CN109128584A - A kind of welding rod and preparation method - Google Patents

A kind of welding rod and preparation method Download PDF

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Publication number
CN109128584A
CN109128584A CN201811266780.9A CN201811266780A CN109128584A CN 109128584 A CN109128584 A CN 109128584A CN 201811266780 A CN201811266780 A CN 201811266780A CN 109128584 A CN109128584 A CN 109128584A
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China
Prior art keywords
parts
coating
welding rod
core wire
powder
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CN201811266780.9A
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Chinese (zh)
Inventor
许晓强
许宪斌
许嘉强
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Shijiazhuang Xu Home Welding Material Co Ltd
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Shijiazhuang Xu Home Welding Material Co Ltd
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Priority to CN201811266780.9A priority Critical patent/CN109128584A/en
Publication of CN109128584A publication Critical patent/CN109128584A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding
    • B23K35/404Coated rods; Coated electrodes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/365Selection of non-metallic compositions of coating materials either alone or conjoint with selection of soldering or welding materials

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

The present invention provides a kind of welding rods, belong to technical field of welding materials, and including core wire and the coating for being wrapped in the core wire surface, by proportion by weight, the component of the coating includes: titanium 50-60 parts of reduction;6-9 parts of manganese iron;2-4 parts of carclazyte;1-3 parts of wood powder;1-3 parts of cellulose;3-6 parts of mica;7-10 parts of white clay;1-4 parts of clay;6-10 parts of marble;4-7 parts of feldspar;Each component is taken according to said ratio, bonding agent wet-mixing is added, mixed-powder is uniformly made, by mixed-powder extrusion on core wire, welding rod is made through high temperature drying.Welding rod lower production costs provided by the invention and coating better performances, the raw material used is less, and the production is simple and convenient, and coating is not susceptible to crackle and falls when drying, it is high-quality, coating is good with core wire switching performance, and the striking ability of welding rod is good, and slag is few, it splashes small, smog is few, takes off slag and is easy, improves working efficiency.

Description

A kind of welding rod and preparation method
Technical field
The invention belongs to technical field of welding materials, are to be related to a kind of welding rod and preparation method more specifically.
Background technique
Welding rod is the consumable electrode used for arc welding for being coated with coating, is made of core wire and coating two parts;Core wire is The metal core of welding rod, when welding, there are two effects for core wire: first is that conduction welding current, generates electric arc and converts electrical current into thermal energy, Second is that core wire fusing itself fuses to form weld seam as filling metal and liquid base metals;Coating, which refers to, is coated in core wire surface Dope layer is an important factor for determining weldquality, to there is following several respects in the welding process: one, improving electric arc combustion The stability of burning, two, protection welding pool;Three, guarantee weld seam deoxidation, desulfuration phosphorus impurities, four, for weld seam supplement alloying element, Five, welding productivity is improved, reduces and splashes, therefore, coating plays particularly important effect in the welding process.
Electric arc is very unstable when in use for existing welding rod, and smog is larger, splashes serious, appearance of weld is very poor and compares Crisp, weld seam slag is difficult to remove, and welding quality is caused to decline.
Summary of the invention
The purpose of the present invention is to provide a kind of welding rods, it is intended to solve existing welding rod when in use electric arc it is very unstable, Smog is larger, splashing is serious, appearance of weld is very poor and more crisp and weld seam slag is difficult to remove etc. causes welding quality to decline The technical issues of.
To achieve the above object, the technical solution adopted by the present invention is that: a kind of welding rod is provided, including core wire and is wrapped in institute The coating for stating core wire surface, by proportion by weight, the component of the coating includes:
Titanium 50-60 parts of reduction;
6-9 parts of manganese iron;
2-4 parts of carclazyte;
1-3 parts of wood powder;
1-3 parts of cellulose;
3-6 parts of mica;
7-10 parts of white clay;
1-4 parts of clay;
6-10 parts of marble;
4-7 parts of feldspar.
Further, the component of the coating includes: titanium 55-60 parts of reduction, 6-8 parts of manganese iron, 2.5-3.5 parts of carclazyte, wooden 1.5-3 parts of powder, 1.5-3 parts of cellulose, 4.5-6 parts of mica, 8-9 parts of white clay, 1.5-3.5 parts of clay, 7-9 parts of marble, feldspar 5-7 parts.
Further, the component of the coating include: reduction 56.6 parts of titanium, 7.4 parts of manganese iron, 2.9 parts of carclazyte, wood powder 1.9 Part, 1.9 parts of cellulose, 4.7 parts of mica, 8.5 parts of white clay, 1.9 parts of clay, 8.5 parts of marble, 5.7 parts of feldspar.
Further, the core wire is carbon steel or steel alloy.
Further, the 25%-35% with a thickness of the electrode size of the coating;The quality of the coating is welding rod The 28%-36% of gross mass;The coating of the welding rod front end is provided with chamfering.
Another object of the present invention is to also provide the preparation method of above-mentioned welding rod, specific process step are as follows:
Milling step;By proportion by weight, takes each raw material through crushing ball milling, powder is made;
Wet-mixing step;The powder for crushing ball milling is uniformly mixed, bonding agent is added, stirs 10-25min, wet-mixing under room temperature Uniformly, electrode coating powdery paints;
Extrusion step;The hybrid powder coatings of prepared electrode coating is subjected to extrusion on core wire under room temperature;
Drying steps;It is placed into after the good wet welding item of extrusion is directly placed into curer or at normal temperature natural drying 1-8h Curer is dried to obtain the final product.
Further, the bonding agent being added in the wet-mixing step be modulus be M3.1-3.4, Baume degrees 43%-46% Potassium-sodium water glass solution;Mixed-powder described in every 100 ㎏ at least adds 1 ㎏ bonding agent.
Further, the weight of the bonding agent and the mixed-powder is 20-25:100.
Further, the granularity that powder is made in the milling step is 100-400 mesh.
Further, the drying process in the drying steps includes low-temperature prewarming, medium temperature drying and high temperature drying;It is described The temperature that low-temperature prewarming uses is 40-100 DEG C, preheating time 15-35min;The temperature that the medium temperature drying uses is 80- 140 DEG C, medium temperature drying time is 10-25min;For 130-210 DEG C, high temperature drying time is the temperature that high temperature drying uses 10-20min。
A kind of beneficial effect of welding rod provided by the invention is: compared with prior art, a kind of medicine of welding rod of the present invention Skin does not contain common raw material titanium dioxide, reduces production cost and coating better performances, and the raw material used is less, makes simple side Just, coating is not susceptible to crackle and falls when drying, high-quality, and coating is good with core wire switching performance, and the striking ability of welding rod is good, Slag is few, splashes small, and smog is few, takes off slag and is easy, and good economy performance improves working efficiency.
Specific embodiment
In order to which technical problems, technical solutions and advantages to be solved are more clearly understood, tie below Embodiment is closed, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only used to solve The present invention is released, is not intended to limit the present invention.
Now a kind of welding rod provided by the invention is illustrated.A kind of welding rod, including core wire and it is wrapped in the weldering The coating of wicking surface, by proportion by weight, the component of the coating includes:
Titanium 50-60 parts of reduction;
6-9 parts of manganese iron;
2-4 parts of carclazyte;
1-3 parts of wood powder;
1-3 parts of cellulose;
3-6 parts of mica;
7-10 parts of white clay;
1-4 parts of clay;
6-10 parts of marble;
4-7 parts of feldspar.
A kind of beneficial effect of welding rod provided by the invention is: compared with prior art, a kind of medicine of welding rod of the present invention Skin does not contain common raw material titanium dioxide, reduces production cost and coating better performances, and the raw material used is less, makes simple side Just, coating is not susceptible to crackle and falls when drying, and welding rod is specious, high-quality, and coating is good with core wire switching performance, welding rod Striking ability it is good, slag is few, splash it is small, smog is few, take off slag be easy, good economy performance, improve working efficiency.
As a kind of a kind of specific embodiment of welding rod provided by the invention, the component of the coating is reduction titanium 55- 60 parts, 6-8 parts of manganese iron, 2.5-3.5 parts of carclazyte, 1.5-3 parts of wood powder, 1.5-3 parts of cellulose, 4.5-6 parts of mica, 8-9 parts of white clay, 1.5-3.5 parts of clay, 7-9 parts of marble, 5-7 parts of feldspar;Herein it should also be noted that, the component quality of the technical program It can also include rutile in proportion, the number of rutile is the 20-30% for restoring titanium number.
As a kind of a kind of specific embodiment of welding rod provided by the invention, the component of the coating is reduction titanium 56.6 Part, 7.4 parts of manganese iron, 2.9 parts of carclazyte, 1.9 parts of wood powder, 1.9 parts of cellulose, 4.7 parts of mica, 8.5 parts of white clay, 1.9 parts of clay, greatly 8.5 parts of fibrous gypsum, 5.7 parts of feldspar.
As a kind of a kind of specific embodiment of welding rod provided by the invention, the core wire is carbon steel or steel alloy, excellent Choosing, the core wire is H08A steel or H08 steel;Herein it should be noted that carbon steel is mild steel or medium carbon steel, welding Strength grade can be needed according to welding when connecing to select the welding rod of respective strengths, rigidly big in welding structure, stress condition is complicated When, the welding rod of level-one lower than steel strength is selected, in this way, postwelding can guarantee the existing some strength of weld seam, and satisfaction can be obtained Plasticity avoids making weld seam tear because structural rigidity is excessive;The diameter of core wire is 1.6-6 millimeters, and length is 200-700 millimeters, The diameter and length for increasing core wire, can extend the time of arc burning, increase deposited metal amount, welding production can be improved Rate;The tail portion of core wire may be provided with one section of naked core wire, account for the 3%-10% of welding rod overall length, clamps convenient for soldering turret and is conducive to lead Electricity.
As a kind of a kind of specific embodiment of welding rod provided by the invention, the coating it is straight with a thickness of the core wire The 25%-35% of diameter;The quality of the coating is the 28%-36% of welding rod gross mass;The coating of the welding rod front end is provided with 45 ° of chamfering guarantees easy arc striking.
Herein it should be noted that the component of electrode coating is more complicated, the purposes of every kind of component is not also identical:
Titanium, manganese iron dust are restored in deoxidier, reduces the oxidisability of coating or slag, for removing the oxygen for melting metal, with Improve Weld Performance;
Manganese iron dust is in alloying constituent, for compensating in welding process the scaling loss of alloying element and to alloy necessary to weld seam transition Element, to guarantee that weld metal obtains necessary chemical component and performance;
Reduction titanium, feldspar, cellulose and waterglass belong to arc stabilizer, and arc stabilizer can make welding rod in striking and welding process Play the role of improving striking performance and stablize arc burning, be all the substance for being easy ionization, arc stabilizer mostly uses potassium, sodium, calcium Compound, arc burning stability can be improved, and electric arc is made to be easy to ignite;
Reduction titanium, manganese iron, marble, rutile, feldspar, white clay, carclazyte, clay and mica these minerals belong to slag making Agent generates slag protection liquid metal when welding and improves appearance of weld, after causing slag, mainly some oxides, and slag making Agent dilutes slag, increases its activity;Wherein, feldspar is adjustable the physical property of slag and improves the acidity of slag, plays steady Arc improves arc voltage, refines molten drop, improves the effect of fusing coefficient;Marble calcium carbonate >=95%, increases in coating The main purpose of fibrous gypsum is slag making and gas making, and the calcium oxide generated after being decomposed due to marble is basic anhydride, therefore its energy Therefore the basicity for improving slag makes the ability enhancing of desulfurization by slag, dephosphorization, propose the ability of the anti-solidification cracking of weld metal Height, marble decompose the carbon dioxide gas generated, enhance the oxidisability of arc atmosphere, can reduce the hydrogen partial pressure in electric arc, Platform hydrogen amount in weld metal is caused to reduce, at the same time, moreover it is possible to prevent the invasion of nitrogen, calcium oxide can increase the surface of slag Power and slag and fusing metal interface tension, are roughened molten drop, change the transitional form of molten drop;Wood powder and cellulose also belong to gas making Agent, gas-forming agent can generate a large amount of carbon monoxide, carbon dioxide and hydrogen etc. when welding rod melts, and enclosing electric arc protects metal Not oxidized and nitridation, plays mechanical protection to the metal of liquid;Wood powder is hydrocarbon, and main function is gas making and changes Kind paintability;Cellulose is natural organic polymer compounds, as long as effect is slag making gas making, can also improve paintability, Coating intensity is improved, is allowed to not easy to crack, is the main source of hydrogen in arc atmosphere, the oxidisability of arc atmosphere can be reduced;
White clay, carclazyte and clay are the aluminosilicate containing the crystallization water, main function be improve coating paintability and Slag making can make weld seam hydrogenation due to containing the crystallization water;
Mica is the aluminosilicate of layer structure, and main function is the paintability and slag making for improving coating, next is helped In raising arc stability;
Binder uses potassium-sodium water glass, and potassium-sodium water glass can make coating each component bonding get up and be bonded in core wire table Face, and after electrode coating drying there is certain intensity to have both arc stabilizer in addition, potassium-sodium water glass also belongs to arc stabilizer Function.
It can also include rutile in the technical program, rutile also has fluxing effect in addition to stabilising arc, can adjust molten Fusing point, viscosity, surface tension and the mobility of slag improve appearance of weld, reduce splashing and undercut, are conducive to all positon welding, Therefore, rutile is added in coating has good welding technological properties;But rutile price is more expensive, needs to illustrate herein , since reduction titanium is made reducing agent high-temperature roasting by natural ilmenite carbon or carbon monoxide and is formed, wherein containing titanium dioxide, Iron, iron oxide, other oxides, sulphur and phosphorus, therefore restore titanium and can replace rutile use, cost can be not only reduced, also Be conducive to improve quality.
Prove that the proportion composition of above-mentioned coating can guarantee welding rod by a large amount of test when the welding rod of the technical program uses Easy arc striking and arc stability splash small in the welding process;If welding rod without coating, in the welding process the oxygen in air and Nitrogen can largely invade fusing metal, and the oxidations such as metallic iron and beneficial element carbon, silicon, manganese and nitridation are formed various oxides and nitrogen Compound, and remain in weld seam, cause weld seam slag inclusion or crackle;And the gas fused into molten bath may make weld seam generate a large amount of gas Hole, these factors can be such that the mechanical performance (intensity, impact value etc.) of weld seam substantially reduces, while weld seam being made to become fragile, this technology The burn-off rate of scheme electrode coating is slower than the burn-off rate of core wire, causes the horn-like sleeve less than electrode size, is conducive to Droplet transfer and cause protective atmosphere;The specific gravity of slag is less than the specific gravity of fusing metal, and setting temperature is lower than metal freezing temperature, Skull is easy to fall off;Welding with blending gold and Metallurgical processing effect, suitable for various positions;In addition, electrode coating of the present invention Technical solution in not using the titanium dioxide being commonly used in coating, content of titanium dioxide >=97% of titanium dioxide is main to rise Slag making and the plasticity effect for increasing coating with stabilising arc and improve the mobility of slag, but when additional amount is more, easily make welding rod It is rubescent when welding, increase and splash, and price is more expensive, the technical program does not use titanium dioxide, and one can reduce splashing, and two can reduce into This.
Another object of the present invention is to also provide the preparation method of above-mentioned welding rod, specific process step are as follows:
Milling step;By proportion by weight, takes each raw material through crushing ball milling, powder is made;
Wet-mixing step;The powder for crushing ball milling is uniformly mixed, bonding agent is added, stirs 10-25min, wet-mixing under room temperature Uniformly, electrode coating powdery paints;Binder needs are slowly added to, and guarantee that wet-mixing is uniform;
Extrusion step;The hybrid powder coatings of prepared electrode coating is subjected to extrusion on core wire under room temperature;Wherein, Extrusion is carried out using variable speed welding rod spiral coating machine, electrode surface is extruded into bright and clean, uniformly densely coated;
Drying steps;It is placed into after the good wet welding item of extrusion is directly placed into curer or at normal temperature natural drying 1-8h Curer is dried to obtain the final product.
Welding rod preparation method provided by the invention, high production efficiency, speed is fast, and the electrode coating thickness of preparation is uniform and smooth Closely knit, coating is not likely to produce crackle, not easily to fall off, and coating is good with core wire switching performance, and welding rod quality is stablized, appearance looks elegant.
As a kind of specific embodiment of welding rod preparation method provided by the invention, what is be added in the wet-mixing step is viscous Connect agent be modulus be M3.1-3.4, Baume degrees is 43%-46% and potassium sodium is than the potassium-sodium water glass solution for 2:1;Every 100 ㎏ institute It states mixed-powder and at least adds 1 ㎏ bonding agent, guarantee that mixed-powder wet-mixing is uniform.
As a kind of specific embodiment of welding rod preparation method provided by the invention, the bonding agent and the mixed powder The weight at end is 20-25:100;The weight of preferred potassium-sodium water glass solution and mixed-powder is 22:100, Humidity is suitable for that bonding securely and is easily dried.
As a kind of specific embodiment of welding rod preparation method provided by the invention, powder is made in the milling step The granularity at end is 100-400 mesh.
As a kind of specific embodiment of welding rod preparation method provided by the invention, at dry in the drying steps Reason includes low-temperature prewarming, medium temperature drying and high temperature drying;For 40-100 DEG C, preheating time is the temperature that the low-temperature prewarming uses 15-35min;For the temperature that the medium temperature drying uses for 80-140 DEG C, medium temperature drying time is 10-25min;The high temperature drying For the temperature used for 130-210 DEG C, high temperature drying time is 10-20min.
In the present embodiment, the temperature of each drying link is adjusted according to the size of electrode size, and according to difference Seasonal adjustment drying time, low-temperature prewarming, medium temperature drying, high temperature drying links drying time be 10-35min, Finally the dry welding rod taking-up completed is dried in the air to room temperature and can be packed.
When electrode size is 1.6 millimeters, low-temperature prewarming temperature is 40-50 DEG C, preheating time 15-20min, medium temperature drying Temperature is 80-90 DEG C, and medium temperature drying time is 10-15min, and high temperature drying temperature is 130-150 DEG C, and high temperature drying time is 10-15min。
When electrode size is 2 millimeters, low-temperature prewarming temperature is 40-50 DEG C, preheating time 15-20min, medium temperature drying temperature Degree is 80-100 DEG C, and medium temperature drying time is 10-15min, and high temperature drying temperature is 140-160 DEG C, and high temperature drying time is 10- 15min。
When electrode size is 2.5 millimeters, low-temperature prewarming temperature is 50-70 DEG C, preheating time 15-20min, medium temperature drying Temperature is 80-100 DEG C, and medium temperature drying time is 10-15min, and high temperature drying temperature is 150-170 DEG C, and high temperature drying time is 10-15min。
When electrode size is 3.2 millimeters, low-temperature prewarming temperature is 60-80 DEG C, preheating time 15-25min, medium temperature drying Temperature is 80-100 DEG C, and medium temperature drying time is 15-20min, and high temperature drying temperature, 160-180 DEG C, high temperature drying time is 10-15min。
When electrode size is 4 millimeters, low-temperature prewarming temperature is 70-100 DEG C, preheating time 20-30min, medium temperature drying Temperature is 100-120 DEG C, and medium temperature drying time is 15-20min, and high temperature drying temperature is 180-200 DEG C, and high temperature drying time is 15-20min。
When electrode size is 5 millimeters, low-temperature prewarming temperature is 80-100 DEG C, preheating time 20-30min, medium temperature drying Temperature is 110-130 DEG C, and medium temperature drying time is 20-25min, and high temperature drying temperature is 200-210 DEG C, and high temperature drying time is 15-20min。
When electrode size is 6 millimeters, low-temperature prewarming temperature is 80-100 DEG C, preheating time 25-35min, medium temperature drying Temperature is 110-140 DEG C, and medium temperature drying time is 20-25min, and high temperature drying temperature is 200-210 DEG C, and high temperature drying time is 15-20min。
For more specific description technical solution of the present invention, now it is described in detail by following embodiment.
Embodiment one:
A kind of welding rod, including core wire and the coating for being wrapped in the core wire surface, the coating includes that following mass parts are matched The component of ratio: 50 parts of titanium of reduction;9 parts of manganese iron;2.5 parts of carclazyte;1 part of wood powder;2 parts of cellulose;6 parts of mica;10 parts of white clay;Clay 2.5 part;10 parts of marble;7 parts of feldspar;Each component is taken according to said ratio, bonding agent wet-mixing is added, mixed powder is uniformly made Welding rod is made through high temperature drying by mixed-powder extrusion on core wire in end;Core wire is carbon steel, and the diameter of core wire is 2 millimeters, long Degree is 250 millimeters, and core wire tail portion is provided with one section of naked core wire, is 15 millimeters;Coating with a thickness of 0.5 millimeter, the quality of coating It is the 30% of welding rod gross mass, the coating of welding rod front end is provided with 45 ° of chamfering.
The specific process step of welding rod preparation method are as follows:
Milling step;By proportion by weight, 50 parts of titanium are restored;9 parts of manganese iron;2.5 parts of carclazyte;1 part of wood powder;2 parts of cellulose; 6 parts of mica;10 parts of white clay;2.5 parts of clay;10 parts of marble;7 parts of feldspar;Through crushing ball milling, 200 mesh powders are made;
Wet-mixing step;The powder for crushing ball milling is uniformly mixed, bonding agent, the parts by weight of bonding agent and powder are slowly added to Proportion is 20:100, stirs 15min under room temperature, and wet-mixing is uniform, electrode coating powdery paints;Wherein, bonding agent is mould Number is M3.2, and Baume degrees is 43% and potassium sodium is than the potassium-sodium water glass solution for 2:1;
Extrusion step;Use variable speed welding rod spiral coating machine by the powdery paints of prepared electrode coating under room temperature Extrusion is carried out on core wire, and electrode surface is extruded into bright and clean, uniformly densely coated;
Drying steps;The good wet welding item of extrusion is directly placed into curer to be dried, 40 DEG C of low-temperature prewarmings 15min, 85 DEG C of medium temperatures dry 15min, and 140 DEG C of high temperature dry 12min, finally take out and dry in the air to room temperature, then by the weldering after drying Item is according to regulation weight packaging.
Embodiment two:
A kind of welding rod, including core wire and the coating for being wrapped in the core wire surface, the coating is by following proportion by weight Component be made: reduction 55 parts of titanium;9 parts of manganese iron;2 parts of carclazyte;3 parts of wood powder;3 parts of cellulose;5 parts of mica;8 parts of white clay;Clay 3.5 part;7 parts of marble;4.5 parts of feldspar;Each component is taken according to said ratio, bonding agent wet-mixing is added, mixed powder is uniformly made Welding rod is made through high temperature drying by mixed-powder extrusion on core wire in end;Core wire is carbon steel, and the diameter of core wire is 3.2 millimeters, Length is 400 millimeters, and core wire tail portion is provided with one section of naked core wire, is 25 millimeters;Coating with a thickness of 1 millimeter, the quality of coating It is the 30% of welding rod gross mass, the coating of welding rod front end is provided with 45 ° of chamfering.
The specific process step of welding rod preparation method are as follows:
Milling step;By proportion by weight, 55 parts of titanium are restored;9 parts of manganese iron;2 parts of carclazyte;3 parts of wood powder;3 parts of cellulose;Cloud It is 5 parts female;8 parts of white clay;3.5 parts of clay;7 parts of marble;4.5 parts of feldspar;Through crushing ball milling, 200 mesh powders are made;
Wet-mixing step;The powder for crushing ball milling is uniformly mixed, bonding agent, the parts by weight of bonding agent and powder are slowly added to Proportion is 22:100, stirs 15min under room temperature, and wet-mixing is uniform, electrode coating powdery paints;Wherein, bonding agent is mould Number is M3.1, and Baume degrees is 45% and potassium sodium is than the potassium-sodium water glass solution for 2:1;
Extrusion step;Use variable speed welding rod spiral coating machine by the powdery paints of prepared electrode coating under room temperature Extrusion is carried out on core wire, and electrode surface is extruded into bright and clean, uniformly densely coated;
Drying steps;Natural drying under the good wet welding room temperature of extrusion is placed into curer afterwards for a period of time to be dried Processing, 80 DEG C of low-temperature prewarming 25min, 90 DEG C of medium temperatures dry 15min, and 160 DEG C of high temperature dry 15min, finally take out and dry in the air to room temperature, Then by the welding rod after drying according to regulation weight packaging.
Embodiment three:
A kind of welding rod, including core wire and the coating for being wrapped in the core wire surface, the coating is by following proportion by weight Component be made: reduction 58 parts of titanium;8.5 parts of manganese iron;4 parts of carclazyte;1 part of wood powder;1 part of cellulose;3 parts of mica;10 parts of white clay;It is viscous 1 part of soil;9.5 parts of marble;4 parts of feldspar;Each component is taken according to said ratio, bonding agent wet-mixing is added, mixed powder is uniformly made Welding rod is made through high temperature drying by mixed-powder extrusion on core wire in end;Core wire is carbon steel, and the diameter of core wire is 3.2 millimeters, Length is 450 millimeters, and core wire tail portion is provided with one section of naked core wire, is 25 millimeters;Coating with a thickness of 1.5 millimeters, the matter of coating Amount is the 36% of welding rod gross mass, and the coating of welding rod front end is provided with 45 ° of chamfering.
The specific process step of welding rod preparation method are as follows:
Milling step;By proportion by weight, core wire and the coating for being wrapped in the core wire surface, the coating is by following matter The component of amount part proportion is made: 58 parts of titanium of reduction;8.5 parts of manganese iron;4 parts of carclazyte;1 part of wood powder;1 part of cellulose;3 parts of mica;It is white 10 parts of mud;1 part of clay;9.5 parts of marble;4 parts of feldspar;Through crushing ball milling, 300 mesh powders are made;
Wet-mixing step;The powder for crushing ball milling is uniformly mixed, bonding agent, the parts by weight of bonding agent and powder are slowly added to Proportion is 22:100, stirs 25min under room temperature, and wet-mixing is uniform, electrode coating powdery paints;Wherein, bonding agent is mould Number is M3.4, and Baume degrees is 46% and potassium sodium is than the potassium-sodium water glass solution for 2:1;
Extrusion step;Use variable speed welding rod spiral coating machine by the powdery paints of prepared electrode coating under room temperature Extrusion is carried out on core wire, and electrode surface is extruded into bright and clean, uniformly densely coated;
Drying steps;Natural drying under the good wet welding room temperature of extrusion is placed into curer afterwards for a period of time to be dried Processing, 80 DEG C of low-temperature prewarming 25min, 90 DEG C of medium temperatures dry 20min, and 160 DEG C of high temperature dry 15min, finally take out and dry in the air to room temperature, Then by the welding rod after drying according to regulation weight packaging.
Example IV:
A kind of welding rod, including core wire and the coating for being wrapped in the core wire surface, the coating is by following proportion by weight Component be made: reduction 50 parts of titanium;8 parts of manganese iron;2 parts of carclazyte;1.5 parts of wood powder;1.5 parts of cellulose;3.5 parts of mica;White clay 10 Part;1.5 parts of clay;8 parts of marble;4 parts of feldspar, 10 parts of rutile;Each component is taken according to said ratio, it is wet through bonding agent is added It mixes and mixed-powder uniformly is made, by mixed-powder extrusion on core wire, welding rod is made through high temperature drying;Core wire is carbon steel, core wire Diameter be 5 millimeters, length be 450 millimeters, core wire tail portion is provided with one section of naked core wire, be 25 millimeters;Coating with a thickness of 1.5 Millimeter, the quality of coating are the 32% of welding rod gross mass, and the coating of welding rod front end is provided with 45 ° of chamfering.
The specific process step of welding rod preparation method are as follows:
Milling step;By proportion by weight, core wire and the coating for being wrapped in the core wire surface, the coating is by following matter The component of amount part proportion is made: 50 parts of titanium of reduction;8 parts of manganese iron;2 parts of carclazyte;1.5 parts of wood powder;1.5 parts of cellulose;Mica 3.5 Part;10 parts of white clay;1.5 parts of clay;8 parts of marble;4 parts of feldspar, 10 parts of rutile;Through crushing ball milling, the powder of 200 mesh is made End;
Wet-mixing step;The powder for crushing ball milling is uniformly mixed, bonding agent, the parts by weight of bonding agent and powder are slowly added to Proportion is 25:100, stirs 25min under room temperature, and wet-mixing is uniform, electrode coating powdery paints;Wherein, bonding agent is mould Number is M3.1, and Baume degrees is 46% and potassium sodium is than the potassium-sodium water glass solution for 2:1;
Extrusion step;Use variable speed welding rod spiral coating machine by the powdery paints of prepared electrode coating under room temperature Extrusion is carried out on core wire, and electrode surface is extruded into bright and clean, uniformly densely coated;
Drying steps;Natural drying under the good wet welding room temperature of extrusion is placed into curer afterwards for a period of time to be dried Processing, 80 DEG C of low-temperature prewarming 30min, 120 DEG C of medium temperatures dry 25min, and 210 DEG C of high temperature dry 15min, finally take out and dry in the air to room Temperature, then by the welding rod after drying according to regulation weight packaging.
Embodiment five:
A kind of welding rod, including core wire and the coating for being wrapped in the core wire surface, the coating is by following proportion by weight Component be made: reduction 56.6 parts of titanium, 7.4 parts of manganese iron, 2.9 parts of carclazyte, 1.9 parts of wood powder, 1.9 parts of cellulose, 4.7 parts of mica, 8.5 parts of white clay, 1.9 parts of clay, 8.5 parts of marble, 5.7 parts of feldspar;Each component is taken according to said ratio, it is wet through bonding agent is added It mixes and mixed-powder uniformly is made, by mixed-powder extrusion on core wire, welding rod is made through high temperature drying;Core wire is carbon steel, core wire Diameter be 2.5 millimeters, length be 350 millimeters, core wire tail portion is provided with one section of naked core wire, be 20 millimeters;Coating with a thickness of 0.8 millimeter, the quality of coating is the 30% of welding rod gross mass, and the coating of welding rod front end is provided with 45 ° of chamfering.
The specific process step of welding rod preparation method are as follows:
Milling step;By proportion by weight, core wire and the coating for being wrapped in the core wire surface, the coating is by following matter The component of amount part proportion is made: 56.6 parts of titanium of reduction, and 7.4 parts of manganese iron, 2.9 parts of carclazyte, 1.9 parts of wood powder, 1.9 parts of cellulose, cloud It is 4.7 parts, 8.5 parts of white clay, 1.9 parts of clay, 8.5 parts of marble, 5.7 parts of feldspar female;Through crushing ball milling, 200 mesh powders are made;
Wet-mixing step;The powder for crushing ball milling is uniformly mixed, bonding agent, the parts by weight of bonding agent and powder are slowly added to Proportion is 22:100, stirs 25min under room temperature, and wet-mixing is uniform, electrode coating powdery paints;Wherein, bonding agent is mould Number is M3.1, and Baume degrees is 46% and potassium sodium is than the potassium-sodium water glass solution for 2:1;
Extrusion step;Use variable speed welding rod spiral coating machine by the powdery paints of prepared electrode coating under room temperature Extrusion is carried out on core wire, and electrode surface is extruded into bright and clean, uniformly densely coated;
Drying steps;Natural drying under the good wet welding room temperature of extrusion is placed into curer afterwards for a period of time to be dried Processing, 60 DEG C of low-temperature prewarming 15min, 80 DEG C of medium temperatures dry 15min, and 170 DEG C of high temperature dry 15min, finally take out and dry in the air to room temperature, Then by the welding rod after drying according to regulation weight packaging.
Embodiment six:
A kind of welding rod, including core wire and the coating for being wrapped in the core wire surface, the coating is by following proportion by weight Component be made: reduction 55 parts of titanium, 6.4 parts of manganese iron, 2 parts of carclazyte, 1.6 parts of wood powder, 1.6 parts of cellulose, 3 parts of mica, white clay 7 Part, 1.4 parts of clay, 6.3 parts of marble, 4.7 parts of feldspar, 11 parts of rutile;Each component is taken according to said ratio, is bonded through being added Mixed-powder is uniformly made in agent wet-mixing, and by mixed-powder extrusion on core wire, welding rod is made through high temperature drying;Core wire is carbon steel, The diameter of core wire is 2.5 millimeters, and length is 350 millimeters, and core wire tail portion is provided with one section of naked core wire, is 20 millimeters;The thickness of coating Degree is 0.8 millimeter, and the quality of coating is the 30% of welding rod gross mass, and the coating of welding rod front end is provided with 45 ° of chamfering.
The specific process step of welding rod preparation method are as follows:
Milling step;By proportion by weight, core wire and the coating for being wrapped in the core wire surface, the coating is by following matter The component of amount part proportion is made: 55 parts of titanium of reduction, and 6.4 parts of manganese iron, 2 parts of carclazyte, 1.6 parts of wood powder, 1.6 parts of cellulose, mica 3 Part, 7 parts of white clay, 1.4 parts of clay, 6.3 parts of marble, 4.7 parts of feldspar, 11 parts of rutile;Through crushing ball milling, 200 purposes are made Powder;
Wet-mixing step;The powder for crushing ball milling is uniformly mixed, bonding agent, the parts by weight of bonding agent and powder are slowly added to Proportion is 22:100, stirs 25min under room temperature, and wet-mixing is uniform, electrode coating powdery paints;Wherein, bonding agent is mould Number is M3.1, and Baume degrees is 46% and potassium sodium is than the potassium-sodium water glass solution for 2:1;
Extrusion step;Use variable speed welding rod spiral coating machine by the powdery paints of prepared electrode coating under room temperature Extrusion is carried out on core wire, and electrode surface is extruded into bright and clean, uniformly densely coated;
Drying steps;Natural drying under the good wet welding room temperature of extrusion is placed into curer afterwards for a period of time to be dried Processing, 60 DEG C of low-temperature prewarming 20min, 100 DEG C of medium temperatures dry 15min, and 170 DEG C of high temperature dry 15min, finally take out and dry in the air to room Temperature, then by the welding rod after drying according to regulation weight packaging.
Explanation is needed further exist for, it is whether scientific with quality proportioning in order to examine the raw material of technical solution of the present invention to choose Rationally, inventor has carried out different comparative tests to the type and quality proportioning of each raw material:
Firstly, being adjusted to the quality proportioning of manganese iron, coating is made of the component of following proportion by weight:;Restore titanium 50 parts;15 parts of manganese iron;3.5 parts of carclazyte;3 parts of wood powder;2 parts of cellulose;6 parts of mica;8 parts of white clay;1.5 parts of clay;Marble 6 Part;5 parts of feldspar;Wherein, the content of manganese iron is 15 parts, and quality proportioning is higher than defined by the technical program 6-9 parts;According to above-mentioned Proportion takes each component, bonding agent wet-mixing is added, mixed-powder is uniformly made, by mixed-powder extrusion on core wire, dried through high temperature It is drying at welding rod;Detection discovery, the creep strength characteristics deterioration of welding metal are carried out to welding rod;The constantly content of adjustment manganese iron It was found that manganese iron content is at 6-9 parts, the performance of welding rod and the intensity of welding metal and toughness are best.
Method similar to the above, which changes the proportion by weight of other several raw materials and tests manufactured welding rod, to be found, also Former Ti content is excessively high to will cause extrusion difficulty, and welding plate temperature is excessively high, and slag is thinning, restores titanium proportion by weight in 50-60, also Originality is good, arc stability, molten bath flat mirror, and deposition efficiency increases, and metal is fine mist transition, and electric arc is soft, and appearance of weld is beautiful, Slag covers;Marble too high levels will increase the fusing point of coating, increases dry slag degree, causes speed of welding to slow down, easily make to weld Seam generates inner air vent, and appearance of weld is coarse, and de- slag rate, spatter loss coefficient and power consumption are increase accordingly;Mica content is excessively high to can lead to medicine Skin is loose excessively thick, the fragile head of welding rod and scratch, and electrode coating surface quality is poor;White clay too high levels are unfavorable for welding rod extrusion, make Weld seam generates dry slag, increases weld seam hydrogen content, white clay content is too low to be easy to cause electrode coating to crack;Feldspar content is excessively high to be subtracted Slow speed of welding increases slag viscosity;Thus prove that the proportion by weight of each raw material of technical solution of the present invention is scientific and reasonable.
Secondly, inventor replaces the raw material of electrode coating and has carried out two groups of comparative tests:
First group
Scheme one: 55 parts of titanium of reduction is taken;9 parts of manganese iron;2 parts of carclazyte;3 parts of wood powder;3 parts of cellulose;5 parts of mica;White clay 8 Part;3.5 parts of clay;7 parts of marble;4.5 parts of feldspar;
Scheme two: 35 parts of titanium dioxide, reduction 25 parts of titanium, 9 parts of manganese iron, 2 parts of carclazyte, 3 parts of wood powder, 2 parts of cellulose, white clay are taken 8 parts, 5 parts of mica, 7 parts of marble, 4 parts of feldspar;
Titanium dioxide and reduction titanium main component are titanium dioxide, and titanium dioxide 35 is added in scheme two and divides, reduces reduction The dosage of titanium;Each component is taken according to above two proportion by weight, bonding agent wet-mixing is added, mixed-powder is uniformly made, will mixed Powder extrusion is closed on core wire, welding rod one and welding rod two is made through high temperature drying;Detection discovery is carried out to welding rod one and welding rod two, The production is simple and convenient for two kinds of welding rods, and coating is not susceptible to crackle when drying, and welding rod is specious, high-quality, coating and core wire Switching performance is good, and the striking ability of welding rod is suitable, and slag is less, and de- slag is all easier to, but adds titanium white relative to welding rod one The welding rod two of powder splashes larger, and the easy hot tearing of weld seam, mechanical performance is poor, frangibility when clod wash, wherein the tension of welding base metal is strong Degree is 270N/mm2, the weld seam tensile strength after being welded after testing by welding rod one is 273N/mm2, welded by welding rod two Weld seam tensile strength afterwards is 245N/mm2, found by detection, it is anti-that the welding rod made of scheme two welds the weld seam to be formed Tensile strength reaches the 90.7% of base material tensile strength, and the welding rod made of the technical program welds the weld seam tensile strength formed and omits Higher than the tensile strength of base material, it can be seen that, the weld seam tensile strength after the welding of welding rod made of this programme is higher, and scheme two contains Some raw material titanium dioxides are expensive, and the cost of welding rod two is apparently higher than welding rod one, reduce economic interests.
Second group
Scheme one: 50 parts of titanium of reduction;9 parts of manganese iron;2.5 parts of carclazyte;1 part of wood powder;2 parts of cellulose;6 parts of mica;White clay 10 Part;2.5 parts of clay;10 parts of marble;7 parts of feldspar;
Scheme two: 50 parts of titanium of reduction;9 parts of manganese iron;2.5 parts of carclazyte;1 part of wood powder;2 parts of cellulose;6 parts of mica;White clay 10 Part;2.5 parts of clay;10 parts of fluorite;7 parts of feldspar;
Marble main component be calcium carbonate, the main component of fluorite is calcirm-fluoride, make coating when both effect it is equal For desulfurization and slag making gas making, scheme two replaces marble with fluorite, each component is taken according to above two proportion by weight, through being added Mixed-powder is uniformly made in bonding agent wet-mixing, and by mixed-powder extrusion on core wire, welding rod one and welding rod is made through high temperature drying Two;Detection discovery carried out to welding rod one and welding rod two, the production is simple and convenient for two kinds of welding rods, and coating is not susceptible to split when drying Line, welding rod is specious, high-quality, and coating is good with core wire switching performance, and de- slag is all easier to;Relative to welding rod one, welding rod two The fluorite of addition is lower than marble fusing point, and the electrode coating fusing point of production is lower, and slag is diluter, and de- slag ratio welding rod one more holds Easily, gas in weld metal easily escapes, but welding rod two is poor relative to the stabilising arc ability of welding rod one, and AC welding is difficult, and easily with Hydrogen, which combines, generates hydrogen fluoride, and hydrogen fluoride is volatile and toxic, and when use need to reinforce safeguard protection, but fluorite itself is nontoxic;Wherein, The tensile strength of welding base metal is 300N/mm2, the weld seam tensile strength after being welded after testing by welding rod one is 297N/ mm2, the weld seam tensile strength after being welded by welding rod two is 267N/mm2, found by detection, the welding rod made of scheme two The weld seam tensile strength that welding is formed reaches the 89% of base material tensile strength, and made of the technical program welding rod, which welds, to be formed Weld seam tensile strength reaches the 99% of base material tensile strength, it can be seen that, the weld seam tension after the welding of welding rod made of this programme Intensity is higher, and the raw material fluorite price that scheme two contains is more expensive, comprehensively considers, and technical solution of the present invention is made using marble Electrode coating performance is more preferable, Environmental Safety, and cost is relatively low, can obtain biggish economic benefit.
To sum up, technical solution of the present invention electrode coating raw material type choose and each raw material between proportion by weight be through It crosses what inventor's repetition test was obtained with comparison, is to optimize most scientific reasonable technical solution, is made of the technical program Welding rod production cost tell somebody what one's real intentions are and electrode coating better performances, the raw material used is less, and the production is simple and convenient, and coating is not when drying Crackle easily occurs and falls, welding rod is specious, and high-quality, coating and core wire switching performance are good, and the striking ability of welding rod is good, melts Slag is few, splashes small, and smog is few, takes off slag and is easy, and good economy performance improves working efficiency.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (10)

1. a kind of welding rod, including core wire and the coating for being wrapped in the core wire surface, which is characterized in that press proportion by weight, institute The component for stating coating includes:
Titanium 50-60 parts of reduction;
6-9 parts of manganese iron;
2-4 parts of carclazyte;
1-3 parts of wood powder;
1-3 parts of cellulose;
3-6 parts of mica;
7-10 parts of white clay;
1-4 parts of clay;
6-10 parts of marble;
4-7 parts of feldspar.
2. a kind of welding rod as described in claim 1, which is characterized in that the coating includes following component: reduction titanium 55-60 Part, it 6-8 parts of manganese iron, 2.5-3.5 parts of carclazyte, 1.5-3 parts of wood powder, 1.5-3 parts of cellulose, 4.5-6 parts of mica, 8-9 parts of white clay, glues It is 1.5-3.5 parts native, 7-9 parts of marble, 5-7 parts of feldspar.
3. a kind of welding rod as claimed in claim 2, which is characterized in that the coating includes following components: component is reduction titanium 56.6 parts, 7.4 parts of manganese iron, 2.9 parts of carclazyte, 1.9 parts of wood powder, 1.9 parts of cellulose, 4.7 parts of mica, 8.5 parts of white clay, clay 1.9 Part, 8.5 parts of marble, 5.7 parts of feldspar.
4. a kind of welding rod as described in claim 1, which is characterized in that the core wire is carbon steel or steel alloy.
5. a kind of welding rod as described in claim 1, which is characterized in that the coating with a thickness of the electrode size 25%-35%;The quality of the coating is the 28%-36% of welding rod gross mass;The coating of the welding rod front end is provided with chamfering.
6. the preparation method of welding rod described in claim 1-5 any one, which is characterized in that its specific process step are as follows:
Milling step;By proportion by weight, takes each raw material through crushing ball milling, powder is made;
Wet-mixing step;The powder for crushing ball milling is uniformly mixed, bonding agent is added, stirs 10-25min under room temperature, wet-mixing is uniform, Electrode coating powdery paints;
Extrusion step;The hybrid powder coatings of prepared electrode coating is subjected to extrusion on core wire under room temperature;
Drying steps;Baking is placed into after the good wet welding item of extrusion is directly placed into curer or at normal temperature natural drying 1-8h Case is dried to obtain the final product.
7. preparation method as claimed in claim 6, which is characterized in that the bonding agent being added in the wet-mixing step is that modulus is M3.1-3.4, the potassium-sodium water glass solution that Baume degrees is 43%-46%;Mixed-powder described in every 100 ㎏ at least adds 1 ㎏ bonding Agent.
8. preparation method as claimed in claim 7, which is characterized in that the parts by weight of the bonding agent and the mixed-powder are matched Than for 20-25:100.
9. preparation method as claimed in claim 6, it is characterised in that: the granularity that powder is made in the milling step is 100-400 mesh.
10. preparation method as claimed in claim 6, which is characterized in that the drying process in the drying steps includes low temperature Preheating, medium temperature drying and high temperature drying;The temperature that the low-temperature prewarming uses is 40-100 DEG C, preheating time 15-35min; For the temperature that the medium temperature drying uses for 80-140 DEG C, medium temperature drying time is 10-25min;The temperature that the high temperature drying uses Degree is 130-210 DEG C, and high temperature drying time is 10-20min.
CN201811266780.9A 2018-10-29 2018-10-29 A kind of welding rod and preparation method Pending CN109128584A (en)

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CN110977244A (en) * 2019-12-25 2020-04-10 湖北理工学院 Formula and production process of 07MnNiMoDR steel low-alloy welding rod for spherical tank at-50 DEG C
CN111112877A (en) * 2019-12-25 2020-05-08 湖北理工学院 Welding process of 07MnNiMoDR steel spherical tank at-50 DEG C
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CN113695790A (en) * 2021-08-31 2021-11-26 西安交通大学 Double-layer coating for arc planing and cutting strip and preparation method thereof
CN115926501A (en) * 2022-12-27 2023-04-07 广东省科学院中乌焊接研究所 Method for improving corrosion resistance of super duplex stainless steel structural member manufactured by electric arc additive manufacturing

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CN110977244A (en) * 2019-12-25 2020-04-10 湖北理工学院 Formula and production process of 07MnNiMoDR steel low-alloy welding rod for spherical tank at-50 DEG C
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CN113695790A (en) * 2021-08-31 2021-11-26 西安交通大学 Double-layer coating for arc planing and cutting strip and preparation method thereof
CN115926501A (en) * 2022-12-27 2023-04-07 广东省科学院中乌焊接研究所 Method for improving corrosion resistance of super duplex stainless steel structural member manufactured by electric arc additive manufacturing
CN115926501B (en) * 2022-12-27 2023-08-22 广东省科学院中乌焊接研究所 Method for improving corrosion resistance of super duplex stainless steel structural member manufactured by arc additive

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