CN109207095A - A kind of corrugated paper high viscosity adhesive - Google Patents
A kind of corrugated paper high viscosity adhesive Download PDFInfo
- Publication number
- CN109207095A CN109207095A CN201810801587.4A CN201810801587A CN109207095A CN 109207095 A CN109207095 A CN 109207095A CN 201810801587 A CN201810801587 A CN 201810801587A CN 109207095 A CN109207095 A CN 109207095A
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- parts
- corrugated paper
- high viscosity
- viscosity adhesive
- sodium
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of corrugated paper high viscosity adhesives, are made of following substance: VAE resin emulsion, sodium hydroxide, glutinous rice flour, borax, antioxidant, defoaming agent, nitric acid rare earth salt, sodium pyrophosphate, fatty alcohol polyoxyethylene ether, sodium carboxymethylcellulose, diatomite, enhancing additive, deionized water.The present invention provides a kind of adhesives, have the characteristics that adhesion strength is high, it is good to stablize persistence, and hardly there is moisture absorption phenomenon, drying time is fast, fire resistance characteristic is strong, it is comprehensive to use good quality, it has been obviously prolonged the service life of corrugated paper and its product, the great market competitiveness and application value.
Description
Technical field
The invention belongs to corrugated paper working process technical fields, and in particular to a kind of corrugated paper high viscosity adhesive.
Background technique
Corrugated case is one of category common in present Packaging Box, with good impact resistance, workability
It can wait and be widely used.Corrugated case is made of corrugated paper, in the process of corrugated paper and corrugated case, needs to make
Adhesion process is carried out with adhesive, uses sodium silicate as adhesive in conventional method for many years, but its alkalinity is big, easily inhales
Tide, the whiting of the normal accumulation of salt in the surface soil causes paper product deformation, peels off, or even corrosion commodity, causes the rotten huge economic losses such as scrap.With skill
The continuous development of art is innovated, and mostly uses the adhesive of starch material at present, existing starch-based adhesive type is more, wherein Shen
Please number are as follows: 201310620219.7, a kind of corrugated case is disclosed with imitating adhesive again, with good rate of drying, viscous
The characteristics such as viscosity are tied, but are found in actual use, performance is not able to satisfy the corrugated case of higher quality, requirements at the higher level still
Production, still needs to further improve.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of corrugated paper high viscosity adhesive is provided.
The present invention is achieved by the following technical solutions:
A kind of corrugated paper high viscosity adhesive, is made of the substance of following parts by weight:
120 ~ 140 parts of VAE resin emulsions, 7 ~ 10 parts of sodium hydroxides, 40 ~ 45 parts of glutinous rice flours, 1 ~ 3 part of borax, 4 ~ 7 parts it is anti-oxidant
Agent, 2 ~ 4 parts of defoaming agents, 0.2 ~ 0.4 portion of nitric acid rare earth salt, 3 ~ 5 parts of sodium pyrophosphates, 3 ~ 6 parts of fatty alcohol polyoxyethylene ether, 4 ~ 7 parts
Sodium carboxymethylcellulose, 3 ~ 6 parts of diatomite, 4 ~ 7 parts of enhancing additives, 500 ~ 550 parts of deionized waters.
Preferably, it is made of the substance of following parts by weight:
130 parts of VAE resin emulsions, 9 parts of sodium hydroxides, 43 parts of glutinous rice flours, 2 parts of boraxs, 6 parts of antioxidants, 3 parts of defoaming agents, 0.3
Part nitric acid rare earth salt, 4 parts of sodium pyrophosphates, 5 parts of fatty alcohol polyoxyethylene ether, 6 parts of sodium carboxymethylcelluloses, 5 parts of diatomite, 6 parts
Enhance additive, 530 parts of deionized waters.
Further, the solid content in the VAE resin emulsion is 80 ~ 85%.
Further, the antioxidant is antioxidant 168, any one in antioxidant 1010.
Further, the defoaming agent is AC defoaming agent.
Further, the nitric acid rare earth salt is cerous nitrate, lanthanum nitrate, any one in ytterbium nitrate.
Further, the preparation method of the enhancing additive includes the following steps:
(1) corn fiber gum, water are carried out mixing according to weight ratio 1:6 ~ 8 to be put into reaction kettle, heating is kept in reaction kettle
Temperature be 79 ~ 83 DEG C, after high-speed stirred handles 30 ~ 35min, then the phosphoric acid solution of its gross mass 5% is added dropwise into reaction kettle,
After high-speed stirred handles 1 ~ 1.5h, taking-up, which is poured into ethyl alcohol, to be precipitated, and after then being rinsed one time with deionized water, is taken out using vacuum
It is spare that reactant A is obtained after filter, drying and processing；
(2) step (1) resulting reactant A is put into reaction kettle, be then added its gross mass 2600 ~ 2800% go from
Sub- water, 2 ~ 3% ammonium persulfate, 165 ~ 170% styrene, 185 ~ 190% Butyl Acrylate Monomer, 25 ~ 29% chitosan,
7 ~ 10% nano silica, 11 ~ 15% silane coupling agent, 3 ~ 5% sodium pyrophosphate, 3 ~ 5% disodium ethylene diamine tetraacetate,
After being ultrasonically treated 2 ~ 4h, taking-up, which is poured into ethyl alcohol, to be precipitated, and after then being rinsed one time with deionized water, using vacuum filtration, is dried
After dry-cure to obtain the final product.
Further, the mass fraction of phosphoric acid solution as described in step (1) is 22 ~ 26%.
Further, silane coupling agent described in step (2) be silane coupling agent kh550, silane coupling agent kh560,
Any one in silane coupling agent kh570.
Further, the frequency of ultrasonic wave is 520 ~ 550kHz when ultrasonic treatment described in step (2).
Present invention improves the raw material components of adhesive, effectively improve its synthesis and use quality.Wherein with VAE resin
Lotion and glutinous rice flour compounding ensure that whole bonding, sprawl, the characteristics such as heatproof, the nitre of addition as the bulk composition bonded
Acid rare earth salt can be catalyzed the activity for enhancing each ingredient, promote mutual binding ability, in order to further enhance entirety
Quality, and be added to a kind of special enhancing additive component, be with reactant A styrene, Butyl Acrylate Monomer,
The ingredients such as chitosan, nano silica, silane coupling agent carry out compound, a kind of manufactured chitosan, nano silica etc.
Cooperate filling-modified hydrolysed corn viscose graft phenylethene/butyl acrylate copolymer, this copolymer has good table
Compatibility between face reactivity, with corrugated paper wood fibre is good, and can be good at promoted adhesive entirety consistency with
Adhering capacity improves the bond strength between each material composition, and then improves adhesive for the bond effect of corrugated paper.
The present invention has the advantage that compared with prior art
The present invention provides a kind of adhesive, have the characteristics that adhesion strength is high, it is good to stablize persistence, and hardly inhale
Damp phenomenon, drying time is fast, fire resistance characteristic is strong, comprehensive to use good quality, hence it is evident that extend corrugated paper and its product uses the longevity
Life, the great market competitiveness and application value.
Specific embodiment
Embodiment 1
A kind of corrugated paper high viscosity adhesive, is made of the substance of following parts by weight:
120 parts of VAE resin emulsions, 7 parts of sodium hydroxides, 40 parts of glutinous rice flours, 1 part of borax, 4 parts of antioxidants, 2 parts of defoaming agents, 0.2
Part nitric acid rare earth salt, 3 parts of sodium pyrophosphates, 3 parts of fatty alcohol polyoxyethylene ether, 4 parts of sodium carboxymethylcelluloses, 3 parts of diatomite, 4 parts
Enhance additive, 500 parts of deionized waters.
Further, the solid content in the VAE resin emulsion is 80%.
Further, the antioxidant is antioxidant 168.
Further, the defoaming agent is AC defoaming agent.
Further, the nitric acid rare earth salt is cerous nitrate.
Further, the preparation method of the enhancing additive includes the following steps:
(1) corn fiber gum, water are carried out mixing according to weight ratio 1:6 to be put into reaction kettle, heating is kept in reaction kettle
Temperature is 79 DEG C, after high-speed stirred handles 30min, then the phosphoric acid solution of its gross mass 5%, high-speed stirred is added dropwise into reaction kettle
After handling 1h, taking-up, which is poured into ethyl alcohol, to be precipitated, after then being rinsed one time with deionized water, using vacuum filtration, drying and processing
It is spare that reactant A is obtained afterwards；
(2) step (1) resulting reactant A is put into reaction kettle, be then added its gross mass 2600% deionized water,
2% ammonium persulfate, 165% styrene, 185% Butyl Acrylate Monomer, 25% chitosan, 7% nano silica,
11% silane coupling agent, 3% sodium pyrophosphate, 3% disodium ethylene diamine tetraacetate, after being ultrasonically treated 2h, taking-up is poured into ethyl alcohol
Precipitating, after then being rinsed one time with deionized water, using vacuum filtration, after drying and processing to obtain the final product.
Further, the mass fraction of phosphoric acid solution as described in step (1) is 22%.
Further, silane coupling agent described in step (2) is silane coupling agent kh550.
Further, the frequency of ultrasonic wave is 520kHz when ultrasonic treatment described in step (2).
Embodiment 2
A kind of corrugated paper high viscosity adhesive, is made of the substance of following parts by weight:
130 parts of VAE resin emulsions, 9 parts of sodium hydroxides, 43 parts of glutinous rice flours, 2 parts of boraxs, 6 parts of antioxidants, 3 parts of defoaming agents, 0.3
Part nitric acid rare earth salt, 4 parts of sodium pyrophosphates, 5 parts of fatty alcohol polyoxyethylene ether, 6 parts of sodium carboxymethylcelluloses, 5 parts of diatomite, 6 parts
Enhance additive, 530 parts of deionized waters.
Further, the solid content in the VAE resin emulsion is 83%.
Further, the antioxidant is antioxidant 168.
Further, the defoaming agent is AC defoaming agent.
Further, the nitric acid rare earth salt is lanthanum nitrate.
Further, the preparation method of the enhancing additive includes the following steps:
(1) corn fiber gum, water are carried out mixing according to weight ratio 1:7 to be put into reaction kettle, heating is kept in reaction kettle
Temperature is 81 DEG C, after high-speed stirred handles 33min, then the phosphoric acid solution of its gross mass 5%, high-speed stirred is added dropwise into reaction kettle
After handling 1.3h, taking-up, which is poured into ethyl alcohol, to be precipitated, after then being rinsed one time with deionized water, at vacuum filtration, drying
It is spare that reactant A is obtained after reason；
(2) step (1) resulting reactant A is put into reaction kettle, be then added its gross mass 2700% deionized water,
2.5% ammonium persulfate, 168% styrene, 187% Butyl Acrylate Monomer, 28% chitosan, 9% nanometer titanium dioxide
Silicon, 14% silane coupling agent, 4% sodium pyrophosphate, 4% disodium ethylene diamine tetraacetate, be ultrasonically treated 3h after, taking-up pour into second
Precipitated in alcohol, after then being rinsed one time with deionized water, using vacuum filtration, after drying and processing to obtain the final product.
Further, the mass fraction of phosphoric acid solution as described in step (1) is 24%.
Further, silane coupling agent described in step (2) is silane coupling agent kh560.
Further, the frequency of ultrasonic wave is 540kHz when ultrasonic treatment described in step (2).
Embodiment 3
A kind of corrugated paper high viscosity adhesive, is made of the substance of following parts by weight:
140 parts of VAE resin emulsions, 10 parts of sodium hydroxides, 45 parts of glutinous rice flours, 3 parts of boraxs, 7 parts of antioxidants, 4 parts of defoaming agents,
0.4 portion of nitric acid rare earth salt, 5 parts of sodium pyrophosphates, 6 parts of fatty alcohol polyoxyethylene ether, 7 parts of sodium carboxymethylcelluloses, 6 parts of diatomite, 7
Part enhancing additive, 550 parts of deionized waters.
Further, the solid content in the VAE resin emulsion is 85%.
Further, the antioxidant is antioxidant 1010.
Further, the defoaming agent is AC defoaming agent.
Further, the nitric acid rare earth salt is ytterbium nitrate.
Further, the preparation method of the enhancing additive includes the following steps:
(1) corn fiber gum, water are carried out mixing according to weight ratio 1:8 to be put into reaction kettle, heating is kept in reaction kettle
Temperature is 83 DEG C, after high-speed stirred handles 35min, then the phosphoric acid solution of its gross mass 5%, high-speed stirred is added dropwise into reaction kettle
After handling 1.5h, taking-up, which is poured into ethyl alcohol, to be precipitated, after then being rinsed one time with deionized water, at vacuum filtration, drying
It is spare that reactant A is obtained after reason；
(2) step (1) resulting reactant A is put into reaction kettle, be then added its gross mass 2800% deionized water,
3% ammonium persulfate, 170% styrene, 190% Butyl Acrylate Monomer, 29% chitosan, 10% nano silica,
15% silane coupling agent, 5% sodium pyrophosphate, 5% disodium ethylene diamine tetraacetate, after being ultrasonically treated 4h, taking-up is poured into ethyl alcohol
Precipitating, after then being rinsed one time with deionized water, using vacuum filtration, after drying and processing to obtain the final product.
Further, the mass fraction of phosphoric acid solution as described in step (1) is 26%.
Further, silane coupling agent described in step (2) is silane coupling agent kh570.
Further, the frequency of ultrasonic wave is 550kHz when ultrasonic treatment described in step (2).
Comparative example 1
This comparative example 1 compared with Example 2, in the preparation process of enhancing additive, eliminates the processing of step (1),
Method and step in addition to this is all the same.
Comparative example 2
This comparative example 2 compared with Example 2, eliminates enhancing additive component, and method and step in addition to this is all the same.
Control group
Application No. is: 201310620219.7, a kind of disclosed corrugated case with imitating adhesive again.
It is corresponding to above-described embodiment 2, comparative example 1, comparative example 2, control group in order to compare effect of the present invention
Adhesive is tested for the property, and specific correlation data is as shown in table 1 below:
Table 1
Note: adhesive strength described in upper table 1 carries out test experiments referring to GB/T 6548-1998.
The adhesive strength of the corresponding adhesive of the present invention has been significantly improved it can be seen from upper table 1, protects well
Stability and the service life of product, the great market competitiveness and application value are demonstrate,proved.
Claims (10)
1. a kind of corrugated paper high viscosity adhesive, which is characterized in that be made of the substance of following parts by weight:
120 ~ 140 parts of VAE resin emulsions, 7 ~ 10 parts of sodium hydroxides, 40 ~ 45 parts of glutinous rice flours, 1 ~ 3 part of borax, 4 ~ 7 parts it is anti-oxidant
Agent, 2 ~ 4 parts of defoaming agents, 0.2 ~ 0.4 portion of nitric acid rare earth salt, 3 ~ 5 parts of sodium pyrophosphates, 3 ~ 6 parts of fatty alcohol polyoxyethylene ether, 4 ~ 7 parts
Sodium carboxymethylcellulose, 3 ~ 6 parts of diatomite, 4 ~ 7 parts of enhancing additives, 500 ~ 550 parts of deionized waters.
2. a kind of corrugated paper high viscosity adhesive according to claim 1, which is characterized in that by the object of following parts by weight
Matter is made:
130 parts of VAE resin emulsions, 9 parts of sodium hydroxides, 43 parts of glutinous rice flours, 2 parts of boraxs, 6 parts of antioxidants, 3 parts of defoaming agents, 0.3
Part nitric acid rare earth salt, 4 parts of sodium pyrophosphates, 5 parts of fatty alcohol polyoxyethylene ether, 6 parts of sodium carboxymethylcelluloses, 5 parts of diatomite, 6 parts
Enhance additive, 530 parts of deionized waters.
3. a kind of corrugated paper high viscosity adhesive according to claim 1 or 2, which is characterized in that the VAE resin
Solid content in lotion is 80 ~ 85%.
4. a kind of corrugated paper high viscosity adhesive according to claim 1 or 2, which is characterized in that described is anti-oxidant
Agent is antioxidant 168, any one in antioxidant 1010.
5. a kind of corrugated paper high viscosity adhesive according to claim 1 or 2, which is characterized in that the defoaming agent
For AC defoaming agent.
6. a kind of corrugated paper high viscosity adhesive according to claim 1 or 2, which is characterized in that the nitric acid is dilute
Earth salt is cerous nitrate, lanthanum nitrate, any one in ytterbium nitrate.
7. a kind of corrugated paper high viscosity adhesive according to claim 1 or 2, which is characterized in that the enhancing adds
The preparation method of agent is added to include the following steps:
(1) corn fiber gum, water are carried out mixing according to weight ratio 1:6 ~ 8 to be put into reaction kettle, heating is kept in reaction kettle
Temperature be 79 ~ 83 DEG C, after high-speed stirred handles 30 ~ 35min, then the phosphoric acid solution of its gross mass 5% is added dropwise into reaction kettle,
After high-speed stirred handles 1 ~ 1.5h, taking-up, which is poured into ethyl alcohol, to be precipitated, and after then being rinsed one time with deionized water, is taken out using vacuum
It is spare that reactant A is obtained after filter, drying and processing；
(2) step (1) resulting reactant A is put into reaction kettle, be then added its gross mass 2600 ~ 2800% go from
Sub- water, 2 ~ 3% ammonium persulfate, 165 ~ 170% styrene, 185 ~ 190% Butyl Acrylate Monomer, 25 ~ 29% chitosan,
7 ~ 10% nano silica, 11 ~ 15% silane coupling agent, 3 ~ 5% sodium pyrophosphate, 3 ~ 5% disodium ethylene diamine tetraacetate,
After being ultrasonically treated 2 ~ 4h, taking-up, which is poured into ethyl alcohol, to be precipitated, and after then being rinsed one time with deionized water, using vacuum filtration, is dried
After dry-cure to obtain the final product.
8. a kind of corrugated paper high viscosity adhesive according to claim 7, which is characterized in that as described in step (1)
The mass fraction of phosphoric acid solution is 22 ~ 26%.
9. a kind of corrugated paper high viscosity adhesive according to claim 7, which is characterized in that described in step (2)
Silane coupling agent is silane coupling agent kh550, silane coupling agent kh560, any one in silane coupling agent kh570.
10. a kind of corrugated paper high viscosity adhesive according to claim 7, which is characterized in that described in step (2)
The frequency of ultrasonic wave is 520 ~ 550kHz when ultrasonic treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810801587.4A CN109207095A (en) | 2018-07-20 | 2018-07-20 | A kind of corrugated paper high viscosity adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810801587.4A CN109207095A (en) | 2018-07-20 | 2018-07-20 | A kind of corrugated paper high viscosity adhesive |
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| Publication Number | Publication Date |
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| CN109207095A true CN109207095A (en) | 2019-01-15 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810801587.4A Pending CN109207095A (en) | 2018-07-20 | 2018-07-20 | A kind of corrugated paper high viscosity adhesive |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113755117A (en) * | 2021-07-28 | 2021-12-07 | 厦门稀土材料研究所 | Rare earth modified starch-based quick-drying adhesive |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58162680A (en) * | 1982-03-23 | 1983-09-27 | Koyo Sangyo Kk | Adhesive composition |
| CN103360988A (en) * | 2013-07-05 | 2013-10-23 | 全椒海丰印刷包装有限公司 | Carton environment-friendly formaldehyde-free adhesive and preparation method thereof |
| CN106147649A (en) * | 2016-06-28 | 2016-11-23 | 广东宝雅纸业有限公司 | A kind of corrugated board low temperature adhesion glue and application thereof |
| CN106753032A (en) * | 2016-11-29 | 2017-05-31 | 广西大学 | A kind of corrugated case adhesive of bonding strength high and preparation method thereof |
-
2018
- 2018-07-20 CN CN201810801587.4A patent/CN109207095A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58162680A (en) * | 1982-03-23 | 1983-09-27 | Koyo Sangyo Kk | Adhesive composition |
| CN103360988A (en) * | 2013-07-05 | 2013-10-23 | 全椒海丰印刷包装有限公司 | Carton environment-friendly formaldehyde-free adhesive and preparation method thereof |
| CN106147649A (en) * | 2016-06-28 | 2016-11-23 | 广东宝雅纸业有限公司 | A kind of corrugated board low temperature adhesion glue and application thereof |
| CN106753032A (en) * | 2016-11-29 | 2017-05-31 | 广西大学 | A kind of corrugated case adhesive of bonding strength high and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113755117A (en) * | 2021-07-28 | 2021-12-07 | 厦门稀土材料研究所 | Rare earth modified starch-based quick-drying adhesive |
| CN113755117B (en) * | 2021-07-28 | 2023-08-29 | 厦门稀土材料研究所 | Rare earth modified starch-based quick-drying adhesive |
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