CN109127115A - A method of recycling Pb-Zn deposits object from high sulfur-lead-zinc ore tailing - Google Patents
A method of recycling Pb-Zn deposits object from high sulfur-lead-zinc ore tailing Download PDFInfo
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- CN109127115A CN109127115A CN201811138140.XA CN201811138140A CN109127115A CN 109127115 A CN109127115 A CN 109127115A CN 201811138140 A CN201811138140 A CN 201811138140A CN 109127115 A CN109127115 A CN 109127115A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B7/00—Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B1/00—Conditioning for facilitating separation by altering physical properties of the matter to be treated
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
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Abstract
The method that the invention discloses a kind of to recycle Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, belong to Mineral Processing Engineering technical field, the present invention successively carry out lead roughing after regulator, collecting agent and foaming agent will be added after high sulfur-lead-zinc ore tailing fine grinding, lead scan it is selected with lead, strengthen the recycling of micro-size fraction lead minerals, obtains lead concentrate;Then desliming is carried out to the tailing after plumbum floatation again, vulcanizing agent is added in sand setting after desliming, the roughing of Zinc oxide minerals is successively carried out after collecting agent and foaming agent, it is selected and scan, it can get two kinds of zinc concentrate products of high-grade zinc concentrate and low-grade zinc concentrate, it the roughing of Zinc oxide minerals and scans different collecting agents is respectively adopted, the method of the present invention can solve sludge serious interference during high sulfur-lead-zinc ore spoil reclaming, lead zinc recovery is low, the problems such as process flow complexity and reagent cost height are selected again, be conducive to improve the rate of recovery of the mineral such as lead zinc, present invention process is reasonable, process is simple, good separation effect, it is easy to industrializing implementation.
Description
Technical field
The method that the present invention relates to a kind of to recycle Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, belongs to Mineral Processing Engineering skill
Art field.
Background technique
High sulfur-lead-zinc ore is widely distributed, such as Huize, yunnan lead as a kind of common lead-zinc deposit type in China
Zinc ore, Yiliang Pb-Zn deposits, billows deep blue Pb-Zn deposits, Fankou Lead-zinc Deposit, Guangdong, Qixia Hill In Nanjing Pb-Zn deposits, Hunan Shuikoushan Lead-zinc Mine etc.
Extremely typical high sulfur-lead-zinc ore is belonged to, the content of iron sulfide mineral is usually higher in this kind of ore, up to 30% or more, has
A little even as high as 50% or more;In addition, lead zinc grade and lead zinc oxygenation efficiency are higher in this kind of ore, Pb+Zn grade is logical in ore
15% or more Chang Keda, as the grade of Pb+Zn in Yunnan Huize Pb-Zn, Yiliang Pb-Zn deposits has reached 25% or more.However, by
Pyrite content is high in ore, for the grade for improving lead and zinc concentrate, needs to have used a large amount of lime in raw ore floatation process
To inhibit pyrite.A large amount of uses of lime are also easy to in ore pulp though stronger inhibiting effect can be generated to pyrite
Galena, zincblende and the association rare precious metal mineral of microfine generate inhibiting effect, influence lead zinc and association rare precious metal etc.
The recycling of mineral causes Pb, Zn content in tailing excessively high, as the content of lead zinc in Huize Lead-zinc Mine tailing may be up to 0.81 ~
1.1%, 2.5 ~ 3.2%, the loss of lead zinc is serious.
Further, since the content of the sulfide minerals such as galena, zincblende, pyrite is higher in ore, mineralizing process chats
Geochemistry process between object is more strong, and it is white for leading to the sulfide minerals oxidation alteration such as part galena, zincblende in ore
The oxide minerals such as lead ore, smithsonite, smithsonite.However, the recovery process process due to lead Oxide ores of zinc is complex, big portion
Divide high sulfur-lead-zinc ore to select the recycling for not accounting for the oxide minerals such as lead zinc in the mineral processing circuit of factory, causes a large amount of lead zinc
Mineral loss is in tailing.
Therefore, in the removal process of high-sulfur Pb-Zn tailings, emphasis is needed to consider the work of two aspects: first is that micro- in tailing
The recycling of particulate lead-zinc sulphide minerals;Second is that in tailing lead Oxide ores of zinc recycling.In these areas, although doing both at home and abroad
A large amount of research, but since tailing physical property is special, selects process sludge serious interference, reagent cost height, process flow complexity again etc.
Factor causes selecting again for high sulfur-lead-zinc ore tailing to be difficult to obtain preferable sorting index and be difficult to realize industrial application.As opened
Jin Min has invented a kind of Pb-Zn tailings recoverying and utilizing method (Zhang Jinmin Pb-Zn tailings recoverying and utilizing method [P] again again
Chinese patent: 201210220652.7), in the invention using the concentrated sulfuric acid and sodium chloride saturated solution to Pb-Zn tailings into
Row hydrometallurgic recovery can recycle the metals such as lead, zinc, silver simultaneously, but due to the Pb-Zn tailings enormous amount that China generates every year, and soak
Process is the progress equipment seriously corroded in strong acidic environment out, and there are still certain offices in terms of industrial application for the technology
Limit.Ma Yue et al. has invented the method for Pb-Zn tailings comprehensive recovery of lead zinc a kind of, and (a kind of Pb-Zn tailings of the such as Ma Yue, Li Wei are comprehensive
Close method [P] Chinese patent of recycling lead zinc: 201610670115.0), this method is first classified Pb-Zn tailings ,+
The coarse grain of 0.074mm carries out preenrichment using spiral chute, and the fine fraction of -0.074mm carries out bulk flotation, then again by spiral
The concentrate of chute carries out ore grinding after merging with the concentrate of bulk flotation, carries out roughing, selected and scan after regrinding again, final to obtain
Lead and zinc bulk concentrate.Although the invention lead zinc recovery is higher, due to using the process integrations such as screening, gravity treatment, flotation, work
Skill process is complicated, and the concentrate finally obtained is lead and zinc bulk concentrate, it is difficult to real lead zinc efficiently separates, added value of product compared with
It is low.Feng Zhongwei etc. Guizhou Pb-Zn tailings have been carried out lead zinc sulphur in tailing comprehensive recovery experiment (Feng Zhongwei, Ning Fatian,
Lan Guimi, waits synthetical recovery [J] metal mine of lead zinc sulphur in the Pb-Zn tailings of the Guizhou, and 2009, (394): 157-
160), using the mixed floating concentrate zinc sulphur content of the preferential bulk flotation-of sulphide ore from the technique recycling tailing of-lead oxide ore sulfide flotation
The mineral such as lead zinc sulphur, achieve preferable sorting index, and the final grade and the rate of recovery for aoxidizing lead in lead concentrate reaches respectively
48.56% and 85.38%, but the process flow is primarily directed to the recycling of lead oxide mineral in tailing, to zinc oxide in tailing
Recovering effect it is poor.Therefore, how on the basis of original process flow and equipment, lead zinc in high sulfur-lead-zinc ore tailing is carried out
The high efficiente callback of equal mineral, is still one of the main bugbear that mineral manufacture field faces.
Summary of the invention
The method that the object of the present invention is to provide a kind of to recycle Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, with traditional elder generation
The Pb-Zn tailings of flotation select the technique different again again for desliming, and the present invention is according to the embedding cloth of the mineral such as lead zinc in high sulfur-lead-zinc ore tailing
The physical property feature of feature, enrichment discipline and tailing preferentially carries out flotation recovery to the microfine lead minerals in high-sulfur Pb-Zn tailings,
Loss of the micro-size fraction Pb-Zn deposits object in desliming process is reduced, and roughing and scans the different collecting of use in zinc floatation process
Agent type can reduce sludge to the adverse effect of zinc flotation, the synchronous grade and the rate of recovery for improving zinc concentrate.
The present invention is realized by following technical scheme: a method of recycling Pb-Zn deposits object from high sulfur-lead-zinc ore tailing,
Specific step is as follows:
It (1) by high sulfur-lead-zinc ore tailing in pulp density is first 60 ~ 65% lower progress ore grindings, ore grinding is small to granularity in mass
82 ~ 85% are accounted in 0.074mm;
(2) after regulating step (1) ore grinding then it is inclined that dispersing agent six is successively added to 22 ~ 25% in the pulp density of product into ore pulp
Sodium phosphate, collecting agent butyl xanthate, foaming agent 2#Oil carries out lead roughing, obtains lead rougher concentration and lead rougher tailings;
(3) that the lead rougher concentration that step (2) obtain is carried out lead in the case where not adding medicament is selected, obtains the selected concentrate of lead and lead is smart
Tailing is selected, the selected concentrate of lead is final lead concentrate;
(4) collecting agent butyl xanthate, foaming agent 2 are sequentially added in the lead rougher tailings obtained to step (2)#Oil carries out lead and scans,
It obtains lead scavenger concentrate and lead scans tailing, return again to after lead scavenger concentrate is mixed with the lead cleaner tailings of step (3) to lead
Roughing process forms closed cycle;
(5) lead of step (4), which is scanned tailing, carries out desliming, overflow and sand setting after obtaining desliming, after the concentrated dehydration of overflow
As sludge;
(6) pulp density of the sand setting after regulating step (5) desliming is 32 ~ 35%, and vulcanizing agent vulcanization is then added into ore pulp
Sodium, collecting agent I, foaming agent 2#Oil carries out zinc roughing I, obtains I concentrate of zinc roughing and I tailing of zinc roughing;
(7) I concentrate of zinc roughing of step (6) is subjected under not adding medicine zinc selected I, obtains selected I concentrate of zinc and zinc selected I
Tailing, selected I concentrate of zinc are final zinc concentrate I, and zinc concentrate I is high-grade zinc concentrate;
(8) vulcanizing agent vulcanized sodium, collecting agent I, foaming agent 2 are sequentially added into I tailing of zinc roughing of step (6)#Oil carries out zinc
Roughing II, obtains II concentrate of zinc roughing and II tailing of zinc roughing, II concentrate of zinc roughing are mixed with selected I tailing of the zinc of step (7)
After be back to zinc roughing I, form closed cycle;
(9) vulcanizing agent vulcanized sodium is sequentially added into II tailing of zinc roughing of step (8), collecting agent II carries out zinc and scans I, acquisition
Zinc scans I concentrate and zinc scans I tailing;
(10) scanned to the zinc of step (9) sequentially added in I tailing vulcanizing agent vulcanized sodium, collecting agent II carry out zinc scan II, obtain
Zinc scans II concentrate and zinc scans II tailing, it is final tailing that zinc, which scans II tailing,;
(11) zinc of step (10) is scanned into II concentrate and scans addition inhibitor progress zinc after I concentrate merges with the zinc of step (9)
Selected II, selected II concentrate of zinc and selected II tailing of zinc are obtained, selected II tailing of zinc returns to zinc and scans in I, closed cycle is formed,
Selected II concentrate of zinc is zinc concentrate II, and zinc concentrate II is low grade zinc concentrate.
The collecting agent I is that the mixture of acetic acid octadecylamine and isoamyl xanthate, wherein acetic acid octadecylamine and isopentyl are yellow
The mass ratio of medicine is 4:1, and the purity of acetic acid octadecylamine is 70 ~ 80%.
The collecting agent II is lauryl amine, is formulated as lauryl amine solution with the dilute hydrochloric acid that mass fraction is 3 ~ 5% when use.
The amount that sodium hexametaphosphate dispersant is added in step (2) the lead roughing is 1000 ~ 1200g/t, collecting agent butyl xanthate
Amount be 80 ~ 120g/t, foaming agent 2#The amount of oil is 20 ~ 40g/t, and step (4) lead, which is scanned, is added collecting agent butyl xanthate
Amount is 40 ~ 60 g/t, foaming agent 2#The amount of oil is 15 ~ 20g/t.
Step (5) the desliming device therefor is hydrocyclone.
The amount that vulcanizing agent vulcanized sodium is added in step (6) the zinc roughing I is 1600 ~ 2000g/t, and the amount of collecting agent I is 150
~ 200g/t, foaming agent 2#The amount of oil is 30 ~ 50g/t, and the amount that vulcanizing agent vulcanized sodium is added in step (8) the zinc roughing II is
1000 ~ 1200g/t, the amount of collecting agent I are 80 ~ 100g/t, foaming agent 2#The amount of oil is 20 ~ 30g/t, and step (9) zinc is swept
The amount for selecting I addition vulcanizing agent vulcanized sodium is 800 ~ 1000g/t, and the amount of collecting agent II is 60 ~ 80g/t, and step (10) zinc is swept
The amount for selecting the vulcanizing agent vulcanized sodium of II addition is 400 ~ 500g/t, and the dosage of collecting agent II is 30 ~ 40g/t, the step (11)
The inhibitor that zinc selected II is added is sodium metasilicate, and dosage is 400 ~ 600g/t.
Equipment used in step (1) ore grinding is rod mill.
Acetic acid octadecylamine used in the present invention is bought by Shanghai Ci Tai Yilong Industry Co., Ltd..
Compared with prior art, the beneficial effects of the present invention are:
(1) present invention selects recycling just for mineral such as lead zinc in high sulfur-lead-zinc ore tailing again, is not related to the mines such as lead zinc in raw ore
The flotation recovery of object.
(2) the spoil reclaming technique before plumbum floatation of the present invention without desliming, with traditional " preferential desliming flotation again "
It compares, loss of the micro-size fraction Pb-Zn deposits object in sludge in tailing can be reduced.
(3) in zinc floatation process of the present invention, first using the collecting of the mixture of acetic acid octadecylamine and isoamyl xanthate composition
Agent I carries out roughing, improves concentrate grade, then scanned using lauryl amine, improves zinc recovery, with well known " vulcanization-ten two
Amine " method technique is compared, and gained lead and zinc concentrate grade and the rate of recovery are higher.
(4) zinc roughing of the present invention is using the mixture of acetic acid octadecylamine and isoamyl xanthate as collecting agent I, foam thickness
Spend moderate, gangue mineral entrainment is few, does not easily cause and runs slot phenomenon.
(5) the method for the present invention process flow is reasonable, and flowage structure is simple, is easy to industrializing implementation.
Zinc oxide roughing of the present invention uses the mixture of acetic acid octadecylamine and different isoamyl xanthate as collecting agent I, sufficiently
Using the selectively strong feature of acetic acid octadecylamine and isoamyl xanthate, to improve the grade of zinc concentrate;And zinc oxide scans use
For lauryl amine as collecting agent, the feature for making full use of lauryl amine collecting ability strong improves the rate of recovery of zinc concentrate.With the present invention
Method can significantly improve the rate of recovery of the mineral such as lead zinc in high sulfur-lead-zinc ore tailing, and Zinc oxide minerals returns especially in tailing
It receives, improves the comprehensive utilization ratio of Pb-Zn deposits resource, adverse effect of the lead zinc to environment in reduction tailing.
Detailed description of the invention
Fig. 1 is process flow diagram of the invention.
Specific embodiment
Method of the invention is described in further detail with reference to the accompanying drawings and examples, but the scope of the present invention is not
It is confined to the content.
Embodiment 1: this recycles the method for Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, and selected tailing sample is derived from Yunnan
Huize high sulfur-lead-zinc ore tailing library, tailing contain Pb 0.84%, Zn 3.67%, S 1.89%, Fe 2.94%, wherein containing lead minerals
Predominantly galena and cerussite, zinc-bearing mineral are mainly zincblende, smithsonite and zinc silicate.
(1) tailing is added in rod mill, adds water to adjust after pulp density is 62% and carry out ore grinding, ore grinding is to matter
Meter granularity is less than 0.074mm and accounts for 83.2%;
(2) pulp density of regulating step (1) resulting ore milling product is 24%, then sequentially adds sodium hexametaphosphate dispersant
1000g/t, collecting agent butyl xanthate 100g/t, foaming agent 2#Oily 30g/t carries out lead roughing, obtains lead rougher concentration and lead roughing tail
Mine;
(3) that the lead rougher concentration that step (2) obtain is carried out lead in the case where not adding any medicament is selected, obtain the selected concentrate of lead with
Lead cleaner tailings, the selected concentrate of lead is as final lead concentrate;
(4) butyl xanthate 50g/t, foaming agent 2 are sequentially added in the lead rougher tailings obtained to step (2)#Oily 20g/t carries out lead and sweeps
Choosing obtains lead scavenger concentrate and lead and scans tailing, returned again to after lead scavenger concentrate is mixed with the lead cleaner tailings of step (3) to
Upper level lead roughing forms closed cycle;
(5) lead of step (4) is scanned into tailing and is pumped into hydrocyclone progress desliming, mine is used as after cyclone overflow thickening
Mud is discarded, and hydrocyclone sand, which enters, selects zinc operation;
(6) pulp density of the hydrocyclone sand of regulating step (5) is 32%, sequentially adds vulcanized sodium 1800g/t, collecting agent I
160g/t, foaming agent 2#Oily 40g/t carries out zinc roughing I, obtains I concentrate of zinc roughing and I tailing of zinc roughing, and wherein collecting agent I is
The mixture of acetic acid octadecylamine and isoamyl xanthate, wherein the mass ratio of acetic acid octadecylamine and isoamyl xanthate is 4:1, and acetic acid
The purity of octadecylamine is 70%;
(7) I concentrate of zinc roughing of step (6) is subjected to zinc selected I in the case where not adding any medicament, obtain selected I concentrate of zinc and
Selected I tailing of zinc, selected I concentrate of zinc are high-grade zinc concentrate as zinc concentrate I, zinc concentrate I, and selected I tailing of zinc is back to zinc
Roughing I forms closed cycle;
(8) vulcanized sodium 1000g/t, collecting agent I 80g/t, 2 are added into I tailing of zinc roughing of step (6)#Oily 20g/t carries out zinc
Roughing II, obtains II concentrate of zinc roughing and II tailing of zinc roughing, II concentrate of zinc roughing are mixed with selected I tailing of the zinc of step (7)
After be back to zinc roughing I, form closed cycle;
(9) vulcanizing agent vulcanized sodium 800g/t is sequentially added into II tailing of zinc roughing of step (8), II 80g/t of collecting agent sizes mixing
Carry out zinc afterwards and scan I, obtain that zinc scans I concentrate and zinc scans I tailing, wherein II lauryl amine of collecting agent, and using when quality
The dilute hydrochloric acid that score is 3% is formulated as lauryl amine solution;
(10) it scans after I tailing sequentially adds vulcanizing agent vulcanized sodium 500g/t, II 40g/t of collecting agent and carries out to the zinc of step (9)
Zinc scans II, and acquisition zinc scans II concentrate and zinc scans II tailing, and it is discarded as true tailings that zinc scans II tailing;
(11) zinc of step (10) is scanned into II concentrate and scans addition inhibitor sodium metasilicate after I concentrate merges with the zinc of step (9)
400g/t carries out zinc selected II, obtains selected II concentrate of zinc and selected II tailing of zinc, and selected II tailing of zinc returns to zinc and scans in I,
Closed cycle is formed, selected II concentrate of zinc is zinc concentrate II, and zinc concentrate II is low grade zinc concentrate.
The lead concentrate lead grade finally obtained is 35.23%, lead recovery 59.44%, I zinc grade 39.17% of zinc concentrate, zinc
The rate of recovery 41.40%, II zinc grade 26.78% of zinc concentrate, the rate of recovery 37.29% efficiently realize time of the mineral such as lead zinc in tailing
It receives, reduces the content of lead zinc in secondary tailing.
Embodiment 2: this recycles the method for Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, and it is clear that tailing sample used is derived from Yunnan
Logical Yiliang lead-zinc ore tailings library, tailing contain Pb 1.02%, Zn 2.83%, S 3.14%, Fe 5.28%, Ag 4.2g/t, 3.05 Ge
G/t, wherein containing, lead minerals is mainly galena and granularity is thinner, and zinc-bearing mineral is mainly smithsonite.
(1) tailing is added in rod mill, adds water to adjust after pulp density is 65% and carry out ore grinding, ore grinding is to matter
Meter granularity is less than 0.074mm and accounts for 82%;
(2) pulp density of regulating step (1) resulting ore milling product is 23%, then sequentially adds sodium hexametaphosphate dispersant
1200g/t, collecting agent butyl xanthate 80g/t, foaming agent 2#Oily 20g/t carries out lead roughing, obtains lead rougher concentration and lead roughing tail
Mine;
(3) that the lead rougher concentration that step (2) obtain is carried out lead in the case where not adding any medicament is selected, obtain the selected concentrate of lead with
Lead cleaner tailings, the selected concentrate of lead is as final lead concentrate;
(4) butyl xanthate 40g/t, foaming agent 2 are sequentially added in the lead rougher tailings obtained to step (2)#Oily 15g/t carries out lead and sweeps
Choosing obtains lead scavenger concentrate and lead and scans tailing, returned again to after lead scavenger concentrate is mixed with the lead cleaner tailings of step (3) to
Upper level lead roughing forms closed cycle;
(5) lead of step (4) is scanned into tailing and is pumped into hydrocyclone progress desliming, mine is used as after cyclone overflow thickening
Mud is discarded, and hydrocyclone sand, which enters, selects zinc operation;
(6) pulp density of the hydrocyclone sand of regulating step (5) is 34%, sequentially adds vulcanized sodium 1600g/t, collecting agent I
200g/t, foaming agent 2#Oily 30g/t carries out zinc roughing I, obtains I concentrate of zinc roughing and I tailing of zinc roughing, and wherein collecting agent I is
The mixture of acetic acid octadecylamine and isoamyl xanthate, wherein the mass ratio of acetic acid octadecylamine and isoamyl xanthate is 5:1, and acetic acid
The purity of octadecylamine is 80%;
(7) I concentrate of zinc roughing of step (6) is subjected to zinc selected I in the case where not adding any medicament, obtain selected I concentrate of zinc and
Selected I tailing of zinc, selected I concentrate of zinc are high-grade zinc concentrate as zinc concentrate I, zinc concentrate I, and selected I tailing of zinc is back to zinc
Roughing I forms closed cycle;
(8) vulcanized sodium 1200g/t, collecting agent I 100g/t, 2 are added into I tailing of zinc roughing of step (6)#Oily 25g/t is carried out
Zinc roughing II, obtains II concentrate of zinc roughing and II tailing of zinc roughing, and II concentrate of zinc roughing and selected I tailing of zinc of step (7) are mixed
It is back to zinc roughing I after conjunction, forms closed cycle;
(9) vulcanizing agent vulcanized sodium 1000g/t is sequentially added into II tailing of zinc roughing of step (8), II 60g/t of collecting agent sizes mixing
Carry out zinc afterwards and scan I, obtain that zinc scans I concentrate and zinc scans I tailing, wherein II lauryl amine of collecting agent, and using when quality
The dilute hydrochloric acid that score is 4% is formulated as lauryl amine solution;
(10) it scans after I tailing sequentially adds vulcanizing agent vulcanized sodium 400g/t, II 30g/t of collecting agent and carries out to the zinc of step (9)
Zinc scans II, and acquisition zinc scans II concentrate and zinc scans II tailing, and it is discarded as true tailings that zinc scans II tailing;
(11) zinc of step (10) is scanned into II concentrate and scans addition inhibitor sodium metasilicate after I concentrate merges with the zinc of step (9)
500g/t carries out zinc selected II, obtains selected II concentrate of zinc and selected II tailing of zinc, and selected II tailing of zinc returns to zinc and scans in I,
Closed cycle is formed, selected II concentrate of zinc is zinc concentrate II, and zinc concentrate II is low grade zinc concentrate.
The lead concentrate lead grade finally obtained is 38.19%, lead recovery 54.38%, and lead concentrate argentiferous 186.4g/t, silver return
Yield 58.19%, I zinc grade 37.81% of zinc concentrate, zinc recovery 39.54%, the germanic 89.64g/t of zinc concentrate I, the germanium rate of recovery
36.89%, II zinc grade 29.32% of zinc concentrate, the rate of recovery 41.36% realize the multi minerals such as lead in tailing, zinc, silver, germanium
High efficiente callback.
Embodiment 3: this recycles the method for Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, and it is all that tailing sample used is derived from Guangdong
Mouth lead-zinc ore tailings library, tailing contain Pb 0.97%, Zn 1.94%, S 2.27%, Fe 3.22%, SiO232.84%, wherein leaded
Mineral are mainly galena, and zinc-bearing mineral is mainly smithsonite, zincblende and willemite, and main gangue mineral is quartz and white clouds
Stone.
(1) tailing is added in rod mill, adds water to adjust after pulp density is 60% and carry out ore grinding, ore grinding is to matter
Meter granularity is less than 0.074mm and accounts for 85%;
(2) pulp density of regulating step (1) resulting ore milling product is 25%, then sequentially adds sodium hexametaphosphate dispersant
1100g/t, collecting agent butyl xanthate 120g/t, foaming agent 2#Oily 40g/t carries out lead roughing, obtains lead rougher concentration and lead roughing tail
Mine;
(3) that the lead rougher concentration that step (2) obtain is carried out lead in the case where not adding any medicament is selected, obtain the selected concentrate of lead with
Lead cleaner tailings, the selected concentrate of lead is as final lead concentrate;
(4) butyl xanthate 60g/t, foaming agent 2 are sequentially added in the lead rougher tailings obtained to step (2)#Oily 18g/t carries out lead and sweeps
Choosing obtains lead scavenger concentrate and lead and scans tailing, returned again to after lead scavenger concentrate is mixed with the lead cleaner tailings of step (3) to
Upper level lead roughing forms closed cycle;
(5) lead of step (4) is scanned into tailing and is pumped into hydrocyclone progress desliming, mine is used as after cyclone overflow thickening
Mud is discarded, and hydrocyclone sand, which enters, selects zinc operation;
(6) pulp density of the hydrocyclone sand of regulating step (5) is 35%, sequentially adds vulcanized sodium 2000g/t, collecting agent I
150g/t, foaming agent 2#Oily 50g/t carries out zinc roughing I, obtains I concentrate of zinc roughing and I tailing of zinc roughing, and wherein collecting agent I is
The mixture of acetic acid octadecylamine and isoamyl xanthate, wherein the mass ratio of acetic acid octadecylamine and isoamyl xanthate is 2:1, and acetic acid
The purity of octadecylamine is 78%;
(7) I concentrate of zinc roughing of step (6) is subjected to zinc selected I in the case where not adding any medicament, obtain selected I concentrate of zinc and
Selected I tailing of zinc, selected I concentrate of zinc are high-grade zinc concentrate as zinc concentrate I, zinc concentrate I, and selected I tailing of zinc is back to zinc
Roughing I forms closed cycle;
(8) vulcanized sodium 1100g/t, collecting agent I 90g/t, 2 are added into I tailing of zinc roughing of step (6)#Oily 30g/t carries out zinc
Roughing II, obtains II concentrate of zinc roughing and II tailing of zinc roughing, II concentrate of zinc roughing are mixed with selected I tailing of the zinc of step (7)
After be back to zinc roughing I, form closed cycle;
(9) vulcanizing agent vulcanized sodium 900g/t is sequentially added into II tailing of zinc roughing of step (8), II 70g/t of collecting agent sizes mixing
Carry out zinc afterwards and scan I, obtain that zinc scans I concentrate and zinc scans I tailing, wherein II lauryl amine of collecting agent, and using when quality
The dilute hydrochloric acid that score is 5% is formulated as lauryl amine solution;
(10) it scans after I tailing sequentially adds vulcanizing agent vulcanized sodium 450g/t, II 35g/t of collecting agent and carries out to the zinc of step (9)
Zinc scans II, and acquisition zinc scans II concentrate and zinc scans II tailing, and it is discarded as true tailings that zinc scans II tailing;
(11) zinc of step (10) is scanned into II concentrate and scans addition inhibitor sodium metasilicate after I concentrate merges with the zinc of step (9)
600g/t carries out zinc selected II, obtains selected II concentrate of zinc and selected II tailing of zinc, and selected II tailing of zinc returns to zinc and scans in I,
Closed cycle is formed, selected II concentrate of zinc is zinc concentrate II, and zinc concentrate II is low grade zinc concentrate.
The lead concentrate lead grade finally obtained is 40.13%, lead recovery 48.52%, and lead concentrate argentiferous 232.6g/t, silver return
Yield 46.58%, 1 zinc grade 35.48% of zinc concentrate, zinc recovery 42.72%, 2 zinc grade 26.58% of zinc concentrate, the rate of recovery
45.24%, realize the high efficiente callback of the multi minerals such as lead in tailing, zinc, silver.
Claims (7)
1. a kind of method for recycling Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, which is characterized in that specific step is as follows:
It (1) by high sulfur-lead-zinc ore tailing in pulp density is first 60 ~ 65% lower progress ore grindings, ore grinding is small to granularity in mass
82 ~ 85% are accounted in 0.074mm;
(2) after regulating step (1) ore grinding then it is inclined that dispersing agent six is successively added to 22 ~ 25% in the pulp density of product into ore pulp
Sodium phosphate, collecting agent butyl xanthate, foaming agent 2#Oil carries out lead roughing, obtains lead rougher concentration and lead rougher tailings;
(3) that the lead rougher concentration that step (2) obtain is carried out lead in the case where not adding medicament is selected, obtains the selected concentrate of lead and lead is smart
Tailing is selected, the selected concentrate of lead is final lead concentrate;
(4) collecting agent butyl xanthate, foaming agent 2 are sequentially added in the lead rougher tailings obtained to step (2)#Oil carries out lead and scans, and obtains
It obtains lead scavenger concentrate and lead scans tailing, returned again to after lead scavenger concentrate is mixed with the lead cleaner tailings of step (3) thick to lead
Choosing forms closed cycle;
(5) lead of step (4), which is scanned tailing, carries out desliming, overflow and sand setting after obtaining desliming, after the concentrated dehydration of overflow
As sludge;
(6) pulp density of the sand setting after regulating step (5) desliming is 32 ~ 35%, and vulcanizing agent vulcanization is then added into ore pulp
Sodium, collecting agent I, foaming agent 2#Oil carries out zinc roughing I, obtains I concentrate of zinc roughing and I tailing of zinc roughing;
(7) I concentrate of zinc roughing of step (6) is subjected under not adding medicine zinc selected I, obtains selected I concentrate of zinc and zinc selected I
Tailing, selected I concentrate of zinc are final zinc concentrate I, and zinc concentrate I is high-grade zinc concentrate;
(8) vulcanizing agent vulcanized sodium, collecting agent I, foaming agent 2 are sequentially added into I tailing of zinc roughing of step (6)#It is thick that oil carries out zinc
II is selected, II concentrate of zinc roughing and II tailing of zinc roughing are obtained, after II concentrate of zinc roughing is mixed with selected I tailing of the zinc of step (7)
It is back to zinc roughing I, forms closed cycle;
(9) vulcanizing agent vulcanized sodium is sequentially added into II tailing of zinc roughing of step (8), collecting agent II carries out zinc and scans I, acquisition
Zinc scans I concentrate and zinc scans I tailing;
(10) scanned to the zinc of step (9) sequentially added in I tailing vulcanizing agent vulcanized sodium, collecting agent II carry out zinc scan II, obtain
Zinc scans II concentrate and zinc scans II tailing, it is final tailing that zinc, which scans II tailing,;
(11) zinc of step (10) is scanned into II concentrate and scans addition inhibitor progress zinc after I concentrate merges with the zinc of step (9)
Selected II, selected II concentrate of zinc and selected II tailing of zinc are obtained, selected II tailing of zinc returns to zinc and scans in I, closed cycle is formed,
Selected II concentrate of zinc is zinc concentrate II, and zinc concentrate II is low grade zinc concentrate.
2. the method according to claim 1 for recycling Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, it is characterised in that: described
Collecting agent I is the mixture of acetic acid octadecylamine and isoamyl xanthate, and wherein the mass ratio of acetic acid octadecylamine and isoamyl xanthate is 2
~ 5:1, and the purity of acetic acid octadecylamine is 70 ~ 80%.
3. the method according to claim 1 for recycling Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, it is characterised in that: described
Collecting agent II is lauryl amine, is formulated as lauryl amine solution with the dilute hydrochloric acid that mass fraction is 3 ~ 5% when use.
4. the method according to claim 1 for recycling Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, it is characterised in that: described
The amount that sodium hexametaphosphate dispersant is added in step (2) lead roughing is 1000 ~ 1200g/t, the amount of collecting agent butyl xanthate is 80 ~
120g/t, foaming agent 2#The amount of oil is 20 ~ 40g/t, and it is 40 ~ 60 that step (4) lead, which is scanned and the amount of collecting agent butyl xanthate is added,
G/t, foaming agent 2#The amount of oil is 15 ~ 20g/t.
5. the method according to claim 1 for recycling Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, it is characterised in that: described
Step (5) desliming device therefor is hydrocyclone.
6. the method according to claim 1 for recycling Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, it is characterised in that: described
The amount that vulcanizing agent vulcanized sodium is added in step (6) zinc roughing I is 1600 ~ 2000g/t, and the amount of collecting agent I is 150 ~ 200g/t, blistering
Agent 2#The amount of oil is 30 ~ 50g/t, and the amount that vulcanizing agent vulcanized sodium is added in step (8) the zinc roughing II is 1000 ~ 1200g/t, is caught
The amount for receiving agent I is 80 ~ 100g/t, foaming agent 2#The amount of oil is 20 ~ 30g/t, and step (9) zinc scans I addition vulcanizing agent sulphur
The amount for changing sodium is 800 ~ 1000g/t, and the amount of collecting agent II is 60 ~ 80g/t, and step (10) zinc scans the vulcanizing agent of II addition
The amount of vulcanized sodium is 400 ~ 500g/t, and the dosage of collecting agent II is 30 ~ 40g/t, the suppression that step (11) zinc selected II is added
Preparation is sodium metasilicate, and dosage is 400 ~ 600g/t.
7. the method according to claim 1 for recycling Pb-Zn deposits object from high sulfur-lead-zinc ore tailing, it is characterised in that: described
Equipment used in step (1) ore grinding is rod mill.
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CN112958271A (en) * | 2021-02-25 | 2021-06-15 | 广东省科学院资源综合利用研究所 | Separation flotation method for dolomite-barite type lead-zinc ore |
CN113210123A (en) * | 2021-04-26 | 2021-08-06 | 吉林大学 | Lead separation method for lead-containing tailings |
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CN112958271A (en) * | 2021-02-25 | 2021-06-15 | 广东省科学院资源综合利用研究所 | Separation flotation method for dolomite-barite type lead-zinc ore |
CN113210123A (en) * | 2021-04-26 | 2021-08-06 | 吉林大学 | Lead separation method for lead-containing tailings |
CN113731638A (en) * | 2021-07-27 | 2021-12-03 | 甘肃省合作早子沟金矿有限责任公司 | Method for improving gold separation recovery rate of ore by regrinding middling |
CN114453129A (en) * | 2022-01-13 | 2022-05-10 | 湖南有色金属研究院有限责任公司 | Lead-zinc ore recycling method |
CN114453129B (en) * | 2022-01-13 | 2023-09-26 | 湖南有色金属研究院有限责任公司 | Lead zinc ore recycling method |
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