CN109137495B - A kind of antistatic and the compound hydrosol of antibacterial and its application in field of textiles - Google Patents

A kind of antistatic and the compound hydrosol of antibacterial and its application in field of textiles Download PDF

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Publication number
CN109137495B
CN109137495B CN201811010922.5A CN201811010922A CN109137495B CN 109137495 B CN109137495 B CN 109137495B CN 201811010922 A CN201811010922 A CN 201811010922A CN 109137495 B CN109137495 B CN 109137495B
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antibacterial
antistatic
fabric
weight
parts
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CN109137495A (en
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曾朝辉
姚湘
谭艳林
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Longshan Jaoba Mei Handicraft Fabrics Co Ltd
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Longshan Jaoba Mei Handicraft Fabrics Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65—Salts of oxyacids of nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B32B2262/065—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A kind of antistatic and the compound hydrosol of antibacterial and its application in field of textiles are also beneficial to the diffusion of electrostatic wherein being added to the silver ion with excellent conductive performance, nano zine oxide etc., will not generate the phenomenon that electrostatic gathers；It is compound using chitosan and silver ion, the two cooperation synergistic effect, so that fabric has good antibacterial functions.Its application with after textile fabric; the textile fabric has good antistatic property; it can be avoided electrostatic phenomenon of the cloth textile fabric in further production process; for handicraft, practitioner is more friendly; and the product processed is not easy to adsorb and gather dust; have the function of antibacterial, can preferably protect the health of consumer.

Description

A kind of antistatic and the compound hydrosol of antibacterial and its application in field of textiles
Technical field:
The invention belongs to field of fabric producing technology, and in particular to a kind of antistatic and compound hydrosol of antibacterial and its weave The application in field.
Background technique:
With the progress of science and technology and the raising of living standards of the people, people are in production and life to textile Functionality proposes more and higher requirement, such as the comfort, aesthetics, health of product, if environmentally protective, if It can satisfy outstanding industry requirement etc..In order to meet the market demand of functional textile, accelerate opening for functional textile Hair and research, many scientific research institutions and enterprise accelerate the research steps of functional textile.Such as there is soft, heat preservation, moisture absorption The textile of the comfortable function of the features such as quick-drying, Waterproof Breathable;Have the spies such as fire-retardant, antistatic, waterproof, antiultraviolet, antibacterial The household and fabrics for industrial use of point.
Textile in production and processing and use easily because rubbing and incuding generation electrostatic, and the resistance of conventional fibrous materials Rate is 1010Ω cm or more, generated charge are not easy loss.Electrostatic phenomenon is still unknown in cellulose fibre processing It is aobvious;The electrostatic interference of protein fibre is with regard to more serious.Although wool fibre has higher equilibrium moisture regain, but its mass specific resistance Reach highest in natural fiber;The resistivity of the universal lower synthetic fibers of regain is up to 1414Ω cm or more, electricity Lotus accumulation phenomena is more significant.Wool manufacturing production in textile material electrification phenomenon often will lead to fiber winding or blocking parts, Semi-products or yarn is scared, broken end, Warp opening is unclear when weaving, and fabric folds phenomena such as uneven, influences the smooth of production It carries out;In use, the accumulation of electrostatic charge easily causes dust to adhere to, clothes tangle limbs and generate adherency sense of discomfort textile. For hand woven product or fabric toy, for weaver, there are certain injuries, such as static guiding for the presence of electrostatic PH value of blood is caused to rise, calcium content reduces in blood, calcium content increases in urine, blood glucose rise, the decline of vitamin C content etc., And electrostatic also causes dust to adsorb and gather, and seriously affects image appearance and the sale of fabrics class product.
In addition, major consumers crowd detects towards children population according to scientific research personnel: disappearing for toy production After the toy that poison is crossed is played 10 days to baby, the bacteria colonies number on plastic toy is up to more than 3000, up to close on wooden toy 5000, and it is unexpectedly a up to more than 20,000 on the toy of fur production, it also detected Escherichia coli, hepatitis type B virus in toy The problem of equal pathogenic microorganisms, pollution level is even more serious than clothes, bedding and tableware etc. therefore child stings toy, should Paid attention to.Therefore, there is also urgent demands for the anti-microbial property of fabrics or braiding type toy.
In the prior art, more for individual antistatic textile fabric research, for example, application for a patent for invention CN201310685527.8 is related to a kind of antistatic textile fabric, is made of fabric, outer shell fabric, the internal layer each component Parts by weight be 65 ~ 82 parts of pure cotton, 8 ~ 22 parts of silk, antistatic silk interweave 10 ~ 23 parts；The parts by weight of the surface layer each component Number is 61 ~ 79 parts of bamboo fibre, 11 ~ 19 parts of cotton fiber, 12 ~ 28 parts of spandex fibre.Antistatic textile fabric of the present invention is quiet with resisting Electricity Functional avoids fabric since material easily generates electrostatic between skin below for dehydration, and structure is simple, and fabric can be effectively reduced Coefficient of friction reduces the yield of electrostatic charge in friction, static electricity resistance with higher.Application for a patent for invention CN201110436608.5 discloses a kind of Antistatic nylon textile.The single fiber surface of the textile is covered with epithelium resin Layer, and epithelium resin layer is crosslinked the polyether polyurethane resin reacted and fluorine system by the end group with nylon fiber Resin is formed.The initial stage of the textile, which is charged by friction, is pressed in 2000V hereinafter, water repellent degree is at 4 grades or more, refuse oil content 4 grades with On；Home washings 20 are charged by friction pressure 2500V hereinafter, water repellent degree at 3 grades or more, refuses oil content at 3 grades or more after returning.The present invention fills out The blank that nylon textile cannot have both antistatic property, water and oil repellant performance simultaneously is mended.Application for a patent for invention CN201511028832.5 provides a kind of antibacterial fabric and preparation method thereof, and antibacterial fabric provided by the invention passes through Silver nano-grain is deposited on the textile of carried titanium dioxide to obtain；The present invention by first depositing titanium dioxide on the textile Titanium, and the pattern of the titanium dioxide deposited is flower pattern, then silver nano-grain is deposited on to the weaving of carried titanium dioxide again On product, so that the washability for the antibacterial fabric that the present invention obtains is good, and the method for preparing textile is simple, the production cycle Short, the three wastes are few.Xu Huashan etc. introduces resistance aiming at the problem that comprehensive performance of flame-retardant and anti-static fabric cannot be met the requirements Fire-retardant principle, the fire retardant mechanism of action, preparation and the flame retardant property evaluation of textile material are fired, and to the system of flame-retardant and anti-static fabric Preparation Method and points for attention are summarized (weaving report the 7th phase in 2016).
Antistatic and antibacterial characteristics textile materials are had both it is found that not yet producing at present based on the above prior art, it is special Be not for toy manufacturer or hand-made braiding production for staple market meaning have both it is antistatic and The textile fabric of antibacterial characteristics.And this be exactly current toy, braiding, cloth spinning process product production in urgent need to resolve the technical issues of.
Summary of the invention:
Antistatic and antibacterial characteristics textile materials are had both based on not developing in the prior art, are not well positioned to meet object for appreciation Tool, braiding and the production of cloth spinning process product and the market demand, the present invention is intended to provide a kind of compound hydrosol of antistatic and antibacterial and It is also beneficial to quiet in the application of field of textiles wherein being added to the silver ion with excellent conductive performance, nano zine oxide etc. The diffusion of electricity, will not generate the phenomenon that electrostatic gathers；It is compound using chitosan and silver ion, the two cooperation synergistic effect, so that Fabric has good antibacterial functions.With after textile fabric, the textile fabric has good antistatic property, energy for its application Electrostatic phenomenon of the cloth textile fabric in further production process is enough avoided, practitioner is more friendly for handicraft, and adds The product that work goes out is not easy to adsorb and gather dust, has the function of antibacterial, can preferably protect the health of consumer.
In order to solve the above technical problems, the present invention uses following technological means:
A kind of antistatic and compound hydrosol of antibacterial, which is characterized in that the compound hydrosol of described antistatic and antibacterial uses Following method is prepared:
Step 1, the polyethylene glycol of the isopropanol of 5-7 parts by weight, the nano-ZnO of 1-2 parts by weight and 2-3 parts by weight is molten Solution is in 80-85 DEG C of water of 100 parts by weight, then with glacial acetic acid according to 1:(1-1.5) volume ratio mix, obtain Composite vinegar Acid solution；
2-5 parts by weight chitosan is dissolved into the compound acetum that step 1 is prepared by step 2, and it is poly- to obtain shell Sweet and sour acid solution, then by the AgNO of 0.8-2 parts by weight3It is dissolved into chitosan-acetic acid solution that obtain Chitosan-Silver compound anti- Bacterium solution；
80-90 parts by weight ethyl orthosilicate is added to step 2 under high velocity agitation with 1 drop/sec of speed by step 3 In the Chitosan-Silver composite antibacterial solution being prepared, magnetic stirrer is quickly stirred 3 hours at room temperature, obtains chitosan- Silver-SiO2The compound hydrosol, i.e., described antistatic and compound hydrosol of antibacterial.
The antistatic and compound hydrosol of antibacterial of the present invention field of textiles application, specifically, for pair Cloth is infiltrated, and is then dried, is baked the antistatic and antibacterial textile fabric described in obtaining.
The drying refers to dries 20-30 minutes at 80-85 DEG C；The baking, which refers to, bakes 5-8 at 120-130 DEG C Minute.
The invention further relates to a kind of antistatic and antibacterial textile fabrics, are made of fabric, outer shell fabric, feature exists In the fabric is made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber.
Antistatic and antibacterial textile fabric the fabric is binded by adhesive and the outer shell fabric.
The antistatic and antibacterial textile fabric is sticking the fabric by adhesive and the outer shell fabric It is further impregnated into the antistatic and compound hydrosol of antibacterial and is infiltrated after conjunction, then drying, baking obtain described Antistatic and antibacterial textile fabric.
The fabric is to be interwoven using pure cotton as warp using intertexture with antistatic silk as weft, the outer layer surface Material is to be interwoven using bamboo fibre as warp by weft of cotton fiber.The specification that pure cotton described in fabric uses for 16.0-17.1 tex, the intertexture are 1.8-2.3tex with the specification of antistatic silk；In outer shell fabric, the rule of the bamboo fibre Lattice are 15.2-15.8 tex, and the specification of the cotton fiber is 3-5tex.
Described antistatic and antibacterial textile fabric preparation method includes the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk；It is with bamboo fibre Warp interweaves to obtain outer shell fabric as weft using cotton fiber；
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric；
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and soaks by step 3 Profit then dries, bakes the antistatic and antibacterial textile fabric described in obtaining.
The drying refers to dries 20-30 minutes at 80-85 DEG C；The baking, which refers to, bakes 5-8 at 120-130 DEG C Minute.
Based on above technical scheme, the present invention has following advantages and beneficial effects:
Firstly, inventor is based on antistatic and antibacterial demand present in toy and fabrics processing, system is originally proposed The standby a kind of antistatic and compound hydrosol of antibacterial, thus solve toy, the electrostatic hazard in fabrics production and later period sale, The problem of easily adsorbing during showing and gather dust, while the addition based on antibacterial material uses, and obtains prepared by the present invention Product have certain antibacterial activity, and poisonous and hazardous ingredient is not used in present invention production, to consumer safety, friend It is good.
Secondly, the present invention uses dual antistatic treatment technology, uses and interweave with anti-in fabric production process Electrostatic silk is weft, has good electric conductivity, can sufficiently be discharged in production and product use process since friction is led The phenomenon that electrostatic of cause gathers, on the other hand, the present invention also use the antistatic and compound hydrosol of antibacterial, wherein being added to has Silver ion, nano zine oxide of excellent conductive performance etc. are also beneficial to the diffusion of electrostatic, will not generate the phenomenon that electrostatic gathers.
Again, compound using chitosan and silver ion in the present invention, the two cooperation synergistic effect, so that fabric is with good Antibacterial functions.
In conclusion solving toy, fabrics production the present invention relates to a kind of antistatic and compound hydrosol of antibacterial In electrostatic hazard and later period sale, show during the problem of easily adsorbing and gathering dust, while adding based on antibacterial material Add use, the preparation-obtained product of the present invention has certain antibacterial activity, improves the safety of product.
Specific embodiment:
A kind of embodiment 1: antistatic and compound hydrosol of antibacterial, which is characterized in that described antistatic and antibacterial Compound Water Colloidal sol is prepared with the following method:
The polyethylene glycol of the isopropanol of 6 parts by weight, the nano-ZnO of 2 parts by weight and 3 parts by weight is dissolved in 100 by step 1 In 80-85 DEG C of water of parts by weight, is then mixed with glacial acetic acid according to the volume ratio of 1:1, obtain compound acetum；
4 parts by weight chitosans are dissolved into the compound acetum that step 1 is prepared, obtain chitosan by step 2 Acetum, then by the AgNO of 1 parts by weight3It is dissolved into chitosan-acetic acid solution and obtains Chitosan-Silver composite antibacterial solution；
85 parts by weight ethyl orthosilicates are added to step 2 preparation under high velocity agitation with 1 drop/sec of speed by step 3 In obtained Chitosan-Silver composite antibacterial solution, magnetic stirrer is quickly stirred 3 hours at room temperature, obtains Chitosan-Silver- SiO2The compound hydrosol, i.e., described antistatic and compound hydrosol of antibacterial.
A kind of embodiment 2: antistatic and compound hydrosol of antibacterial, which is characterized in that described antistatic and antibacterial Compound Water Colloidal sol is prepared with the following method:
The polyethylene glycol of the isopropanol of 7 parts by weight, the nano-ZnO of 1 parts by weight and 2 parts by weight is dissolved in 100 by step 1 In 80-85 DEG C of water of parts by weight, is then mixed with glacial acetic acid according to the volume ratio of 1:1.5, obtain compound acetum；
5 parts by weight chitosans are dissolved into the compound acetum that step 1 is prepared, obtain chitosan by step 2 Acetum, then by the AgNO of 2 parts by weight3It is dissolved into chitosan-acetic acid solution and obtains Chitosan-Silver composite antibacterial solution；
80 parts by weight ethyl orthosilicates are added to step 2 preparation under high velocity agitation with 1 drop/sec of speed by step 3 In obtained Chitosan-Silver composite antibacterial solution, magnetic stirrer is quickly stirred 3 hours at room temperature, obtains Chitosan-Silver- SiO2The compound hydrosol, i.e., described antistatic and compound hydrosol of antibacterial.
A kind of embodiment 3: antistatic and compound hydrosol of antibacterial, which is characterized in that described antistatic and antibacterial Compound Water Colloidal sol is prepared with the following method:
The polyethylene glycol of the isopropanol of 5 parts by weight, the nano-ZnO of 2 parts by weight and 3 parts by weight is dissolved in 100 by step 1 In 80-85 DEG C of water of parts by weight, is then mixed with glacial acetic acid according to the volume ratio of 1:1, obtain compound acetum；
3 parts by weight chitosans are dissolved into the compound acetum that step 1 is prepared, obtain chitosan by step 2 Acetum, then by the AgNO of 0.9 parts by weight3It is dissolved into chitosan-acetic acid solution that obtain Chitosan-Silver composite antibacterial molten Liquid；
85 parts by weight ethyl orthosilicates are added to step 2 preparation under high velocity agitation with 1 drop/sec of speed by step 3 In obtained Chitosan-Silver composite antibacterial solution, magnetic stirrer is quickly stirred 3 hours at room temperature, obtains Chitosan-Silver- SiO2The compound hydrosol, i.e., described antistatic and compound hydrosol of antibacterial.
Embodiment 4: a kind of antistatic and antibacterial textile fabric is made of fabric, outer shell fabric, which is characterized in that The fabric is made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber.
Described antistatic and antibacterial textile fabric preparation method includes the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk；It is with bamboo fibre Warp interweaves to obtain outer shell fabric as weft using cotton fiber；
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric；
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and infiltrates, then by step 3 Drying bakes the antistatic and antibacterial textile fabric described in obtaining.
The drying refers to dries 20 minutes at 85 DEG C；The baking refers to be baked 5 minutes at 130 DEG C.
The specification that pure cotton described in fabric uses is 16.0-17.1 tex, the rule to interweave with antistatic silk Lattice are 1.8-2.3tex；In outer shell fabric, the specification of the bamboo fibre is 15.2-15.8 tex, and the specification of the cotton fiber is 3-5tex。
The described antistatic and compound hydrosol of antibacterial is using the described in embodiment 1 antistatic and compound hydrosol of antibacterial.
Embodiment 5: a kind of antistatic and antibacterial textile fabric is made of fabric, outer shell fabric, which is characterized in that The fabric is made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber.
Described antistatic and antibacterial textile fabric preparation method includes the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk；It is with bamboo fibre Warp interweaves to obtain outer shell fabric as weft using cotton fiber；
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric；
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and infiltrates, then by step 3 Drying bakes the antistatic and antibacterial textile fabric described in obtaining.
The drying refers to dries 30 minutes at 80 DEG C；The baking refers to be baked 8 minutes at 120 DEG C.
The specification that pure cotton described in fabric uses is 16.0-17.1 tex, the rule to interweave with antistatic silk Lattice are 1.8-2.3tex；In outer shell fabric, the specification of the bamboo fibre is 15.2-15.8 tex, and the specification of the cotton fiber is 3-5tex。
The described antistatic and compound hydrosol of antibacterial is using the as described in example 2 antistatic and compound hydrosol of antibacterial.
Embodiment 6: a kind of antistatic and antibacterial textile fabric is made of fabric, outer shell fabric, which is characterized in that The fabric is made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber.
Described antistatic and antibacterial textile fabric preparation method includes the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk；It is with bamboo fibre Warp interweaves to obtain outer shell fabric as weft using cotton fiber；
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric；
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and infiltrates, then by step 3 Drying bakes the antistatic and antibacterial textile fabric described in obtaining.
The drying refers to dries 20 minutes at 85 DEG C；The baking refers to be baked 8 minutes at 120 DEG C.
The specification that pure cotton described in fabric uses is 16.0-17.1 tex, the rule to interweave with antistatic silk Lattice are 1.8-2.3tex；In outer shell fabric, the specification of the bamboo fibre is 15.2-15.8 tex, and the specification of the cotton fiber is 3-5tex。
The described antistatic and compound hydrosol of antibacterial is using the described in embodiment 3 antistatic and compound hydrosol of antibacterial.
Embodiment 7: antistatic test
With reference to textile machine and textile industry standard FZ/T 01042-1996, " textile material antistatic property electrostatic pressure partly declines The measurement of phase " induced electricity of test fabric on II fabric induction type electro static instrument (having an area of Instrument Ltd. in Wenzhou) of FY342E- Pressure and half-life period, wherein being compared using following comparative example 1 as reference, concrete outcome such as the following table 1:
The antistatic test result of table 1
Sample Induced voltage (V) Half-life period (s)
Comparative example 1 3200.0 8.50
Embodiment 4 2735.5 1.25
Embodiment 5 2698.0 1.10
Wherein comparative example 1 are as follows: a kind of textile fabric is made of fabric, outer shell fabric, which is characterized in that institute It states fabric and is made of pure cotton and intertexture with antistatic silk, the outer shell fabric is made of bamboo fibre and cotton fiber.The spinning The preparation method of knitted fabric includes the following steps: step 1: using pure cotton as warp, interweaving using intertexture with antistatic silk as weft To fabric；Using bamboo fibre as warp, interweave to obtain outer shell fabric as weft using cotton fiber；Step 2, by the inner layer surface Material binds to obtain the textile fabric by adhesive and the outer shell fabric.
By the result of the above table 1 it is found that preparation-obtained antistatic and antibacterial textile fabric of the invention, quiet using resisting Electricity and the compound hydrosol processing of antibacterial, induced voltage and half-life period are obviously reduced, i.e., antistatic performance has obtained greatly Improve, illustrate antistatic and antibacterial textile fabric surface of the invention can quick loss charge, assemble it can not.Compared to not Using the textile fabric of the compound hydrosol processing of antistatic and antibacterial, antistatic property has obtained greatly being promoted.
Embodiment 5: antibacterial tests
Main antibacterial characteristics of the invention are tested from the compound hydrosol processing of antistatic and antibacterial based on antibacterial activity Following comparative testing example is arranged in the needs of card, inventor:
Comparative example 2: silver-SiO2The compound hydrosol is prepared with the following method: step 1, by 5 parts by weight The polyethylene glycol of isopropanol, the nano-ZnO of 2 parts by weight and 3 parts by weight is dissolved in 80-85 DEG C of water of 100 parts by weight, then It is mixed with glacial acetic acid according to the volume ratio of 1:1, obtains compound acetum；Step 2, by the AgNO of 0.9 parts by weight3It is dissolved into In the compound acetum that step 1 is prepared, silver ion composite antibacterial solution is obtained；Step 3, by the positive silicic acid of 85 parts by weight Ethyl ester is added in the silver ion composite antibacterial solution that step 2 is prepared under high velocity agitation with 1 drop/sec of speed, room temperature Lower magnetic stirrer quickly stirs 3 hours, obtains silver-SiO2The compound hydrosol.
Comparative example 3: chitosan-SiO2The compound hydrosol is prepared with the following method: step 1, by 6 weight The isopropanol, the nano-ZnO of 2 parts by weight and the polyethylene glycol of 3 parts by weight of part are dissolved in 80-85 DEG C of water of 100 parts by weight, It is then mixed with glacial acetic acid according to the volume ratio of 1:1, obtains compound acetum；4 parts by weight chitosans are dissolved by step 2 In the compound acetum that step 1 is prepared, chitosan-acetic acid solution is obtained；Step 3, by 85 parts by weight ethyl orthosilicates It is added under high velocity agitation with 1 drop/sec of speed in the chitosan-acetic acid solution that step 2 is prepared, magnetic force stirs at room temperature It mixes machine quickly to stir 3 hours, obtains chitosan-SiO2The compound hydrosol.
Same pieces of cloth are carried out to Escherichia coli, Pseudomonas aeruginosa, staphylococcus aureus processing respectively, are then respectively put into The embodiment of the present invention 1,2, in the compound hydrosol solution of comparative test 2 and 3, the time is 15 minutes, counts big in each processing group The sterilizing rate of enterobacteria, Pseudomonas aeruginosa, staphylococcus aureus, concrete outcome such as the following table 2:
2 antibacterial tests result of table
Escherichia coli Staphylococcus aureus Pseudomonas aeruginosa
Embodiment 4 100% 100% 100%
Embodiment 5 99.8% 100% 99.7%
Comparative example 2 92.5% 87.3% 85.5%
Comparative example 3 77.7% 75.3% 70.3%
Test result based on the above table 2 is it is found that the compound hydrosol of antistatic and antibacterial of the invention is silver-colored due to using Ion and chitosan, the two cooperate, and synergistic effect is so that it is used with good sterilization and anti-microbial property compared to independent The comparative example 2 of silver ion and the comparative example 3 for individually using chitosan, bactericidal effect is greatly improved.With Upper test result shows there is synergistic effect between silver ion and chitosan in the compound hydrosol of antistatic and antibacterial, can Significantly increase the anti-microbial property of fabric.

Claims (10)

1. a kind of for toy, the compound hydrosol of antistatic and antibacterial of fabrics production, which is characterized in that described antistatic It is prepared with the following method with the compound hydrosol of antibacterial:
The polyethylene glycol of the isopropanol of 5-7 parts by weight, the nano-ZnO of 1-2 parts by weight and 2-3 parts by weight is dissolved in by step 1 In 80-85 DEG C of water of 100 parts by weight, then with glacial acetic acid according to 1:(1-1.5) volume ratio mix, it is molten to obtain compound acetic acid Liquid；
2-5 parts by weight chitosan is dissolved into the compound acetum that step 1 is prepared, obtains chitosan vinegar by step 2 Acid solution, then by the AgNO of 0.8-2 parts by weight3It is dissolved into chitosan-acetic acid solution that obtain Chitosan-Silver composite antibacterial molten Liquid；
80-90 parts by weight ethyl orthosilicate is added to step 2 preparation under high velocity agitation with 1 drop/sec of speed by step 3 In obtained Chitosan-Silver composite antibacterial solution, magnetic stirrer is quickly stirred 3 hours at room temperature, obtains Chitosan-Silver- SiO2The compound hydrosol, i.e., described antistatic and compound hydrosol of antibacterial；
The antistatic and compound hydrosol of antibacterial solve toy, the electrostatic hazard in fabrics production and later period sale, The problem of easily adsorbing during showing and gather dust, while the addition based on antibacterial material uses, preparation-obtained toy, Fabrics product has certain antibacterial activity.
2. the according to claim 1 antistatic and compound hydrosol of antibacterial, which is characterized in that described antistatic and antibacterial is multiple Heshui colloidal sol is prepared with the following method:
The polyethylene glycol of the isopropanol of 6 parts by weight, the nano-ZnO of 2 parts by weight and 3 parts by weight is dissolved in 100 weight by step 1 In 80-85 DEG C of the water of part, is then mixed with glacial acetic acid according to the volume ratio of 1:1, obtain compound acetum；
4 parts by weight chitosans are dissolved into the compound acetum that step 1 is prepared, obtain chitosan acetic acid by step 2 Solution, then by the AgNO of 1 parts by weight3It is dissolved into chitosan-acetic acid solution and obtains Chitosan-Silver composite antibacterial solution；
85 parts by weight ethyl orthosilicates are added to step 2 under high velocity agitation with 1 drop/sec of speed and are prepared by step 3 Chitosan-Silver composite antibacterial solution in, magnetic stirrer quickly stirs 3 hours at room temperature, obtains Chitosan-Silver-SiO2It is multiple Heshui colloidal sol, i.e., described antistatic and compound hydrosol of antibacterial.
3. the according to claim 1 antistatic and compound hydrosol of antibacterial, which is characterized in that described antistatic and antibacterial is multiple Heshui colloidal sol is prepared with the following method:
The polyethylene glycol of the isopropanol of 7 parts by weight, the nano-ZnO of 1 parts by weight and 2 parts by weight is dissolved in 100 weight by step 1 In 80-85 DEG C of the water of part, is then mixed with glacial acetic acid according to the volume ratio of 1:1.5, obtain compound acetum；
5 parts by weight chitosans are dissolved into the compound acetum that step 1 is prepared, obtain chitosan acetic acid by step 2 Solution, then by the AgNO of 2 parts by weight3It is dissolved into chitosan-acetic acid solution and obtains Chitosan-Silver composite antibacterial solution；
80 parts by weight ethyl orthosilicates are added to step 2 under high velocity agitation with 1 drop/sec of speed and are prepared by step 3 Chitosan-Silver composite antibacterial solution in, magnetic stirrer quickly stirs 3 hours at room temperature, obtains Chitosan-Silver-SiO2It is multiple Heshui colloidal sol, i.e., described antistatic and compound hydrosol of antibacterial.
4. the of any of claims 1-3 antistatic and compound hydrosol of antibacterial is in the application of field of textiles, specifically, For being infiltrated to cloth, then dries, bakes the antistatic and antibacterial textile fabric described in obtaining, it is described antistatic and anti- Bacterium textile fabric is the fabric for toy, fabrics production.
5. application according to claim 4, the drying refers to dries 20-30 minutes at 80-85 DEG C；The baking is Finger bakes 5-8 minutes at 120-130 DEG C.
6. a kind of antistatic and antibacterial textile fabric, which is characterized in that in described antistatic and antibacterial textile fabric preparation process It is handled to obtain using the described in any item antistatic and compound hydrosols of antibacterial of claim 1-3, it is described antistatic and anti- Bacterium textile fabric is the fabric for toy, fabrics production.
7. according to claim 6 antistatic and antibacterial textile fabric, which is characterized in that the processing refers to using power Benefit requires the described in any item antistatic and compound hydrosols of antibacterial of 1-3 to infiltrate cloth, then dries, bakes and obtain institute The antistatic and antibacterial textile fabric stated.
8. according to claim 6 antistatic and antibacterial textile fabric, which is characterized in that by fabric, outer shell fabric Composition, the fabric are made of pure cotton and intertexture with antistatic silk, and the outer shell fabric is made of bamboo fibre and cotton fiber；
Antistatic and antibacterial textile fabric the fabric is binded by adhesive and the outer shell fabric；
The antistatic and antibacterial textile fabric is after binding the fabric by adhesive and the outer shell fabric It is infiltrated in the antistatic and compound hydrosol of antibacterial described in being further impregnated into, then dries, bakes resisting described in obtaining Electrostatic and antibacterial textile fabric.
9. according to claim 8 antistatic and antibacterial textile fabric, which is characterized in that the fabric is with pure cotton It for warp, is interwoven using intertexture with antistatic silk as weft, the outer shell fabric is to be with cotton fiber using bamboo fibre as warp Weft is interwoven；The specification that pure cotton described in fabric uses is described to interweave with antistatic silk for 16.0-17.1 tex Specification be 1.8-2.3tex；In outer shell fabric, the specification of the bamboo fibre is 15.2-15.8 tex, the rule of the cotton fiber Lattice are 3-5tex.
10. the preparation method of antistatic and antibacterial textile fabric according to claim 6, which is characterized in that it is described resist it is quiet The preparation method of electricity and antibacterial textile fabric includes the following steps:
Step 1: using pure cotton as warp, interweave to obtain fabric as weft using intertexture with antistatic silk；It is warp with bamboo fibre Line interweaves to obtain outer shell fabric as weft using cotton fiber；
The fabric is binded to obtain basic fabric by step 2 by adhesive and the outer shell fabric；
The basic fabric of step 2 is impregnated into the antistatic and compound hydrosol of antibacterial and infiltrates by step 3, and It dries afterwards, bake the antistatic and antibacterial textile fabric described in obtaining.
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