CN109233505A - It is a kind of based on formaldehydeless substrate and to discharge the coating of anion - Google Patents

It is a kind of based on formaldehydeless substrate and to discharge the coating of anion Download PDF

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Publication number
CN109233505A
CN109233505A CN201710365383.6A CN201710365383A CN109233505A CN 109233505 A CN109233505 A CN 109233505A CN 201710365383 A CN201710365383 A CN 201710365383A CN 109233505 A CN109233505 A CN 109233505A
Authority
CN
China
Prior art keywords
parts
coating
anion
formaldehydeless
discharge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710365383.6A
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Chinese (zh)
Inventor
赵文刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TAICANG SHUNRUCHENG BUILDING MATERIALS Co Ltd
Original Assignee
TAICANG SHUNRUCHENG BUILDING MATERIALS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by TAICANG SHUNRUCHENG BUILDING MATERIALS Co Ltd filed Critical TAICANG SHUNRUCHENG BUILDING MATERIALS Co Ltd
Priority to CN201710365383.6A priority Critical patent/CN109233505A/en
Publication of CN109233505A publication Critical patent/CN109233505A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/221Oxides; Hydroxides of metals of rare earth metal
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

It is a kind of based on formaldehydeless substrate and to discharge the coating of anion, the raw material composition including following parts by weight: 10 ~ 25 parts of polyacrylate;8 ~ 15 parts of organic siliconresin;5 ~ 15 parts of functional filler;1 ~ 5 part of negative ion powder;0.5 ~ 3 part of thickener;1 ~ 3 part of dispersing agent;0.5 ~ 2 part of wetting agent;0.5 ~ 2 part of levelling agent;0.5 ~ 1 part of pigment;80 ~ 100 parts of water.Formulation for coating material proposed by the present invention is reasonable, formaldehydeless etc. harmful components of raw materials, can prevent the pollution of free formaldehyde, simultaneously from the root, pass through the formula of negative ion powder and functional filler, the effect that antibacterial can be played, purified the air of a room can effectively improve indoor air quality, guarantee people's health, and, this coating has certain waterproof, and wear-resisting property meets requirement of the people to high-quality coating.

Description

It is a kind of based on formaldehydeless substrate and to discharge the coating of anion
Technical field
The present invention relates to indoor decorating and refurnishing materials technical fields, and in particular to one kind is based on formaldehydeless substrate and discharges negative The coating of ion.
Background technique
Formaldehyde (HCHO) is a kind of colourless readily soluble irritative gas, and formaldehyde can be absorbed through respiratory tract, aqueous solution " Fu Er Malin " can absorb through alimentary canal.It can stimulate eyes to Long Term Contact low dosage formaldehyde that can cause chronic respiratory disease, women Paramenia, pregnancy syndrome cause newborn's constitution to reduce, chromosome abnormality, or even cause nasopharyngeal carcinoma.High-concentration formaldehyde pair Nervous system, immune system, liver etc. are all toxic.There are also teratogenesis, carcinogenic effect for formaldehyde, according to epidemiological survey, for a long time The people of Formaldehyde Exposed can cause nasal cavity, oral cavity, nasopharynx, throat, skin and gastral cancer.
Used paint, coating are fitted up indoors, in binder, formaldehyde common solvent, and be also that Lauxite etc. bonds The synthesis material of agent, indoors in the long period in fitment process and after finishing, formaldehyde solvent and unreacted formaldehyde It can gradually discharge.Especially interior decoration plate, it is slower to penetrate into Form aldehyde release speed therein, after often fitting up latter wheat harvesting period It remains as the mankind and brings harm.Currently, formaldehyde has become the maximum problem in interior decoration field.
Meanwhile harmful minimum gas that constructional ornamental material in daily and furniture usually discharge, such as formaldehyde, ammonia, benzene In the sky, its occurrence status and form is complicated and diversified, gas of some to dissociate for the floatings such as the peculiar smell generated with human body Molecular forms exist, and some forms cation, some minimum gas point by the absorption of a large amount of positive charge, the encirclement that float in air Son deposits on already present particle surface, is condensed into aerosol system etc..Just because of depositing for the above cation or aerosol The indoor serious air pollution of new finishing is being caused, great harm is caused to human health.
Significant impact of the anion to the health of people, longevity and ecology has passed through for domestic and international medical field expert clinical real It tramples and is verified.Anion can not only facilitate human body synthesis and vitamin storage, strengthen the physiological activity with human activin, therefore it Be otherwise known as " air vitamin ", it is believed that it has the vital movement of human body and other biological as the vitamin of food Highly important influence, in medical field, anion be identified be with kill germ and purify air effective means.Its machine After reason essentially consists in anion in conjunction with bacterium, so that bacterium is generated the change of structure or the transfer of energy, lead to bacterial death, most Final decline is sunken to ground.
And currently used coating only serves the effect of decoration, does not have any work to the health of the improvement of environment and human body With.
Therefore, in view of the above-mentioned problems, the invention proposes a kind of new technical solutions.
Summary of the invention
The object of the present invention is to provide a kind of formulas rationally, formaldehydeless release, safety and environmental protection, meanwhile, have good anti- Bacterium effect, can improve room air based on formaldehydeless substrate and discharge the coating of anion.
The present invention is achieved through the following technical solutions:
It is a kind of based on formaldehydeless substrate and to discharge the coating of anion, the raw material composition including following parts by weight:
10 ~ 25 parts of polyacrylate;
8 ~ 15 parts of organic siliconresin;
5 ~ 15 parts of functional filler;
1 ~ 5 part of negative ion powder;
0.5 ~ 3 part of thickener;
1 ~ 3 part of dispersing agent;
0.5 ~ 2 part of wetting agent;
0.5 ~ 2 part of levelling agent;
0.5 ~ 1 part of pigment;
80 ~ 100 parts of water.
Further, the functional filler includes 1 ~ 5 part of iron dravite powder, 1 ~ 5 part of terbium oxide and 1 ~ 5 part Hollow microspheres.
Further, the negative ion powder and iron dravite powder are nano-scale particle material.
Further, the negative ion powder and iron dravite powder are the composite nano materials being carried on carrier.
Further, the carrier is hollow microspheres.
Further, the thickener is polyurethane thickener.
The beneficial effects of the present invention are: formulation for coating material proposed by the present invention is reasonable, formaldehydeless etc. nocuousness of raw materials Ingredient can prevent the pollution of free formaldehyde from the root, meanwhile, by the formula of negative ion powder and functional filler, can rise To antibacterial, the effect to purify the air of a room, indoor air quality can be effectively improved, guarantees people's health, moreover, this coating With certain waterproof, wear-resisting property meets requirement of the people to high-quality coating.
Specific embodiment
The present embodiment is described further below with reference to embodiment.
Embodiment 1
It is a kind of based on formaldehydeless substrate and to discharge the coating of anion, the raw material composition including following parts by weight:
20 parts of polyacrylate;
12 parts of organic siliconresin;
5 parts of functional filler;
1 part of negative ion powder;
1.5 parts of thickener;
1 part of dispersing agent;
1 part of wetting agent;
1 part of levelling agent;
0.8 part of pigment;
80 parts of water.
In the present embodiment, functional filler include 2 parts iron dravite powder, 1 part of terbium oxide and 2 parts it is hollow micro- Sphere, negative ion powder and iron dravite powder are nano-scale particle material, and negative ion powder and iron dravite powder are to be carried on Composite nano materials on carrier, carrier are hollow microspheres, and thickener is polyurethane thickener.
Embodiment 2
It is a kind of based on formaldehydeless substrate and to discharge the coating of anion, the raw material composition including following parts by weight:
20 parts of polyacrylate;
12 parts of organic siliconresin;
10 parts of functional filler;
3 parts of negative ion powder;
1.5 parts of thickener;
1 part of dispersing agent;
1 part of wetting agent;
1 part of levelling agent;
0.8 part of pigment;
80 parts of water.
In the present embodiment, functional filler include 3 parts iron dravite powder, 4 parts of terbium oxides and 4 parts it is hollow micro- Sphere, negative ion powder and iron dravite powder are nano-scale particle material, and negative ion powder and iron dravite powder are to be carried on Composite nano materials on carrier, carrier are hollow microspheres, and thickener is polyurethane thickener.
Embodiment 3
It is a kind of based on formaldehydeless substrate and to discharge the coating of anion, the raw material composition including following parts by weight:
20 parts of polyacrylate;
12 parts of organic siliconresin;
15 parts of functional filler;
5 parts of negative ion powder;
1.5 parts of thickener;
1 part of dispersing agent;
1 part of wetting agent;
1 part of levelling agent;
0.8 part of pigment;
80 parts of water.
In the present embodiment, functional filler include 5 parts iron dravite powder, 2 parts of terbium oxides and 8 parts it is hollow micro- Sphere, negative ion powder and iron dravite powder are nano-scale particle material, and negative ion powder and iron dravite powder are to be carried on Composite nano materials on carrier, carrier are hollow microspheres, and thickener is polyurethane thickener.
Formulation for coating material proposed by the present invention is reasonable, and formaldehydeless etc. harmful components of raw materials can shut out from the root The pollution of exhausted free formaldehyde, meanwhile, by the formula of negative ion powder and functional filler, antibacterial can be played, purified the air of a room Effect, can effectively improve indoor air quality, guarantee people's health, it is wear-resisting moreover, this coating has certain waterproof Performance meets requirement of the people to high-quality coating.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (6)

  1. Based on formaldehydeless substrate and the coating of anion is discharged 1. a kind of, it is characterised in that: the raw material including following parts by weight Composition:
    10 ~ 25 parts of polyacrylate;
    8 ~ 15 parts of organic siliconresin;
    5 ~ 15 parts of functional filler;
    1 ~ 5 part of negative ion powder;
    0.5 ~ 3 part of thickener;
    1 ~ 3 part of dispersing agent;
    0.5 ~ 2 part of wetting agent;
    0.5 ~ 2 part of levelling agent;
    0.5 ~ 1 part of pigment;
    80 ~ 100 parts of water.
  2. 2. a kind of according to claim 1 based on formaldehydeless substrate and discharge the coating of anion, it is characterised in that: the function Energy property filler includes 1 ~ 5 part of iron dravite powder, 1 ~ 5 part of terbium oxide and 1 ~ 5 part of hollow microspheres.
  3. A kind of based on formaldehydeless substrate and the coating of anion is discharged 3. according to claim 1 or claim 2, it is characterised in that: institute Stating negative ion powder and iron dravite powder is nano-scale particle material.
  4. 4. a kind of according to claim 1 based on formaldehydeless substrate and discharge the coating of anion, it is characterised in that: described negative Ion powder and iron dravite powder are the composite nano materials being carried on carrier.
  5. 5. a kind of according to claim 4 based on formaldehydeless substrate and discharge the coating of anion, it is characterised in that: the load Body is hollow microspheres.
  6. 6. a kind of according to claim 1 based on formaldehydeless substrate and discharge the coating of anion, it is characterised in that: the increasing Thick dose is polyurethane thickener.
CN201710365383.6A 2017-05-22 2017-05-22 It is a kind of based on formaldehydeless substrate and to discharge the coating of anion Pending CN109233505A (en)

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CN201710365383.6A CN109233505A (en) 2017-05-22 2017-05-22 It is a kind of based on formaldehydeless substrate and to discharge the coating of anion

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Application Number Priority Date Filing Date Title
CN201710365383.6A CN109233505A (en) 2017-05-22 2017-05-22 It is a kind of based on formaldehydeless substrate and to discharge the coating of anion

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113216808A (en) * 2021-05-12 2021-08-06 广东福临门世家智能家居有限公司 Anion glass door and window with sterilization and formaldehyde removal functions and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1648178A (en) * 2004-01-19 2005-08-03 范存玉 Long action negative ion antiseptic function paint
CN1687268A (en) * 2005-05-02 2005-10-26 复旦大学 Controlled released stably coating material capable of purifying air and preparation method thereof
CN104497772A (en) * 2015-01-15 2015-04-08 宁波保税区韬鸿化工科技有限公司 Negative ion environment-friendly coating
CN104559413A (en) * 2015-01-15 2015-04-29 宁波保税区韬鸿化工科技有限公司 Negative-ion putty powder

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1648178A (en) * 2004-01-19 2005-08-03 范存玉 Long action negative ion antiseptic function paint
CN1687268A (en) * 2005-05-02 2005-10-26 复旦大学 Controlled released stably coating material capable of purifying air and preparation method thereof
CN104497772A (en) * 2015-01-15 2015-04-08 宁波保税区韬鸿化工科技有限公司 Negative ion environment-friendly coating
CN104559413A (en) * 2015-01-15 2015-04-29 宁波保税区韬鸿化工科技有限公司 Negative-ion putty powder

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113216808A (en) * 2021-05-12 2021-08-06 广东福临门世家智能家居有限公司 Anion glass door and window with sterilization and formaldehyde removal functions and preparation method thereof
CN113216808B (en) * 2021-05-12 2022-01-18 广东福临门世家智能家居有限公司 Anion glass door and window with sterilization and formaldehyde removal functions and preparation method thereof

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Application publication date: 20190118