with water 15-20min;The formula of the dye liquor are as follows: disperse grey E-N0.085%owf, Disperse Red 3B 0.089%owf, disperse yellow E-GL0.053owf;The auxiliary agent comprises the following components in parts by weight: the sulphur ammonium that 20-30 parts of water, 3-8 parts of mass concentrations are 0.6-0.9g/L is molten Dressing agent that levelling agent that liquid, 4-9 part mass concentration are 0.3-0.5g/L, 3-5 parts of mass concentrations are 0.3-0.5g/L, 4-8 parts Mass concentration is the yarn agent of deoiling of 0.3-0.4g/L;Wherein levelling agent is dacron ultrafine fiber high temperature levelling agent TF-212K, repairs color Agent is dressing agent S-8231, and yarn agent of deoiling is the yarn agent TF-106T that deoils;The step (5) is to realize in accordance with the following methods: fabric is subjected to soft sizing by forming machine, it will be with fabric quality ratio It is added in forming machine for the softening agent TF-404A and sizing aids of 20:1:1,165-185 DEG C of setting temperature, be formed speed 40- 45m/min, be formed overfeeding+4%-+6%, setting time 30-50s, and the door width of forming machine is 153-155cm;Wherein the concentration of softening agent TF-404A is 20-30g/L;The sizing aids include the substance of following parts by weight: 3-8 parts of hydroxymethyl-2 dihydroxy-ethylene urea resins, 4-8 parts of poly- ammonia Ester modified organosilicon, 3-6 portions of strong fiber protective agents LH-034,2-5 parts of cationic ammonia tomb silicone fabric finishing agents, 3- 6 parts of melamine resins.
- 2. precious jade imitation memory fabric dyeing and finishing processing method according to claim 1 of partly fluffing cotton, it is characterised in that: described partly to fluff cotton The warp and weft of precious jade imitation memory fabric are 75D terylene, broadwise twisting, twist 22T/2S2Z.
- 3. precious jade imitation memory fabric dyeing and finishing processing method according to claim 1 of partly fluffing cotton, it is characterised in that: the sizing helps It further include the antistatic agent for being 1:1 with sizing aids mass ratio in agent;The antistatic agent comprises the following components in parts by weight: Sodium Polyacrylate, the 3-7 that 2-5 parts of mass fractions are 0.1-1.0% Macrogol ester, 1-3 parts of graphenes, 2-5 parts of zinc oxide, the 2-6 parts of sodium lignin sulfonates, 2-5 parts that part mass fraction is 1-3% Conductive mica.
- 4. precious jade imitation memory fabric dyeing and finishing processing method according to claim 1 of partly fluffing cotton, it is characterised in that: the step (1) in accordance with the following methods realize: precious jade imitation memory fabric of partly fluffing cotton is placed on fill desizing liquid pad padded in slot twice, protect The temperature for holding desizing liquid is 85-90 DEG C, pads 2-3 hours every time, banks up at 60-80 DEG C 8-10 hours, rushed later with clear water It washes.
- 5. precious jade imitation memory fabric dyeing and finishing processing method according to claim 1 of partly fluffing cotton, it is characterised in that: the step (2) it realizes in accordance with the following methods: water is added in flat cylinder, keeping the temperature of water is 50-60 DEG C, helps refining being added into flat cylinder Precious jade imitation memory fabric of partly fluffing cotton after desizing is placed in flat cylinder by agent, and control water-bath ratio is 1:10, then temperature is risen to It 95-100 DEG C, refines cloth 3-4 hours, is washed after refining cloth;Wherein auxiliary scouring agent comprises the following components in parts by weight: 10-15 parts of mass concentrations be the liquid alkaline of 5-10g/L, 3-7 parts deoil Spirit, 2-5 parts of mass concentrations be 2-5g/L soda ash, 3-5 parts of mass concentrations be 1-3g/L scouring agent;Spirit deoil wherein as deoil clever TF-108A, scouring agent WT-N6.
- 6. precious jade imitation memory fabric dyeing and finishing processing method according to claim 5 of partly fluffing cotton, it is characterised in that: the desizing liquid Comprise the following components in parts by weight: 10-15 parts of mass concentrations are 5-9 parts of sodium hydroxide, the tripolyphosphate ammonium of 10-20g/L, 12 4-7 parts of sodium alkyl benzene sulfonate, 3-5 parts of sodium secondary alkyl sulfonate, 3-6 parts of alkali lignin, 20-30 parts of water.
- 7. precious jade imitation memory fabric dyeing and finishing processing method according to claim 5 of partly fluffing cotton, it is characterised in that: the auxiliary scouring agent The mixed liquor for the vulcanized sodium that middle liquid alkaline is the sodium hydroxide that mass fraction is 30-32% and mass fraction is 14-18%.
- 8. precious jade imitation memory fabric dyeing and finishing processing method according to claim 4 of partly fluffing cotton, it is characterised in that: the step (1) heap is postponed in is padded twice with the dilute sulfuric acid that mass concentration is 4-6g/L, then is banked up 3-6 hours.
- 9. precious jade imitation memory fabric dyeing and finishing processing method according to claim 1 of partly fluffing cotton, it is characterised in that: the step (3) dye liquor is uniformly injected into the form of ratio material feeding in, and total injection time is 15min.
- 10. precious jade imitation memory fabric dyeing and finishing processing method according to claim 1 of partly fluffing cotton, it is characterised in that: the step (4) the preshrunk temperature of preshrunk is 110-130 DEG C, speed 10-20m/min.
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