CN109207047A - 一种pvc表面装饰专用超亚肤感耐磨水性涂料及其制备方法 - Google Patents
一种pvc表面装饰专用超亚肤感耐磨水性涂料及其制备方法 Download PDFInfo
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- CN109207047A CN109207047A CN201811359019.XA CN201811359019A CN109207047A CN 109207047 A CN109207047 A CN 109207047A CN 201811359019 A CN201811359019 A CN 201811359019A CN 109207047 A CN109207047 A CN 109207047A
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Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
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Abstract
本发明公开了一种PVC表面装饰专用超亚肤感耐磨水性涂料及其制备方法。该涂料包含超亚光水性聚氨酯乳液、聚碳酸酯型水性聚氨酯乳液、水性抗污剂、水性固化剂、水性绒感剂、水性润湿剂、水性消泡剂、水性流平剂等。本发明的涂料采用超亚光水性聚氨酯乳液作为双组分连接料之一，形成的涂层具有极低的光泽度，无需另外添加消光剂。本发明的涂料采用胺基水性树脂交联剂作为固化剂，在常温条件下印刷，涂层可达到很好的附着牢度和耐水、抗粘连性，硬度≥2H、光泽度≤2度，具有超亚光的视觉效果，触摸绒感亲肤，且增加了耐磨、耐酒精、抗污等特性。
Description
技术领域
本发明涉及一种水性涂料，具体涉及一种PVC表面装饰专用超亚肤感耐磨水性涂料。
背景技术
随着人民生活水平的提高，大量商品住房、酒店及展览馆的涌现，人们对室内装饰材料的要求不断提高。PVC表面装饰包覆的家具由于具有良好的装饰效果，得到了广泛的应用。
PVC表面装饰包覆的家具的表面涂层主要起着抗污耐摩擦的作用，传统的PVC表面涂层以有机溶剂作为分散介质，溶剂的挥发不仅造成大气污染破坏生态平衡，且印品干燥后仍会残留部分甲醛等有机溶剂，长期接触就会对人体造成危害，甚至引起慢性中毒。
水性涂层是以水代替传统涂层中的有机溶剂作为分散介质的高分子材料，具有无毒无污染、不燃不爆和成本低等优点。但市场上的水性PVC表面涂层在应用上也存在一系列问题，如附着力较低，抗污耐磨性能较差，功能单一，装饰能力较弱。因此，本发明提供一种PVC表面装饰专用的水性涂层，在健康、环保的基础上，提高其使用性能，如抗污、耐水、耐摩擦等，并提高其表面装饰性及舒适性。
发明内容
本发明的主要目的，在于提供一种PVC表面装饰专用超亚肤感耐磨水性涂料，能有效地克服上述不足，具有无污染、耐磨、抗污、防涂鸦、耐水、耐酒精的特性，有超亚光的视觉效果，触摸绒感亲肤，提高了表面装饰性和舒适性。
为了实现上述目的，本发明的专用水性涂料原料是由超亚光水性聚氨酯乳液、聚碳酸酯型水性聚氨酯乳液、水性固化剂、水性抗污剂、水性润湿剂、水性消泡剂、水性流平剂、水性绒感剂等组成。
本发明专用水性油墨各组分的重量百分比为：
超亚光水性聚氨酯乳液 50～60％
聚碳酸酯型水性聚氨酯乳液 15～20％
水性固化剂 0.5～2％
水性抗污剂 3～4％
水性润湿剂 0.1～2％
水性消泡剂 0.1～0.7％
水性流平剂 0.1～1％
水性绒感剂 2～3％
纯净水 余量％；
作为优选，所述的印刷用的基材是软质PVC，在挤出成型的过程中加入了45％～55％的塑化剂邻苯二甲酸二辛酯(DOP)，在印刷过程中遇高温析出，会破坏涂层，使印刷后成品出现反粘现象。本发明涂料能够有效克服这种PVC的该缺点。
作为优选，所述的水性涂料是以纯净水为溶剂来调整聚碳酸酯型水性聚氨酯乳液和各助剂。
作为优选，所述超亚光水性聚氨酯乳液的原料组成，按单体总质量计，包括聚己二酸丁二醇酯二元醇55-60份，异氟尔酮二异氰酸酯35-40份，三羟甲基丙烷0.5-1.5份，二月桂酸二丁基锡0.05-0.3份，二羟甲基丁酸2.5-3份，三乙胺0.5-1.5份，二甲基乙醇胺0.5-1.5份，乙二胺基乙磺酸钠0.5-1份，40％水合肼0.5-1份；将计量好的聚己二酸丁二醇酯二元醇、三羟甲基丙烷和催化剂二月桂酸二丁基锡加入到反应釜中，加热至50-65℃时开始缓慢加入异氟尔酮二异氰酸酯，随后加入二羟甲基丁酸，继续加热至70-80℃，保温搅拌1-3小时；降温至30-40℃以下，加入三乙胺和二甲基乙醇胺分散完全，然后加入乙二胺基乙磺酸钠和水同时进行乳化和扩链反应，水的加入量为单体总质量的1.8-2.4倍，最后加入40％水合肼进行后扩链反应，即为超亚光水性聚氨酯乳液。具有良好的超亚光效果，且具有优异的耐化学性、耐溶剂性、耐水性，高弹性、抗张强度高，伸长率高，通过交联可获得柔软的质地。
作为优选，所述聚碳酸酯型水性聚氨酯乳液的原料组成，按单体总质量计，包括聚碳酸酯二醇60-65份，异氟尔酮二异氰酸酯30-35份，二月桂酸二丁基锡0.05-0.3份，三羟甲基丙烷0.5-1.5份，二羟甲基丁酸2.5-5份，三乙胺1-3份，乙二胺0.5-1份；将计量好的聚碳酸酯二醇、异氟尔酮二异氰酸酯、三羟甲基丙烷和催化剂二月桂酸二丁基锡加入到反应釜中，加热至70-80℃，保温搅拌0.5-1.5小时，加入二羟甲基丁酸继续反应0.5-1.5小时；然后降温至35℃以下，加入三乙胺中和，分散完全后加入水进行高速乳化，水的加入量为单体总质量的1.8-2.2倍；最后加入用8-12倍体积水稀释的乙二胺扩链，即为聚碳酸酯型水性聚氨酯乳液。
作为优选，所述的水性固化剂是水性高温架桥剂，优选胺基型水性树脂交联剂，型号D-04，固含量60％，它与水性聚氨酯能在高温下产生交联作用，形成绸状结构。所述的D-04胺基型水性树脂交联剂是高温交联型固化剂，在常温下不交联，温度达到120℃以上，产生开封交联反应，明显提高水性树脂的硬度、耐磨性及耐污染性。
作为优选，所述的水性抗污剂是含羟基官能团的聚二甲基硅氧烷乳液，德国TEGO5100N，不挥发物CA.55％，基于不挥发物的羟值ca.25mg KOH/g。
作为优选，所述的水性润湿剂是高性能乙氧基化非离子超强润湿剂，型号HH-607，活性物含量100％。
作为优选，所述的水性消泡剂是水性聚氨酯消泡剂F-828，其有效含量98％，pH值5-8。
作为优选，所述的水性流平剂是聚醚改性聚二甲基硅氧烷溶液，德国BYK346。
作为优选，所述的水性绒感剂，型号CG-90，外观为半透明液体，PH值6.0-7.0。
本发明一种PVC表面装饰专用高光抗污耐磨水性涂料的制备方法，包括如下步骤：第一步，制备超亚光水性聚氨酯乳液；第二步，制备聚碳酸酯型水性聚氨酯乳液；第三步，按重量分数比例称取原料，将所需消泡剂的60-80％、超亚光水性聚氨酯乳液、聚碳酸酯型水性聚氨酯乳液、纯净水加入搅拌釜中搅拌均匀，再加入水性固化剂、水性抗污剂、水性流平剂、水性绒感剂，高速分散混合，停机加入剩余消泡剂、水性润湿剂，低速搅拌均匀，过滤包装，即为PVC表面装饰专用超亚肤感耐磨水性涂料。
本发明与现有的技术相比具有以下优点：
1)本发明的水性涂料用水作为溶剂，有效减少使用有机溶剂，低VOCs排放；
2)本发明的涂料印品无溶剂残留，有效消除工作场所易燃易爆的隐患，对印刷操作人员无不良影响；
3)本发明的水性涂料能有效地封闭软质PVC基材中DOP塑化剂的迁移，解决了印刷过程中DOP析出造成的反粘现象，抗粘连性佳；在PVC基材上附着力强；无毒、无污染；还具有耐水、耐酒精、耐磨、抗污、防记号笔、防涂鸦、抗老化的特性；
4)本发明的水性涂料无需添加消光剂，可达到光泽度极低的效果，视觉柔和，触摸绒感，亲肤性佳。
5)本发明的水性涂料并非在印刷时即完成全部反应，而是在后续装饰面板高温贴合工艺中产生最终交联反应，不浪费不损耗，使产品利用率得到极大提高。
具体实施方式
下面通过实施例对本发明做进一步的详细说明，这些实施例仅用于帮助理解本发明的方法和核心思想，并不限制本发明的范围。应当指出，在不脱离本发明的前提下，本领域的技术人员仍可对本发明进行若干的改进和修饰，这些改进和修饰也落入本发明权利要求的保护范围内。
实施例1
本实施例所述的乳液制备的原料和试剂主要有：聚己二酸丁二醇酯二元醇、聚碳酸酯二醇来自济宁华凯树脂有限公司；异氟尔酮二异氰酸酯来自无锡东润电子材料科技有限公司；二羟甲基丁酸来自安徽中恩化工有限公司；三羟甲基丙烷、二月桂酸二丁基锡、三乙胺、乙二胺基乙磺酸钠来自广东翁江化学试剂有限公司；二甲基乙醇胺来自阿拉丁试剂(上海)有限公司；40％水合肼来自天津坤华化工有限公司；乙二胺来自山东西亚化学工业有限公司。
本实施例的水性涂料分三步制作，第一步是制备超亚光水性聚氨酯乳液；第二步是制备聚碳酸酯型水性聚氨酯乳液；第三步是水性涂料的调配。具体制备方法如下：
第一步，超亚光水性聚氨酯乳液的制备
按单体总质量计，称取57％聚己二酸丁二醇酯二元醇、1.2％三羟甲基丙烷和0.1％二月桂酸二丁基锡加入到反应釜中，加热至60℃时开始缓慢加入36％异氟尔酮二异氰酸酯和2.7％二羟甲基丁酸，继续加热至75℃，保温搅拌2小时；降温至35℃以下，加入0.8％三乙胺和1％二甲基乙醇胺搅拌，随后加入0.5％乙二胺基乙磺酸钠和单体总质量2倍的水反应1小时，最后将0.7％水合肼(含量为40％)加入反应釜中搅拌1小时，得到水性涂料的双组分连接料之一——超亚光水性聚氨酯乳液。
第二步，聚碳酸酯型水性聚氨酯乳液的制备
按单体总质量计，称取62％聚碳酸酯二醇、31％异氟尔酮二异氰酸酯、1％三羟甲基丙烷和0.1％二月桂酸二丁基锡加入到反应釜中，加热至75℃，保温搅拌1小时；加入3.5％二羟甲基丁酸，继续反应1小时；然后降温至35℃以下，加入1.6％三乙胺和单体总质量1.9倍的水高速搅拌0.5小时；最后将0.8％乙二胺用十倍体积水稀释，加入反应釜搅拌1小时，得到水性涂料的双组分连接料之二——聚碳酸酯型水性聚氨酯乳液。
第三步，水性涂料的调配
配方如下(按重量分数比)：
自制的超亚光水性聚氨酯乳液60％；
自制的聚碳酸酯型水性聚氨酯乳液15％；
水性抗污剂3％，含羟基官能团的聚二甲基硅氧烷乳液，型号德国TEGO 5100N，来自厦门市百桂全贸易有限公司；
水性固化剂0.8％，胺基型水性树脂交联剂，型号D-04，来自厦门市百桂全贸易有限公司；
水性润湿剂1％，高性能乙氧基化非离子超级润湿剂，型号HH-607，来自台州恒海化工有限公司；
水性消泡剂0.7％，水性聚氨酯消泡剂，型号F-828，来自厦门市百桂全贸易有限公司；
水性流平剂0.5％，聚醚改性聚二甲基硅氧烷溶液，型号德国BYK346，来自厦门市百桂全贸易有限公司；
水性绒感剂3％，型号CG-90，来自厦门市百桂全贸易有限公司；
纯净水余量。
按重量分数比例称取原料，将超亚光水性聚氨酯乳液、聚碳酸酯型水性聚氨酯乳液、所需消泡剂的70％、纯净水加入搅拌釜中搅拌均匀，再加入水性固化剂、水性抗污剂、水性流平剂、水性绒感剂，高速分散混合0.5小时，停机加入剩余消泡剂、水性润湿剂，低速搅拌均匀，过滤包装，即为PVC表面装饰专用超亚肤感耐磨水性涂料。
将该水性涂料用于PVC装饰薄膜表面，通过260线的网纹辊辊涂后，形成超亚光乳白涂层，涂层参数：根据GB/T 13217.8-2009标准测得抗粘连度96％；根据GB/T13217.7-2009标准测得附着牢度95％；60°光泽度仪测得光泽度1.7度；铅笔硬度＜1H；用水浸泡48h不起皱不起泡，耐水性好；耐磨测试仪加压500g，硬质橡皮干磨50次，无明显变化，湿磨50次，无明显变化，不耐酒精；记号笔涂鸦后用湿布擦拭，残留大部分墨迹，不耐记号笔；触摸绒感亲肤。
将印有涂层的PVC薄膜通过150℃-180℃贴合缸，形成最终水性涂层成品，涂层参数：根据GB/T 13217.8-2009标准测得抗粘连度96％，受热后抗粘连性能未降低，说明塑料中的DOP得到有效封闭；根据GB/T 13217.7-2009标准测得附着牢度95％；60°光泽度仪测得光泽度1.7度；铅笔硬度达到2H，经过高温交联，硬度得到有效提高；用水浸泡48h不起皱不起泡，耐水性好；耐磨测试仪加压500g，硬质橡皮干磨200次，无明显变化，湿磨200次，无明显变化，酒精磨200次，无明显变化，实现良好的耐磨、耐湿擦、耐酒精性能；记号笔涂鸦后用湿布擦，无墨迹残留，可用湿布擦除，实现耐记号笔、防涂鸦的功能；触摸绒感亲肤。
实施例2
配方如下(按重量分数比)：
自制的超亚光水性聚氨酯乳液55％(同实施例1)；
自制的聚碳酸酯型水性聚氨酯乳液20％(同实施例1)；
水性抗污剂3％，含羟基官能团的聚二甲基硅氧烷乳液，型号德国TEGO 5100N，来自厦门市百桂全贸易有限公司；
水性固化剂0.8％，胺基型水性树脂交联剂，型号D-04，来自厦门市百桂全贸易有限公司；
水性润湿剂1％，高性能乙氧基化非离子超级润湿剂，型号HH-607，来自台州恒海化工有限公司；
水性消泡剂0.7％，水性聚氨酯消泡剂，型号F-828，来自厦门市百桂全贸易有限公司；
水性流平剂0.5％，聚醚改性聚二甲基硅氧烷溶液，型号德国BYK346，来自厦门市百桂全贸易有限公司；
水性绒感剂3％，型号CG-90，来自厦门市百桂全贸易有限公司；
纯净水余量。
按重量分数比例称取原料，将超亚光水性聚氨酯乳液、聚碳酸酯型水性聚氨酯乳液、所需消泡剂的75％、纯净水加入搅拌釜中搅拌均匀，再加入水性固化剂、水性抗污剂、水性流平剂、水性绒感剂，高速分散混合0.5小时，停机加入剩余消泡剂、水性润湿剂，低速搅拌均匀，过滤包装，即为PVC表面装饰专用超亚肤感耐磨水性涂料。
将该水性涂料用于PVC装饰薄膜表面，通过260线的网纹辊辊涂后，形成超亚光乳白涂层，涂层参数：根据GB/T 13217.8-2009标准测得抗粘连度96％；根据GB/T13217.7-2009标准测得附着牢度98％；60°光泽度仪测得光泽度2度；铅笔硬度＜1H；用水浸泡48h不起皱不起泡，耐水性好；耐磨测试仪加压500g，硬质橡皮干磨50次，无明显变化，湿磨50次，无明显变化，不耐酒精；记号笔涂鸦后用湿布擦拭，残留大部分墨迹，不耐记号笔；触摸绒感亲肤。
将印有涂层的PVC薄膜通过150℃～180℃贴合缸，形成最终水性涂层成品，涂层参数：根据GB/T 13217.8-2009标准测得抗粘连度96％，受热后抗粘连性能未降低，说明塑料中的DOP得到有效封闭；根据GB/T 13217.7-2009标准测得附着牢度98％；60°光泽度仪测得光泽度2度；铅笔硬度达到2H，经过高温交联，硬度得到有效提高；用水浸泡48h不起皱不起泡，耐水性好；耐磨测试仪加压500g，硬质橡皮干磨200次，无明显变化，湿磨200次，无明显变化，酒精磨200次，无明显变化，实现良好的耐磨、耐湿擦、耐酒精性能；记号笔涂鸦后用湿布擦，无墨迹残留，可用湿布擦除，实现耐记号笔、防涂鸦的功能；触摸绒感亲肤。
实施例3
配方如下(按重量分数比)：
自制的超亚光水性聚氨酯乳液55％(同实施例1)；
自制的聚碳酸酯型水性聚氨酯乳液20％(同实施例1)；
水性抗污剂3％，含羟基官能团的聚二甲基硅氧烷乳液，型号德国TEGO 5100N，来自厦门市百桂全贸易有限公司；
水性固化剂0.8％，胺基型水性树脂交联剂，型号D-04，来自厦门市百桂全贸易有限公司；
水性润湿剂2％，高性能乙氧基化非离子超级润湿剂，型号HH-607，来自台州恒海化工有限公司；
水性消泡剂0.7％，水性聚氨酯消泡剂，型号F-828，来自厦门市百桂全贸易有限公司；
水性流平剂0.5％，聚醚改性聚二甲基硅氧烷溶液，型号德国BYK346，来自厦门市百桂全贸易有限公司；
水性绒感剂3％，型号CG-90，来自厦门市百桂全贸易有限公司；
纯净水余量。
按重量分数比例称取原料，将超亚光水性聚氨酯乳液、聚碳酸酯型水性聚氨酯乳液、所需消泡剂的70％、纯净水加入搅拌釜中搅拌均匀，再加入水性固化剂、水性抗污剂、水性流平剂、水性绒感剂，高速分散混合0.5小时，停机加入剩余消泡剂、水性润湿剂，低速搅拌均匀，过滤包装，即为PVC表面装饰专用超亚肤感耐磨水性涂料。
将该水性涂料用于PVC装饰薄膜表面，通过260线的网纹辊辊涂后，形成超亚光乳白涂层，涂层参数：根据GB/T 13217.8-2009标准测得抗粘连度98％；根据GB/T13217.7-2009标准测得附着牢度98％；60°光泽度仪测得光泽度2度；铅笔硬度＜1H；用水浸泡48h不起皱不起泡，耐水性好；耐磨测试仪加压500g，硬质橡皮干磨50次，无明显变化，湿磨50次，无明显变化，不耐酒精；记号笔涂鸦后用湿布擦拭，残留大部分墨迹，不耐记号笔；触摸绒感亲肤。
将印有涂料的PVC薄膜通过150℃～180℃贴合缸，形成最终水性涂层成品，涂层参数：根据GB/T 13217.8-2009标准测得抗粘连度98％，受热后抗粘连性能未降低，说明塑料中的DOP得到有效封闭；根据GB/T 13217.7-2009标准测得附着牢度98％；60°光泽度仪测得光泽度2度；铅笔硬度达到2H，经过高温交联，硬度得到有效提高；用水浸泡48h不起皱不起泡，耐水性好；耐磨测试仪加压500g，硬质橡皮干磨200次，无明显变化，湿磨200次，无明显变化，酒精磨200次，无明显变化，实现良好的耐磨、耐湿擦、耐酒精性能；记号笔涂鸦后用湿布擦，无墨迹残留，可用湿布擦除，实现耐记号笔、防涂鸦的功能；触摸绒感亲肤。
上述仅为本发明的具体实施例，但本发明的设计构思并不局限于此，凡利用此构思对本发明进行非实质性的改动，均应属于侵犯本发明保护范围的行为。
Claims (9)
1.一种PVC表面装饰专用超亚肤感耐磨水性涂料，原料按重量百分比，包括；
其中，所述超亚光水性聚氨酯乳液的原料组成，按单体总质量计，包括聚己二酸丁二醇酯二元醇55-60份，异氟尔酮二异氰酸酯35-40份，三羟甲基丙烷0.5-1.5份，二月桂酸二丁基锡0.05-0.3份，二羟甲基丁酸2.5-3份，三乙胺0.5-1.5份，二甲基乙醇胺0.5-1.5份，乙二胺基乙磺酸钠0.5-1份，40％水合肼0.5-1份；将计量好的聚己二酸丁二醇酯二元醇、三羟甲基丙烷和催化剂二月桂酸二丁基锡加入到反应釜中，加热至50-65℃时开始缓慢加入异氟尔酮二异氰酸酯，随后加入二羟甲基丁酸，继续加热至70-80℃，保温搅拌1-3小时；降温至30-40℃以下，加入三乙胺和二甲基乙醇胺分散完全，然后加入乙二胺基乙磺酸钠和水同时进行乳化和扩链反应，水的加入量为单体总质量的1.8-2.4倍，最后加入40％水合肼进行后扩链反应，即为超亚光水性聚氨酯乳液；
所述聚碳酸酯型水性聚氨酯乳液的原料组成，按单体总质量计，包括聚碳酸酯二醇60-65份，异氟尔酮二异氰酸酯30-35份，二月桂酸二丁基锡0.05-0.3份，三羟甲基丙烷0.5-1.5份，二羟甲基丁酸2.5-5份，三乙胺1-3份，乙二胺0.5-1份；将计量好的聚碳酸酯二醇、异氟尔酮二异氰酸酯、三羟甲基丙烷和催化剂二月桂酸二丁基锡加入到反应釜中，加热至70-80℃，保温搅拌0.5-1.5小时，加入二羟甲基丁酸继续反应0.5-1.5小时；然后降温至35℃以下，加入三乙胺中和，分散完全后加入水进行高速乳化，水的加入总量为单体总质量的1.8-2.2倍；最后加入用8-10倍体积水稀释的乙二胺扩链，即为聚碳酸酯型水性聚氨酯乳液。
2.根据权利要求1所述的PVC表面装饰专用超亚肤感耐磨水性涂料，其特征在于：印刷所用的基材是PVC装饰薄膜，在挤出成型的过程中加入了塑化剂邻苯二甲酸二辛酯,在印刷过程中遇高温析出，会破坏涂料，使印刷后成品出现反粘现象。
3.根据权利要求1所述的PVC表面装饰专用超亚肤感耐磨水性涂料，其特征在于：所述的水性固化剂是胺基型水性树脂交联剂。
4.根据权利要求1所述的PVC表面装饰专用超亚肤感耐磨水性涂料，其特征在于：所述的水性抗污剂是含羟基官能团的聚二甲基硅氧烷乳液。
5.根据权利要求1所述的PVC表面装饰专用超亚肤感耐磨水性涂料，其特征在于：所述的水性润湿剂是高性能乙氧基化非离子超强润湿剂。
6.根据权利要求1所述的PVC表面装饰专用超亚肤感耐磨水性涂料，其特征在于：所述的水性消泡剂是水性聚氨酯消泡剂。
7.根据权利要求1所述的PVC表面装饰专用超亚肤感耐磨水性涂料，其特征在于：所述的水性流平剂是聚醚改性聚二甲基硅氧烷溶液。
8.根据权利要求1所述的PVC表面装饰专用超亚肤感耐磨水性涂料，其特征在于：所述的水性绒感剂不含烷基酚类物质。
9.根据权利要求1所述的PVC表面装饰专用超亚肤感耐磨水性涂料的制备方法，包括以下步骤：
第一步，制备超亚光水性聚氨酯乳液；
第二步，制备聚碳酸酯型水性聚氨酯乳液；
第三步，按重量分数比例称取原料，将所需消泡剂的60-80％、超亚光水性聚氨酯乳液、聚碳酸酯型水性聚氨酯乳液、纯净水加入搅拌釜中搅拌均匀，再加入水性固化剂、水性抗污剂、水性流平剂、水性绒感剂，高速分散混合，停机加入剩余消泡剂、水性润湿剂，低速搅拌均匀，过滤包装，即为PVC表面装饰专用超亚肤感耐磨水性涂料。
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