CN109129852A - Environment-friendly type fine spar architectural ornament plate and its processing technology - Google Patents
Environment-friendly type fine spar architectural ornament plate and its processing technology Download PDFInfo
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- CN109129852A CN109129852A CN201710455133.1A CN201710455133A CN109129852A CN 109129852 A CN109129852 A CN 109129852A CN 201710455133 A CN201710455133 A CN 201710455133A CN 109129852 A CN109129852 A CN 109129852A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/04—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
- B28B11/048—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers by spraying or projecting
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Abstract
The invention discloses a kind of environment-friendly type fine spar architectural ornament board machining process comprising following steps: (1) substrate chooses process, chooses high emulation fireproof substrate, and carry out performance detection, chooses the substrate for meeting decorative panel GB8624-2006 standard；(2) substrate preprocessing process carries out preprocessing to selected substrate, keeps substrate surface flat and smooth, closely knit；(3) priming paint roller coating or spraying process, the substrate surface after preprocessing carry out priming paint roller coating or spraying, form transition zone, play the anastomosis between substrate and finishing coat；(4) transfer or printing process carry out transfer or printing process on the substrate after roller coating or spray-applied primer, by the transfer of emulation pattern or are printed on substrate, and solidifying and setting；(5) postprocessing working procedures carry out showering, coating processing to substrate, complete entire environment-friendly type fine spar architectural ornament board machining process process.The present invention has a series of good characteristics such as body is light, matter is soft, porous, sound insulation, heat-resisting, acidproof, large specific surface area and chemical property are stablized using diatomite, the Kieselguhr composite decoration plate of production has low conductivity to sound, heat, electricity, the advantages that zero formaldehyde, water proof fire retardant, there is nailable, sawable, planable processing characteristic simultaneously, can be widely used for home interior external decoration.
Description
Technical field
The present invention relates to a kind of fire-resistant decoration plate and preparation method thereof and including the fire proofing of the fire-resistant decoration plate.
Background technique
In the prior art, the type of ornament materials is many in the world at home, many high emulation of indoor furniture industry
Dalle, there are two types of mode: a kind of achieving the purpose that emulation by the way of pasting printing paper, and another kind is by direct
The purpose of printing reaches simulated effect.But these are all made on the substrate of wooden splint etc..Because timber is to glue, paint, ink
Affinity is all very good, and adhesive force is not present, the problem being layered etc..When paint and ink are made in cement concrete and others
When on fire-retardant decorative substrate, since the characteristic of this this material is poor to the affinity of oils, just there is the problems such as adhesive force, layering.This
Invention is high emulation fire-proof decorative board, is completed according to the principle of printing or transfer, and fireproof substrate, cement matrix and oil are breached
The consistency problem of paint, the problems such as solving the processing of substrate and improve adhesive force.Wood-plastic material, since it is with very high anti-
Fire, plasticity and sound-proofing, have both high-environmental, nuisanceless, pollution-free, recyclable, and alternative color and
The material mostly favor by more and more people.It is substantially stable for the moulding process of insulating plastic pipe at present, but in life
There are still the problems that some costs are excessively high, condition is harsh, bonding is insecure etc. during producing.
Summary of the invention
The purpose of the present invention is make Kieselguhr composite decoration plate and its production technology by primary raw material of diatomite.
To achieve the above object, the adopted technical solution is that:
A kind of environment-friendly type fine spar architectural ornament board machining process, which is characterized in that itself the following steps are included:
(1) substrate chooses process, chooses high emulation fireproof substrate, and carry out performance detection, selection meets decorative panel
The substrate of GB8624-2006 standard；
(2) substrate preprocessing process carries out preprocessing to selected substrate, keeps substrate surface flat and smooth, closely knit；
(3) priming paint roller coating or spraying process, the substrate surface after preprocessing carry out priming paint roller coating or spraying, form transition zone,
Play the anastomosis between substrate and finishing coat；
(4) transfer or printing process carry out transfer or printing process on the substrate after roller coating or spray-applied primer, will emulate pattern
It transfers or is printed on substrate, and solidifying and setting；
(5) postprocessing working procedures carry out showering, coating processing to substrate, complete entire environment-friendly type fine spar architectural ornament plate processing
Process flow；In the step (1),
Itself the following steps are included:
(11) high emulation fireproof substrate is chosen, it is magnesite environment protection pressed-fibre board or cement fibrolite plate, the height which, which emulates fireproof substrate,
Emulate fireproof substrate fire-proof insulation, A grades non-ignitable, waterproof and dampproof, light high-strength, safe and harmless, processable and secondary decoration performance
It is good；
(12) physics and chemical detection are carried out, content of formaldehyde, the width for measuring height emulation fireproof substrate penetrate index, mechanical property refers to
Mark chooses the material for meeting decorative panel GB8624-2006, carries out trip and drenches chloride ion content detection, water is detected containing rate；The step
Suddenly in (2) comprising following steps:
(21) fixed thick sanding, dedusting, the height emulate fireproof substrate and pass through three groups of contact calibrating machines of heavy type 120-180-240 purpose
Fixed thickness, it is ensured that the consistency of product quality, then the dust on surface is removed by dust removal machine, it is ensured that surface strength；
(22) bottom is permeated, the material of high penetration is penetrated by coating roller the high emulation fireproof substrate after the dedusting
In, so that the thick position of high emulation fireproof substrate face table 0.5 to 1mm is become unusual closely knit, to strengthen the combination of interlayer；
(23) soil is mended, native machine is mended using heavy type, the free time thatch on height emulation fireproof substrate surface is filled up using high-strength UV powder of lacquer putty for use on,
Powder of lacquer putty for use on bottom is formed, high emulation fireproof substrate smooth surface is made；
(24) light is solid, solidifies powder of lacquer putty for use on bottom by UV-light photocuring machine；
(25) heavy sanding is rolled, it is ensured that the height emulates fireproof substrate surface quality, sand using two groups of sand of heavy 240-360 purpose
Guarantee that powder of lacquer putty for use on underlayer thickness thinnest part is not more than 5um after light is complete；
In the step (3) comprising following steps:
(31) priming paint carries out priming paint roller coating or spraying process on height emulation fireproof substrate surface after sanding is complete, this layer is transition zone,
The anastomosis of high emulation fireproof substrate and finishing coat is played, the film thickness for spraying or smearing is 10-20um；
(32) priming paint sanding guarantees product surface flatness and increases surface roughness, improves the adhesive force between upper and lower level, bottom
Painting sand is double rolling light weight sand high precision sanders, precision controlling 5um；
In the step (4) comprising following steps:
(41) it transfers or prints pretreatment, after priming paint sanding, painted using UV high viscosity, by being applied with machine, formed on priming paint
The adhesive layer of one of 5um-10um；
(42) it transfers or prints, transfer interpreter or printing machine are entered by conveyer, the transfer of preset emulation pattern or print
A kind of Kieselguhr composite decoration plate, it is characterised in that: the parts by weight of raw materials composition of the decorative panel is made are as follows:
50~70 polyvinyl chloride of diatomite, 30~50 processing aid 5~10；
The processing aid includes following substance, the parts by weight composition of each substance are as follows:
A, heat stabilizer: calcium stearate, zinc stearate and organotin 1.6~3.2, wherein calcium stearate in heat stabilizer, hard
Resin acid zinc and organotin parts by weight are respectively 0.95~1.9,0.35~0.7 and 0.3~0.6
B, fire retardant: tricresyl phosphate 1~2
C, antioxidant: antioxidant 1076 0.5~1
D, impact modifying agent: haloflex 1.5~3
E, lubricant: stearic acid, paraffin 0.4~0.8
Wherein stearic acid, paraffin parts by weight are respectively 0.15~0.3 and 0.25~0.5 in lubricant.
Tricresyl phosphate (β-chloro-ethyl ester) is added in fire retardant tricresyl phosphate in the processing aid, parts by weight
Respectively 0.75~1.5 and 0.25~0.5.
UV-531 is added in the processing aid in antioxidant 1076, parts by weight are respectively 0.3~0.6 He
0.2~0.4；Acrylic resin ACR, parts by weight are added in the processing aid in impact modifying agent haloflex
Respectively 1~2 and 0.5~1.
The invention has the benefit that production technology of the present invention is rationally easy to operate, high production efficiency, quality of production stabilization can
It leans on, material used is environment friendly decoration board substrate, and material advantage is insect prevention, mothproof, fire prevention, is free of formaldehyde, high-strength, good toughness
The features such as, solve wooden splint not insect prevention, it is not mothproof, do not prevent fires, the deficiency that content of formaldehyde is exceeded, solve granite substrate
High-strength frangible, weight weight deficiency.This environment friendly decoration board substrate is using recycling and reusings material and other gelling materials such as flyash
Material is made, and is more conducive to environmental protection.Ecology will not be destroyed because exploiting rock.
Specific embodiment
A kind of environment-friendly type fine spar architectural ornament board machining process, which is characterized in that itself the following steps are included:
(1) substrate chooses process, chooses high emulation fireproof substrate, and carry out performance detection, selection meets decorative panel
The substrate of GB8624-2006 standard；
(2) substrate preprocessing process carries out preprocessing to selected substrate, keeps substrate surface flat and smooth, closely knit；
(3) priming paint roller coating or spraying process, the substrate surface after preprocessing carry out priming paint roller coating or spraying, form transition zone,
Play the anastomosis between substrate and finishing coat；
(4) transfer or printing process carry out transfer or printing process on the substrate after roller coating or spray-applied primer, will emulate pattern
It transfers or is printed on substrate, and solidifying and setting；
(5) postprocessing working procedures carry out showering, coating processing to substrate, complete entire environment-friendly type fine spar architectural ornament plate processing
Process flow；In the step (1),
Itself the following steps are included:
(11) high emulation fireproof substrate is chosen, it is magnesite environment protection pressed-fibre board or cement fibrolite plate, the height which, which emulates fireproof substrate,
Emulate fireproof substrate fire-proof insulation, A grades non-ignitable, waterproof and dampproof, light high-strength, safe and harmless, processable and secondary decoration performance
It is good；
(12) physics and chemical detection are carried out, content of formaldehyde, the width for measuring height emulation fireproof substrate penetrate index, mechanical property refers to
Mark chooses the material for meeting decorative panel GB8624-2006, carries out trip and drenches chloride ion content detection, water is detected containing rate；The step
Suddenly in (2) comprising following steps:
(21) fixed thick sanding, dedusting, the height emulate fireproof substrate and pass through three groups of contact calibrating machines of heavy type 120-180-240 purpose
Fixed thickness, it is ensured that the consistency of product quality, then the dust on surface is removed by dust removal machine, it is ensured that surface strength；
(22) bottom is permeated, the material of high penetration is penetrated by coating roller the high emulation fireproof substrate after the dedusting
In, so that the thick position of high emulation fireproof substrate face table 0.5 to 1mm is become unusual closely knit, to strengthen the combination of interlayer；
(23) soil is mended, native machine is mended using heavy type, the free time thatch on height emulation fireproof substrate surface is filled up using high-strength UV powder of lacquer putty for use on,
Powder of lacquer putty for use on bottom is formed, high emulation fireproof substrate smooth surface is made；
(24) light is solid, solidifies powder of lacquer putty for use on bottom by UV-light photocuring machine；
(25) heavy sanding is rolled, it is ensured that the height emulates fireproof substrate surface quality, sand using two groups of sand of heavy 240-360 purpose
Guarantee that powder of lacquer putty for use on underlayer thickness thinnest part is not more than 5um after light is complete；
In the step (3) comprising following steps:
(31) priming paint carries out priming paint roller coating or spraying process on height emulation fireproof substrate surface after sanding is complete, this layer is transition zone,
The anastomosis of high emulation fireproof substrate and finishing coat is played, the film thickness for spraying or smearing is 10-20um；
(32) priming paint sanding guarantees product surface flatness and increases surface roughness, improves the adhesive force between upper and lower level, bottom
Painting sand is double rolling light weight sand high precision sanders, precision controlling 5um；
In the step (4) comprising following steps:
(41) it transfers or prints pretreatment, after priming paint sanding, painted using UV high viscosity, by being applied with machine, formed on priming paint
The adhesive layer of one of 5um-10um；
(42) it transfers or prints, transfer interpreter or printing machine are entered by conveyer, the transfer of preset emulation pattern or print
A kind of Kieselguhr composite decoration plate, it is characterised in that: the parts by weight of raw materials composition of the decorative panel is made are as follows: diatomite 50~
70 polyvinyl chloride, 30~50 processing aid 5~10；
The processing aid includes following substance, the parts by weight composition of each substance are as follows:
A, heat stabilizer: calcium stearate, zinc stearate and organotin 1.6~3.2, wherein calcium stearate in heat stabilizer, hard
Resin acid zinc and organotin parts by weight are respectively 0.95~1.9,0.35~0.7 and 0.3~0.6
B, fire retardant: tricresyl phosphate 1~2
C, antioxidant: antioxidant 1076 0.5~1
D, impact modifying agent: haloflex 1.5~3
E, lubricant: stearic acid, paraffin 0.4~0.8
Wherein stearic acid, paraffin parts by weight are respectively 0.15~0.3 and 0.25~0.5 in lubricant.
Tricresyl phosphate (β-chloro-ethyl ester) is added in fire retardant tricresyl phosphate in the processing aid, parts by weight
Respectively 0.75~1.5 and 0.25~0.5.
UV-531 is added in the processing aid in antioxidant 1076, parts by weight are respectively 0.3~0.6 He
0.2~0.4；Acrylic resin ACR, parts by weight are added in the processing aid in impact modifying agent haloflex
Respectively 1~2 and 0.5~1.
The plug-in stone material for exterior decorative materials, decorative stone weight increase the cost of construction and decoration attachment.And mesh
All stone materials of preceding exploitation are very big to environmental disruption.And there are resource withered the phenomenon that taking off for more precious material.
Production technology of the present invention is rationally easy to operate, and high production efficiency, the quality of production is reliable and stable, and material used is environmental protection
Decorative panel substrate, material advantage be insect prevention, mothproof, fire prevention, without formaldehyde, high-strength, good toughness the features such as, solve wooden splint
Not insect prevention, it is not mothproof, do not prevent fires, the deficiency that content of formaldehyde is exceeded, solve high-strength frangible, the weight weight of granite substrate not
Foot.This environment friendly decoration board substrate is made of the recycling and reusings materials such as flyash and other cementitious materials, is more conducive to ring
It protects.Ecology will not be destroyed because exploiting rock.
The above disclosure is only a preferred embodiment of the invention, cannot limit the right of the present invention with this certainly
Range, therefore according to equivalent variations made by scope of the present invention patent, it is still within the scope of the present invention.
Claims (9)
1. a kind of environment-friendly type fine spar architectural ornament board machining process, which is characterized in that itself the following steps are included:
(1) substrate chooses process, chooses high emulation fireproof substrate, and carry out performance detection, selection meets decorative panel
The substrate of GB8624-2006 standard；
(2) substrate preprocessing process carries out preprocessing to selected substrate, keeps substrate surface flat and smooth, closely knit；
(3) priming paint roller coating or spraying process, the substrate surface after preprocessing carry out priming paint roller coating or spraying, form transition zone,
Play the anastomosis between substrate and finishing coat；
(4) transfer or printing process carry out transfer or printing process on the substrate after roller coating or spray-applied primer, will emulate pattern
It transfers or is printed on substrate, and solidifying and setting；
(5) postprocessing working procedures carry out showering, coating processing to substrate, complete entire environment-friendly type fine spar architectural ornament plate processing
Process flow；In the step (1),
Itself the following steps are included:
(11) high emulation fireproof substrate is chosen, it is magnesite environment protection pressed-fibre board or cement fibrolite plate, the height which, which emulates fireproof substrate,
Emulate fireproof substrate fire-proof insulation, A grades non-ignitable, waterproof and dampproof, light high-strength, safe and harmless, processable and secondary decoration performance
It is good；
(12) physics and chemical detection are carried out, content of formaldehyde, the width for measuring height emulation fireproof substrate penetrate index, mechanical property refers to
Mark chooses the material for meeting decorative panel GB8624-2006, carries out trip and drenches chloride ion content detection, water is detected containing rate；The step
Suddenly in (2) comprising following steps:
(21) fixed thick sanding, dedusting, the height emulate fireproof substrate and pass through three groups of contact calibrating machines of heavy type 120-180-240 purpose
Fixed thickness, it is ensured that the consistency of product quality, then the dust on surface is removed by dust removal machine, it is ensured that surface strength；
(22) bottom is permeated, the material of high penetration is penetrated by coating roller the high emulation fireproof substrate after the dedusting
In, so that the thick position of high emulation fireproof substrate face table 0.5 to 1mm is become unusual closely knit, to strengthen the combination of interlayer；
(23) soil is mended, native machine is mended using heavy type, the free time thatch on height emulation fireproof substrate surface is filled up using high-strength UV powder of lacquer putty for use on,
Powder of lacquer putty for use on bottom is formed, high emulation fireproof substrate smooth surface is made；
(24) light is solid, solidifies powder of lacquer putty for use on bottom by UV-light photocuring machine；
(25) heavy sanding is rolled, it is ensured that the height emulates fireproof substrate surface quality, sand using two groups of sand of heavy 240-360 purpose
Guarantee that powder of lacquer putty for use on underlayer thickness thinnest part is not more than 5um after light is complete；
In the step (3) comprising following steps:
(31) priming paint carries out priming paint roller coating or spraying process on height emulation fireproof substrate surface after sanding is complete, this layer is transition zone,
The anastomosis of high emulation fireproof substrate and finishing coat is played, the film thickness for spraying or smearing is 10-20um；
(32) priming paint sanding guarantees product surface flatness and increases surface roughness, improves the adhesive force between upper and lower level, bottom
Painting sand is double rolling light weight sand high precision sanders, precision controlling 5um；
In the step (4) comprising following steps:
(41) it transfers or prints pretreatment, after priming paint sanding, painted using UV high viscosity, by being applied with machine, formed on priming paint
The adhesive layer of one of 5um-10um；
(42) it transfers or prints, transfer interpreter or printing machine are entered by conveyer, the transfer of preset emulation pattern or print
A kind of Kieselguhr composite decoration plate, it is characterised in that: the parts by weight of raw materials composition of the decorative panel is made are as follows:
50~70 polyvinyl chloride of diatomite, 30~50 processing aid 5~10；
The processing aid includes following substance, the parts by weight composition of each substance are as follows:
A, heat stabilizer: calcium stearate, zinc stearate and organotin 1.6~3.2, wherein calcium stearate in heat stabilizer, hard
Resin acid zinc and organotin parts by weight are respectively 0.95~1.9,0.35~0.7 and 0.3~0.6
B, fire retardant: tricresyl phosphate 1~2
C, antioxidant: antioxidant 1076 0.5~1
D, impact modifying agent: haloflex 1.5~3
E, lubricant: stearic acid, paraffin 0.4~0.8
Wherein stearic acid, paraffin parts by weight are respectively 0.15~0.3 and 0.25~0.5 in lubricant.
2. tricresyl phosphate (β-chloro-ethyl ester) is added in fire retardant tricresyl phosphate in processing aid described in, parts by weight point
It Wei 0.75~1.5 and 0.25~0.5.
3. UV-531 is added in processing aid described in antioxidant 1076, parts by weight are respectively 0.3~0.6 and 0.2
~0.4；Acrylic resin ACR, parts by weight difference is added in the processing aid in impact modifying agent haloflex
For 1~2 and 0.5~1.
4. environment-friendly type fine spar architectural ornament board machining process described in claim 1, it is characterised in that:
A, by diatomite original soil, embryo, drying, crushing, selection by winnowing are beaten, its granularity is made to reach 600 mesh or more；
B, the diatomite that granularity is reached to 600 mesh or more is spare by surface activation process；
C, diatomite is added in high-speed mixer bucket, temperature reaches 100 degree under high revolving speed, and moisture is excluded；
D, hard polyvinyl chloride of the degree of polymerization 800 or so is added under the slow-speed of revolution；
E, processing aid is added under 80 degree or so, high revolving speed in temperature；
F, temperature is discharged in the cooling mixing tank that material to host has rotated under the slow-speed of revolution at 120~125 degree；
G, the cold temperature of charge that mixes is down to 40 degree or so, and discharging is packed into container；
H, the material being put into extruder hopper, extruder screw temperature is respectively as follows: 150 DEG C, 170 DEG C, 185 DEG C, 195 DEG C,
Skinning forms in the case that skinning die head temperature is 180 DEG C, skinning section temperature is 80 DEG C, then through shaper water-cooled shaping, together
Step traction, fixed length cut into required size.
5. the first step mixes material, second step squeezes out mixed material investment extruder, third step sizing, and the 4th step is viscous
It closes, the cutting of the 5th step is packaged.
6. environment-friendly type fine spar architectural ornament board machining process described in claim 1, it is characterised in that the first step is by object
Material mixing, is material polystyrene, the wood fibre, foaming that will first be used for the foam thermal insulation wood plastic layer of Foam heat-insulation wood-plastic board
Agent, binder, plasticizer are uniformly mixed in continuous high-speed mixing machine.
7. environment-friendly type fine spar architectural ornament board machining process described in claim 1, it is characterised in that the second step is logical
It crosses dosing feeder and mixed material is put into extruder extrusion molding, meanwhile, it is squeezed simultaneously in an other extruder
It is used for the waterproof and dampproof layer of common PP, PE of the Foam heat-insulation wood-plastic board bottom out.
8. environment-friendly type fine spar architectural ornament board machining process described in claim 1, it is characterised in that the third step be by
The foam thermal insulation wood plastic layer of extrusion and waterproof and dampproof layer are formed respectively.
9. environment-friendly type fine spar architectural ornament board machining process described in claim 1, it is characterised in that the 4th step is viscous
Conjunction is top layer's bonding decoration while foam thermal insulation wood plastic layer and waterproof and dampproof layer are bonded together by hot press simultaneously
Layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710455133.1A CN109129852A (en) | 2017-06-16 | 2017-06-16 | Environment-friendly type fine spar architectural ornament plate and its processing technology |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710455133.1A CN109129852A (en) | 2017-06-16 | 2017-06-16 | Environment-friendly type fine spar architectural ornament plate and its processing technology |
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ID=64830396
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109909689A (en) * | 2019-03-25 | 2019-06-21 | 淄博齐鲁包装制品有限公司 | Its ladle body roller coating coating process of 200 ~ 208L of one kind steel drum |
| CN110092992A (en) * | 2019-05-10 | 2019-08-06 | 江苏沐时代新材料科技有限公司 | Floor Shi Jing and preparation method thereof |
| CN111822229A (en) * | 2020-07-13 | 2020-10-27 | 安徽海鑫科技建材有限公司 | Preparation process of decorative fresco with diatom ooze board |
| CN112208260A (en) * | 2020-09-28 | 2021-01-12 | 山东彬伟装饰材料有限公司 | Microcrystal stone decorative plate production process |
-
2017
- 2017-06-16 CN CN201710455133.1A patent/CN109129852A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109909689A (en) * | 2019-03-25 | 2019-06-21 | 淄博齐鲁包装制品有限公司 | Its ladle body roller coating coating process of 200 ~ 208L of one kind steel drum |
| CN110092992A (en) * | 2019-05-10 | 2019-08-06 | 江苏沐时代新材料科技有限公司 | Floor Shi Jing and preparation method thereof |
| CN111822229A (en) * | 2020-07-13 | 2020-10-27 | 安徽海鑫科技建材有限公司 | Preparation process of decorative fresco with diatom ooze board |
| CN112208260A (en) * | 2020-09-28 | 2021-01-12 | 山东彬伟装饰材料有限公司 | Microcrystal stone decorative plate production process |
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| WD01 | Invention patent application deemed withdrawn after publication |