CN109137548A - Vehicle internal decoration cloth fire retardant - Google Patents

Vehicle internal decoration cloth fire retardant Download PDF

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Publication number
CN109137548A
CN109137548A CN201811016670.7A CN201811016670A CN109137548A CN 109137548 A CN109137548 A CN 109137548A CN 201811016670 A CN201811016670 A CN 201811016670A CN 109137548 A CN109137548 A CN 109137548A
Authority
CN
China
Prior art keywords
vehicle internal
internal decoration
decoration cloth
fire retardant
surplus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811016670.7A
Other languages
Chinese (zh)
Inventor
邵敏
张树斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changshu Huashang New Material Technology Co Ltd
Original Assignee
Changshu Huashang New Material Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changshu Huashang New Material Technology Co Ltd filed Critical Changshu Huashang New Material Technology Co Ltd
Priority to CN201811016670.7A priority Critical patent/CN109137548A/en
Publication of CN109137548A publication Critical patent/CN109137548A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042Acrylic polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/06Properties of the materials having thermal properties
    • D06N2209/067Flame resistant, fire resistant
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/26Vehicles, transportation
    • D06N2211/263Cars

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of vehicle internal decoration cloth fire retardants, it is composed of the following components by weight percentage: dispersing agent 1%~2%, 2- diethylhexyl sodium sulphate 0.4%~1%, melamine cyanurate salt 15%~20%, high polymerization degree APP 15%~20%, triazine carbon forming agent 12%~15%, emulsion acrylic resin 20%~25%, sodium hydroxide 0.1%~0.5%, surplus are deionized water.Vehicle internal decoration cloth fire retardant of the present invention is coated in vehicle internal decoration cloth, can form flame-retardant layer after drying, and do not influence the appearance of vehicle internal decoration cloth.

Description

Vehicle internal decoration cloth fire retardant
Technical field
The present invention relates to vehicle internal decoration cloth fire retardants.
Background technique
The security configuration of automobile is increasingly taken seriously recently, and automobile interior decoration is largely made of fabric and engineering plastics, is used Automotive interior material by flame retardant treatment can effectively reduce the security performance of automobile, reduce caused by automobile internal cause or external cause The personal safety of passenger when burning.Automotive interior material requires to be free of heavy metal and halogen, avoids generating when burning a large amount of Pernicious gas damages human body.It develops nontoxic, efficient, inexpensive halogen-free flame retardants and meets current market needs.
The fire-retardant of nylon facing material (Fypro) is obviously difficult to polyester fabric (pet fiber), And common fire retardant is mostly halogen, does not have positive effect to the fire-retardant of nylon;But the excellent properties of nylon itself, so that Present nylon facing material increasingly receives an acclaim.The fire retardant that exploitation is suitable for nylon meets current market needs.
Summary of the invention
The purpose of the present invention is to provide a kind of vehicle internal decoration cloth fire retardants, vehicle internal decoration cloth are coated in, after drying Flame-retardant layer can be formed, and does not influence the appearance of vehicle internal decoration cloth.
To achieve the above object, the technical scheme is to design a kind of vehicle internal decoration cloth fire retardant, by weight hundred Divide more composed of the following components than counting:
Dispersing agent 1%~2%,
2- diethylhexyl sodium sulphate 0.4%~1%,
Melamine cyanurate salt 15%~20%,
High polymerization degree APP 15%~20%,
Triazine carbon forming agent 12%~15%,
Emulsion acrylic resin 20%~25%,
Sodium hydroxide 0.1%~0.5%,
Surplus is deionized water.
Preferably, the vehicle internal decoration cloth fire retardant, composed of the following components by weight percentage:
Dispersing agent 1%,
2- diethylhexyl sodium sulphate 0.4%,
Melamine cyanurate salt 15%,
High polymerization degree APP 15%,
Triazine carbon forming agent 12%,
Emulsion acrylic resin 20%,
Sodium hydroxide 0.1%,
Surplus is deionized water.
Preferably, the vehicle internal decoration cloth fire retardant, composed of the following components by weight percentage:
Dispersing agent 1.5%,
2- diethylhexyl sodium sulphate 0.6%,
Melamine cyanurate salt 18%,
High polymerization degree APP 17%,
Triazine carbon forming agent 13%,
Emulsion acrylic resin 22%,
Sodium hydroxide 0.3%,
Surplus is deionized water.
Preferably, the vehicle internal decoration cloth fire retardant, composed of the following components by weight percentage:
Dispersing agent 1%~2%,
2- diethylhexyl sodium sulphate 0.4%~1%,
Melamine cyanurate salt 15%~20%,
High polymerization degree APP 15%~20%,
Triazine carbon forming agent 12%~15%,
Emulsion acrylic resin 20%~25%,
Sodium hydroxide 0.1%~0.5%,
Surplus is deionized water.
Advantages and advantages of the present invention are to provide a kind of vehicle internal decoration cloth fire retardant, is coated in automobile Cloth is adornd, flame-retardant layer can be formed after drying, and do not influence the appearance of vehicle internal decoration cloth.
1) fire retardant of the present invention is free of eight big heavy metals, meets REACH and RoHS standard, to the sheet of polyester fiber sofa cloth Color is without influence.
2) fire retardant of the present invention is low in cost.
3) fire retardant of the present invention is halogen-free, environment protection health.
3) good flame retardation effect of fire retardant of the present invention meets 302 Federal Motor Vehicle Safety Standards of FMVSS, 302 U.S., CPAI- 84 U.S.'s tent cloth flame-retardant standards.
4) preparation process of fire retardant of the present invention is simple.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.Following embodiment is only used for more Add and clearly demonstrate technical solution of the present invention, and not intended to limit the protection scope of the present invention.
Embodiment 1
It prepares:
The 2- diethylhexyl sodium sulphate of the dispersing agent of 1Kg and 0.5 Kg are added in the water of 30Kg, 500r/min disperses 5min Afterwards, the melamine cyanurate salt of 20Kg, the high polymerization degree APP of 20Kg, 15Kg are slowly added under lasting stirring action Triazine carbon forming agent, mixing speed is promoted to 1500r/min, disperses 30 min;Then the acrylic emulsion of 30Kg, stirring is added Speed is down to 1200r/min, disperses 20min;It is finally slowly added to suitable sodium hydroxide, its pH value is made to avoid PH in 6.5-7( It is excessively high to decompose triazine carbon forming agent, damage nylon facing material), fire retardant is made.
It uses:
Fire retardant is coated in vehicle internal decoration cloth (nylon woven plain cloth) surface, doctor back applies weight gain to about 50%, and thermal finalization is dried It is dry, taking-up.
Embodiment 2
It prepares:
The 2- diethylhexyl sodium sulphate of the dispersing agent of 1Kg and 0.5 Kg are added in the water of 30Kg, 500r/min disperses 5min Afterwards, the melamine cyanurate salt of 20Kg, the high polymerization degree APP of 20Kg, 15Kg are slowly added under lasting stirring action Triazine carbon forming agent, mixing speed is promoted to 1500r/min, disperses 30 min;Then the acrylic emulsion of 30Kg, stirring is added Speed is down to 1200r/min, disperses 20min;It is finally slowly added to suitable sodium hydroxide, its pH value is made to avoid PH in 7-7.5( It is excessively high to decompose triazine carbon forming agent, avoid too low PH from damaging the automobile inner decoration facing of terylene material), fire retardant is made.
It uses:
Fire retardant is coated in vehicle internal decoration cloth (terylene material) surface, doctor back applies weight gain to about 20-30%, and thermal finalization is dried, Taking-up.
The flame retardant effect of each embodiment is tested:
The flame retardant test result of each embodiment polyester fiber sofa cloth is as shown in the table
Embodiment 1 Examination criteria Fire source flame Flame retardant test
Embodiment 1 CPAI-84 1# Afterflame 0-2 seconds, pass through.
Embodiment 2 FMVSS 302 1# Afterflame 0S damages 0.8 inch, passes through.
The above is only a preferred embodiment of the present invention, it is noted that those skilled in the art are come It says, without departing from the technical principles of the invention, several improvements and modifications can also be made, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (4)

1. vehicle internal decoration cloth fire retardant, which is characterized in that composed of the following components by weight percentage:
Dispersing agent 1%~2%,
2- diethylhexyl sodium sulphate 0.4%~1%,
Melamine cyanurate salt 15%~20%,
High polymerization degree APP 15%~20%,
Triazine carbon forming agent 12%~15%,
Emulsion acrylic resin 20%~25%,
Sodium hydroxide 0.1%~0.5%,
Surplus is deionized water.
2. vehicle internal decoration cloth fire retardant according to claim 1, which is characterized in that by weight percentage by with the following group It is grouped as:
Dispersing agent 1%,
2- diethylhexyl sodium sulphate 0.4%,
Melamine cyanurate salt 15%,
High polymerization degree APP 15%,
Triazine carbon forming agent 12%,
Emulsion acrylic resin 20%,
Sodium hydroxide 0.1%,
Surplus is deionized water.
3. vehicle internal decoration cloth fire retardant according to claim 1, which is characterized in that by weight percentage by with the following group It is grouped as:
Dispersing agent 1.5%,
2- diethylhexyl sodium sulphate 0.6%,
Melamine cyanurate salt 18%,
High polymerization degree APP 17%,
Triazine carbon forming agent 13%,
Emulsion acrylic resin 22%,
Sodium hydroxide 0.3%,
Surplus is deionized water.
4. vehicle internal decoration cloth fire retardant according to claim 1, which is characterized in that by weight percentage by with the following group It is grouped as:
Dispersing agent 1%~2%,
2- diethylhexyl sodium sulphate 0.4%~1%,
Melamine cyanurate salt 15%~20%,
High polymerization degree APP 15%~20%,
Triazine carbon forming agent 12%~15%,
Emulsion acrylic resin 20%~25%,
Sodium hydroxide 0.1%~0.5%,
Surplus is deionized water.
CN201811016670.7A 2018-09-03 2018-09-03 Vehicle internal decoration cloth fire retardant Pending CN109137548A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811016670.7A CN109137548A (en) 2018-09-03 2018-09-03 Vehicle internal decoration cloth fire retardant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811016670.7A CN109137548A (en) 2018-09-03 2018-09-03 Vehicle internal decoration cloth fire retardant

Publications (1)

Publication Number Publication Date
CN109137548A true CN109137548A (en) 2019-01-04

Family

ID=64826179

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811016670.7A Pending CN109137548A (en) 2018-09-03 2018-09-03 Vehicle internal decoration cloth fire retardant

Country Status (1)

Country Link
CN (1) CN109137548A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102219957A (en) * 2011-05-13 2011-10-19 上海化工研究院 Functional masterbatch of halogen-free intumescent flame retardant, and preparation method thereof
CN102509594A (en) * 2011-11-23 2012-06-20 沈阳天荣电缆材料有限公司 Fire-retardant binding belt for cable and manufacturing method therefor
CN104448560A (en) * 2014-12-01 2015-03-25 黑龙江省润特科技有限公司 Polypropylene halogen-free intumescent flame retardant
CN106930093A (en) * 2016-12-16 2017-07-07 中山康诺德新材料有限公司 A kind of fabric coating efficient halogen-free environmental protection fire retarding agent and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102219957A (en) * 2011-05-13 2011-10-19 上海化工研究院 Functional masterbatch of halogen-free intumescent flame retardant, and preparation method thereof
CN102509594A (en) * 2011-11-23 2012-06-20 沈阳天荣电缆材料有限公司 Fire-retardant binding belt for cable and manufacturing method therefor
CN104448560A (en) * 2014-12-01 2015-03-25 黑龙江省润特科技有限公司 Polypropylene halogen-free intumescent flame retardant
CN106930093A (en) * 2016-12-16 2017-07-07 中山康诺德新材料有限公司 A kind of fabric coating efficient halogen-free environmental protection fire retarding agent and preparation method thereof

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Application publication date: 20190104

RJ01 Rejection of invention patent application after publication