CN104695233B - Fire-retardant crease-shedding finishing agent used for textiles and preparation method thereof, purposes - Google Patents
Fire-retardant crease-shedding finishing agent used for textiles and preparation method thereof, purposes Download PDFInfo
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- CN104695233B CN104695233B CN201510097253.XA CN201510097253A CN104695233B CN 104695233 B CN104695233 B CN 104695233B CN 201510097253 A CN201510097253 A CN 201510097253A CN 104695233 B CN104695233 B CN 104695233B
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- 239000004753 textile Substances 0.000 title claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 42
- 239000003063 flame retardant Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 102
- 239000000203 mixture Substances 0.000 claims abstract description 43
- 238000013019 agitation Methods 0.000 claims abstract description 37
- -1 triisopropyl borate ester Chemical class 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 16
- 229960005070 ascorbic acid Drugs 0.000 claims abstract description 16
- 235000010323 ascorbic acid Nutrition 0.000 claims abstract description 16
- 239000011668 ascorbic acid Substances 0.000 claims abstract description 16
- 229940008099 dimethicone Drugs 0.000 claims abstract description 16
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 16
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 16
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 16
- 239000003996 polyglycerol polyricinoleate Substances 0.000 claims abstract description 16
- 235000010958 polyglycerol polyricinoleate Nutrition 0.000 claims abstract description 16
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 16
- 150000003333 secondary alcohols Chemical class 0.000 claims abstract description 16
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 claims abstract description 16
- SJHCUXCOGGKFAI-UHFFFAOYSA-N tripropan-2-yl phosphite Chemical compound CC(C)OP(OC(C)C)OC(C)C SJHCUXCOGGKFAI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 18
- 230000006641 stabilisation Effects 0.000 claims description 9
- 238000011105 stabilization Methods 0.000 claims description 9
- 238000009988 textile finishing Methods 0.000 claims description 3
- 230000037303 wrinkles Effects 0.000 abstract description 6
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 229920004934 Dacron® Polymers 0.000 description 3
- 229920004933 Terylene® Polymers 0.000 description 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N acrylaldehyde Natural products C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000001153 anti-wrinkle effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses fire-retardant crease-shedding finishing agent used for textiles and preparation method thereof, purposes；Described used for textiles fire-retardant crease-shedding finishing agent includes the composition of following weight parts: NSC 6513 8-15 part, triisopropyl phosphite 4-9 part, triisopropyl borate ester 4-7 part, aminopropanol ascorbic acid phosphoric acid esters 3-7 part, polyglycerol polyricinoleate 8-15 part, dimethicone 14-20 part, dimethiconol stearate 5-13 part, secondary alcohol polyoxyethylene ether 4-8 part, propylene glycol 12-20 part, water 300-400 part.Preparation method step includes mixing, heating, magnetic agitation etc..Wrinkle resistance and the fire-retardant intensity of the textile that the finishing agent prepared arranged are significantly improved.
Description
Technical field
The invention belongs to textile dyeing and finishing field, relate to finishing agent and preparation method thereof, purposes, particularly relate to fire-retardant crease-shedding finishing agent used for textiles and preparation method thereof, purposes.
Background technology
The conventional fire retardant of inflaming retarding fabric is divided three classes by ignition-proof element.1. halogen containing flame-retardant: in thermal decomposition process, decomposites the material catching transmission burning free radical, its fuel gas produced when can dilute fiber cracking, or cuts off and the contacting of air.2. phosphonium flame retardant: combustion process, at the phosphoric anhydride produced or phosphoric acid, promotes textile dehydration carbonization, stops or reduces fuel gas producing.Simultaneously phosphoric anhydride forms similar glass fused mass when thermal decomposition and covers on fabric, promotes its oxidation to generate carbon dioxide, plays fire retardation.3. nitrogenous flame ratardant, nitrogen compound with cellulose effect, can promote to be cross-linked into carbon, reduces the decomposition temperature of fabric, the non-flammable compressive gas of generation, plays the effect of dilution fuel gas.Covalent cross-linking and the fixing crease-resistant mechanism of both of resin are the crease-resistant means that people commonly use.Both by changing the internal structure of textile product thus reaching to improve the purpose of anti-wrinkle effect.Covalent cross-linking is under the effect of catalyst, is combined with fibrous inner structure, firm internal structure.When fabric is subject to external forces, due to the existence of cross-linking agent, fabric is not susceptible to plastic deformation.As long as resin is fixed forms " framework " at fibrous inside.Thus limiting moving freely of fibrous inside molecule.When fabric is subject to load effect time, fibrous inside molecule does not have significantly sliding, and self original chemical bond is more firm, and substantially without forming new chemical bond, fabric can reply original form quickly.The finishing agent that simultaneously can provide the crease-resistant of fabric and flame retardant effect is less, therefore also needs finishing agent is carried out more deep research and development.
Summary of the invention
Solve the technical problem that: conventional finishing agent function used for textiles is comparatively single, and effect inconspicuous on the fire-retardant and wrinkle resistance improving textile, it is an object of the invention to provide a kind of can the used for textiles fire-retardant crease-shedding finishing agent and preparation method thereof of highly effective raising Fire-proof Finishing Agents for Textile performance and crease-resistant intensity, purposes.
Technical scheme: in order to effectively improve the fire-retardant and crease-resistant intensity of textile, the invention discloses fire-retardant crease-shedding finishing agent used for textiles and preparation method thereof, purposes；
Described used for textiles fire-retardant crease-shedding finishing agent includes the composition of following weight parts:
NSC 6513 8-15 part,
Triisopropyl phosphite 4-9 part,
Triisopropyl borate ester 4-7 part,
Aminopropanol ascorbic acid phosphoric acid esters 3-7 part,
Polyglycerol polyricinoleate 8-15 part,
Dimethicone 14-20 part,
Dimethiconol stearate 5-13 part,
Secondary alcohol polyoxyethylene ether 4-8 part,
Propylene glycol 12-20 part,
Water 300-400 part.
It is further preferred that described used for textiles fire-retardant crease-shedding finishing agent, including the composition of following weight parts:
NSC 6513 10-13 part,
Triisopropyl phosphite 5-8 part,
Triisopropyl borate ester 5-6 part,
Aminopropanol ascorbic acid phosphoric acid esters 4-6 part,
Polyglycerol polyricinoleate 10-12 part,
Dimethicone 16-18 part,
Dimethiconol stearate 7-10 part,
Secondary alcohol polyoxyethylene ether 5-7 part,
Propylene glycol 14-18 part,
Water 320-380 part.
Further preferred, described used for textiles fire-retardant crease-shedding finishing agent, including the composition of following weight parts:
NSC 6513 12 parts,
Triisopropyl phosphite 7 parts,
Triisopropyl borate ester 6 parts,
Aminopropanol ascorbic acid phosphoric acid esters 5 parts,
Polyglycerol polyricinoleate 11 parts,
Dimethicone 17 parts,
Dimethiconol stearate 8 parts,
Secondary alcohol polyoxyethylene ether 6 parts,
Propylene glycol 16 parts,
350 parts of water.
The preparation method of fire-retardant crease-shedding finishing agent used for textiles, described preparation method comprises the following steps:
(1) taking propylene glycol by weight be 12-20 part, water is 300-400 part, heats propylene glycol and water to 55 DEG C, and by propylene glycol with carried out magnetic agitation after temperature stabilization, magnetic agitation rotating speed is 100rpm, and stirring is to uniformly, for mixed liquor A；
(2) keep temperature-resistant, be slowly added dropwise polyglycerol polyricinoleate by weight in the mixed liquor A of step (1) to be successively 8-15 part, dimethicone be 14-20 part, dimethiconol stearate is 5-13 part, secondary alcohol polyoxyethylene ether is 4-8 part, magnetic agitation is carried out while dripping above-mentioned each composition, speed of agitator is still 100rpm, stirring is all dissolved completely to above-mentioned composition, for mixed liquid B；
(3) temperature is kept to be still 55 DEG C, add NSC 6513 in mixed liquid B to be 8-15 part, triisopropyl phosphite be 4-9 part, triisopropyl borate ester is 4-7 part, aminopropanol ascorbic acid phosphoric acid esters is 3-7 part, again above-mentioned all the components is carried out magnetic agitation, stirring is to all of composition mix homogeneously, for the used for textiles fire-retardant crease-shedding finishing agent of preparation.
Described used for textiles fire-retardant crease-shedding finishing agent purposes in textile finishing.
Described used for textiles fire-retardant crease-shedding finishing agent purposes in textile finishing, described textile includes bafta, terylene, acrylon, spandex, dacron fabric, bamboo fiber or blended yarn weaved fabric.
Beneficial effect: the fire-retardant crease-shedding finishing agent of the present invention is after arranging pure cotton fabric, terylene and acrylon, the fire-retardant intensity of pure cotton fabric after arrangement, terylene and acrylon is obtained for raising, except fire resistance, textile after arrangement is under remaining the premise of ultimate strength and Tear strength, the anti-wrinkle effect of textile is also greatly improved, finishing agent mesoboric acid three isopropyl ester and the aminopropanol ascorbic acid phosphoric acid esters of the present invention have played synergism jointly, and highly significant improves the fire-retardant intensity of textile.In the finishing agent of the present invention, dimethiconol stearate and secondary alcohol polyoxyethylene ether also achieve extraordinary effect, the very effective wrinkle resistance that improve textile.
Detailed description of the invention
Embodiment 1
(1) taking propylene glycol by weight be 20Kg, water is 400Kg, heats propylene glycol and water to 55 DEG C, and by propylene glycol with carried out magnetic agitation after temperature stabilization, magnetic agitation rotating speed is 100rpm, and stirring is to uniformly, for mixed liquor A；(2) keep temperature-resistant, be slowly added dropwise polyglycerol polyricinoleate by weight in the mixed liquor A of step (1) to be successively 15Kg, dimethicone be 20Kg, dimethiconol stearate is 13Kg, secondary alcohol polyoxyethylene ether is 8Kg, magnetic agitation is carried out while dripping above-mentioned each composition, speed of agitator is still 100rpm, stirring is all dissolved completely to above-mentioned composition, for mixed liquid B；(3) temperature is kept to be still 55 DEG C, add NSC 6513 in mixed liquid B to be 15Kg, triisopropyl phosphite be 9Kg, triisopropyl borate ester is 7Kg, aminopropanol ascorbic acid phosphoric acid esters is 3Kg, again above-mentioned all the components is carried out magnetic agitation, stirring is to all of composition mix homogeneously, for the used for textiles fire-retardant crease-shedding finishing agent of preparation.
Embodiment 2
(1) taking propylene glycol by weight be 12Kg, water is 300Kg, heats propylene glycol and water to 55 DEG C, and by propylene glycol with carried out magnetic agitation after temperature stabilization, magnetic agitation rotating speed is 100rpm, and stirring is to uniformly, for mixed liquor A；(2) keep temperature-resistant, be slowly added dropwise polyglycerol polyricinoleate by weight in the mixed liquor A of step (1) to be successively 8Kg, dimethicone be 14Kg, dimethiconol stearate is 5Kg, secondary alcohol polyoxyethylene ether is 4Kg, magnetic agitation is carried out while dripping above-mentioned each composition, speed of agitator is still 100rpm, stirring is all dissolved completely to above-mentioned composition, for mixed liquid B；(3) temperature is kept to be still 55 DEG C, add NSC 6513 in mixed liquid B to be 8Kg, triisopropyl phosphite be 4Kg, triisopropyl borate ester is 4Kg, aminopropanol ascorbic acid phosphoric acid esters is 7Kg, again above-mentioned all the components is carried out magnetic agitation, stirring is to all of composition mix homogeneously, for the used for textiles fire-retardant crease-shedding finishing agent of preparation.
Embodiment 3
(1) taking propylene glycol by weight be 14Kg, water is 320Kg, heats propylene glycol and water to 55 DEG C, and by propylene glycol with carried out magnetic agitation after temperature stabilization, magnetic agitation rotating speed is 100rpm, and stirring is to uniformly, for mixed liquor A；(2) keep temperature-resistant, be slowly added dropwise polyglycerol polyricinoleate by weight in the mixed liquor A of step (1) to be successively 10Kg, dimethicone be 18Kg, dimethiconol stearate is 7Kg, secondary alcohol polyoxyethylene ether is 7Kg, magnetic agitation is carried out while dripping above-mentioned each composition, speed of agitator is still 100rpm, stirring is all dissolved completely to above-mentioned composition, for mixed liquid B；(3) temperature is kept to be still 55 DEG C, add NSC 6513 in mixed liquid B to be 13Kg, triisopropyl phosphite be 8Kg, triisopropyl borate ester is 5Kg, aminopropanol ascorbic acid phosphoric acid esters is 6Kg, again above-mentioned all the components is carried out magnetic agitation, stirring is to all of composition mix homogeneously, for the used for textiles fire-retardant crease-shedding finishing agent of preparation.
Embodiment 4
(1) taking propylene glycol by weight be 18Kg, water is 380Kg, heats propylene glycol and water to 55 DEG C, and by propylene glycol with carried out magnetic agitation after temperature stabilization, magnetic agitation rotating speed is 100rpm, and stirring is to uniformly, for mixed liquor A；(2) keep temperature-resistant, be slowly added dropwise polyglycerol polyricinoleate by weight in the mixed liquor A of step (1) to be successively 12Kg, dimethicone be 16Kg, dimethiconol stearate is 10Kg, secondary alcohol polyoxyethylene ether is 5Kg, magnetic agitation is carried out while dripping above-mentioned each composition, speed of agitator is still 100rpm, stirring is all dissolved completely to above-mentioned composition, for mixed liquid B；(3) temperature is kept to be still 55 DEG C, add NSC 6513 in mixed liquid B to be 10Kg, triisopropyl phosphite be 8Kg, triisopropyl borate ester is 6Kg, aminopropanol ascorbic acid phosphoric acid esters is 4Kg, again above-mentioned all the components is carried out magnetic agitation, stirring is to all of composition mix homogeneously, for the used for textiles fire-retardant crease-shedding finishing agent of preparation.
Embodiment 5
(1) taking propylene glycol by weight be 16Kg, water is 350Kg, heats propylene glycol and water to 55 DEG C, and by propylene glycol with carried out magnetic agitation after temperature stabilization, magnetic agitation rotating speed is 100rpm, and stirring is to uniformly, for mixed liquor A；(2) keep temperature-resistant, be slowly added dropwise polyglycerol polyricinoleate by weight in the mixed liquor A of step (1) to be successively 11Kg, dimethicone be 17Kg, dimethiconol stearate is 8Kg, secondary alcohol polyoxyethylene ether is 6Kg, magnetic agitation is carried out while dripping above-mentioned each composition, speed of agitator is still 100rpm, stirring is all dissolved completely to above-mentioned composition, for mixed liquid B；(3) temperature is kept to be still 55 DEG C, add NSC 6513 in mixed liquid B to be 12Kg, triisopropyl phosphite be 7Kg, triisopropyl borate ester is 6Kg, aminopropanol ascorbic acid phosphoric acid esters is 5Kg, again above-mentioned all the components is carried out magnetic agitation, stirring is to all of composition mix homogeneously, for the used for textiles fire-retardant crease-shedding finishing agent of preparation.
Comparative example 1
(1) taking propylene glycol by weight be 20Kg, water is 400Kg, heats propylene glycol and water to 55 DEG C, and by propylene glycol with carried out magnetic agitation after temperature stabilization, magnetic agitation rotating speed is 100rpm, and stirring is to uniformly, for mixed liquor A；(2) keep temperature-resistant, being slowly added dropwise polyglycerol polyricinoleate by weight in the mixed liquor A of step (1) successively be 15Kg, dimethicone is 20Kg, magnetic agitation is carried out while dripping above-mentioned each composition, speed of agitator is still 100rpm, stirring is all dissolved completely to above-mentioned composition, for mixed liquid B；(3) temperature is kept to be still 55 DEG C, add NSC 6513 in mixed liquid B to be 15Kg, triisopropyl phosphite be 9Kg, triisopropyl borate ester is 7Kg, aminopropanol ascorbic acid phosphoric acid esters is 3Kg, again above-mentioned all the components is carried out magnetic agitation, stirring is to all of composition mix homogeneously, for the used for textiles fire-retardant crease-shedding finishing agent of preparation.
Comparative example 2
(1) taking propylene glycol by weight be 20Kg, water is 400Kg, heats propylene glycol and water to 55 DEG C, and by propylene glycol with carried out magnetic agitation after temperature stabilization, magnetic agitation rotating speed is 100rpm, and stirring is to uniformly, for mixed liquor A；(2) keep temperature-resistant, be slowly added dropwise polyglycerol polyricinoleate by weight in the mixed liquor A of step (1) to be successively 15Kg, dimethicone be 20Kg, dimethiconol stearate is 13Kg, secondary alcohol polyoxyethylene ether is 8Kg, magnetic agitation is carried out while dripping above-mentioned each composition, speed of agitator is still 100rpm, stirring is all dissolved completely to above-mentioned composition, for mixed liquid B；(3) temperature is kept to be still 55 DEG C, adding NSC 6513 in mixed liquid B be 15Kg, triisopropyl phosphite is 9Kg, above-mentioned all the components carries out magnetic agitation again, and stirring is to all of composition mix homogeneously, for the used for textiles fire-retardant crease-shedding finishing agent of preparation.
Respectively the finishing agent of pure cotton fabric, dacron and acrylic fabric embodiment 1 to 5, comparative example 1 and 2 preparation is arranged, finishing technique is as follows: is at room temperature dipped into by above-mentioned fabric in the finishing agent of embodiment 1 to 5, comparative example 1 and 2 and soaks 2h, two leachings two are rolled, pick-up is 70%, dries at 100 DEG C.Determining its limited oxygen index, additionally also measured were its wrinkle resistance, result is as follows.
Before arrangement, the limited oxygen index of bafta is 18, and the limited oxygen index of dacron is 16, and the limited oxygen index of acrylic fabric is 14.
Limited oxygen index after table 1 arrangement
Table 2 wrinkle resistance test result
The wrinkle resistance of the fabric after arrangement and and limited oxygen index all significantly improve, the invention provides a kind of crease-resistant antiflaming finishing agent of new textile and preparation method thereof.
Claims (5)
1. fire-retardant crease-shedding finishing agent used for textiles, it is characterised in that described used for textiles fire-retardant crease-shedding finishing agent includes the composition of following weight parts:
NSC 6513 8-15 part,
Triisopropyl phosphite 4-9 part,
Triisopropyl borate ester 4-7 part,
Aminopropanol ascorbic acid phosphoric acid esters 3-7 part,
Polyglycerol polyricinoleate 8-15 part,
Dimethicone 14-20 part,
Dimethiconol stearate 5-13 part,
Secondary alcohol polyoxyethylene ether 4-8 part,
Propylene glycol 12-20 part,
Water 300-400 part.
2. fire-retardant crease-shedding finishing agent used for textiles according to claim 1, it is characterised in that described used for textiles fire-retardant crease-shedding finishing agent includes the composition of following weight parts:
NSC 6513 10-13 part,
Triisopropyl phosphite 5-8 part,
Triisopropyl borate ester 5-6 part,
Aminopropanol ascorbic acid phosphoric acid esters 4-6 part,
Polyglycerol polyricinoleate 10-12 part,
Dimethicone 16-18 part,
Dimethiconol stearate 7-10 part,
Secondary alcohol polyoxyethylene ether 5-7 part,
Propylene glycol 14-18 part,
Water 320-380 part.
3. fire-retardant crease-shedding finishing agent used for textiles according to claim 1, it is characterised in that described used for textiles fire-retardant crease-shedding finishing agent includes the composition of following weight parts:
NSC 6513 12 parts,
Triisopropyl phosphite 7 parts,
Triisopropyl borate ester 6 parts,
Aminopropanol ascorbic acid phosphoric acid esters 5 parts,
Polyglycerol polyricinoleate 11 parts,
Dimethicone 17 parts,
Dimethiconol stearate 8 parts,
Secondary alcohol polyoxyethylene ether 6 parts,
Propylene glycol 16 parts,
350 parts of water.
4. the preparation method of fire-retardant crease-shedding finishing agent used for textiles, it is characterised in that described preparation method comprises the following steps:
(1) taking propylene glycol by weight be 12-20 part, water is 300-400 part, heats propylene glycol and water to 55 DEG C, after temperature stabilization, propylene glycol and water is carried out magnetic agitation, and magnetic agitation rotating speed is 100rpm, and stirring is to uniformly, for mixed liquor A；
(2) keep temperature-resistant, be slowly added dropwise polyglycerol polyricinoleate by weight in the mixed liquor A of step (1) to be successively 8-15 part, dimethicone be 14-20 part, dimethiconol stearate is 5-13 part, secondary alcohol polyoxyethylene ether is 4-8 part, magnetic agitation is carried out while dripping above-mentioned each composition, speed of agitator is still 100rpm, and stirring is equal to above-mentioned composition
Dissolve completely, for mixed liquid B；
(3) temperature is kept to be still 55 DEG C, add NSC 6513 in mixed liquid B to be 8-15 part, triisopropyl phosphite be 4-9 part, triisopropyl borate ester is 4-7 part, aminopropanol ascorbic acid phosphoric acid esters is 3-7 part, again above-mentioned all the components is carried out magnetic agitation, stirring is to all of composition mix homogeneously, for the used for textiles fire-retardant crease-shedding finishing agent of preparation.
5. the used for textiles fire-retardant crease-shedding finishing agent purposes in textile finishing according to claim 1 or 2 or 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510097253.XA CN104695233B (en) | 2015-03-05 | 2015-03-05 | Fire-retardant crease-shedding finishing agent used for textiles and preparation method thereof, purposes |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510097253.XA CN104695233B (en) | 2015-03-05 | 2015-03-05 | Fire-retardant crease-shedding finishing agent used for textiles and preparation method thereof, purposes |
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| Publication Number | Publication Date |
|---|---|
| CN104695233A CN104695233A (en) | 2015-06-10 |
| CN104695233B true CN104695233B (en) | 2016-07-06 |
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| CN201510097253.XA Expired - Fee Related CN104695233B (en) | 2015-03-05 | 2015-03-05 | Fire-retardant crease-shedding finishing agent used for textiles and preparation method thereof, purposes |
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| CN105401320B (en) * | 2015-12-15 | 2017-08-29 | 无锡百和织造股份有限公司 | Flame-retardant elastic band for vehicle and manufacturing method thereof |
| CN106592202A (en) * | 2016-12-15 | 2017-04-26 | 吴江市北厍盛源纺织品助剂厂 | Antifouling flame-retardant finishing agent special for textile and preparation method thereof |
| CN107164960A (en) * | 2017-06-23 | 2017-09-15 | 华娜 | A kind of crease-shedding finishing agent used for textiles and its production and use |
| CN108252088A (en) * | 2017-12-12 | 2018-07-06 | 江苏新瑞贝科技股份有限公司 | A kind of textile flame-retardant finishing agent and preparation method thereof |
| CN109972389B (en) * | 2019-04-09 | 2021-12-17 | 广州市弘邦纺织用品制造有限公司 | Flame-retardant crease-resistant finishing agent for textiles and preparation method and application thereof |
| CN111778725A (en) * | 2020-05-25 | 2020-10-16 | 浙江丑鸭实业有限公司 | Protective clothing |
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| CN102978929A (en) * | 2012-12-04 | 2013-03-20 | 海泰纺织（苏州）有限公司 | Shrinkproof crease-resist chemical finishing agent for fabrics and method for preparing same |
| CN104018350A (en) * | 2014-06-12 | 2014-09-03 | 常州美胜生物材料有限公司 | Laundering-durable flame-retarding finishing agent for fabrics |
| CN104372618A (en) * | 2013-08-13 | 2015-02-25 | 杨林贵 | Wrinkle-resistant textile softening agent |
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| CN102978929A (en) * | 2012-12-04 | 2013-03-20 | 海泰纺织（苏州）有限公司 | Shrinkproof crease-resist chemical finishing agent for fabrics and method for preparing same |
| CN104372618A (en) * | 2013-08-13 | 2015-02-25 | 杨林贵 | Wrinkle-resistant textile softening agent |
| CN104018350A (en) * | 2014-06-12 | 2014-09-03 | 常州美胜生物材料有限公司 | Laundering-durable flame-retarding finishing agent for fabrics |
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