CN110153595A - Applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side - Google Patents

Applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side Download PDF

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Publication number
CN110153595A
CN110153595A CN201910598489.XA CN201910598489A CN110153595A CN 110153595 A CN110153595 A CN 110153595A CN 201910598489 A CN201910598489 A CN 201910598489A CN 110153595 A CN110153595 A CN 110153595A
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CN
China
Prior art keywords
parts
stainless steel
welding
back side
exempted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910598489.XA
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Chinese (zh)
Inventor
肖辉英
侯云昌
牛月军
刘文利
唐艳丽
耿宽宽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Golden Bridge Welding Materials Group Co Ltd
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Tianjin Golden Bridge Welding Materials Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Golden Bridge Welding Materials Group Co Ltd filed Critical Tianjin Golden Bridge Welding Materials Group Co Ltd
Priority to CN201910598489.XA priority Critical patent/CN110153595A/en
Publication of CN110153595A publication Critical patent/CN110153595A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261Rods, electrodes, wires
    • B23K35/0266Rods, electrodes, wires flux-cored
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3608Titania or titanates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/365Selection of non-metallic compositions of coating materials either alone or conjoint with selection of soldering or welding materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/16Arc welding or cutting making use of shielding gas
    • B23K9/167Arc welding or cutting making use of shielding gas and of a non-consumable electrode

Abstract

The present invention provides a kind of back sides to exempt from applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire, including stainless steel welding stick and wraps in the coating on stainless steel wire surface;The coating powder raw material includes the component of following parts by weight, 30~45 parts of rutile, 10~20 parts of marble, 2~7 parts of fluorite, 3~10 parts of SILICA FUME, 2~7 parts of titanium dioxide, 5~15 parts of crome metal, 2~10 parts of manganese metal, 5~15 parts of iron powder.The present invention wraps up coating outside stainless steel welding stick, when welding protection coating can melt infiltration to the molten bath back side form one layer of fine and close protection skull, skull falls off after natural cooling, to the release applying argon gas measure of the pipeline back side and keep back of weld fully protected.Welding wire application method of the present invention and common stainless steel argon arc solid welding wire are essentially identical, flexible operation.Without splashing in welding process, the defects of arc stability, no undercut, slag inclusion.Molten iron, pulp water good fluidity, wellability are good.

Description

Applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side
Technical field
The invention belongs to field of welding material, exempt from applying argon gas self-shield stainless steel tungsten argon arc more particularly, to a kind of back side Welding wire.
Background technique
Argon tungsten-arc welding has welding arc stablility, welding bead beautiful appearance, the high feature of weldquality, in order to guarantee to weld Quality and cleaning inside degree generally use the welding method of argon arc bottoming in soldering stainless steel pipeline.Due to stainless steel and oxygen Affinity it is very big, if not taking weld seam protection measure, the weld metal at the back side is easy to aoxidize in the welding process, alloy Melting loss of elements, and the back side cannot form neat weld seam, be also easy to produce welding defect.Therefore, in stainless steel pipes argon arc welding, in order to Guarantee back of weld welding quality, it is necessary to when taking the measure of being effectively protected, i.e. backing welding welding bead front and the welding bead back side all When needing argon filling gas shielded, especially weld ell or three-port structure, safeguard measure is increasingly complex, and otherwise the back side of weld seam can be serious Oxidation.
But there are following difficulties for filling steel pipes with argon: argon gas consumption first is big, and time is long, and welding cost increases; Easily lead to welding quality unstable when followed by inner air tube displacement is not thorough;It is finally argon filling in large diameter pipeline and complexity Performance difficulty under the particular surroundings such as pipe network.
Summary of the invention
In view of this, the present invention is directed to propose applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side, with It solves the above problems.
In order to achieve the above objectives, the technical scheme of the present invention is realized as follows:
Applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side, including stainless steel welding stick and is wrapped in stainless The coating of steel wire surface;The coating powder raw material includes the component of following parts by weight, and 30~45 parts of rutile, marble 10~ 20 parts, 2~7 parts of fluorite, 3~10 parts of SILICA FUME, 2~7 parts of titanium dioxide, 5~15 parts of crome metal, 2~10 parts of manganese metal, iron powder 5 ~15 parts.
Preferably, the component including following parts by weight: 35~45 parts of rutile, 12~18 parts of marble, fluorite 2~7 Part, 5~8 parts of SILICA FUME, 3~5 parts of titanium dioxide, 8~12 parts of crome metal, 4~8 parts of manganese metal, 8-12 parts of iron powder.
Preferably, TiO in rutile2CaCO in mass content >=97.0%, marble3Mass content >=97.0%, fluorite Middle CaF2Mass content >=96.0%.
Preferably, the coating further includes binder, and additive amount is the 22-32% of powder.
Preferably, the binder is low mould potassium-sodium water glass, modulus 2.4-2.8.
Preferably, the coating accounts for the 15~25% of welding wire total weight.
Preferably, the diameter of the stainless steel wire is 1.6mm~3.2mm.
The effect of coating component:
Rutile: main component TiO2, there is stabilising arc and fluxing effect, can adjust fusing point, the viscosity, surface tension of slag And mobility.Improve appearance of weld, reduce splashing and undercut, and largely improves removability of slag energy.Excessive TiO2 The fusing point of slag will be improved, reduce the solidification temperature range of slag, hinder the mobilization between slag and liquid metal, influenced The abundant progress of metallurgical reaction makes the evolution resistance increase of bath gas, the defects of easily forming stomata, be mingled with.
Marble: main composition-calcium carbonate resolves into CaO and CO under the action of arc heat2, play gas slag Combined Protection The effect in molten bath.It can guarantee blow force of arc when welding, stablize electric arc, increase slag and metal interface tension and surface tension, Improve de- slag.Excessive marble improves the setting temperature of slag, reduces the viscosity of slag, sleeve is made to shorten, and blowing force increases, together When splash increase, appearance of weld is bad, and welding technological properties is made to degenerate.
Fluorite: main component is CaF2, it can reduce the fusing point of basic clinker, increase the mobility of slag, be conducive to drop The gaseous impurity of low weld metal can also reduce the hydrogen-sucking amount of liquid metals.CaF2When additional amount is excessive, welding arc will affect Stability, increase the molten drop diameter in welding process, splash increase, coating fusing it is too fast.
SILICA FUME: SILICA FUME is added, slag fluidity is adjusted, but to will lead to slag fluidity excessive for too high levels.
Titanium dioxide: the granularity of titanium dioxide is fine and smooth, can increase coating plasticity, welding rod extrusion performance and welding rod epidermis quality. But titanium dioxide is added should not be excessive, is added and excessively easily causes coating crackle.And processing performance is not so good as rutile.
Manganese metal, chromium powder main function be Transition-metal Alloys, guarantee alloy element component in weld seam.
Iron powder: iron powder can purify bath, while it can refine crystal grain again, accelerate the burn-off rate of coating, improve deposition effect Rate.
The invention also discloses the use that argon filling self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side as described above On the way, applying argon gas welding is exempted from the back side for stainless steel pipe, plate etc..
Compared with the existing technology, the weldering of applying argon gas self-shield argon tungsten arc welding of stainless steel is exempted from a kind of back side of the present invention Silk, the utility model has the advantages that
1, welding wire of the present invention wraps up coating outside stainless steel welding stick, when welding protection coating can melt infiltration to melting The pond back side forms one layer of fine and close protection skull, and skull falls off after natural cooling, so that the pipeline back side is exempted argon filling measure and made Back of weld is fully protected.
2, welding wire application method of the present invention and common stainless steel argon arc solid welding wire are essentially identical, flexible operation. Without splashing in welding process, the defects of arc stability, no undercut, slag inclusion.Molten iron, pulp water good fluidity, wellability are good.
3, welding wire postwelding of the present invention front back bead beautiful appearance, positive back side welding slag take off slag and are easy, solderless Splashing is connect, all-position welding can be carried out to workpiece.
4, welding wire postwelding weld seam corrosion resistance of the present invention is strong, and welding quality is high, reduces the preparation of argon filling, Welding cost is reduced, is improved work efficiency.
Specific embodiment
In addition to being defined, technical term used in following embodiment has and the invention one of ordinary skill in the art The identical meanings being commonly understood by.Test reagent used in following embodiment is unless otherwise specified conventional biochemical reagent; The experimental method is unless otherwise specified conventional method.
Below with reference to embodiment, the present invention will be described in detail.
Each ingredient powder of coating is taken in proportion;After mixing by powder, the water glass of the total composition quality 25% of medicinal powder is added Glass is uniformly mixed as coating binder;It is sent into hydraulic type extrusion press and is wrapped on ER308L stainless steel welding stick, It is baked again through low temperature and high temperature, argon filling self-shield stainless steel tungsten argon arc is exempted from manufacture growth 1000mm, the back side that specification is 2.5mm Welding wire.
Embodiment 1
Applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side, and the coating powder includes following parts by weight Several components, 40 parts of rutile, 13 parts of marble, 5 parts of fluorite, 6 parts of SILICA FUME, 4 parts of titanium dioxide, 11 parts of crome metal, manganese metal 5 Part, 11 parts of iron powder.
The ratio that the coating accounts for welding rod total weight is 20%.
Embodiment 2
Applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side, and the coating powder includes following parts by weight Several components, 36 parts of rutile, 16 parts of marble, 7 parts of fluorite, 6 parts of SILICA FUME, 5 parts of titanium dioxide, 10 parts of crome metal, manganese metal 6 Part, 10 parts of iron powder.
The ratio that the coating accounts for welding rod total weight is 20%.
Embodiment 3
Applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side, and the coating powder includes following parts by weight Several components, 45 parts of rutile, 10 parts of marble, 3 parts of fluorite, 6 parts of SILICA FUME, 3 parts of titanium dioxide, 9 parts of crome metal, manganese metal 5 Part, 10 parts of iron powder.
The ratio that the coating accounts for welding rod total weight is 20%.
Embodiment 4
Applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side, and the coating powder includes following parts by weight Several components, 42 parts of rutile, 11 parts of marble, 7 parts of fluorite, 7 parts of SILICA FUME, 4 parts of titanium dioxide, 11 parts of crome metal, manganese metal 7 Part, 11 parts of iron powder.
Comparative example 1
A kind of welding wire, the coating powder include the component of following parts by weight, 34 parts of rutile, 16 parts of marble, firefly 7 parts of stone, quartzy 6 parts, 4 parts of titanium dioxide, 11 parts of crome metal, 5 parts of manganese metal, 11 parts of iron powder.
The ratio that the coating accounts for welding rod total weight is 20%.
Comparative example 2
A kind of welding wire, the coating powder include the component of following parts by weight, 2 parts of rutile, 40 parts of marble, fluorite 5 parts, 1 part of SILICA FUME, 5 parts of titanium dioxide, 10 parts of crome metal, 4 parts of manganese metal, 15 parts of iron powder.
The ratio that the coating accounts for welding rod total weight is 20%.
Comparative example 3
A kind of welding wire, the coating powder include the component of following parts by weight, 22 parts of rutile, 30 parts of marble, firefly 17 parts of stone, 3 parts of SILICA FUME, 4 parts of titanium dioxide, 13 parts of crome metal, 5 parts of manganese metal, 17 parts of iron powder.
Comparative example 4
A kind of welding wire, the coating powder include the component of following parts by weight, 15 parts of rutile, 40 parts of marble, firefly 15 parts of stone, 4 parts of SILICA FUME, 5 parts of titanium dioxide, 5 parts of crome metal, 3 parts of manganese metal, 15 parts of iron powder.
The ratio that the coating accounts for welding rod total weight is 20%.
By above embodiments and the resulting welding wire of comparative example, presentation quality inspection is carried out to it, and use welds it Technological parameter: 110~140A of welding current, arc voltage are that 14~15V carries out welding process performance test, experimental result such as table Shown in one.
Table one
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (8)

1. applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side, it is characterised in that: including stainless steel welding stick and It wraps in the coating on stainless steel wire surface;The coating powder raw material includes the component of following parts by weight, 30~45 parts of rutile, 10~20 parts of marble, 2~7 parts of fluorite, 3~10 parts of SILICA FUME, 2~7 parts of titanium dioxide, 5~15 parts of crome metal, manganese metal 2~ 10 parts, 5~15 parts of iron powder.
2. applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side according to claim 1, feature exists In: the component including following parts by weight: 35~45 parts of rutile, 12~18 parts of marble, 2~7 parts of fluorite, SILICA FUME 5~8 Part, 3~5 parts of titanium dioxide, 8~12 parts of crome metal, 4~8 parts of manganese metal, 8-12 parts of iron powder.
3. applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side according to claim 1, feature exists In: TiO in rutile2CaCO in mass content >=97.0%, marble3CaF in mass content >=97.0%, fluorite2Quality contains Amount >=96.0%.
4. applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side according to claim 1, feature exists In: the coating further includes binder, and additive amount is the 22-32% of powder gross mass.
5. applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side according to claim 1, feature exists In: the binder is low mould potassium-sodium water glass, modulus 2.4-2.8.
6. applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side according to claim 1, feature exists In: the coating accounts for the 15~25% of welding wire total weight.
7. applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side according to claim 1, feature exists In: the diameter of the stainless steel wire is 1.6mm~3.2mm.
8. as the use of applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of described in any item back sides claim 1-8 On the way, it is characterised in that: exempt from applying argon gas welding in the back side for stainless steel pipe, plate etc..
CN201910598489.XA 2019-07-04 2019-07-04 Applying argon gas self-shield argon tungsten arc welding of stainless steel welding wire is exempted from a kind of back side Pending CN110153595A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111843286A (en) * 2020-07-16 2020-10-30 上海电机学院 Flux-cored wire and preparation method thereof
CN112975199A (en) * 2021-02-26 2021-06-18 天津市金桥焊材集团股份有限公司 Stainless steel welding rod for improving vertical welding process performance
CN114178739A (en) * 2021-12-27 2022-03-15 宣达实业集团有限公司 High-toughness high-silicon stainless steel argon-filling-free argon arc welding wire and preparation process thereof
CN115975513A (en) * 2023-03-16 2023-04-18 天津市金桥焊材集团股份有限公司 Binder for producing welding electrode

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1958213A (en) * 2005-11-01 2007-05-09 哈尔滨理工大学 Stainless steel welding rod of new dregs series
CN104191110A (en) * 2014-08-28 2014-12-10 北京金威焊材有限公司 One-face welding and two-face forming welding wire with back face argon-filling-free protection
CN105537801A (en) * 2015-09-01 2016-05-04 上海大西洋焊接材料有限责任公司 Stainless steel welding rod used for 904 L steel welding
CN106181127A (en) * 2016-08-24 2016-12-07 天津大桥金属焊丝有限公司 Argon filling self-shield argon tungsten-arc welding flux-cored wire is exempted from the stainless steel pipes back side

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1958213A (en) * 2005-11-01 2007-05-09 哈尔滨理工大学 Stainless steel welding rod of new dregs series
CN104191110A (en) * 2014-08-28 2014-12-10 北京金威焊材有限公司 One-face welding and two-face forming welding wire with back face argon-filling-free protection
CN105537801A (en) * 2015-09-01 2016-05-04 上海大西洋焊接材料有限责任公司 Stainless steel welding rod used for 904 L steel welding
CN106181127A (en) * 2016-08-24 2016-12-07 天津大桥金属焊丝有限公司 Argon filling self-shield argon tungsten-arc welding flux-cored wire is exempted from the stainless steel pipes back side

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111843286A (en) * 2020-07-16 2020-10-30 上海电机学院 Flux-cored wire and preparation method thereof
CN112975199A (en) * 2021-02-26 2021-06-18 天津市金桥焊材集团股份有限公司 Stainless steel welding rod for improving vertical welding process performance
CN112975199B (en) * 2021-02-26 2023-02-21 天津市金桥焊材集团股份有限公司 Stainless steel welding rod for improving vertical welding process performance
CN114178739A (en) * 2021-12-27 2022-03-15 宣达实业集团有限公司 High-toughness high-silicon stainless steel argon-filling-free argon arc welding wire and preparation process thereof
CN115975513A (en) * 2023-03-16 2023-04-18 天津市金桥焊材集团股份有限公司 Binder for producing welding electrode
CN115975513B (en) * 2023-03-16 2023-08-04 天津市金桥焊材集团股份有限公司 Adhesive for producing welding rod

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Address after: 300300 No. 1 Liujing Road, Dongli Development Zone, Dongli District, Tianjin

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Application publication date: 20190823