CN106731782A - A kind of green plant auxotype formaldehyde scavenger and preparation method thereof - Google Patents

A kind of green plant auxotype formaldehyde scavenger and preparation method thereof Download PDF

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Publication number
CN106731782A
CN106731782A CN201710057351.XA CN201710057351A CN106731782A CN 106731782 A CN106731782 A CN 106731782A CN 201710057351 A CN201710057351 A CN 201710057351A CN 106731782 A CN106731782 A CN 106731782A
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China
Prior art keywords
parts
auxotype
green plant
formaldehyde
added
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CN201710057351.XA
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Chinese (zh)
Inventor
王盛良
王加吉
储林梅
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Nanjing Suntrans Technology Co Ltd
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Nanjing Suntrans Technology Co Ltd
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Priority to CN201710057351.XA priority Critical patent/CN106731782A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • B01D53/85Biological processes with gas-solid contact
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G7/00Botany in general
    • A01G7/06Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/22Ionisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/704Solvents not covered by groups B01D2257/702 - B01D2257/7027
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

The invention provides the green plant auxotype formaldehyde scavenger of one kind, it is made up of following compositions:5 40 parts of compound amino acid, 1 10 parts of shitosan, 20 80 parts of ferrous sulfate, 5 50 parts of organic acid, surfactant 18,1 10 parts of negative ion powder, 967 802 parts of water.Invention also provides a kind of green preparation method for planting battalion's auxotype formaldehyde scavenger, carry out as follows:1) by above-mentioned composition and ratio, raw material for standby is weighed;2) by the moisture in formula into 2 parts, acetic acid, the shitosan of formula ratio are added in portion wherein, after after all dissolvings, adds compound amino acid, ferrous sulfate;3) negative ion powder is added in another water in being formulated, surfactant is added, then ultrasonic wave(20KHZ)After dissolving, dispersion, modified 60min, then with step 2)Mix, dispersed with stirring is uniform, obtains final product this formulation product.Green plant auxotype formaldehyde scavenger of the invention, can not only provide green plant certain nutrition, while the anion burst size of green plant can be improved, improve its formaldehyde removing effect.

Description

A kind of green plant auxotype formaldehyde scavenger and preparation method thereof
Technical field
The present invention relates to green plant auxotype formaldehyde scavenger of one kind and preparation method thereof, it belongs to afforestation application technology Field.
Background technology
New house finishing is inevitable to have the pollution such as formaldehyde, and urban atmospheric pollution also makes the PM2.5 dust that haze brings dirty The harm of dye is increasingly severe.Formaldehyde is more highly toxic material, and formaldehyde has been defined as carcinogenic and has caused by the World Health Organization Deformed material, is generally acknowledged allergen, is also one of potential strong mutagen, in Chinese toxic chemical priority acccess control Formaldehyde is in second on list, with strong carcinogenic and tumor promotion.Influence of the formaldehyde to health is mainly manifested in The aspects such as allotriosmia, stimulation, allergy, abnormal pulmonary function, dysfunction of liver and immunologic dysfunction.Formaldehyde reaches in atmosphere 0.06-0.07mg/m3During concentration, children will occur slight asthma.When formaldehyde content in indoor air is 0.1mg/m 3, Just there are peculiar smell and sense of discomfort;When reaching 0.5mg/m3, eyes can be stimulated, cause and shed tears;0.6mg/m 3 is reached, throat can be caused Uncomfortable or pain.When concentration is higher, n and V can be caused, coughed uncomfortable in chest, asthma even pulmonary edema;When reaching 30mg/m3, meeting Causing death immediately.
Technical products and method about removing formaldehyde have been carried out many researchs.The A of Chinese patent CN 104474882 (Application number:201410741523.1)A kind of method of room air plant ecological purification is disclosed, by detecting indoor pollution The type and quantity of thing, different types of plant bonsai is combined, and forms a purifying ecological system for three-dimensional, institute The described plant bonsai stated based on Chinese yew, also including bracketplant, aloe, ivy, asparagus fern, the bamboo palm, dripping guanyin or celestial being People the palm in one or more.The patent claims the inventive method is simply used, Non-energy-consumption and with the energy of lasting purify air Power.
The A of Chinese patent CN 103143242(Application number:201210508680.9)Disclose a kind of finishing pure plant first Aldehyde remover, it is made up of by weight following components:Bracketplant 10-15 parts, sansevieria trifasciata 10-15 parts, ivy 10-15 parts, Aloe 3-7 parts, American aloe 10-15 parts, African daisy 10-15 parts and dayflower 10-15 parts, directly crush and weighed by formula, It is placed in living environment, inventor claims that this finishing pure plant formaldehyde removal agent prescription is natural, and formaldehyde removal effect is good.
It is placed in living environment using potted plant green plants, can be beautified the environment, and energy purify air, this has turned into more Carry out the common recognition of more people.Plant can by photosynthesis suction part harmful substance, but this kind of method effect extremely It is limited.Reason is as follows:What one, plant were carried out is photosynthesis, typically in suction part harmful substance on daytime, and night not Possesses this function.The rule of life of people is typically all that outside room on daytime, night indoors, when people needs most purification of air, plants Thing has no idea to play corresponding effect.Secondly, the harmful substance of plant absorption is extremely limited.The release of national standard PARA FORMALDEHYDE PRILLS(91,95) Value requires to be less than 0.08 mg/m3, the houses just fitted up of the overwhelming majority, formaldehyde is not less than 0.2 mg/m3, and absorb formaldehyde efficiency Epipremnum aureum higher, the formaldehyde for absorbing per hour is only 20 micrograms.With 100 square meters, room is high 3 meters, and formolite number is 0.2 mg/ m3Room for, while need 1800 basin epipremnum aureums, almost whole house space is filled, formaldehyde could be reduced to 0.08 Milligram, what this was still carried out in the case where daytime is bright and clear, and to ensure during being absorbed there is no first The release of aldehyde.And in fact, finishing after furniture in formaldehyde also always constantly release.Therefore, up to the present, plant is only The harmful substances such as energy PARA FORMALDEHYDE PRILLS(91,95), benzene play the governance role of auxiliary.
The purpose of the present invention aims to provide a kind of green plant auxotype formaldehyde scavenger, directly sprays onto potted plant green plant, no It is only capable of meeting the certain nutritional need of green plant, and its anion burst size can be strengthened, especially in weaker photoenvironment condition Under can also carry out photosynthesis, play continuing purge air ambient, the purpose of the air pollution such as removal formaldehyde.
The content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of green plant auxotype formaldehyde scavenger, can not only provide It is green to plant certain nutrition, green being implanted under weaker illumination condition is also carried out photosynthesis, and improve the anion of green plant Burst size, reaches removal formaldehyde, lifts the ability of purify air.
In order to solve the above technical problems, the present invention is achieved through the following technical solutions.
A kind of green plant auxotype formaldehyde scavenger, is made up of following compositions:
Compound amino acid 5-40 parts;
Shitosan 1-10 parts;
Ferrous sulfate 20-80 parts;Organic acid 5-50 parts
Surfactant 1-8;
Negative ion powder 1-10 parts;
Water 967-802 parts.
Described compound amino acid is purchased from Shanghai Yuan Ye Bioisystech Co., Ltd, content 99%.
The shitosan is purchased from Jiangxi Hai Deli Industrial Co., Ltd.s, deacetylation more than 80%.
The ferrous sulfate is purchased from Langfang Peng Cai Chemical Co., Ltd.s.
The organic acid can be that acetic acid, citric acid, laurate etc. can normally be purchased and used;The surfactant can To be anion surfactant, or nonionic surfactant, such as dodecyl sodium sulfate, sldium lauryl sulfate or Person's polysorbas20-60, span 20-60, purchased from Nantong Bo Si Chemical Co., Ltd.s.
Nanjing Du Xiu developments in science and technology Co., Ltd, negative ion amount >=50,000/cm are purchased from selected from the negative ion powder3Nanometer Superfine powder, granularity is less than 1500 mesh.
The effect of each raw material:Compound amino acid can provide it is green plant growth needed for partial nitrogen source, while compound amino acid with Shitosan contains active amino, and chemical bonding reaction can at normal temperatures occur with formaldehyde, plays a part of to remove formaldehyde.Sulfuric acid is sub- Iron under mildly acidic conditions, forms acid ferrous ion, and after spray to green plant blade face, divalence ferrous ion can replace chlorophyll The central atom magnesium of porphyrin ring structure, to form ferrous de-magnesium pheophytin, so that green plants is in the illumination weaker dusk Proceed photosynthesis, continuing purge air, absorbing carbon dioxide improves indoor and outdoor surroundingses;Negative ion powder can be provided in itself It is green to plant growth and the part micro-element nutrition needed for photosynthesis, the green plant of nutrition, while the anion for increasing the green plant for the treatment of is released High-volume, the negative ion concentration for putting green plant environment is improved, further coordinates the air-filtering ability of the green plant of enhancing.
Invention also provides the preparation method of green plant auxotype formaldehyde scavenger, comprise the following steps:
1) by above-mentioned composition and ratio, raw material for standby is chosen;
2) by the moisture in formula into 2 parts, acetic acid, the shitosan of formula ratio are added in portion wherein, treats whole dissolvings Afterwards, compound amino acid, ferrous sulfate are added;
3) negative ion powder is added in another water in being formulated, surfactant is added, then ultrasonic wave(20KHZ)Dissolve, divide After dissipating modified 60min, then with 2)Mix, dispersed with stirring is uniform, obtains final product this formulation product.
The beneficial effects of the invention are as follows:Conventional green plant is potted plant, bright after spraying auxotype formaldehyde scavenger of the invention It is aobvious to improve its photosynthesis under weak light, its air-filtering ability is improved, and also its ability for removing formaldehyde is substantially carried It is high.Meanwhile, auxotype formaldehyde scavenger of the invention is sprayed, and the green part planted needed for growth photosynthesis can be provided The negative ion concentration in green plant space is put in nutrient, raising, has both maintained the effect beautified the environment for putting green plant, improves again Its detergent power to environmental air pollution especially formaldehyde pollution.
Specific embodiment
With reference to embodiments further the present invention will be described, but present disclosure be not limited solely to it is following Embodiment.
Embodiment 1.
Green plant auxotype formaldehyde scavenger, by compound amino acid(Shanghai Yuan Ye Bioisystech Co., Ltd, content 99%)、 Shitosan(Jiangxi Hai Deli Industrial Co., Ltd.s, deacetylation more than 80%), ferrous sulfate(Langfang Peng Cai Chemical Co., Ltd.s, Analysis is pure), negative ion powder(Nanjing Du Xiu developments in science and technology Co., Ltd, negative ion amount >=50,000/cm3Nano ultrafine powderses body, grain Degree is less than 1500 mesh), acetic acid(It is commercially available), Tween-40(Nantong Bo Si Chemical Co., Ltd.s, content 98%)Raw material prepare and Into.Mass fraction shared by each raw material is as follows:10 parts of compound amino acid, 2 parts of shitosan, 40 parts of ferrous sulfate, 8 parts of acetic acid, tween- 40 2 parts, 5 parts of negative ion powder, 933 parts of water.
The present embodiment is carried out as follows:
1) by above-mentioned composition and ratio, raw material for standby is chosen;
2) by the moisture in formula into 2 parts, acetic acid, the shitosan of formula ratio are added in portion wherein, treats whole dissolvings Afterwards, compound amino acid, ferrous sulfate are added;
3) negative ion powder is added in another water in being formulated, surfactant is added, then ultrasonic wave(20KHZ)Dissolve, divide After dissipating modified 60min, then with 2)Mix, dispersed with stirring is uniform, obtains final product the present embodiment formulation product.
By green plant auxotype formaldehyde scavenger spray in potted plant green plant leaf surfaces, including epipremnum aureum, the fruit of glossy privet, bracketplant, reed The sprayable product of the present invention such as luxuriant growth and red bean is refined, Monstera deliciosa, cyanines wormwood artemisia.
Spray the measure of the epipremnum aureum PARA FORMALDEHYDE PRILLS(91,95) absorbability of the green plant auxotype formaldehyde scavenger of embodiment 1.
Take in 1m3It is measured in climate box.The basin of empty vector control epipremnum aureum plant 3 is first put into, the formaldehyde of 10 μ L is molten Liquid is opened built-in fans and allows formalin to evaporate into mist completely, using first with sprayer note people to confined reaction room Aldehyde analyzer Interscan4160 types measure initial concentration of formaldehyde and 24 hour concentrations.Experimental group still selects an equal amount of The basin of epipremnum aureum plant 3, sprays the green plant auxotype formaldehyde scavenger of embodiment 1 in whole plant, 50 grams/basin of spray flux, every 1 hour Repeat spray once, the experiment epipremnum aureum of embodiment 1 is then put into 1m3In climate box, the formalin of 10 μ L is sprayed into, opened Built-in fans, initial concentration of formaldehyde and 24 hour concentrations are measured using Interscan4160 type direct-reading Formaldehyde analyzer.Simultaneously Using IT-10 anionic textiles instrument(Purchased from Guangzhou Yi Hong Electronics Co., Ltd.s), the anion in measurement climate box in air is dense Degree.Experiment repeats 3 times, as a result takes 3 result averages, is shown in Table 1.
Table 1:It is green plant auxotype formaldehyde scavenger except effect of formaldehyde and negative ion concentration measurement result.
Group Initial formaldehyde is dense Degree (mg/m3) Formaldehyde after 24 hours Concentration (mg/m3) Remove Rate(%) Initial negative ion concentration (Individual/cm3 Anion is dense after 24 hours Degree(Individual/cm3
Control group 1.36 0.59 56.6 26 28
Embodiment 1 1.29 0.06 95.3 850 853
As it can be seen from table 1 by after the green plant auxotype formaldehyde scavenger of the present embodiment spray, embodiment group and control group phase Than formaldehyde removing effect is significantly improved.And embodiment 1 is compared with control group, the anion release of green plant is greatly improved Concentration.
It is that, to supplement of the invention, but should not be construed above-mentioned subject area of the invention and only limit to the embodiment of the present invention In embodiment.Without departing from the idea case in the present invention described above, according to ordinary skill knowledge and customary means, Various replacements and change are made, all should be included within the scope of the present invention.

Claims (2)

1. one kind is green plants auxotype formaldehyde scavenger, it is characterised in that be made up of following compositions:
Compound amino acid 5-40 parts;
Shitosan 1-10 parts;
Ferrous sulfate 20-80 parts;
Organic acid 5-50 parts;
Surfactant 1-8;
Negative ion powder 1-10 parts;
Water 967-802 parts.
2. the green plant auxotype formaldehyde scavenger according to claim 1, its preparation method is as follows:
1) by above-mentioned composition and ratio, raw material for standby is weighed;
2) by the moisture in formula into 2 parts, acetic acid, the shitosan of formula ratio are added in portion wherein, treats whole dissolvings Afterwards, compound amino acid, ferrous sulfate are added;
3) negative ion powder is added in another water in being formulated, surfactant is added, then ultrasonic wave(20KHZ)Dissolve, divide After dissipating modified 60min, then with 2)Mix, dispersed with stirring is uniform, obtains final product this formulation product.
CN201710057351.XA 2017-01-26 2017-01-26 A kind of green plant auxotype formaldehyde scavenger and preparation method thereof Pending CN106731782A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110180363A (en) * 2019-06-14 2019-08-30 郑州淳野生物科技有限公司 A kind of formaldehyde remover and preparation method thereof with sterilizing function
CN110523148A (en) * 2018-05-24 2019-12-03 沃纳·纽斯勒 Equipment for filtering room air

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1229589A (en) * 1999-01-18 1999-09-29 贺盛堂 Substance compsn. for promoting growth of plant and its prepn. method
CN101623594A (en) * 2009-08-04 2010-01-13 广州城市职业学院 Method for purifying air pollution by plant nano composite material
CN104054526A (en) * 2014-04-02 2014-09-24 蒋泰龙 Method and application for changing chlorophyll of green plant
CN105413454A (en) * 2015-11-24 2016-03-23 沈阳领拓科技有限公司 Formaldehyde purifying agent and application thereof in non-woven formaldehyde purifying wallpaper

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1229589A (en) * 1999-01-18 1999-09-29 贺盛堂 Substance compsn. for promoting growth of plant and its prepn. method
CN101623594A (en) * 2009-08-04 2010-01-13 广州城市职业学院 Method for purifying air pollution by plant nano composite material
CN104054526A (en) * 2014-04-02 2014-09-24 蒋泰龙 Method and application for changing chlorophyll of green plant
CN105413454A (en) * 2015-11-24 2016-03-23 沈阳领拓科技有限公司 Formaldehyde purifying agent and application thereof in non-woven formaldehyde purifying wallpaper

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110523148A (en) * 2018-05-24 2019-12-03 沃纳·纽斯勒 Equipment for filtering room air
CN110180363A (en) * 2019-06-14 2019-08-30 郑州淳野生物科技有限公司 A kind of formaldehyde remover and preparation method thereof with sterilizing function

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Application publication date: 20170531