CN109235029A - 棉类织物用阻燃剂 - Google Patents

棉类织物用阻燃剂 Download PDF

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Publication number
CN109235029A
CN109235029A CN201811016638.9A CN201811016638A CN109235029A CN 109235029 A CN109235029 A CN 109235029A CN 201811016638 A CN201811016638 A CN 201811016638A CN 109235029 A CN109235029 A CN 109235029A
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cotton fabric
fire retardant
fabric category
retardant
fire
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张树斌
孙延昌
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Changshu Huashang New Material Technology Co Ltd
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Changshu Huashang New Material Technology Co Ltd
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/72Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/432Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/05Cellulose or derivatives thereof
    • D06M15/09Cellulose ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

本发明公开了一种棉类织物用阻燃剂,按重量百分比计由以下组分组成:醋酸钾15%~25%,氢氧化钾1%~1.5%,三聚磷酸钠1%~2%,羧甲基纤维素钠0.5%~1%,聚氧乙烯辛基苯酚醚%~100.5%~1%,尿素3%~8%,余量为水。本发明阻燃剂为高效的渗透类阻燃水性药剂,棉类织物每次清洗完后,在该阻燃剂中浸泡并晾干,可达到使用时阻燃的目的。

Description

棉类织物用阻燃剂
技术领域
本发明涉及棉类织物用阻燃剂。
背景技术
人员密集场所如宾馆、写字楼、KTV、酒吧、培训教室等地方为了遮阳、装饰,容易使用窗帘、竖直设置的布艺等。这些棉织物一旦发生燃烧,蔓延速度快,极容易引燃周边可燃物导致大的火灾。近年来对这些人员密集场所使用的窗帘、装饰织物等阻燃的需求越来越大,开发无毒、高效、低成本的阻燃剂具备较好的市场需求。
高附着型阻燃剂是现行织物阻燃剂的一个发展方向,其要求是多次清洗后仍然保持阻燃效果,但是这种阻燃剂为了减少每次洗涤带来的损失,往往需要添加很多组分提高附着力以及高效阻燃药剂。
发明内容
本发明的目的在于提供一种棉类织物用阻燃剂,该阻燃剂为高效的渗透类阻燃水性药剂,棉类织物每次清洗完后,在该阻燃剂中浸泡并晾干,可达到使用时阻燃的目的。
为实现上述目的,本发明的技术方案是设计一种棉类织物用阻燃剂,按重量百分比计由以下组分组成:
醋酸钾 15%~25%,
氢氧化钾 1%~1.5%,
三聚磷酸钠 1%~2%,
羧甲基纤维素钠 0.5%~1%,
聚氧乙烯辛基苯酚醚%~10 0.5%~1%,
尿素 3%~8%,
余量为水。
优选的,所述棉类织物用阻燃剂,按重量百分比计由以下组分组成:
醋酸钾 15%,
氢氧化钾 1%,
三聚磷酸钠 1%,
羧甲基纤维素钠 0.5%,
聚氧乙烯辛基苯酚醚%~10 0.5%,
尿素 3%,
余量为水。
优选的,所述棉类织物用阻燃剂,按重量百分比计由以下组分组成:
醋酸钾 17%,
氢氧化钾 1.2%,
三聚磷酸钠 1.5%,
羧甲基纤维素钠 0.8%,
聚氧乙烯辛基苯酚醚%~10 0.7%,
尿素 5%,
余量为水。
优选的,所述棉类织物用阻燃剂,按重量百分比计由以下组分组成:
醋酸钾 25%,
氢氧化钾 1.5%,
三聚磷酸钠 2%,
羧甲基纤维素钠 1%,
聚氧乙烯辛基苯酚醚%~10 1%,
尿素 8%,
余量为水。
本发明的优点和有益效果在于:提供一种棉类织物用阻燃剂,该阻燃剂为高效的渗透类阻燃水性药剂,棉类织物每次清洗完后,在该阻燃剂中浸泡并晾干,可达到使用时阻燃的目的。
1)本发明阻燃剂无毒无害,对棉类织物本色污染小。
2)本发明阻燃剂成本低廉。
3)本发明阻燃剂的阻燃效果好。
4)本发明阻燃剂制备工艺简单。
具体实施方式
下面结合实施例,对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案,而不能以此来限制本发明的保护范围。
配置:
将15~25%的醋酸钾和1~1.5%氢氧化钾加入水中,搅拌溶解后,在持续搅拌作用下缓慢加入0.5~1%羧甲基纤维素钠,搅拌超过20 min,静置超过4 h至完全溶解(羧甲基纤维素钠的溶解需要较长时间的静置,该物质不断水合并溶解),搅拌下加入1~2%的三聚磷酸钠、0.5~1%的聚氧乙烯辛基苯酚醚~10和3~8%的尿素,搅拌至溶液澄清,制得阻燃剂。
使用:
新的棉类织物或清洗晾干后的棉类织物,在上述阻燃剂溶液中浸泡并搅动超过15min,至彻底渗透,取出晾干即可。
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明技术原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。

Claims (4)

1.棉类织物用阻燃剂,其特征在于,按重量百分比计由以下组分组成:
醋酸钾 15%~25%,
氢氧化钾 1%~1.5%,
三聚磷酸钠 1%~2%,
羧甲基纤维素钠 0.5%~1%,
聚氧乙烯辛基苯酚醚%~10 0.5%~1%,
尿素 3%~8%,
余量为水。
2.根据权利要求1所述的棉类织物用阻燃剂,其特征在于,按重量百分比计由以下组分组成:
醋酸钾 15%,
氢氧化钾 1%,
三聚磷酸钠 1%,
羧甲基纤维素钠 0.5%,
聚氧乙烯辛基苯酚醚%~10 0.5%,
尿素 3%,
余量为水。
3.根据权利要求1所述的棉类织物用阻燃剂,其特征在于,按重量百分比计由以下组分组成:
醋酸钾 17%,
氢氧化钾 1.2%,
三聚磷酸钠 1.5%,
羧甲基纤维素钠 0.8%,
聚氧乙烯辛基苯酚醚%~10 0.7%,
尿素 5%,
余量为水。
4.根据权利要求1所述的棉类织物用阻燃剂,其特征在于,按重量百分比计由以下组分组成:
醋酸钾 25%,
氢氧化钾 1.5%,
三聚磷酸钠 2%,
羧甲基纤维素钠 1%,
聚氧乙烯辛基苯酚醚%~10 1%,
尿素 8%,
余量为水。
CN201811016638.9A 2018-09-03 2018-09-03 棉类织物用阻燃剂 Pending CN109235029A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115738159A (zh) * 2022-11-22 2023-03-07 晋西铁路车辆有限责任公司 一种水系灭火剂及其制备方法

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Application publication date: 20190118