CN109137497A - Application of the environment-friendly type without fluoro water proofing agent on umbrella cloth - Google Patents
Application of the environment-friendly type without fluoro water proofing agent on umbrella cloth Download PDFInfo
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- CN109137497A CN109137497A CN201810620587.4A CN201810620587A CN109137497A CN 109137497 A CN109137497 A CN 109137497A CN 201810620587 A CN201810620587 A CN 201810620587A CN 109137497 A CN109137497 A CN 109137497A
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- base fabric
- proofing agent
- environment
- water proofing
- friendly type
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/16—Multi-step processes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
- D06M11/71—Salts of phosphoric acids
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Abstract
Application of a kind of environment-friendly type provided by the invention without fluoro water proofing agent on umbrella cloth, comprising the following steps: 1) concise: water and desizing agent are added in the fluid cylinder of scouring machine, is configured to concise liquid；After being warming up to 50-70 DEG C, base fabric is put into fluid cylinder, concise liquid cycle rotation in fluid cylinder together with base fabric is made；It then heats to (80-100) DEG C, after concise 30-60min, venting refining liquid takes out base fabric after cold water washing is added；2) arrange: be added in the liquid bath of collator water and 0.6-0.8g/L without fluoro water proofing agent, be configured to working fluid, and use acid solution tune pH, reach 5.6-6.0；By one immersing and rolling working fluid of base fabric；Base fabric is carried out to drying and shaping in drying and setting machine again.Acid solution is added in the present invention to maintain to maintain working fluid pH value to the lasting processing stability between 5.6-6.0, greatly improving the waterproofing agent.
Description
Technical field
The present invention relates to textile production fields, and in particular to a kind of environment-friendly type the answering on umbrella cloth without fluoro water proofing agent
With.
Background technique
Fluoride PFOA(perfluorooctane sulfonyl compound in currently used waterproofing agent), PFOS(perfluoro caprylic acid
Ammonium), belong to environment, people and the unfriendly compound of animal, there is bioaccumulation, genetoxic, and performance to stablize, be not easy to drop
Solution.Higher and higher to the environmental requirement of waterproofing agent with the promotion of environmental requirement, the application of waterproofing agent is from 8 carbon waterproofing agents to 6 carbon
Waterproofing agent arrives no fluoro water proofing agent again.American-European commodity are especially exported, often there is floride-free requirement.And existing floride-free waterproof
Agent often contains active hydrogen or amino, and in process, temperature is higher when processing, and no fluoro water proofing agent is oxidized easily, and causes to prevent
Aqua is difficult to be attached to umbrella cloth, eventually reduces the waterproof performance of product.
The existing patent document application No. is CN201510645951.9 discloses that " a kind of cotton of environment-friendly waterproof is colored
Polish the preparation method of coating checked fabric ", in the finishing technique first by C6 waterproofing agent or without fluoro water proofing agent and bleeding agent it is deployed
It pours into sink；Baking oven is warming up to 150 DEG C -180 DEG C, checked fabric is then imported into sink, enters baking oven after pressing from both sides rod；Add
Working hour temperature is higher, and no fluoro water proofing agent is oxidized easily, and causes waterproofing agent to be difficult to be attached to umbrella cloth, eventually reduces product
Waterproof performance.
Summary of the invention
(1) technical problems to be solved
A kind of application it is an object of the present invention to provide environment-friendly type without fluoro water proofing agent on umbrella cloth solves existing make
It is higher that there are temperature when being processed with environment-friendly type without the fabric finishing process of fluoro water proofing agent, and no fluoro water proofing agent is oxidized easily, and is caused
Waterproofing agent is difficult to be attached to umbrella cloth, eventually reduces the defect of the waterproof performance of product.
A kind of application it is a further object to provide environment-friendly type without fluoro water proofing agent on umbrella cloth solves existing
Some is using environment-friendly type without fluoro water proofing agent
(2) technical solution
In order to solve the above technical problem, the present invention provides a kind of application of environment-friendly type without fluoro water proofing agent on umbrella cloth, packet
Include following steps:
1) concise: water and desizing agent being added in the fluid cylinder of scouring machine, is configured to concise liquid；After being warming up to 50-70 DEG C, by base fabric
It puts into fluid cylinder, makes concise liquid cycle rotation in fluid cylinder together with base fabric；It then heats to (80-100) DEG C, concise 30-
After 60min, venting refining liquid takes out base fabric after cold water washing is added；
2) arrange: be added in the liquid bath of collator water and 0.6-0.8g/L without fluoro water proofing agent, be configured to working fluid, and use
Acid solution tune pH, reaches 5.6-6.0；By one immersing and rolling working fluid of base fabric；Base fabric is carried out in drying and setting machine again
Drying and shaping.
Acid solution is added in the present invention to maintain to maintain working fluid pH value between 5.6-6.0, greatly improving the waterproof
The lasting processing stability of agent.
Preferably, concise liquid and base fabric cycle rotation 15-20min in the refining procedure.
Preferably, in the refining procedure, a length of 46-50min when more preferably refining.
Preferably, in the arranging process, the temperature of drying machine drying sizing is 160-170 DEG C,.
Preferably, in the arranging process, the speed of dryer operation is 60-70m/min.
Preferably, the acid solution includes acetic acid, potassium dihydrogen phosphate, citric acid and stabilizer, wherein in acid solution
The concentration of the three of acetic acid, potassium dihydrogen phosphate and citric acid is respectively (2.2%-2.4%), (0.6%-1.0%) and (0.3%-
0.5%), the concentration of stabilizer is 0.5-0.7g/L.The acid that acetic acid, potassium dihydrogen phosphate, citric acid and stabilizer of the invention forms
Property buffer solution, the working fluid pH of allotment is more stable, and under acid condition, 0.5-0.7g/L stabilizer is added and makes free-floride
Waterproofing agent is not easy to be oxidized, and under the premise of ensuring that waterproof effect reaches requirement, reduces the probability of waterproof cloth roll banding, greatly
The application performance of the waterproofing agent is promoted greatly；Reduce the demand to no fluoro water proofing agent.
Preferably, the no fluoro water proofing agent is by the poly dimethyl silicon simultaneously containing amino, active hydrogen and long-chain fat alkyl
Oxygen alkane and paraffin compounding are made；By weight percentage, the stabilizer includes 5-7 parts of ethylene diamine tetra methylene phosphonic acid sodium, 1-3 parts of lemons
Lemon three ammoniums of acid and 1-3 parts of cationic surfactants.It can be settled in stabilizer of the invention using ethylene diamine tetra methylene phosphonic acid sodium
Fall the heavy metal in water, reduce heavy metal adsorption influences the absorption of subsequent pigment in base fabric；Triammonium citrate and acetic acid, phosphorus
Acid dihydride potassium and citric acid may make up stablizing solution system, while Triammonium citrate can be protected in the presence of more active reproducibility group
The dimethyl silicone polymer simultaneously containing amino, active hydrogen and long-chain fat alkyl is protected to be not easy to be oxidized；It enhances floride-free anti-
The stability of aqua, ethylene diamine tetra methylene phosphonic acid sodium and potassium dihydrogen phosphate further mix into stabilizing ion solution, are not easily decomposed.
Preferably, the cationic surfactant, by weight percentage, including 2-3 parts of Dodecyl Dimethyl Amines
The organic copper silicon quaternary ammonium salt of acetate, 0.5-0.7 part octadecyl and 1-2 parts of sodium citrate.It is used in the present invention and contains amino, work
The dimethyl silicone polymer of hydrogen and long-chain fat alkyl is sprinkled, the present invention is made in stabilizers using cationic surfactant collocation
It obtains and is easier to be attached in base fabric without fluoro water proofing agent, and increase the flexibility of base fabric.
Preferably, in the arranging process, the pick-up in one immersing and rolling working fluid of base fabric is 74%-76%.
Preferably, the concise process, cold water washing times be twice, first time cold water wash when, water temperature 10-12
DEG C, when washing a length of 10-14min；When the washing of second cold water, water temperature is 20-25 DEG C, when washing a length of 20-30min.It is divided to two
It is secondary to be washed, and the temperature of the first washing is lower, the fiber rapid desufflation of base fabric is made by the temperature difference, fibrous septum is more
It is small, it enhances the flexibility of fiber, be more advantageous to the attachment of waterproofing agent.
(3) beneficial effect
A kind of application of the environment-friendly type provided by the invention without fluoro water proofing agent on umbrella cloth, has the advantage that
1, in the present invention addition acid solution to maintain to maintain working fluid pH value between 5.6-6.0, greatly improving the waterproofing agent
Lasting processing stability.
2, the acidic buffer solution of acetic acid of the invention, potassium dihydrogen phosphate, citric acid and stabilizer composition, allotment add
Work liquid pH is more stable, and under acid condition, 0.5-0.7g/L stabilizer is added, no fluoro water proofing agent is made to be not easy to be oxidized, and
And under the premise of ensuring that waterproof effect reaches requirement, the probability of waterproof cloth roll banding is reduced, the application of the waterproofing agent is greatly promoted
Performance；Reduce the demand to no fluoro water proofing agent.
3, heavy metal in water can be settled using ethylene diamine tetra methylene phosphonic acid sodium in stabilizer of the invention, reduces weight
Metal adsorption influences the absorption of subsequent pigment in base fabric；Triammonium citrate may make up with acetic acid, potassium dihydrogen phosphate and citric acid
Stablizing solution system, while Triammonium citrate can protect in the presence of more active reproducibility group and contain amino, active hydrogen simultaneously
And the dimethyl silicone polymer of long-chain fat alkyl is not easy to be oxidized；Enhance the stability of no fluoro water proofing agent, ethylenediamine tetraacetic
Methylenephosphonic acid sodium and potassium dihydrogen phosphate further mix into stabilizing ion solution, are not easily decomposed.
4, the dimethyl silicone polymer containing amino, active hydrogen and long-chain fat alkyl is used in the present invention, the present invention adopts
Make no fluoro water proofing agent be easier to be attached in base fabric in stabilizers with cationic surfactant collocation, and increases base fabric
Flexibility.
5, it is washed in two times, and the temperature of the first washing is lower, and the fiber rapid desufflation of base fabric is made by the temperature difference,
Its fibrous septum is smaller, enhances the flexibility of fiber, is more advantageous to the attachment of waterproofing agent.
Detailed description of the invention
Fig. 1 is the flow diagram of the application of environment-friendly type of the invention without fluoro water proofing agent on umbrella cloth.
Specific embodiment
With reference to embodiment, the embodiment of the present invention is furthur described in detail.Following instance is for saying
The bright present invention, but be not intended to limit the scope of the invention.
Cloth is umbrella cloth in following embodiment.
Embodiment 1: as shown in Fig. 1, a kind of application of the environment-friendly type provided by the invention without fluoro water proofing agent on umbrella cloth,
The following steps are included:
1) concise: water and desizing agent being added in the fluid cylinder of scouring machine, is configured to concise liquid；After being warming up to 50 DEG C, base fabric is thrown
Enter in fluid cylinder, makes concise liquid cycle rotation 15min in fluid cylinder together with base fabric.；Then heat to 80 DEG C, after concise 30min,
Venting refining liquid takes out base fabric after cold water washing is added；Cold water washing times be twice, first time cold water wash when, water temperature
Be 10 DEG C, when washing a length of 10min；When the washing of second cold water, water temperature is 20-25 DEG C, when washing a length of 20min.
2) arrange: be added in the liquid bath of collator water and 0.6g/L without fluoro water proofing agent, be configured to working fluid, and use
Acid solution tune pH, reaches 5.6；By one immersing and rolling working fluid of base fabric；Pick-up in one immersing and rolling working fluid of base fabric is
74%.Base fabric is carried out to drying and shaping in drying and setting machine again, the temperature of drying machine drying sizing is 160 DEG C, and speed is
60m/min.Wherein, the acid solution includes acetic acid, potassium dihydrogen phosphate, citric acid and stabilizer, wherein vinegar in acid solution
The concentration of the three of acid, potassium dihydrogen phosphate and citric acid is respectively 2.2%, 0.6% and 0.3%, and the concentration of stabilizer is 0.5g/L.
The no fluoro water proofing agent is made by compounding simultaneously containing amino, the dimethyl silicone polymer of active hydrogen and long-chain fat alkyl and paraffin
At；By weight percentage, the stabilizer includes 5 parts of ethylene diamine tetra methylene phosphonic acid sodium, 1 part of Triammonium citrate and 1 part of cation
Surfactant.The cationic surfactant, by weight percentage, including 2 parts of Dodecyl Dimethyl Amine acetate,
The organic copper silicon quaternary ammonium salt of 0.5 part of octadecyl and 1 part of sodium citrate.
Embodiment 2: a kind of application of the environment-friendly type provided by the invention without fluoro water proofing agent on umbrella cloth, including following step
It is rapid:
1) concise: water and desizing agent being added in the fluid cylinder of scouring machine, is configured to concise liquid；After being warming up to 70 DEG C, base fabric is thrown
Enter in fluid cylinder, makes concise liquid cycle rotation 20min in fluid cylinder together with base fabric.；100 DEG C are then heated to, concise 60min
Afterwards, venting refining liquid takes out base fabric after cold water washing is added；Cold water washing times be twice, first time cold water wash when, water
Temperature is 12 DEG C, when washing a length of 14min；When the washing of second cold water, water temperature is 25 DEG C, when washing a length of 30min.
2) arrange: be added in the liquid bath of collator water and 0.8g/L without fluoro water proofing agent, be configured to working fluid, and use
Acid solution tune pH, reaches 6.0；By one immersing and rolling working fluid of base fabric；Pick-up in one immersing and rolling working fluid of base fabric is
76%.Base fabric is carried out to drying and shaping in drying and setting machine again, the temperature of drying machine drying sizing is 170 DEG C, and speed is
70m/min.Wherein, the acid solution includes acetic acid, potassium dihydrogen phosphate, citric acid and stabilizer, wherein vinegar in acid solution
The concentration of the three of acid, potassium dihydrogen phosphate and citric acid is respectively 2.4%, 1.0% and 0.5%, and the concentration of stabilizer is 0.7g/L.
The no fluoro water proofing agent is made by compounding simultaneously containing amino, the dimethyl silicone polymer of active hydrogen and long-chain fat alkyl and paraffin
At；By weight percentage, the stabilizer include 5-7 parts of ethylene diamine tetra methylene phosphonic acid sodium, 3 parts of Triammonium citrates and 3 parts of sun from
Sub- surfactant.The cationic surfactant, by weight percentage, including 3 parts of Dodecyl Dimethyl Amine acetic acid
Salt, the organic copper silicon quaternary ammonium salt of 0.7 part of octadecyl and 2 parts of sodium citrate.
Embodiment 3: a kind of application of the environment-friendly type provided by the invention without fluoro water proofing agent on umbrella cloth, including following step
It is rapid:
1) concise: water and desizing agent being added in the fluid cylinder of scouring machine, is configured to concise liquid；After being warming up to 60 DEG C, base fabric is thrown
Enter in fluid cylinder, makes concise liquid cycle rotation 17.5min in fluid cylinder together with base fabric.；90 DEG C are then heated to, concise 46min
Afterwards, venting refining liquid takes out base fabric after cold water washing is added；Cold water washing times be twice, first time cold water wash when, water
Temperature is 11 DEG C, when washing a length of 12min；When the washing of second cold water, water temperature is 22.5 DEG C, when washing a length of 25min.
2) arrange: be added in the liquid bath of collator water and 0.7g/L without fluoro water proofing agent, be configured to working fluid, and use
Acid solution tune pH, reaches 5.8；By one immersing and rolling working fluid of base fabric；Pick-up in one immersing and rolling working fluid of base fabric is
75%.Base fabric is carried out to drying and shaping in drying and setting machine again, the temperature of drying machine drying sizing is 165 DEG C, and speed is
65m/min.Wherein, the acid solution includes acetic acid, potassium dihydrogen phosphate, citric acid and stabilizer, wherein vinegar in acid solution
The concentration of the three of acid, potassium dihydrogen phosphate and citric acid is respectively 2.3%, 0.8% and 0.4%, and the concentration of stabilizer is 0.6g/L.
The no fluoro water proofing agent is made by compounding simultaneously containing amino, the dimethyl silicone polymer of active hydrogen and long-chain fat alkyl and paraffin
At；By weight percentage, the stabilizer includes 6 parts of ethylene diamine tetra methylene phosphonic acid sodium, 2 parts of Triammonium citrates and 2 parts of cations
Surfactant.The cationic surfactant, by weight percentage, including 2.5 parts of Dodecyl Dimethyl Amine acetic acid
Salt, the organic copper silicon quaternary ammonium salt of 0.6 part of octadecyl and 1.5 parts of sodium citrate.
Embodiment 4: a kind of application of the environment-friendly type provided by the invention without fluoro water proofing agent on umbrella cloth, including following step
It is rapid:
1) concise: water and desizing agent being added in the fluid cylinder of scouring machine, is configured to concise liquid；After being warming up to 60 DEG C, base fabric is thrown
Enter in fluid cylinder, makes concise liquid cycle rotation 18min in fluid cylinder together with base fabric.；Then heat to 90 DEG C, after concise 50min,
Venting refining liquid takes out base fabric after cold water washing is added；Cold water washing times be twice, first time cold water wash when, water temperature
Be 11 DEG C, when washing a length of 12min；When the washing of second cold water, water temperature is 23 DEG C, when washing a length of 25min.
2) arrange: be added in the liquid bath of collator water and 0.7g/L without fluoro water proofing agent, be configured to working fluid, and use
Acid solution tune pH, reaches 5.8；By one immersing and rolling working fluid of base fabric；Pick-up in one immersing and rolling working fluid of base fabric is
75%.Base fabric is carried out to drying and shaping in drying and setting machine again, the temperature of drying machine drying sizing is 165 DEG C, and speed is
65m/min.Wherein, the acid solution includes acetic acid, potassium dihydrogen phosphate, citric acid and stabilizer, wherein vinegar in acid solution
The concentration of the three of acid, potassium dihydrogen phosphate and citric acid is respectively 2.3%, 0.8% and 0.4%, and the concentration of stabilizer is 0.6g/L.
The no fluoro water proofing agent is made by compounding simultaneously containing amino, the dimethyl silicone polymer of active hydrogen and long-chain fat alkyl and paraffin
At；By weight percentage, the stabilizer includes 6 parts of ethylene diamine tetra methylene phosphonic acid sodium, 2 parts of Triammonium citrates and 2 parts of cations
Surfactant.The cationic surfactant, by weight percentage, including 2.5 parts of Dodecyl Dimethyl Amine acetic acid
Salt, the organic copper silicon quaternary ammonium salt of 0.6 part of octadecyl and 1.5 parts of sodium citrate.
Comparative example 1: a kind of application of the environment-friendly type provided by the invention without fluoro water proofing agent on umbrella cloth, including following step
It is rapid:
1) concise: water and desizing agent being added in the fluid cylinder of scouring machine, is configured to concise liquid；After being warming up to 49 DEG C, base fabric is thrown
Enter in fluid cylinder, makes concise liquid cycle rotation 14min in fluid cylinder together with base fabric.；Then heat to 79 DEG C, after concise 29min,
Venting refining liquid takes out base fabric after cold water washing is added；Cold water washing times be twice, first time cold water wash when, water temperature
Be 9 DEG C, when washing a length of 9min；When the washing of second cold water, water temperature is 19 DEG C, when washing a length of 19min.
2) arrange: be added in the liquid bath of collator water and 0.5g/L without fluoro water proofing agent, be configured to working fluid, and use
Acid solution tune pH, reaches 5.0；By one immersing and rolling working fluid of base fabric；Pick-up in one immersing and rolling working fluid of base fabric is
73%.Base fabric is carried out to drying and shaping in drying and setting machine again, the temperature of drying machine drying sizing is 159 DEG C, and speed is
59m/min.Wherein, the acid solution includes acetic acid, potassium dihydrogen phosphate, citric acid and stabilizer, wherein vinegar in acid solution
The concentration of the three of acid, potassium dihydrogen phosphate and citric acid is respectively 2.1%, 0.5% and 0.2%, and the concentration of stabilizer is 0.4g/L.
The no fluoro water proofing agent is made by compounding simultaneously containing amino, the dimethyl silicone polymer of active hydrogen and long-chain fat alkyl and paraffin
At；By weight percentage, the stabilizer includes 8 parts of ethylene diamine tetra methylene phosphonic acid sodium, 0.9 part of Triammonium citrate and 0.9 part of sun
Ionic surface active agent.The cationic surfactant, by weight percentage, including 1 portion of Dodecyl Dimethyl Amine vinegar
Hydrochlorate, the organic copper silicon quaternary ammonium salt of 0.4 part of octadecyl and 0.9 part of sodium citrate.
Comparative example 2: a kind of application of the environment-friendly type provided by the invention without fluoro water proofing agent on umbrella cloth, including following step
It is rapid:
1) concise: water and desizing agent being added in the fluid cylinder of scouring machine, is configured to concise liquid；After being warming up to 71 DEG C, base fabric is thrown
Enter in fluid cylinder, makes concise liquid cycle rotation 21min in fluid cylinder together with base fabric.；101 DEG C are then heated to, concise 61min
Afterwards, venting refining liquid takes out base fabric after cold water washing is added；Cold water washing times be twice, first time cold water wash when, water
Temperature is 13 DEG C, when washing a length of 15min；When the washing of second cold water, water temperature is 26 DEG C, when washing a length of 31min.
2) arrange: be added in the liquid bath of collator water and 0.9g/L without fluoro water proofing agent, be configured to working fluid, and use
Acid solution tune pH, reaches 6.5；By one immersing and rolling working fluid of base fabric；Pick-up in one immersing and rolling working fluid of base fabric is
74%-76%.Base fabric is carried out to drying and shaping in drying and setting machine again, the temperature of drying machine drying sizing is 171 DEG C, and speed
For 71m/min.Wherein, the acid solution includes acetic acid, potassium dihydrogen phosphate, citric acid and stabilizer, wherein in acid solution
The concentration of the three of acetic acid, potassium dihydrogen phosphate and citric acid is respectively 2.5%, 1.1% and 0.6%, and the concentration of stabilizer is 0.8g/
L.The no fluoro water proofing agent containing amino, the dimethyl silicone polymer of active hydrogen and long-chain fat alkyl and paraffin by compounding simultaneously
It is made；By weight percentage, the stabilizer include 4 parts of ethylene diamine tetra methylene phosphonic acid sodium, 4 parts of Triammonium citrates and 4 parts of sun from
Sub- surfactant.The cationic surfactant, by weight percentage, including 4 parts of Dodecyl Dimethyl Amine acetic acid
Salt, the organic copper silicon quaternary ammonium salt of 0.8 part of octadecyl and 3 parts of sodium citrate.
Textile (umbrella cover made from above-described embodiment 1, embodiment 2, embodiment 3, embodiment 4 and comparative example 1, comparative example 2
Cloth) performance parameter be compared as follows:
Wherein color fastness is detected using GB/T 5713-2013 (textile color stability test color fastness to water).Hydrostatic
Pressure test is using standard GB/T/T4744-1997 " textile fabric water permeability resistance measures hydrostatic test ".Glue film fastness is adopted
Use company standard.Wherein, waterproof performance is that AATCC22-2014 is tested by testing standard.
| Product index project | Color fastness | Hydrostatic pressing test | Waterproof performance |
| Embodiment 1 | 4.5 grade | 9100 MM/H2O | 91 points |
| Embodiment 2 | 4.5 grade | 9000 MM/H2O | 92 points |
| Embodiment 3 | 5.0 grade | 9700 MM/H2O | 96 points |
| Embodiment 4 | 5.0 grade | 9600 MM/H2O | 95 points |
| Comparative example 1 | 3.5 grade | 7800 MM/H2O | 85 points |
| Comparative example 2 | 3.5 grade | 8000 MM/H2O | 84 points |
| Dye printing and pigment printing product on the market | 3.5 grade | 8200 MM/H2O | 72 points |
In conclusion using the color of the embodiment 1 of present invention process, embodiment 2, embodiment 3, embodiment 4 product made from it
Fastness, hydrostatic pressing and waterproof performance be better than comparative example 1 beyond processing range, comparative example 2 and on the market dye printing and
Pigment printing product.Embodiment 3, the embodiment 4 of optimization technique are especially taken, color fastness is higher than embodiment 1, embodiment 2
0.5 grade, hydrostatic pressing is also higher；Waterproof performance is also more excellent.
The various embodiments described above are merely to illustrate the present invention, wherein the structure of each component, connection type etc. are all can be
Variation, all equivalents and improvement carried out based on the technical solution of the present invention should not be excluded of the invention
Except protection scope.
Claims (10)
1. a kind of application of environment-friendly type without fluoro water proofing agent on umbrella cloth, which comprises the following steps:
1) concise: water and desizing agent being added in the fluid cylinder of scouring machine, is configured to concise liquid；After being warming up to 50-70 DEG C, by base fabric
It puts into fluid cylinder, makes concise liquid cycle rotation in fluid cylinder together with base fabric；It then heats to (80-100) DEG C, concise 30-
After 60min, venting refining liquid takes out base fabric after cold water washing is added；
2) arrange: be added in the liquid bath of collator water and 0.6-0.8g/L without fluoro water proofing agent, be configured to working fluid, and use
Acid solution tune pH, reaches 5.6-6.0；By one immersing and rolling working fluid of base fabric；Base fabric is carried out in drying and setting machine again
Drying and shaping.
2. application of the environment-friendly type as described in claim 1 without fluoro water proofing agent on umbrella cloth, which is characterized in that the refining work
Concise liquid and base fabric cycle rotation 15-20min in sequence.
3. application of the environment-friendly type as described in claim 1 without fluoro water proofing agent on umbrella cloth, which is characterized in that the refining work
In sequence, a length of 46-50min when more preferably refining.
4. application of the environment-friendly type without fluoro water proofing agent on umbrella cloth as described in claims 1 or 2 or 3, which is characterized in that described
In arranging process, the temperature of drying machine drying sizing is 160-170 DEG C.
5. application of the environment-friendly type as claimed in claim 4 without fluoro water proofing agent on umbrella cloth, which is characterized in that the finisher
In sequence, the speed of dryer operation is 60-70m/min.
6. application of the environment-friendly type without fluoro water proofing agent on umbrella cloth as described in claims 1 or 2 or 3, which is characterized in that described
Acid solution includes acetic acid, potassium dihydrogen phosphate, citric acid and stabilizer, wherein acetic acid, potassium dihydrogen phosphate and lemon in acid solution
The concentration of the three of lemon acid is respectively (2.2%-2.4%), (0.6%-1.0%) and (0.3%-0.5%), and the concentration of stabilizer is 0.5-
0.7g/L。
7. application of the environment-friendly type as claimed in claim 6 without fluoro water proofing agent on umbrella cloth, which is characterized in that described floride-free anti-
Aqua containing amino, the dimethyl silicone polymer of active hydrogen and long-chain fat alkyl and paraffin compounding by being made simultaneously；By weight
Percentage, the stabilizer include 5-7 parts of ethylene diamine tetra methylene phosphonic acid sodium, 1-3 parts of Triammonium citrates and 1-3 parts of cationic surfaces
Activating agent.
8. application of the environment-friendly type as claimed in claim 7 without fluoro water proofing agent on umbrella cloth, which is characterized in that the cation
Surfactant, by weight percentage, including 2-3 parts of Dodecyl Dimethyl Amine acetate, 0.5-0.7 parts of octadecyls are organic
Copper silicon quaternary ammonium salt and 1-2 parts of sodium citrate.
9. application of the environment-friendly type without fluoro water proofing agent on umbrella cloth as described in claims 1 or 2 or 3, which is characterized in that described
In arranging process, the pick-up in one immersing and rolling working fluid of base fabric is 74%-76%.
10. application of the environment-friendly type without fluoro water proofing agent on umbrella cloth as described in claims 1 or 2 or 3, which is characterized in that institute
State concise process, cold water washing times are that twice, when first time cold water washs, water temperature is 10-12 DEG C, when washing a length of 10-
14min；When the washing of second cold water, water temperature is 20-25 DEG C, when washing a length of 20-30min.
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Cited By (1)
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| CN110904686A (en) * | 2019-11-28 | 2020-03-24 | 浙江圣山科纺有限公司 | Application of environment-friendly fluorine-free waterproof agent to umbrella surface cloth |
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