CN1078005A - A kind of manufacture method of antistatic, antiseptic and deodorant fabrics - Google Patents
A kind of manufacture method of antistatic, antiseptic and deodorant fabrics Download PDFInfo
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- CN1078005A CN1078005A CN 92102766 CN92102766A CN1078005A CN 1078005 A CN1078005 A CN 1078005A CN 92102766 CN92102766 CN 92102766 CN 92102766 A CN92102766 A CN 92102766A CN 1078005 A CN1078005 A CN 1078005A
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- fabric
- manufacture method
- antistatic
- acrylic fibers
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Abstract
The present invention is a kind of manufacture method of antistatic, antiseptic and deodorant fabrics.Belong to the modification of acrylic fibers is handled.The technology that adopts is for firmly be grafted on the relevant group of acrylic fibers the cation group of copper ion and some basic-dyeable fibre by chemical reaction.Recipe ingredient is copper sulphate, sodium thiosulfate, natrium citricum and some basic-dyeable fibre.This modified acrylic fibers antibacterial action is good, and can be antistatic.The footgear, underwear, indoor amenities, health that can be used for making antibacterial and deodouring is with Work Clothes etc.
Description
The present invention is a kind of manufacture method of antistatic, antiseptic and deodorant fabrics, belongs to the technical field that modifying orlon is handled.
Textiles is the good medium of microbial adhesion, breeding and propagation.If textiles is carried out antibiotic finish, make it have antibacterial or kill the function of bacterium, can reduce or eliminate the harm that microorganism brings to people, promote the healthy of people.Along with the progress of science and the raising of living standards of the people, in recent years, people have proposed many higher requirements to the sanitation performance of textiles.Various types of textiless with antibacterial and deodouring function constantly occur.Acrylic fibers-copper sulfide class antiseptic and deodorant fabrics is exactly wherein a kind of.
Since the eighties, the sulfide that some countries have delivered with copper combines the report that the conductive fiber of making has antibacterial action with acrylic fibers
[1]The document that has
[2] [3] [4]Proposed acrylic fibers and handled the conductive fiber that to make function admirable through reduction with bivalent cupric ion and sulfur-containing compound (sodium thiosulfate etc.).Its action principle is that the cyano group complexing of copper ion and acrylic fibers makes it have electric conductivity and antibiotic property.But this conductive fiber acquires a certain degree of difficulty in dyeing, and directly making civilian weaving amenities sale has certain difficulty.According to the interrelated data introduction, the basic-dyeable fibre of some band positive electricity has certain antibacterial action.At present, the anti-microbial property sold of market antibiotic odourproof fiber and fabric preferably.Its action principle has improved antibacterial ability for to connect copper ion and Viride Nitens 4 cation groups simultaneously on acrylic fibers, enlarges antibacterial range.But this fiber does not have antistatic property, and range of application is under some influence.
The objective of the invention is to propose a kind of manufacture method of antistatic, antiseptic and deodorant fabrics.Make the anti-microbial property of this fabric more remarkable, and enlarged range of application.
The technology that the present invention adopts firmly is grafted on the relevant group of acrylic fibers with the cation group of some basic-dyeable fibre (as Viride Nitens, alkalescence orchid, basic fuchsin etc.) for make copper ion by chemical reaction, makes fibre modification.
Prescription of the present invention is: copper sulphate: sodium thiosulfate: natrium citricum: basic-dyeable fibre=1: (0.01-0.3): (0.05-0.1): (0.05-0.5): (weight ratio) copper sulfate solution bulk concentration is 0.5-2%.
Manufacture method of the present invention is: be mixed with the aqueous solution of copper sulphate and sodium thiosulfate by above-mentioned prescription with demineralized water, acrylic fibers (fiber or fabric) are put into, control bath raio 1: (50-100), temperature is 35-75 ℃.0.5 after hour fiber or fabric are taken out, clean.Put into the aqueous solution that is added with basic-dyeable fibre then, transfer PH4-5, temperature is 70-100 ℃, takes out after 1 hour and cleans, dries.
Fabric of the present invention has good washability and security, and anti-microbial property reaches the level of domestic better antiseptic and deodorant fabrics.To gram-positive bacteria, more remarkable as effects such as golden grape, Fructus Vins, hay bacilluses.This modified acrylic fibers also has antistatic effect preferably, is 1 * 10 than resistance
4-1 * 10
8Ω cm
-1Above the acrylic fibers that antistatic property is arranged, dust are difficult for being adsorbed on, make its range of application more extensive.The shoe-pad, socks, underwear, indoor amenities, health that can be used for making antibacterial and deodouring is with Work Clothes etc.
Implement 1:
5 gram acrylic fibers (21) are put into 500 milliliters of aqueous solution that contain the natrium citricum of 5 gram copper sulphate, 0.5 gram thio-acid sodium and 0.05 gram, be warmed up to 60-75 ℃, be incubated 0.5 hour.Take out to put into after fiber is cleaned and contain 0.12% the blue aqueous solution of alkalescence, transfer PH4-5 with acetic acid, temperature 70-100 ℃, be incubated 1 hour, taking-up is dried, and puts in order.
Example 2:
5 gram acrylic fibers cloth are put into 400 milliliters contain the aqueous solution that 4 gram copper sulphate, 1 gram sulfo-restrain sour sodium and 0.4 gram natrium citricum, be warmed up to 60-75 ℃, be incubated 0.5 hour, take out and put into the aqueous solution that contains 0.15% Viride Nitens after acrylic fibers cloth is cleaned, transfer PH 4-5 with acetic acid, temperature 70-100 ℃, be incubated 1 hour, taking-up is dried, arrangement.
List of references:
(1) macromolecule association annual meeting report, 1982, vol 31(day).
(2) rich portion believes two Fiber association will 1985,41(7).
（3）JK 55-51873
（4）JK 56-128311
Claims (3)
1, a kind of manufacture method of antistatic antibiotic deodorant fabric is characterized in that fabric-modifying handles by prescription: copper sulphate: sodium thiosulfate: natrium citricum: basic-dyeable fibre=1: (0.01-0.3): (0.05-0.1): (0.05-0.5) carry out.The copper sulfate solution bulk concentration is 0.5-2%.Bath raio 1: (50-100).
2, the manufacture method of antistatic antibiotic deodorant fabric according to claim 1, the manufacturing technique that it is characterized in that it is: prepare copper sulphate with demineralized water, the aqueous solution of sodium thiosulfate and natrium citricum is put into acrylic fabric (fiber), temperature is 35-75 ℃, takes out after 0.5 hour.Then fabric is put into the aqueous solution that contains basic-dyeable fibre, temperature is 70-100 ℃, PH 4-5.
3,, it is characterized in that the fabric of making can be used for making shoe-pad, socks, underwear, indoor article, health with Work Clothes etc. according to the manufacture method of claim 1 and 2 described antistatic antibiotic deodorant fabrics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92102766 CN1078005A (en) | 1992-04-21 | 1992-04-21 | A kind of manufacture method of antistatic, antiseptic and deodorant fabrics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92102766 CN1078005A (en) | 1992-04-21 | 1992-04-21 | A kind of manufacture method of antistatic, antiseptic and deodorant fabrics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1078005A true CN1078005A (en) | 1993-11-03 |
Family
ID=4939831
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92102766 Pending CN1078005A (en) | 1992-04-21 | 1992-04-21 | A kind of manufacture method of antistatic, antiseptic and deodorant fabrics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1078005A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101716019B (en) * | 2009-12-16 | 2012-05-30 | 深圳市新纶科技股份有限公司 | Antistatic antibiotic sock |
| CN104963191A (en) * | 2015-07-22 | 2015-10-07 | 湖南莎丽袜业股份有限公司 | Copper ion fiber prepared by two-step method and socks |
| CN105369608A (en) * | 2015-12-28 | 2016-03-02 | 河南省科学院化学研究所有限公司 | Functional fibers loaded with copper (II) ions and synthetic method of functional fibers |
| CN105483887A (en) * | 2015-11-18 | 2016-04-13 | 安徽新虹纺织有限公司 | Preparation method of antibacterial blended yarn |
| CN105603737A (en) * | 2015-12-21 | 2016-05-25 | 无锡科莱欣机电制造有限公司 | Antibacterial dustproof textile dye |
-
1992
- 1992-04-21 CN CN 92102766 patent/CN1078005A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101716019B (en) * | 2009-12-16 | 2012-05-30 | 深圳市新纶科技股份有限公司 | Antistatic antibiotic sock |
| CN104963191A (en) * | 2015-07-22 | 2015-10-07 | 湖南莎丽袜业股份有限公司 | Copper ion fiber prepared by two-step method and socks |
| CN105483887A (en) * | 2015-11-18 | 2016-04-13 | 安徽新虹纺织有限公司 | Preparation method of antibacterial blended yarn |
| CN105483887B (en) * | 2015-11-18 | 2017-06-27 | 安徽新虹纺织有限公司 | A kind of anti-bacterial blended yarn preparation method |
| CN105603737A (en) * | 2015-12-21 | 2016-05-25 | 无锡科莱欣机电制造有限公司 | Antibacterial dustproof textile dye |
| CN105369608A (en) * | 2015-12-28 | 2016-03-02 | 河南省科学院化学研究所有限公司 | Functional fibers loaded with copper (II) ions and synthetic method of functional fibers |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |