CN109252380A - Chemical & blended fabric environmental protection fire retarding agent - Google Patents
Chemical & blended fabric environmental protection fire retarding agent Download PDFInfo
- Publication number
- CN109252380A CN109252380A CN201811016687.2A CN201811016687A CN109252380A CN 109252380 A CN109252380 A CN 109252380A CN 201811016687 A CN201811016687 A CN 201811016687A CN 109252380 A CN109252380 A CN 109252380A
- Authority
- CN
- China
- Prior art keywords
- chemical
- blended fabric
- environmental protection
- fire retarding
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a kind of chemical & blended fabric environmental protection fire retarding agents, it is composed of the following components by weight percentage: pentaerythritol phosphate 18%~22%, melamine 10%~15%, silica 3%~5%, ammonium sulfate 5%~8%, sodium hydroxide 0.5%~1%, dispersing agent 1%~2%, wetting agent 0.5%~1%, acrylic emulsion 25%~30%, surplus are water.Chemical & blended fabric environmental protection fire retarding agent of the present invention is coated in chemical & blended fabric surface, can form flame-retardant layer after drying, and do not influence appearance of fabrics.
Description
Technical field
The present invention relates to chemical & blended fabric environmental protection fire retarding agents.
Background technique
With the development of science and technology with the raising of living standard, people propose peace to the functionality of textile product
Entirely, comfortable wait requires.Since natural fiber is limited by natural conditions, so the consumption of fiber product is growing.Chemical fibre
The shortcomings that be easily to burn and spread rapidly, fire caused by chemical fibre textile almost accounts for the half of fire total amount.In recent years
Chemical fibre textile flame-retarded technology is developed rapidly, and in addition to synthesizing fire resistance fibre, weaving flame retardant coating is arranged because of its strong flexibility,
It is at low cost that there is certain market demand.But currently on the market still based on halogen and antimony, but the combustion toxicity of these fire retardants
Too big, developing the novel fire retardant of one kind thus has realistic meaning.The place such as large-scale public place such as hotel, movie theatre is in order to mention
For comfortable resting space, a large amount of textile, such as sofa, curtain, carpet are all employed, and often these are all by chemical fibre system
At.Once burning, rate of propagation is fast, and the periphery combustible that is easy to ignite leads to big fire.It develops nontoxic, efficient, low
The fire retardant of cost meets current market needs.
The appearance fire retardant for not influencing fabric is a developing direction of existing fabric flame-retardant agent, it is required that being after arranging
Cloth cover has flame retardant property, and does not cause discoloration, but the ingredient of existing fire retardant tends to cause discoloration.
Summary of the invention
The purpose of the present invention is to provide a kind of chemical & blended fabric environmental protection fire retarding agents, are coated in chemical & blended fabric surface, dry
Flame-retardant layer can be formed after dry, and does not influence appearance of fabrics.
To achieve the above object, the technical scheme is to design a kind of chemical & blended fabric environmental protection fire retarding agents, by weight
Percentages are composed of the following components:
Pentaerythritol phosphate 18%~22%,
Melamine 10%~15%,
Silica 3%~5%,
Ammonium sulfate 5%~8%,
Sodium hydroxide 0.5%~1%,
Dispersing agent 1%~2%,
Wetting agent 0.5%~1%,
Acrylic emulsion 25%~30%,
Surplus is water.
Preferably, the chemical & blended fabric environmental protection fire retarding agent, composed of the following components by weight percentage:
Pentaerythritol phosphate 18%,
Melamine 10%,
Silica 3%,
Ammonium sulfate 5%,
Sodium hydroxide 0.5%,
Dispersing agent 1%,
Wetting agent 0.5%,
Acrylic emulsion 25%,
Surplus is water.
Preferably, the chemical & blended fabric environmental protection fire retarding agent, composed of the following components by weight percentage:
Pentaerythritol phosphate 20%,
Melamine 13%,
Silica 4%,
Ammonium sulfate 6%,
Sodium hydroxide 0.8%,
Dispersing agent 1.5%,
Wetting agent 0.6%,
Acrylic emulsion 28%,
Surplus is water.
Preferably, the chemical & blended fabric environmental protection fire retarding agent, composed of the following components by weight percentage:
Pentaerythritol phosphate 22%,
Melamine 15%,
Silica 5%,
Ammonium sulfate 8%,
Sodium hydroxide 1%,
Dispersing agent 2%,
Wetting agent 1%,
Acrylic emulsion 30%,
Surplus is water.
Advantages and advantages of the present invention are to provide a kind of chemical & blended fabric environmental protection fire retarding agent, is coated in chemical fibre
Fabric surface can form flame-retardant layer, and not influence appearance of fabrics after drying.
1) fire retardant of the present invention is free of eight big heavy metals, meets REACH and RoHS standard, to chemical & blended fabric (especially Buddhist nun
The true qualities of dragon 6) are without influence.
2) fire retardant of the present invention is low in cost.
3) good flame retardation effect of fire retardant of the present invention meets Britain flame-retardant standard BS-5852.
4) preparation process of fire retardant of the present invention is simple.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.Following embodiment is only used for more
Add and clearly demonstrate technical solution of the present invention, and not intended to limit the protection scope of the present invention.
Embodiment 1
Configuration:
The wetting agent of the dispersing agent of 1Kg and 0.5 Kg are added in the water of 33Kg, after 400r/min disperses 10min, are persistently being stirred
The sulfuric acid of the pentaerythritol phosphate of 20Kg, the melamine of 15Kg, the silica of 3Kg, 8Kg are slowly added under the effect of mixing
Ammonium；Mixing speed is promoted to 1500r/min, disperses 30 min；In sodium hydroxide dissolution and 5Kg water by 0.5Kg, very long addition
In reactor, it is stirred to react 30 min；The acrylic emulsion of 30Kg is continuously added, mixing speed is down to 1200r/min；Dispersion
After 20min, obtained chemical & blended fabric environmental protection fire retarding agent.
It uses:
Chemical & blended fabric environmental protection fire retarding agent is coated in chemical & blended fabric surface, weight gain is applied to about 35% using doctor back, thermal finalization is dried
It is dry, taking-up.
Embodiment 2
Configuration:
The wetting agent of the dispersing agent of 1 g and 0.5 g are added in the water of 33 g, after 400r/min disperses 10min, are persistently being stirred
The ammonium sulfate of the pentaerythritol phosphate of 18 g, the melamine of 15 g, 8 g are slowly added under the effect of mixing；Mixing speed is promoted
To 1500r/min, disperse 30 min；By the sodium hydroxide dissolution of 0.5 g in 5 g water, in very long addition reactor, stirring is anti-
Answer 30 min；The acrylic emulsion of 30 g is continuously added, mixing speed is down to 1200r/min；After dispersing 20min, chemical fibre is made
Fabric environmental protection fire retarding agent.
It uses:
Chemical & blended fabric environmental protection fire retarding agent is coated in chemical & blended fabric surface, weight gain is applied to about 35% using doctor back, thermal finalization is dried
It is dry, taking-up.
The flame retardant effect of each embodiment is tested:
The flame retardant test result of each embodiment chemical & blended fabric is as shown in the table
| Embodiment | Examination criteria | Fire source flame | Afterflame |
| Embodiment 1 | BS-5852 | 1# | 0 second |
| Embodiment 2 | BS-5852 | 1# | 12 seconds |
The above is only a preferred embodiment of the present invention, it is noted that those skilled in the art are come
It says, without departing from the technical principles of the invention, several improvements and modifications can also be made, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (4)
1. chemical & blended fabric environmental protection fire retarding agent, which is characterized in that composed of the following components by weight percentage:
Pentaerythritol phosphate 18%~22%,
Melamine 10%~15%,
Silica 3%~5%,
Ammonium sulfate 5%~8%,
Sodium hydroxide 0.5%~1%,
Dispersing agent 1%~2%,
Wetting agent 0.5%~1%,
Acrylic emulsion 25%~30%,
Surplus is water.
2. chemical & blended fabric environmental protection fire retarding agent according to claim 1, which is characterized in that by weight percentage by following
Group is grouped as:
Pentaerythritol phosphate 18%,
Melamine 10%,
Silica 3%,
Ammonium sulfate 5%,
Sodium hydroxide 0.5%,
Dispersing agent 1%,
Wetting agent 0.5%,
Acrylic emulsion 25%,
Surplus is water.
3. chemical & blended fabric environmental protection fire retarding agent according to claim 1, which is characterized in that by weight percentage by following
Group is grouped as:
Pentaerythritol phosphate 20%,
Melamine 13%,
Silica 4%,
Ammonium sulfate 6%,
Sodium hydroxide 0.8%,
Dispersing agent 1.5%,
Wetting agent 0.6%,
Acrylic emulsion 28%,
Surplus is water.
4. chemical & blended fabric environmental protection fire retarding agent according to claim 1, which is characterized in that by weight percentage by following
Group is grouped as:
Pentaerythritol phosphate 22%,
Melamine 15%,
Silica 5%,
Ammonium sulfate 8%,
Sodium hydroxide 1%,
Dispersing agent 2%,
Wetting agent 1%,
Acrylic emulsion 30%,
Surplus is water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811016687.2A CN109252380A (en) | 2018-09-03 | 2018-09-03 | Chemical & blended fabric environmental protection fire retarding agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811016687.2A CN109252380A (en) | 2018-09-03 | 2018-09-03 | Chemical & blended fabric environmental protection fire retarding agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109252380A true CN109252380A (en) | 2019-01-22 |
Family
ID=65050071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811016687.2A Pending CN109252380A (en) | 2018-09-03 | 2018-09-03 | Chemical & blended fabric environmental protection fire retarding agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109252380A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1335332A (en) * | 2001-08-28 | 2002-02-13 | 巴陵石化岳阳石油化工总厂 | Expanding fire retardant composition without halide for polyolefine |
| CN101950623A (en) * | 2010-09-08 | 2011-01-19 | 沈阳天荣电缆材料有限公司 | Semiconductive flame retardant belt for cables and manufacture method thereof |
| CN105256572A (en) * | 2015-11-16 | 2016-01-20 | 济南泰星精细化工有限公司 | Halogen-free flame retardant coating adhesive and preparing method thereof |
| CN107354749A (en) * | 2017-09-05 | 2017-11-17 | 绍兴思安阻燃科技有限公司 | A kind of natural fiber sofa fabric flame retardant |
| CN107556840A (en) * | 2017-09-05 | 2018-01-09 | 绍兴思安阻燃科技有限公司 | A kind of chemical fibre sofa fabric flame retardant |
| CN108265516A (en) * | 2017-11-28 | 2018-07-10 | 杭州纳尔森精细化工有限公司 | A kind of flame retardant for textile and preparation method thereof |
-
2018
- 2018-09-03 CN CN201811016687.2A patent/CN109252380A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1335332A (en) * | 2001-08-28 | 2002-02-13 | 巴陵石化岳阳石油化工总厂 | Expanding fire retardant composition without halide for polyolefine |
| CN101950623A (en) * | 2010-09-08 | 2011-01-19 | 沈阳天荣电缆材料有限公司 | Semiconductive flame retardant belt for cables and manufacture method thereof |
| CN105256572A (en) * | 2015-11-16 | 2016-01-20 | 济南泰星精细化工有限公司 | Halogen-free flame retardant coating adhesive and preparing method thereof |
| CN107354749A (en) * | 2017-09-05 | 2017-11-17 | 绍兴思安阻燃科技有限公司 | A kind of natural fiber sofa fabric flame retardant |
| CN107556840A (en) * | 2017-09-05 | 2018-01-09 | 绍兴思安阻燃科技有限公司 | A kind of chemical fibre sofa fabric flame retardant |
| CN108265516A (en) * | 2017-11-28 | 2018-07-10 | 杭州纳尔森精细化工有限公司 | A kind of flame retardant for textile and preparation method thereof |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190122 |
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| RJ01 | Rejection of invention patent application after publication |