CN109233474A - A kind of inner wall decorative coating and its preparation process - Google Patents
A kind of inner wall decorative coating and its preparation process Download PDFInfo
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- CN109233474A CN109233474A CN201811076003.8A CN201811076003A CN109233474A CN 109233474 A CN109233474 A CN 109233474A CN 201811076003 A CN201811076003 A CN 201811076003A CN 109233474 A CN109233474 A CN 109233474A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
- C08K2003/2213—Oxides; Hydroxides of metals of rare earth metal of cerium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of inner wall decorative coatings, in parts by weight, the coating is composed of the following components: 1-3 parts of collagen, 50-75 parts of lotion, 1-3 parts of dispersing agent, 5-9 parts of photocatalyst, 10-20 parts of filler, 5-10 parts of negative ion powder, 4-8 parts of water-soluble resin, 5-10 parts of conch meal, 0.5-2 parts of graphene, 3-5 parts of defoaming agent, 3-6 parts of preservative, 2-5 parts of binder, 20-50 parts of water.The paint ingredient is nontoxic, and the coating film forming and compactness are high, water-tolerant, strong with substrate binding force, conch meal has loose porous structure, the moisture and room peculiar smell stored in adsorbable wall, also have the function of sterilizing degerming, negative ion powder has effects that also to contain photocatalyst to indoor release anion, the effect of degradation of formaldehyde can be realized without special illumination in it, is a kind of coating of health environment-friendly.The preparation process of the coating is also disclosed, step is simple, mild condition, is suitable for mass industrial production.
Description
Technical field
The invention belongs to building material technical field, it is related to a kind of inner wall decorative coating and its preparation process, specifically
It is related to a kind of environment-friendly type, inner wall decorative coating capable of releasing negative ion and its preparation process.
Background technique
With the development and improvement of living standard of society, people increasingly reinforce the attention rate of environmental protection, health aspect,
People need to stop between floors for a long time daily, therefore gradually require the environmental-protecting performance of indoor building material higher and higher.
Interior wall coating is a kind of for decorating and protecting the material of metope and ceiling, and beautiful and comfortable living environment can be provided for people.
Interior wall coating generally has the characteristics that rich in color, material is fine and smooth, water-tolerant, is not pulverized easily, but traditional interior wall coating is logical
Frequently with a large amount of organic solvents and the auxiliary agent with certain toxicity, the paint filler containing heavy metal, in the production and use process
All there may be harmful substances, influence human health, cause environmental pollution.Therefore a kind of nonhazardous substance, environmental protection, health are developed
Inner wall decorative coating become urgent problem to be solved.
Summary of the invention
For this purpose, the present invention exactly will solve above-mentioned technical problem, to propose a kind of inner wall decorative coating of environment protection health
And its preparation process.
In order to solve the above technical problems, the technical solution of the present invention is as follows:
The present invention provides a kind of inner wall decorative coating, and in parts by weight, the coating is composed of the following components: collagen
1-3 parts, 50-75 parts of lotion, 1-3 parts of dispersing agent, 5-9 parts of photocatalyst, 10-20 parts of filler, 5-10 parts of negative ion powder, water-soluble tree
4-8 parts of rouge, 5-10 parts of conch meal, 0.5-2 parts of graphene, 3-5 parts of defoaming agent, 3-6 parts of preservative, 2-5 parts of binder, water 20-
50 parts.
Preferably, the coating is composed of the following components: 2 parts of collagen, 60 parts of lotion, 2 parts of dispersing agent, photocatalyst
6 parts, 15 parts of filler, 8 parts of negative ion powder, 6 parts of water-soluble resin, 7 parts of conch meal, 1 part of graphene, 4 parts of defoaming agent, preservative 5
Part, 3 parts of binder, 40 parts of water.
Preferably, the photocatalyst is in parts by weight, by 6-8 parts of silver nano-grains, 20-25 parts of praseodymium oxides and 50-65
Part molecular sieve composition.
Preferably, the negative ion powder is in parts by weight, by 3-5 parts of cerium oxide, 6-8 parts of terbium oxides and 30-50 parts of electricity
Gas stone composition and modified processing.
Preferably, the partial size of the negative ion powder is 30-50 μm.
Preferably, the water-soluble resin is water-based acrylic resin, the lotion is styrene-acrylic emulsion, and the filler is
Microcrystalline cellulose.
Preferably, the dispersing agent is one of lauryl sodium sulfate, alkyl phenol；The defoaming agent is octadecane
Based isocyanate；The preservative is Kathon CG；The binder is inorganic binder.
The present invention also provides a kind of methods for preparing the inner wall decorative coating comprising following steps:
S1, modification negative ion powder by negative ion powder and surfactant co-dissolve in water, and are stirred evenly,
It is ultrasonically treated after 5-10min up to modified negative-ion powder；
S2, after collagen is dissolved in the water, solution ph is adjusted to 9-10, under conditions of stirring be added lotion,
Photocatalyst, modified negative-ion powder and water-soluble resin, are stirred together for 1-3h；
Dispersing agent, filler, conch meal, graphene, defoaming agent, preservative are added in S3, the mixture obtained to step S2
And binder, it stirs evenly to get inner wall decorative coating.
Preferably, supersonic frequency is 30-50Hz in the step S1, speed step S2, stirred in S3 is 600-
800r/min。
The above technical solution of the present invention has the following advantages over the prior art:
(1) inner wall decorative coating of the present invention, in parts by weight, the coating are composed of the following components: collagen egg
1-3 parts white, 50-75 parts of lotion, 1-3 parts of dispersing agent, 5-9 parts of photocatalyst, 10-20 parts of filler, 5-10 parts of negative ion powder, water solubility
4-8 parts of resin, 5-10 parts of conch meal, 0.5-2 parts of graphene, 3-5 parts of defoaming agent, 3-6 parts of preservative, 2-5 parts of binder, water
20-50 parts.The paint ingredient is nontoxic, and the coating film forming and compactness are high, water-tolerant, with substrate binding force
By force, conch meal has loose porous structure, and the moisture and room peculiar smell stored in adsorbable wall also have sterilization degerming
It acts on, negative ion powder has effects that also to contain photocatalyst to indoor release anion, and drop can be realized without special illumination
The effect of solving formaldehyde, is a kind of coating of health environment-friendly.
(2) preparation process of inner wall decorative coating of the present invention, step is simple, mild condition, is suitable for batch
Chemical industry production, and the negative ion powder dispersion stabilization after modification is good, can be uniformly distributed in metope, plays uniform release
The effect of anion.
Specific embodiment
In order to make the content of the present invention more clearly understood, below according to specific embodiments of the present invention to this hair
It is bright to be described in further detail.
Embodiment 1
The present embodiment provides a kind of inner wall decorative coatings, and in parts by weight, the interior wall coating is composed of the following components: glue
1 part of former albumen, 50 parts of styrene-acrylic emulsion, 1 part of alkyl phenol, 5 parts of photocatalyst, 10 parts of microcrystalline cellulose, 5 parts of negative ion powder, water solubility
4 parts of acrylic resin, 5 parts of conch meal, 0.5 part of graphene, 3 parts of octadecylisocyanate, 3 parts of Kathon CG, phosphate binders 2
Part, 20 parts of water.
Wherein, the partial size of the negative ion powder is 30 μm, in parts by weight, by 3 parts of cerium oxide, 6 parts of terbium oxide (seven oxygen
Change four terbiums) and 30 parts of tourmaline form and modified processing.
The photocatalyst in parts by weight, is made of 6 parts of silver nano-grains, 20 parts of praseodymium oxides and 50 parts of ZSM-5 molecular sieves,
The partial size of the silver nano-grain is 50nm.
The present embodiment also provides a kind of method for preparing above-mentioned inner wall decorative coating comprising following steps:
S1, modification negative ion powder, by negative ion powder (cerium oxide, terbium oxide and tourmaline powder) and surfactant ten
Six alkyl trimethyl ammonium bromides (CTAB) co-dissolve stirs evenly in water, the ultrasonic treatment 5min for being 30Hz with frequency
Afterwards up to modified negative ion powder.
S2, after collagen is dissolved in the water, solution ph is adjusted to 9 with sodium hydroxide, added under conditions of stirring
Enter lotion, photocatalyst, modified negative-ion powder and water-soluble resin, stirs 1h under the speed of 600r/min jointly.
Dispersing agent, filler, conch meal, graphene, defoaming agent, preservative are added in S3, the mixture obtained to step S2
And binder, it stirs evenly under the mixing speed of 600r/min to get inner wall decorative coating.
Embodiment 2
The present embodiment provides a kind of inner wall decorative coatings, and in parts by weight, the interior wall coating is composed of the following components: glue
3 parts of former albumen, 75 parts of styrene-acrylic emulsion, 3 parts of lauryl sodium sulfate, 9 parts of photocatalyst, 20 parts of microcrystalline cellulose, negative ion powder 10
Part, 8 parts of water soluble acrylic resin, 10 parts of conch meal, 2 parts of graphene, 5 parts of octadecylisocyanate, 6 parts of Kathon CG, boric acid
5 parts of salt binder, 50 parts of water.
Wherein, the partial size of the negative ion powder is 50 μm, in parts by weight, by 5 parts of cerium oxide, 8 parts of terbium oxide (seven oxygen
Change four terbiums) and 50 parts of tourmaline form and modified processing.
The photocatalyst in parts by weight, is made of 8 parts of silver nano-grains, 25 parts of praseodymium oxides and 65 parts of ZSM-5 molecular sieves,
The partial size of the silver nano-grain is 80nm.
The present embodiment also provides a kind of method for preparing above-mentioned inner wall decorative coating comprising following steps:
S1, modification negative ion powder, by negative ion powder (cerium oxide, terbium oxide and tourmaline powder) and surfactant ten
Six alkyl trimethyl ammonium bromides (CTAB) co-dissolve stirs evenly in water, the ultrasonic treatment 10min for being 50Hz with frequency
Afterwards up to modified negative ion powder.
S2, after collagen is dissolved in the water, solution ph is adjusted to 10 with sodium hydroxide, added under conditions of stirring
Enter lotion, photocatalyst, modified negative-ion powder and water-soluble resin, stirs 3h under the speed of 800r/min jointly.
Dispersing agent, filler, conch meal, graphene, defoaming agent, preservative are added in S3, the mixture obtained to step S2
And binder, it stirs evenly under the mixing speed of 800r/min to get inner wall decorative coating.
Embodiment 3
The present embodiment provides a kind of inner wall decorative coatings, and in parts by weight, the interior wall coating is composed of the following components: glue
2 parts of former albumen, 60 parts of styrene-acrylic emulsion, 2 parts of lauryl sodium sulfate, 6 parts of photocatalyst, 15 parts of microcrystalline cellulose, negative ion powder 8
Part, 6 parts of water soluble acrylic resin, 7 parts of conch meal, 1 part of graphene, 4 parts of octadecylisocyanate, 5 parts of Kathon CG, borate
3 parts of binder, 40 parts of water.
Wherein, the partial size of the negative ion powder is 40 μm, in parts by weight, by 4 parts of cerium oxide, 7 parts of terbium oxide (seven oxygen
Change four terbiums) and 40 parts of tourmaline form and modified processing.
The photocatalyst in parts by weight, is made of 7 parts of silver nano-grains, 23 parts of praseodymium oxides and 60 parts of ZSM-5 molecular sieves,
The partial size of the silver nano-grain is 60nm.
The present embodiment also provides a kind of method for preparing above-mentioned inner wall decorative coating comprising following steps:
S1, modification negative ion powder, by negative ion powder (cerium oxide, terbium oxide and tourmaline powder) and surfactant ten
Six alkyl trimethyl ammonium bromides (CTAB) co-dissolve stirs evenly in water, the ultrasonic treatment 8min for being 40Hz with frequency
Afterwards up to modified negative ion powder.
S2, after collagen is dissolved in the water, solution ph is adjusted to 10 with sodium hydroxide, added under conditions of stirring
Enter lotion, photocatalyst, modified negative-ion powder and water-soluble resin, stirs 2h under the speed of 700r/min jointly.
Dispersing agent, filler, conch meal, graphene, defoaming agent, preservative are added in S3, the mixture obtained to step S2
And binder, it stirs evenly under the mixing speed of 700r/min to get inner wall decorative coating.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or
It changes still within the protection scope of the invention.
Claims (9)
1. a kind of inner wall decorative coating, which is characterized in that in parts by weight, the coating is composed of the following components: collagen
1-3 parts, 50-75 parts of lotion, 1-3 parts of dispersing agent, 5-9 parts of photocatalyst, 10-20 parts of filler, 5-10 parts of negative ion powder, water-soluble tree
4-8 parts of rouge, 5-10 parts of conch meal, 0.5-2 parts of graphene, 3-5 parts of defoaming agent, 3-6 parts of preservative, 2-5 parts of binder, water 20-
50 parts.
2. inner wall decorative coating according to claim 1, which is characterized in that in parts by weight, the coating is by with the following group
It is grouped as: 2 parts of collagen, 60 parts of lotion, 2 parts of dispersing agent, 6 parts of photocatalyst, 15 parts of filler, 8 parts of negative ion powder, water-soluble tree
6 parts of rouge, 7 parts of conch meal, 1 part of graphene, 4 parts of defoaming agent, 5 parts of preservative, 3 parts of binder, 40 parts of water.
3. inner wall decorative coating according to claim 1 or 2, which is characterized in that the photocatalyst in parts by weight, by 6-
8 parts of silver nano-grains, 20-25 parts of praseodymium oxides and 50-65 parts of molecular sieve compositions.
4. inner wall decorative coating according to claim 3, which is characterized in that the negative ion powder in parts by weight, by 3-5
Part cerium oxide, 6-8 parts of terbium oxides and 30-50 parts of tourmaline compositions and modified processing.
5. inner wall decorative coating according to claim 4, which is characterized in that the partial size of the negative ion powder is 30-50 μm.
6. inner wall decorative coating according to claim 5, which is characterized in that the water-soluble resin is water soluble acrylic acid tree
Rouge, the lotion are styrene-acrylic emulsion, and the filler is microcrystalline cellulose.
7. inner wall decorative coating according to claim 6, which is characterized in that the dispersing agent be lauryl sodium sulfate,
One of alkyl phenol；The defoaming agent is octadecylisocyanate；The preservative is Kathon CG；The binder is inorganic
Binder.
8. a kind of prepare the method such as the described in any item inner wall decorative coatings of claim 1-7, which is characterized in that including as follows
Step:
S1, modification negative ion powder by negative ion powder and surfactant co-dissolve in water, and are stirred evenly, ultrasound
Up to modified negative-ion powder after processing 5-10min；
S2, after collagen is dissolved in the water, solution ph is adjusted to 9-10, lotion, light touching is added under conditions of stirring
Matchmaker, modified negative-ion powder and water-soluble resin, are stirred together for 1-3h；
Dispersing agent, filler, conch meal, graphene, defoaming agent, preservative are added in S3, the mixture obtained to step S2 and glues
Agent is tied, is stirred evenly to get inner wall decorative coating.
9. the preparation method of inner wall decorative coating according to claim 8, which is characterized in that supersonic frequency in the step S1
Rate is 30-50Hz, and speed step S2, stirred in S3 is 600-800r/min.
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Cited By (6)
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| CN110256907A (en) * | 2019-06-28 | 2019-09-20 | 合复新材料科技(无锡)有限公司 | It is a kind of with the long-acting spray coating liquor and preparation method thereof de-tasted except organic pernicious gas of anion emission function |
| CN110405910A (en) * | 2019-07-26 | 2019-11-05 | 西安红元节能材料有限公司 | A kind of preparation method of the energy-saving integrated wall of Far infrared health preservation health-care environmental-protecting |
| CN111621189A (en) * | 2020-07-05 | 2020-09-04 | 潍坊鼎盛化学工业有限公司 | Additive for water-based paint |
| CN112980268A (en) * | 2021-02-22 | 2021-06-18 | 陈冬芬 | Water-based paint coating with air purification function and preparation method thereof |
| CN113214715A (en) * | 2021-06-11 | 2021-08-06 | 江西省千色绘装饰有限公司 | Ecological artistic crystal coating and preparation method thereof |
| CN117429157A (en) * | 2023-10-18 | 2024-01-23 | 华川建设集团有限公司 | Environment-friendly paint decorative building wall and preparation method thereof |
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| CN107674515A (en) * | 2017-03-31 | 2018-02-09 | 滑黎明 | A kind of novel environment friendly function interior wall coating and preparation method thereof |
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| CN104046156A (en) * | 2014-06-30 | 2014-09-17 | 南通蛇类治疗研究所 | Nano multicolor interior wall environment-friendly paint |
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|---|---|---|---|---|
| CN110256907A (en) * | 2019-06-28 | 2019-09-20 | 合复新材料科技(无锡)有限公司 | It is a kind of with the long-acting spray coating liquor and preparation method thereof de-tasted except organic pernicious gas of anion emission function |
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| CN111621189A (en) * | 2020-07-05 | 2020-09-04 | 潍坊鼎盛化学工业有限公司 | Additive for water-based paint |
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Application publication date: 20190118 |