CN109279814A - One kind can fater disintegration flowerpot and preparation method thereof - Google Patents

One kind can fater disintegration flowerpot and preparation method thereof Download PDF

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Publication number
CN109279814A
CN109279814A CN201811154525.5A CN201811154525A CN109279814A CN 109279814 A CN109279814 A CN 109279814A CN 201811154525 A CN201811154525 A CN 201811154525A CN 109279814 A CN109279814 A CN 109279814A
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parts
flowerpot
preparation
added
outer layer
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CN201811154525.5A
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CN109279814B (en
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邓琪
王臻
严治杰
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Wan Zhuo (jiangsu) New Material Co Ltd
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Wan Zhuo (jiangsu) New Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/02Receptacles, e.g. flower-pots or boxes; Glasses for cultivating flowers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00758Uses not provided for elsewhere in C04B2111/00 for agri-, sylvi- or piscicultural or cattle-breeding applications

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Cultivation Receptacles Or Flower-Pots, Or Pots For Seedlings (AREA)

Abstract

It can fater disintegration flowerpot and preparation method thereof the invention discloses one kind, which is characterized in that specifically includes the following steps: the preparation of (1) blend glue stuff claims;(2) prepared by mixed powder, the preparation of internal layer powder: taking 2.5-15 parts of cement, 10-15 parts of quartz sand, 1-3 parts of coupling agent, 15-20 parts of biomass material, is added in kneader and is uniformly mixed;The preparation of outer layer powder: 2.5-15 parts of cement are taken, 10-15 parts of quartz sand, 1-3 parts of coupling agent, 15-20 parts of biomass material, 2-5 parts of water swelling particle, is added in kneader and is uniformly mixed;(3) flowerpot molding.The flowerpot that the present invention is prepared in transplanting process without taking out, apply after water can fater disintegration, be conducive to subsequent flower root system growth.

Description

One kind can fater disintegration flowerpot and preparation method thereof
Technical field
The invention belongs to flower container Material Field, being related to one kind can fater disintegration flowerpot and preparation method thereof.
Background technique
Flowerpot is kind an a kind of vessel for flower, for the small inverted round stage in the big bottom end of mouth or terrace edge shape, according to making material Difference can be divided into many types.It common are ceramic bowl, glass reinforced plastic flower pot, plastic tub, boccaro basin etc..Wherein, such as the work of ceramic bowl Skill is probably needed by pugging, throwing, texturing, glazing, firing, complex process, and is consumed energy.And glass flowerpot, system Standby technique is also complex, and airtight moisture permeability.And for plastic flowerpot, preparation process is relatively easy, but plastics Flowerpot is airtight, is mainly used for soilless cultivation, and cost wants low relative to glass and jardiniere.
More biological material can be generated in agricultural production process, such as the stalk that crops carry over, this kind of life Material the past it is common be exactly burning disposal, burning disposal can bring biggish pollution to atmosphere, and for further Stalk processing is processed, such as carbonization is used as fuel, and is fabricated to biogas, and there are higher costs for these processing methods, puts into larger The problem of, therefore, to the processing of stalk, there are bigger difficulty now.
Chinese invention patent CN107409818A discloses a kind of production side of biology base mycelia material ecological, environmental protective flowerpot Method, by the way that agricultural crop straw is put into different process moulding mould, inoculation edible fungus species culture growth, shaping and demoulding is formed. The ecological, environmental protective flowerpot of this method production in use, can be straight as plant is not necessarily to remove flowerpot when being grown in transplanting Tape splicing basin is transplanted, which 100% can be decomposed into organic matter and utilized by plant as time goes by, is had apparent Cost advantage and environment-friendly advantage.The flowerpot is made of biological material, and the phase is applied only for the cultivation of mycelia, because of bacterium Silk is to attach most importance to biological material using flowerpot as carbon source, and mycelia vitality is strong during the growth process, and environment-adapting ability is strong, because The flowerpot of invention preparation can be used in this, but its use scope is relatively narrow, and the flowerpot being prepared is only by pressure Carry out it is qualitative, in use flowerpot be easy solution collapse, mechanical property is poor.
The present invention is directed to be recycled to the biological material in agricultural production process, reduces and utilize cost, and mention The economic benefit of high biomass, then on the basis of this, it is prepared for a kind of biomass flowerpot, which has preferable mechanical performance, It can satisfy the use of daily flowerpot in daily maintenance processes, and there is good air permeable humidity retaining performance, daily Flowerpot is not disintegrated in maintenance processes, carry out greening transplanting when, without removing flowerpot, band pot transplanting avoids flowers root System is impaired, improves the survival rate of flowers, and flowerpot can be voluntarily disintegrated, flowerpot and soil ultimately form one after with flower transplanting System is conducive to flower root system growth, while the organic matter degraded provides necessary organic fertilizer for flowers.
Summary of the invention
In order to solve the problems in the existing technology, prepare one kind can fater disintegration flowerpot and preparation method thereof, this Invention uses following methods.
Flowerpot raw material packet is by epoxide-resin glue, cement, soil, quartz sand or miberal powder, reactive diluent, curing agent, biology Material, wherein biological material is stalk or sawdust.
Specific flowerpot raw material forms as follows by weight: 20-30 parts of epoxy resin, 2-10 parts of reactive diluent, inorganic Pigment 1-3,5-30 parts of cement, 20-30 parts of quartz sand, 1-3 parts of coupling agent, 5-20 parts of biomass material, are inhaled by 2-10 parts of curing agent 2-5 parts of water expanded granular.
The smashed partial size of biomass material is less than 500 μm.
Biomass material be stalk or sawdust, stalk include production estimation harvest after remainder, including wheat-straw, Rice bar, cornstalk, cotton stem, rape straw, sugarcane bar etc., biomass raw material must be smashed, and guarantee that partial size is small In 500 μm, flowerpot surface smoothness and aesthetics can guarantee in this way, if the partial size of biomass raw material is excessive after crushing, by Small relative to cement sandstone density in the density of biological particles, in the mixed processes of powder, biological material is not allowed It is easily blended uniformly, be easy to cause slurry mixing uneven, and be easy to cause hole on flowerpot more after forming, greatly influence The performance of keeping humidity and mechanical property of flowerpot.
In addition biological material can be degenerated in a natural environment by bacterium, and then obtain organic fertilizer, certain Necessary organic fertilizer can be provided in degree for flowers, be conducive to the growth of flowers.
The flowerpot is double-layer structure, the composition of internal layer are as follows: 10-15 parts of epoxy resin, 1-5 parts of reactive diluent, it is inorganic Pigment 0-3,1-5 parts of curing agent, 2.5-15 parts of cement, 10-15 parts of quartz sand, 1-3 parts of coupling agent, 15-20 parts of biomass material; The composition of outer layer are as follows: 10-15 parts of epoxy resin, 1-5 parts of reactive diluent, inorganic pigment 0-3,1-5 parts of curing agent, cement 2.5- 15 parts, 10-15 parts of quartz sand, 1-3 parts of coupling agent, 15-20 parts of biomass material, 2-5 parts of water swelling particle.
The present invention joined water swelling particle in flowerpot outer layer, and volume can expand tens of after particle absorption moisture Again or even hundreds of times, violent water swelling can make flowerpot structure change, be disintegrated, while water swelling particle A kind of effect for being retained moisturizing is also functioned to, long-time water supply effect can be provided for flower root system, promote root growth, improve flower Grass transplanting survival rate.
The present invention is set as double-layer structure, and endothecium structure can play impermeable role, and flowers are during greenhouse cultivation Prevent after applying water to flowers, moisture penetrates into outer layer by internal layer so that the swollen resin water swelling in outer layer and influence flower The structure of basin.
The present invention uses epoxy resin as glue connection agent, the solidification crosslinked action of cement can be assisted, due to biological material The density of material is small compared to the density of cement, sandstone, and during powder mixing, difficulty or ease are uniformly mixed, the invention Use liquid sizing material epoxy resin, can preferably infiltrate biological material, enable and be uniformly mixed in flowerpot slurry, made It obtains biological material to be evenly distributed in the slurry, and then improves the yield rate and mechanical property of flowerpot.The use of epoxy resin It can be improved the waterproof water retention property of flowerpot simultaneously, and improve its flexibility.
The present invention provides one kind can fater disintegration flowerpot and preparation method thereof, specifically includes the following steps:
(1) prepared by blend glue stuff
20-30 parts of epoxy resin, 2-10 parts of reactive diluent are weighed, inorganic pigment 1-3 is added in stirred tank, and stirring is equal It is even, obtain blend glue stuff.
(2) prepared by mixed powder
The preparation of internal layer powder: taking 2.5-15 parts of cement, and 10-15 parts of quartz sand, 1-3 parts of coupling agent, biomass material 15-20 Part, it is added in kneader and is uniformly mixed;
The preparation of outer layer powder: taking 2.5-15 parts of cement, and 10-15 parts of quartz sand, 1-3 parts of coupling agent, biomass material 15-20 Part, it 2-5 parts of water swelling particle, is added in kneader and is uniformly mixed.
(3) flowerpot molding
The blend glue stuff that step (1) obtains is divided equally two parts, by obtained internal layer mixed powder and outer layer mixed powder point Not Jia Ru step (1) divide equally blend glue stuff in, stir evenly, be added equivalent curing agent, continue to stir, obtain the internal layer of flowerpot Outer layer slurry reverse mould is added internal layer slurry, continues to solidify by slurry and outer layer slurry after solidification, formed, and demoulding obtains one kind It can fater disintegration flowerpot.
The reactive diluent is as in acrylic glycidol ether, butyl glycidyl ether and phenyl glycidyl ether It is a kind of.
Described curing agent 2-10 parts.
Curing agent is one of ethylenediamine, hexamethylene diamine, diethylenetriamine, triethylene tetramine, diethylaminopropylamine or more Kind.
Solidification temperature is 25-40 DEG C, curing time 2-4h.
Using the preparation-obtained one kind of above technical scheme can fater disintegration flowerpot, can occur at room temperature solid Chemical conversion type, and a large amount of biomass material has been used, a kind of outlet is provided for the use of waste biomass materials, is conducive to Environmental protection;The flowerpot that the present invention is prepared, during the transplantation process without removing flowerpot, directly band pot transplanting can subtract Few manual operation difficulty, while flower root system is not damaged, flowers survival rate is improved, flowerpot outer layer contains water swelling particle, After transplanting, in gardens glue or rainfall, the water swelling particle in flowerpot outer layer is contacted with water, a large amount of to absorb moisture and send out Raw expansion is conducive to the growth of subsequent transplantation flower root system so that flowerpot structure deforms and is disintegrated.
Specific embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention will be further described.
Embodiment 1
It is a kind of can fater disintegration flower preparation method, specifically includes the following steps:
(1) prepared by blend glue stuff
30 parts of epoxy resin, 10 parts of reactive diluent are weighed, inorganic pigment 3 is added in stirred tank, is stirred evenly, and is mixed Close sizing material.
(2) prepared by mixed powder
The preparation of internal layer powder: 10 parts of cement, 12 parts of quartz sand, 2 parts of coupling agent, 15 parts of biomass material, it is added to kneading It is uniformly mixed in machine;
The preparation of outer layer powder: 10 parts of cement, 12 parts of quartz sand, 2 parts of coupling agent, 15 parts of biomass material, water swelling 3 parts of grain is added in kneader and is uniformly mixed.
(3) flowerpot molding
The blend glue stuff that step (1) obtains is divided equally two parts, by obtained internal layer mixed powder and outer layer mixed powder point Not Jia Ru step (1) divide equally blend glue stuff in, stir evenly, be added equivalent curing agent, continue to stir, obtain the internal layer of flowerpot Outer layer slurry reverse mould is added internal layer slurry, continues to solidify by slurry and outer layer slurry after solidification, formed, and demoulding obtains one kind It can fater disintegration flowerpot.
Embodiment 2
One kind can fater disintegration flowerpot and preparation method thereof, specifically includes the following steps:
(1) prepared by blend glue stuff
25 parts of epoxy resin, 8 parts of reactive diluent are weighed, inorganic pigment 3 is added in stirred tank, is stirred evenly, and is mixed Close sizing material.
(2) prepared by mixed powder
The preparation of internal layer powder: cement 10,10 parts of quartz sand, 2 parts of coupling agent, biomass material 15 is added in kneader It is uniformly mixed;
The preparation of outer layer powder: 10 parts of cement, 10 parts of quartz sand, 2 parts of coupling agent, 15 parts of biomass material, water swelling 2-5 parts of grain is added in kneader and is uniformly mixed.
(3) flowerpot molding
The blend glue stuff that step (1) obtains is divided equally two parts, by obtained internal layer mixed powder and outer layer mixed powder point Not Jia Ru step (1) divide equally blend glue stuff in, stir evenly, be added 5 parts of equivalent curing agent, continue to stir, obtain flowerpot Outer layer slurry reverse mould is added internal layer slurry, continues to solidify by internal layer slurry and outer layer slurry after solidification, formed, and is demoulded, and is obtained One kind can fater disintegration flowerpot.
Embodiment 3
It is a kind of can fater disintegration flower preparation method, specifically includes the following steps:
(1) prepared by blend glue stuff
30 parts of epoxy resin, 10 parts of reactive diluent are weighed, 3 parts of inorganic pigment are added in stirred tank, stir evenly, obtain Blend glue stuff.
(2) prepared by mixed powder
The preparation of internal layer powder: 5 parts of cement, 12 parts of quartz sand, 2 parts of coupling agent, 15 parts of biomass material, it is added to kneader In be uniformly mixed;
The preparation of outer layer powder: 5 parts of cement, 12 parts of quartz sand, 2 parts of coupling agent, 15 parts of biomass material, water swelling particle It 3 parts, is added in kneader and is uniformly mixed.
(3) flowerpot molding
The blend glue stuff that step (1) obtains is divided equally two parts, by obtained internal layer mixed powder and outer layer mixed powder point Not Jia Ru step (1) divide equally blend glue stuff in, stir evenly, be added 5 parts of equivalent curing agent, continue to stir, obtain flowerpot Outer layer slurry reverse mould is added internal layer slurry, continues to solidify by internal layer slurry and outer layer slurry after solidification, formed, and is demoulded, and is obtained One kind can fater disintegration flowerpot.
Embodiment 4
It is a kind of can fater disintegration flower preparation method, specifically includes the following steps:
(1) prepared by blend glue stuff
30 parts of epoxy resin, 10 parts of reactive diluent are weighed, inorganic pigment 3 is added in stirred tank, is stirred evenly, and is mixed Close sizing material.
(2) prepared by mixed powder
The preparation of internal layer powder: 10 parts of cement, 12 parts of quartz sand, 2 parts of coupling agent, 15 parts of biomass material, it is added to kneading It is uniformly mixed in machine;
The preparation of outer layer powder: 10 parts of cement, 12 parts of quartz sand, 2 parts of coupling agent, 15 parts of biomass material, water swelling 5 parts of grain is added in kneader and is uniformly mixed.
(3) flowerpot molding
The blend glue stuff that step (1) obtains is divided equally two parts, by obtained internal layer mixed powder and outer layer mixed powder point Not Jia Ru step (1) divide equally blend glue stuff in, stir evenly, be added equivalent curing agent, continue to stir, obtain the internal layer of flowerpot Outer layer slurry reverse mould is added internal layer slurry, continues to solidify by slurry and outer layer slurry after solidification, formed, and demoulding obtains one kind It can fater disintegration flowerpot.
Embodiment 5
(1) prepared by blend glue stuff
30 parts of epoxy resin, 10 parts of reactive diluent are weighed, inorganic pigment 3 is added in stirred tank, is stirred evenly, and is mixed Close sizing material.
(2) prepared by mixed powder
The preparation of internal layer powder: 10 parts of cement, 12 parts of quartz sand, 2 parts of coupling agent, 20 parts of biomass material, it is added to kneading It is uniformly mixed in machine;
The preparation of outer layer powder: 10 parts of cement, 12 parts of quartz sand, 2 parts of coupling agent, 20 parts of biomass material, water swelling 3 parts of grain is added in kneader and is uniformly mixed.
(3) flowerpot molding
The blend glue stuff that step (1) obtains is divided equally two parts, by obtained internal layer mixed powder and outer layer mixed powder point Not Jia Ru step (1) divide equally blend glue stuff in, stir evenly, be added equivalent curing agent, continue to stir, obtain the internal layer of flowerpot Outer layer slurry reverse mould is added internal layer slurry, continues to solidify by slurry and outer layer slurry after solidification, formed, and demoulding obtains one kind It can fater disintegration flowerpot.
Comparative example 1
(1) prepared by blend glue stuff
30 parts of epoxy resin, 10 parts of reactive diluent are weighed, inorganic pigment 3 is added in stirred tank, is stirred evenly, and is mixed Close sizing material.
(2) prepared by mixed powder
The preparation of internal layer powder: 10 parts of cement, 12 parts of quartz sand, 2 parts of coupling agent, 15 parts of biomass material, it is added to kneading It is uniformly mixed in machine;
The preparation of outer layer powder: 10 parts of cement, 12 parts of quartz sand, 2 parts of coupling agent, 15 parts of biomass material, it is added to kneading It is uniformly mixed in machine.
(3) flowerpot molding
The blend glue stuff that step (1) obtains is divided equally two parts, by obtained internal layer mixed powder and outer layer mixed powder point Not Jia Ru step (1) divide equally blend glue stuff in, stir evenly, be added equivalent curing agent, continue to stir, obtain the internal layer of flowerpot Outer layer slurry reverse mould is added internal layer slurry, continues to solidify by slurry and outer layer slurry after solidification, formed, and demoulding obtains one kind It can fater disintegration flowerpot.
Test the disintegrating property of flowerpot
The flowerpot that embodiment 1-5 is obtained is as in water, it can be found that deformation occurs for flowerpot outer layer, structure changes, Rupture, and the flowerpot that comparative example is prepared is added to the water, structure does not change.
Degradation property determines, the flowerpot that embodiment 1-5 is prepared is as in soil, keeping the wet of soil, three Check that flowerpot changes after month, it is found that flowerpot is inside and outside to have damaged cavity, these cavities are mostly that biomass corruption is made At.

Claims (6)

1. one kind can fater disintegration flowerpot preparation method, which is characterized in that specifically includes the following steps:
(1) prepared by blend glue stuff
20-30 parts of epoxy resin, 2-10 parts of reactive diluent are weighed, inorganic pigment 1-3 is added in stirred tank, is stirred evenly, and is obtained To blend glue stuff;
(2) prepared by mixed powder
The preparation of internal layer powder: taking 2.5-15 parts of cement, and 10-15 parts of quartz sand, 1-3 parts of coupling agent, 15-20 parts of biomass material, It is added in kneader and is uniformly mixed;
The preparation of outer layer powder: taking 2.5-15 parts of cement, and 10-15 parts of quartz sand, 1-3 parts of coupling agent, 15-20 parts of biomass material, It 2-5 parts of water swelling particle, is added in kneader and is uniformly mixed;
(3) flowerpot molding
The blend glue stuff that step (1) obtains is divided equally two parts, obtained internal layer mixed powder and outer layer mixed powder are added respectively Enter in the blend glue stuff that step (1) is divided equally, stir evenly, equivalent curing agent is added, continues to stir, obtains the internal layer slurry of flowerpot Outer layer slurry reverse mould is added internal layer slurry, continues to solidify after solidification with outer layer slurry, is formed, demoulding, obtaining one kind can be fast Speed disintegration flowerpot.
2. it is a kind of as described in claim 1 can fater disintegration flowerpot preparation method, which is characterized in that it is biological in step (1) Matter raw material is stalk or sawdust, and the smashed partial size of biomass material is less than 500 μm.
3. it is a kind of as described in claim 1 can fater disintegration flowerpot preparation method, which is characterized in that the reactive diluent For one of acrylic glycidol ether, butyl glycidyl ether and phenyl glycidyl ether.
4. it is a kind of as described in claim 1 can fater disintegration flowerpot preparation method, which is characterized in that the curing agent 2-10 Part, curing agent is one of ethylenediamine, hexamethylene diamine, diethylenetriamine, triethylene tetramine, diethylaminopropylamine or a variety of.
5. it is a kind of as described in claim 1 can fater disintegration flowerpot preparation method, which is characterized in that solidification temperature 25- 40 DEG C, curing time 2-4h.
6. it is a kind of it is as described in any one in claim 1-5 can fater disintegration flowerpot the preparation method biomass that is prepared Flowerpot.
CN201811154525.5A 2018-09-30 2018-09-30 Flowerpot capable of being quickly disintegrated and preparation method thereof Expired - Fee Related CN109279814B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110383972A (en) * 2019-07-18 2019-10-29 深圳市朗程师地域规划设计有限公司 A kind of Mangrove Wetlands ecological system degradation method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473647A (en) * 2017-09-29 2017-12-15 成都新柯力化工科技有限公司 A kind of ecological foam concrete for roof plant cultivation and preparation method thereof
CN107935478A (en) * 2017-12-15 2018-04-20 芜湖德司节能科技有限公司 A kind of epoxy resin pervious material and its application
CN108586821A (en) * 2018-05-22 2018-09-28 万卓(武汉)新材料有限公司 A kind of starch composite degradable flowerpot and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473647A (en) * 2017-09-29 2017-12-15 成都新柯力化工科技有限公司 A kind of ecological foam concrete for roof plant cultivation and preparation method thereof
CN107935478A (en) * 2017-12-15 2018-04-20 芜湖德司节能科技有限公司 A kind of epoxy resin pervious material and its application
CN108586821A (en) * 2018-05-22 2018-09-28 万卓(武汉)新材料有限公司 A kind of starch composite degradable flowerpot and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110383972A (en) * 2019-07-18 2019-10-29 深圳市朗程师地域规划设计有限公司 A kind of Mangrove Wetlands ecological system degradation method

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Granted publication date: 20211224