CN106753032A - A kind of corrugated case adhesive of bonding strength high and preparation method thereof - Google Patents
A kind of corrugated case adhesive of bonding strength high and preparation method thereof Download PDFInfo
- Publication number
- CN106753032A CN106753032A CN201611073661.2A CN201611073661A CN106753032A CN 106753032 A CN106753032 A CN 106753032A CN 201611073661 A CN201611073661 A CN 201611073661A CN 106753032 A CN106753032 A CN 106753032A
- Authority
- CN
- China
- Prior art keywords
- parts
- corrugated case
- container
- bonding strength
- strength high
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of corrugated case adhesive of bonding strength high, it is made up of the following raw material of mass parts：80~100 parts of cornstarch, 1~10 part of acrylic resin, 5~10 parts of ethylene vinyl acetate resin, 0.01~0.05 part of Lauxite, 0.1~0.5 part of borax, 0.1~1 part of tributyl phosphate, 1~5 part of polyethylene glycol, 1~2 part of NaOH, 0.1~1 part of oxidant, 0.1~1 part of water quality stabilization agent, 0.1~1 part of oxidation catalyst, 100~200 parts of water.Be combined and cornstarch reaction for Lauxite, ethylene vinyl acetate resin, acrylic resin, polyvinyl alcohol by the present invention, being made adhesive has bonding strength high, there is high permeance property, stability, water resistance, increasing tougheness, adhesive glue face stability simultaneously, and improve the anti-impact force and hardness of corrugated case.
Description
Technical field
The present invention relates to technical field of adhesive, and in particular to a kind of corrugated case adhesive of bonding strength high and its
Preparation method.
Background technology
In the production practices of corrugated case, the bonding between various paper is a key link in production, each layer
Whether close and firm has a strong impact on the quality of corrugated board between paper industry, in the waster that corrugated paper board production line is produced, because
Adhesion problem causes to be in the great majority, and major surfaces are that corrugated board the phenomenons such as foaming, degumming, false grain occurs.Typically, bond properties
Good corrugated board surface is smooth, non-foaming, corrugationless, non-warpage, and separation, outer will not be produced between the corrugated paper after bonding
See and endure with all one's will, with preferable resistance to compression and anti-shock-absorbing capacity.
The content of the invention
It is an object of the present invention in view of the shortcomings of the prior art, there is provided a kind of corrugated case of bonding strength high is used
Adhesive and preparation method thereof.
To achieve the above object, the present invention takes following technical scheme：
A kind of corrugated case adhesive of bonding strength high is made up of the following raw material of mass parts：80~100 parts of cornstarch,
1~10 part of acrylic resin, 5~10 parts of ethylene-vinyl acetate resin, 0.01~0.05 part of Lauxite, borax 0.1~
0.5 part, 0.1~1 part of tributyl phosphate, 1~5 part of polyethylene glycol, 1~2 part of NaOH, 0.1~1 part of oxidant, water quality peace
Determine 0.1~1 part of agent, 0.1~1 part of oxidation catalyst, 100~200 parts of water.
Wherein, described oxidant is preferably one kind of potassium permanganate, hydrogen peroxide, sodium hypochlorite.
Wherein, described oxidation catalyst is one or more of ferrous sulfate, nickel sulfate.
Further, a kind of preparation method of the corrugated case adhesive of bonding strength high is comprised the following steps：
(1) prepare in container and add water and be heated up to 35~40 DEG C, place into the NaOH stirring of a quarter；
(2) prepare in container and be put into cornstarch, acrylic resin, ethylene-vinyl acetate resin, Lauxite and stir；
(3) poured into after remaining NaOH is diluted and prepare container；
(4) viscosity of liquid is reached during up to 29s ± 1s in container to be prepared, is put into water quality stabilization agent and is stirred；
(5) be put into container borax and stir 10min to preparing；
(6) be put into container polyvinyl alcohol, tributyl phosphate, oxidant, oxidation catalyst and at interval of 20~30min to preparing
Stirring 5min, stirring obtains final product a kind of corrugated case adhesive of bonding strength high of the invention for 4~6 times.
In the present invention, NaOH is paste agent, tributyl phosphate is defoamer, Lauxite is dry catalyst, urea
Urea formaldehyde chemically reacts with the oxygen in air, accelerates adhesive agent flocculation crystallization, shortens carton drying time, improves cardboard
Intensity, while Lauxite can crosslink reaction with the hydroxyl in starch forms condensation polymer, the aldehyde radical with oxidized starch reacts
Generation hemiacetal or ethylidene ether structure, while Lauxite can increase the stability of adhesive with polyvinyl alcohol, viscosity is high, and cardboard is hard
Spend.
In the present invention, ethylene-vinyl acetate resin produces reaction with starch hydroxyl in starch gelatinization, increases adhesive
Viscosity, adhesion, increase paper bonding after pliability and impact resistance, while formed adhesive layer there is good waterproof
Effect.
In the present invention, acrylic resin forms copolymer with starch and other resins, can penetrate into the minimum stock of paperboard surface
Very or in hole, the bonding glue surface stabilization of formation, so as to improve the adhesion strength of adhesive, acrylic resin improves this
The adhesive storage stability and permeability of invention.
The beneficial effects of the invention are as follows：The present invention is by Lauxite, ethylene-vinyl acetate resin, acrylic resin, poly-
Vinyl alcohol is compound to react with cornstarch, and being made adhesive has fabulous cohesive, permeance property, stability, water resistance, increasing
Toughness, adhesive glue face stability, and improve the anti-impact force and hardness of corrugated case.
Specific embodiment
With reference to specific embodiment, to further instruction of the present invention.
Embodiment 1
A kind of corrugated case adhesive of bonding strength high is made up of the following raw material of mass parts：100 parts of cornstarch,
1 part of acrylic resin, 10 parts of ethylene-vinyl acetate resin, 0.01 part of Lauxite, 0.5 part of borax, tributyl phosphate 0.1
Part, 5 parts of polyethylene glycol, 1 part of NaOH, 1 part of oxidant, 0.1 part of water quality stabilization agent, 1 part of oxidation catalyst, 100 parts of water；Its
In, oxidant is potassium permanganate, and oxidation catalyst is ferrous sulfate and nickel sulfate.
Its preparation method preparation method is comprised the following steps：
(1) prepare in container and add water and be heated up to 40 DEG C, place into the NaOH stirring of a quarter；
(2) prepare in container and be put into cornstarch, acrylic resin, ethylene-vinyl acetate resin, Lauxite and stir；
(3) poured into after remaining NaOH is diluted and prepare container；
(4) viscosity of liquid is reached during up to 30ss in container to be prepared, is put into water quality stabilization agent and is stirred；
(5) be put into container borax and stir 10min to preparing；
(6) to prepare be put into container polyvinyl alcohol, tributyl phosphate, oxidant, oxidation catalyst and at interval of 30min stir
5min, stirring obtains final product a kind of corrugated case adhesive of bonding strength high of the invention for 6 times.
Embodiment 2
A kind of corrugated case adhesive of bonding strength high is made up of the following raw material of mass parts：80 parts of cornstarch,
10 parts of acrylic resin, 5 parts of ethylene-vinyl acetate resin, 0.05 part of Lauxite, 0.1 part of borax, 1 part of tributyl phosphate,
1 part of polyethylene glycol, 2 parts of NaOH, 0.1 part of oxidant, 1 part of water quality stabilization agent, 0.1 part of oxidation catalyst, 200 parts of water；Its
In, oxidant is hydrogen peroxide, and oxidation catalyst is ferrous sulfate.
Its preparation method preparation method is comprised the following steps：
(1) prepare in container and add water and be heated up to 35 DEG C, place into the NaOH stirring of a quarter；
(2) prepare in container and be put into cornstarch, acrylic resin, ethylene-vinyl acetate resin, Lauxite and stir；
(3) poured into after remaining NaOH is diluted and prepare container；
(4) viscosity of liquid is reached during up to 28s in container to be prepared, is put into water quality stabilization agent and is stirred；
(5) be put into container borax and stir 10min to preparing；
(6) to prepare be put into container polyvinyl alcohol, tributyl phosphate, oxidant, oxidation catalyst and at interval of 30min stir
5min, stirring obtains final product a kind of corrugated case adhesive of bonding strength high of the invention for 6 times.
Embodiment 3
A kind of corrugated case adhesive of bonding strength high is made up of the following raw material of mass parts：90 parts of cornstarch,
5 parts of acrylic resin, 6 parts of ethylene-vinyl acetate resin, 0.04 part of Lauxite, 0.2 part of borax, tributyl phosphate 0.5
Part, 4 parts of polyethylene glycol, 1 part of NaOH, 0.5 part of oxidant, 0.5 part of water quality stabilization agent, 0.5 part of oxidation catalyst, water 180
Part；Wherein, oxidant is sodium hypochlorite, and oxidation catalyst is nickel sulfate.
Its preparation method preparation method is with embodiment 1.
Embodiment 4
A kind of corrugated case adhesive of bonding strength high is made up of the following raw material of mass parts：95 parts of cornstarch,
8 parts of acrylic resin, 9 parts of ethylene-vinyl acetate resin, 0.04 part of Lauxite, 0.2 part of borax, 1 part of tributyl phosphate,
5 parts of polyethylene glycol, 2 parts of NaOH, 0.9 part of oxidant, 0.4 part of water quality stabilization agent, 0.8 part of oxidation catalyst, 140 parts of water；
Wherein, oxidant is sodium hypochlorite, and oxidation catalyst is ferrous sulfate.
Its preparation method preparation method is with embodiment 1.
Claims (4)
1. a kind of corrugated case adhesive of bonding strength high, it is characterised in that it is made up of the following raw material of mass parts：It is beautiful
80~100 parts of rice starch, 1~10 part of acrylic resin, 5~10 parts of ethylene-vinyl acetate resin, Lauxite 0.01~
0.05 part, 0.1~0.5 part of borax, 0.1~1 part of tributyl phosphate, 1~5 part of polyethylene glycol, 1~2 part of NaOH, oxidant
0.1~1 part, 0.1~1 part of water quality stabilization agent, 0.1~1 part of oxidation catalyst, 100~200 parts of water.
2. a kind of corrugated case adhesive of bonding strength high according to claim 1, it is characterised in that described oxygen
Agent is potassium permanganate, hydrogen peroxide, one kind of sodium hypochlorite.
3. a kind of corrugated case adhesive of bonding strength high according to claim 1, it is characterised in that described oxygen
Change catalyst is one or more of ferrous sulfate, nickel sulfate.
4. the preparation method of the corrugated case adhesive according to any described bonding strengths a kind of high of claim 1-3, its
It is characterised by, comprises the following steps：
(1) prepare in container and add water and be heated up to 35~40 DEG C, place into the NaOH stirring of a quarter；
(2) prepare in container and be put into cornstarch, acrylic resin, ethylene-vinyl acetate resin, Lauxite and stir；
(3) poured into after remaining NaOH is diluted and prepare container；
(4) viscosity of liquid is reached during up to 29s ± 1s in container to be prepared, is put into water quality stabilization agent and is stirred；
(5) be put into container borax and stir 10min to preparing；
(6) be put into container polyvinyl alcohol, tributyl phosphate, oxidant, oxidation catalyst and at interval of 20~30min to preparing
Stirring 5min, stirring obtains final product a kind of corrugated case adhesive of bonding strength high of the invention for 4~6 times.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611073661.2A CN106753032A (en) | 2016-11-29 | 2016-11-29 | A kind of corrugated case adhesive of bonding strength high and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611073661.2A CN106753032A (en) | 2016-11-29 | 2016-11-29 | A kind of corrugated case adhesive of bonding strength high and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106753032A true CN106753032A (en) | 2017-05-31 |
Family
ID=58898444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611073661.2A Pending CN106753032A (en) | 2016-11-29 | 2016-11-29 | A kind of corrugated case adhesive of bonding strength high and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106753032A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107663429A (en) * | 2017-11-04 | 2018-02-06 | 舒城宏峰纸板有限公司 | A kind of corrugated board bonding glue |
| CN109207095A (en) * | 2018-07-20 | 2019-01-15 | 蚌埠市奥特纸箱机械有限公司 | A kind of corrugated paper high viscosity adhesive |
| CN109456717A (en) * | 2018-09-29 | 2019-03-12 | 漳州市天辰纸品包装有限公司 | A kind of environment-protecting and non-poisonous food packaging corrugated board |
| CN109575853A (en) * | 2019-01-12 | 2019-04-05 | 宣城华艺包装科技有限公司 | A kind of carton environment-friendly type composite adhesive |
| CN113247442A (en) * | 2021-06-29 | 2021-08-13 | 上海丹麒包装材料有限公司 | Color box processing and producing method |
| CN116836648A (en) * | 2023-07-28 | 2023-10-03 | 威海先优包装科技有限公司 | Adhesive for manufacturing corrugated paper boxes and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349051A (en) * | 2015-10-28 | 2016-02-24 | 阜阳市豪杰工贸有限公司 | Carton adhesive with good waterproof effect |
| CN106147649A (en) * | 2016-06-28 | 2016-11-23 | 广东宝雅纸业有限公司 | A kind of corrugated board low temperature adhesion glue and application thereof |
-
2016
- 2016-11-29 CN CN201611073661.2A patent/CN106753032A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349051A (en) * | 2015-10-28 | 2016-02-24 | 阜阳市豪杰工贸有限公司 | Carton adhesive with good waterproof effect |
| CN106147649A (en) * | 2016-06-28 | 2016-11-23 | 广东宝雅纸业有限公司 | A kind of corrugated board low temperature adhesion glue and application thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107663429A (en) * | 2017-11-04 | 2018-02-06 | 舒城宏峰纸板有限公司 | A kind of corrugated board bonding glue |
| CN109207095A (en) * | 2018-07-20 | 2019-01-15 | 蚌埠市奥特纸箱机械有限公司 | A kind of corrugated paper high viscosity adhesive |
| CN109456717A (en) * | 2018-09-29 | 2019-03-12 | 漳州市天辰纸品包装有限公司 | A kind of environment-protecting and non-poisonous food packaging corrugated board |
| CN109575853A (en) * | 2019-01-12 | 2019-04-05 | 宣城华艺包装科技有限公司 | A kind of carton environment-friendly type composite adhesive |
| CN113247442A (en) * | 2021-06-29 | 2021-08-13 | 上海丹麒包装材料有限公司 | Color box processing and producing method |
| CN116836648A (en) * | 2023-07-28 | 2023-10-03 | 威海先优包装科技有限公司 | Adhesive for manufacturing corrugated paper boxes and preparation method thereof |
| CN116836648B (en) * | 2023-07-28 | 2023-12-19 | 威海先优包装科技有限公司 | Adhesive for manufacturing corrugated paper boxes and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106753032A (en) | A kind of corrugated case adhesive of bonding strength high and preparation method thereof | |
| CN101892023B (en) | Aldehyde-free adhesive and preparation method thereof | |
| CN101760149B (en) | Environmental-friendly amylopectin composite adhesive for paper products and production method thereof | |
| CN105542683A (en) | Environment-friendly high-strength water-resisting and mildew-resisting adhesive for plywood and preparation method of environment-friendly high-strength water-resisting and mildew-resisting adhesive | |
| JP5164483B2 (en) | Eco-friendly cardboard adhesive | |
| CN106915123B (en) | A kind of energy-saving and environment-friendly corrugated board production technique | |
| CN101892022A (en) | Starch adhesive for producing corrugated board and preparation method thereof | |
| CN104845550A (en) | Adhesion agent, preparation method thereof and corrugated board | |
| JP7407876B2 (en) | Melt processed materials with high cellulose fiber content | |
| CN111559121B (en) | Production method of corrugated case | |
| CA1327659C (en) | Aldehyde starch saturant laminating adhesive | |
| US20100024977A1 (en) | Method for Applying Polymeric Adhesive as Adhesive Agent to Bond Wood or Garnish | |
| CN101323764A (en) | High-strength quick-drying energy-saving environment-protective cardboard box glue | |
| CN105602472A (en) | Damp-proofing displacement-proofing corrugated carton | |
| CN107586461A (en) | A kind of preparation method of formaldehydeless flame retardant type fiberboard | |
| US4374217A (en) | Cold-setting starch adhesive | |
| CN106753035A (en) | A kind of starch base corrugation adhesive for paper and preparation method thereof | |
| CN106010371A (en) | High-strength and waterproof wood adhesive and preparation method thereof | |
| JP6735600B2 (en) | Adhesive for corrugated board | |
| US3909469A (en) | Polyethylenimine adhesive | |
| CN111349409A (en) | Preparation process of corrugated board starch adhesive | |
| CN104119816A (en) | Preparation method for high-strength water-resistant starch adhesive for corrugated paperboards | |
| CN106634688B (en) | A kind of thermosetting property oxidation modification Cassava starch adhesive and preparation method thereof | |
| CN110079243A (en) | A kind of energy-saving and environment-friendly packed in cases fast-drying type rubber powder and preparation method | |
| CN107805484A (en) | A kind of preparation method of wood materials starch adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170531 |
|
| WD01 | Invention patent application deemed withdrawn after publication |