CN109125178A - A kind of whitening toothpaste and preparation method thereof effectively removing creamy white spot - Google Patents
A kind of whitening toothpaste and preparation method thereof effectively removing creamy white spot Download PDFInfo
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- CN109125178A CN109125178A CN201811195111.7A CN201811195111A CN109125178A CN 109125178 A CN109125178 A CN 109125178A CN 201811195111 A CN201811195111 A CN 201811195111A CN 109125178 A CN109125178 A CN 109125178A
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- creamy white
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/81—Preparation or application process involves irradiation
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Abstract
The invention discloses a kind of whitening toothpastes and preparation method thereof for effectively removing creamy white spot, the whitening toothpaste of preparation is significant to the removal effect of creamy white spot, make breath freshening persistently, permanent tooth anti-inflammatory, antiallergy, wherein nanometer hydroxyapatite and leached tea oil slag extracting solution act synergistically, the decontamination stain-removing effect for improving gained toothpaste of high degree.Nanometer hydroxyapatite is activated, enhance its reactivity, improve calcium ion, phosphate radical particle rate of release, leached tea oil slag extracting solution is promoted to decompose creamy white spot, and it forms new repair layer and fills up in color spot decomposition position, creamy white spot decomposition rate and discomposing effect are enhanced, its exogenous color spot removal ability, tooth-whitening are improved.It in leached tea oil slag extraction process, is handled using pulse, the extraction efficiency of effective component Tea Saponin in leached tea oil slag can be improved, saved production cost, avoid the waste of resource, also further improve the whitening effect of gained toothpaste.
Description
Technical field
The invention belongs to life chemical product technical field, especially a kind of whitening toothpaste for effectively removing creamy white spot and its system
Preparation Method.
Background technique
Dental exogenous mottle refers to the color spot or calculus of dental surface attachment.Smoking, long-term consumption are rich in the food of tannic acid
Object such as tea, red wine etc., and can all promote external source using certain cationic formulations such as chlorohexidene or multivalent metal salt such as tin, iron etc.
The formation of property color spot.
Currently, the color spot on processing tooth, common selection toothwash+polishing+sandblasting method, although can obtain preferable
Beautiful, cleaning effect, but it is costly, tooth is injured larger.
Summary of the invention
In view of the above-mentioned problems, the present invention is intended to provide a kind of whitening toothpaste and preparation method thereof for effectively removing creamy white spot.
The invention is realized by the following technical scheme:
A kind of whitening toothpaste effectively removing creamy white spot, which is characterized in that be made of raw material from the following weight:
Leached tea oil slag powder 20-40, nanometer hydroxyapatite 20-30, calcium sulfate 5-10, campanulaceae essential oil 3-4, horseradish essential oil 1-2, glycerol
Aliphatic ester 0.5-0.8, Peppermint essential oil 3-5, sodium cellulose glycolate 10-15, olive oil 2-4, sodium chloride 3-5, carragheen 5-
15, zinc citrate 0.6-0.8.
Further, preparation method includes the following steps:
(1) leached tea oil slag powder is crushed using pulverizer, crosses 50-100 mesh, it is 5- that gains, which are then added to mass concentration,
In 10% dilute hydrochloric acid solution, at 50-55 DEG C, it is ultrasonically treated 50-60min, is then filtered, and 3-4 is washed with deionized
It is secondary, gains are added in ethyl alcohol, after stirring 10-20min at 70-72 DEG C, 300-400rpm, dispersion liquid are obtained, using strong
Flow pulsed ionizing beam to dispersion liquid handle 4-5s, continuous processing 6-8 times, interval time 5-6s, then by gained dispersion liquid into
Row refluxing extraction 4-5h, filtering, obtains extracting solution；
(2) nanometer hydroxyapatite, calcium sulfate are added into extracting solution obtained by step (1), then tangerine is added in ball milling 20-30min
Obstruct essential oil, horseradish essential oil, fatty acid glyceride, after continuing ball milling 10-20min, is spray-dried, obtains composite powder；
(3) composite powder obtained by step (2) is added in the propylene glycol of 5-8 times of its volume, it is fine that Peppermint essential oil, methylol is added
Plain sodium, olive oil, sodium chloride, carragheen, zinc citrate are tieed up, thick, cooling is milled at 80-82 DEG C, is transferred in 1-2MPa
3-4h is set, is then vacuumized, 1-2h, pressure release are kept.
Further, the ion energy of step (1) described intense pulsed ion beam is 130-134keV, beam current density is
90-95A/cm2, pulse width 55-58ns.
Further, step (2) the nanometer hydroxyapatite partial size is 10-50nm.
Further, step (2) nanometer hydroxyapatite is by being activated, specific activation step are as follows: by nanometer
Hydroxyapatite is put into microwave device, microwave treatment 20-30s, is then placed in the ethanol solution that mass fraction is 70-76%,
Under 800-850rpm disperse 10-20min after under frequency be 3.2-3.5MPa magnetizer in handle 30-35min, filter,
It is dry at 100-103 DEG C, 60-70min then is calcined at 210-230 DEG C, is cooled to room temperature.
Beneficial effects of the present invention: whitening toothpaste prepared by the present invention is significant to the removal effect of creamy white spot, keeps implication clear
New lasting, permanent tooth anti-inflammatory, antiallergy, wherein nanometer hydroxyapatite and leached tea oil slag extracting solution act synergistically, and high degree mentions
The high decontamination stain-removing effect of gained toothpaste.Nanometer hydroxyapatite is activated, its reactivity is enhanced, is improved
Calcium ion, phosphate radical particle rate of release promote leached tea oil slag extracting solution to decompose creamy white spot, and form new repair layer and fill up in color
Spot decomposes position, enhances creamy white spot decomposition rate and discomposing effect, improves its exogenous color spot removal ability, tooth-whitening.
It in leached tea oil slag extraction process, is handled using pulse, the extraction efficiency of effective component Tea Saponin in leached tea oil slag can be improved, saved
Production cost, avoids the waste of resource, also further improves the whitening effect of gained toothpaste.
Specific embodiment
Illustrate the present invention with specific embodiment below, but is not limitation of the present invention.
Embodiment 1
A kind of whitening toothpaste effectively removing creamy white spot, which is characterized in that be made of raw material from the following weight:
Leached tea oil slag powder 20, nanometer hydroxyapatite 20, calcium sulfate 5, campanulaceae essential oil 3, horseradish essential oil 1, fatty acid glyceride 0.5,
Peppermint essential oil 3, sodium cellulose glycolate 10, olive oil 2, sodium chloride 3, carragheen 5, zinc citrate 0.6.
Further, preparation method includes the following steps:
(1) leached tea oil slag powder is crushed using pulverizer, crosses 50 meshes, gains are then added to dilute salt that mass concentration is 5%
In acid solution, at 50 DEG C, it is ultrasonically treated 50min, then filters, and be washed with deionized 3 times, gains is added to second
In alcohol, after stirring 10min at 70 DEG C, 300rpm, dispersion liquid is obtained, 4s is handled to dispersion liquid using intense pulsed ion beam, even
Continuous processing 6 times, interval time 5s, then carries out refluxing extraction 4h for gained dispersion liquid, and filtering obtains extracting solution；
(2) nanometer hydroxyapatite, calcium sulfate are added into extracting solution obtained by step (1), then campanulaceae is added in ball milling 20min
Essential oil, horseradish essential oil, fatty acid glyceride are spray-dried after continuing ball milling 10min, obtain composite powder；
(3) composite powder obtained by step (2) is added in the propylene glycol of 5 times of its volume, Peppermint essential oil, hydroxylmethyl cellulose is added
Plain sodium, olive oil, sodium chloride, carragheen, zinc citrate, be milled at 80 DEG C it is thick, it is cooling, 3h is placed at 1MPa, so
After vacuumize, keep 1h, pressure release.
Further, the ion energy of step (1) described intense pulsed ion beam be 130keV, beam current density 90A/cm
2, pulse width 55ns.
Further, step (2) the nanometer hydroxyapatite partial size is 10nm.
Further, step (2) nanometer hydroxyapatite is by being activated, specific activation step are as follows: by nanometer
Hydroxyapatite is put into microwave device, microwave treatment 20s, is then placed in the ethanol solution that mass fraction is 70%, 800rpm
30min is handled in the magnetizer that frequency is 3.2MPa under after lower dispersion 10min, is filtered, it is dry at 100 DEG C, then 210
60min is calcined at DEG C, is cooled to room temperature.
Embodiment 2
A kind of whitening toothpaste effectively removing creamy white spot, which is characterized in that be made of raw material from the following weight:
Leached tea oil slag powder 30, nanometer hydroxyapatite 25, calcium sulfate 7, campanulaceae essential oil 4, horseradish essential oil 2, fatty acid glyceride 0.7,
Peppermint essential oil 4, sodium cellulose glycolate 12, olive oil 3, sodium chloride 4, carragheen 10, zinc citrate 0.7.
Further, preparation method includes the following steps:
(1) leached tea oil slag powder is crushed using pulverizer, crosses 80 meshes, gains are then added to dilute salt that mass concentration is 7%
In acid solution, at 52 DEG C, it is ultrasonically treated 55min, then filters, and be washed with deionized 4 times, gains is added to second
In alcohol, after stirring 12min at 71 DEG C, 350rpm, dispersion liquid is obtained, 5s is handled to dispersion liquid using intense pulsed ion beam, even
Continuous processing 7 times, interval time 6s, then carries out refluxing extraction 5h for gained dispersion liquid, and filtering obtains extracting solution；
(2) nanometer hydroxyapatite, calcium sulfate are added into extracting solution obtained by step (1), then campanulaceae is added in ball milling 25min
Essential oil, horseradish essential oil, fatty acid glyceride are spray-dried after continuing ball milling 15min, obtain composite powder；
(3) composite powder obtained by step (2) is added in the propylene glycol of 6 times of its volume, Peppermint essential oil, hydroxylmethyl cellulose is added
Plain sodium, olive oil, sodium chloride, carragheen, zinc citrate, be milled at 81 DEG C it is thick, it is cooling, 4h is placed at 2MPa, so
After vacuumize, keep 2h, pressure release.
Further, the ion energy of step (1) described intense pulsed ion beam be 132keV, beam current density 93A/cm
2, pulse width 56ns.
Further, step (2) the nanometer hydroxyapatite partial size is 30nm.
Further, step (2) nanometer hydroxyapatite is by being activated, specific activation step are as follows: by nanometer
Hydroxyapatite is put into microwave device, microwave treatment 25s, is then placed in the ethanol solution that mass fraction is 72%, 830rpm
32min is handled in the magnetizer that frequency is 3.3MPa under after lower dispersion 15min, is filtered, it is dry at 101 DEG C, then 220
65min is calcined at DEG C, is cooled to room temperature.
Embodiment 3
A kind of whitening toothpaste effectively removing creamy white spot, which is characterized in that be made of raw material from the following weight:
Leached tea oil slag powder 40, nanometer hydroxyapatite 30, calcium sulfate 10, campanulaceae essential oil 4, horseradish essential oil 2, fatty acid glyceride 0.8,
Peppermint essential oil 5, sodium cellulose glycolate 15, olive oil 4, sodium chloride 5, carragheen 15, zinc citrate 0.8.
Further, preparation method includes the following steps:
(1) by leached tea oil slag powder using pulverizer crush, sieve with 100 mesh sieve, then by gains be added to mass concentration be 10% it is dilute
In hydrochloric acid solution, at 55 DEG C, it is ultrasonically treated 60min, then filters, and be washed with deionized 4 times, gains is added to
In ethyl alcohol, after stirring 20min at 72 DEG C, 400rpm, dispersion liquid is obtained, 5s is handled to dispersion liquid using intense pulsed ion beam,
Continuous processing 8 times, interval time 6s, gained dispersion liquid is then subjected to refluxing extraction 5h, filtering obtains extracting solution；
(2) nanometer hydroxyapatite, calcium sulfate are added into extracting solution obtained by step (1), then campanulaceae is added in ball milling 30min
Essential oil, horseradish essential oil, fatty acid glyceride are spray-dried after continuing ball milling 20min, obtain composite powder；
(3) composite powder obtained by step (2) is added in the propylene glycol of 8 times of its volume, Peppermint essential oil, hydroxylmethyl cellulose is added
Plain sodium, olive oil, sodium chloride, carragheen, zinc citrate, be milled at 82 DEG C it is thick, it is cooling, 4h is placed at 2MPa, so
After vacuumize, keep 2h, pressure release.
Further, the ion energy of step (1) described intense pulsed ion beam be 134keV, beam current density 95A/cm
2, pulse width 58ns.
Further, step (2) the nanometer hydroxyapatite partial size is 50nm.
Further, step (2) nanometer hydroxyapatite is by being activated, specific activation step are as follows: by nanometer
Hydroxyapatite is put into microwave device, microwave treatment 30s, is then placed in the ethanol solution that mass fraction is 76%, 850rpm
35min is handled in the magnetizer that frequency is 3.5MPa under after lower dispersion 20min, is filtered, it is dry at 103 DEG C, then 230
70min is calcined at DEG C, is cooled to room temperature.
Comparative example 1
The pulse processing in step (1) is omitted compared to embodiment 2 in this comparative example, and method and step in addition to this is equal
It is identical.
Comparative example 2
The addition of nanometer hydroxyapatite is omitted compared to embodiment 2 in this comparative example, and method and step in addition to this is equal
It is identical.
Comparative example 3
The activation process step of nanometer hydroxyapatite, side in addition to this is omitted compared to embodiment 2 in this comparative example
Method step is all the same.
Comparative example 4
The addition of leached tea oil slag extracting solution is omitted compared to embodiment 2 in this comparative example, and method and step in addition to this is homogeneous
Together.
Clinical test:
Creamy white spot problem, health have been randomly selected, and has agreed to crowd totally 32 that cooperate inspection on time, men and women each 14,
7 groups are divided into, its teeth stains index is recorded, respectively using toothpaste obtained by the various embodiments described above and comparative example, daily
It brushes teeth three times in the morning, afternoon and evening, does not use other toothpaste, checked after 4 weeks, record color spot index, be averaged.Color spot Index area is commented
Minute mark is quasi- as follows: 0- exists without color spot；1- color spot is no more than the l/3 of facing；2- color spot is no more than the 2/3 of facing；
3- color spot is greater than the 2/3 of facing.Color spot index color score standard is as follows: 0- exists without color spot；Color spot (yellow that 1- is slight
Or yellowish-brown)；2- moderate color spot (moderate brown)；3- severe color spot (dark-brown or black) color spot is greater than facing
2/3。
The results are shown in Table 1:
Table 1
As can be seen from Table 1, whitening toothpaste prepared by the present invention is significant to the removal effect of creamy white spot, nanometer hydroxyapatite with
Leached tea oil slag extracting solution synergistic effect, the decontamination stain-removing effect for improving gained toothpaste of high degree.
Claims (5)
1. a kind of whitening toothpaste for effectively removing creamy white spot, which is characterized in that be made of raw material from the following weight:
Leached tea oil slag powder 20-40, nanometer hydroxyapatite 20-30, calcium sulfate 5-10, campanulaceae essential oil 3-4, horseradish essential oil 1-2, glycerol
Aliphatic ester 0.5-0.8, Peppermint essential oil 3-5, sodium cellulose glycolate 10-15, olive oil 2-4, sodium chloride 3-5, carragheen 5-
15, zinc citrate 0.6-0.8.
2. a kind of whitening toothpaste for effectively removing creamy white spot according to claim 1, which is characterized in that preparation method packet
Include following steps:
(1) leached tea oil slag powder is crushed using pulverizer, crosses 50-100 mesh, it is 5- that gains, which are then added to mass concentration,
In 10% dilute hydrochloric acid solution, at 50-55 DEG C, it is ultrasonically treated 50-60min, is then filtered, and 3-4 is washed with deionized
It is secondary, gains are added in ethyl alcohol, after stirring 10-20min at 70-72 DEG C, 300-400rpm, dispersion liquid are obtained, using strong
Flow pulsed ionizing beam to dispersion liquid handle 4-5s, continuous processing 6-8 times, interval time 5-6s, then by gained dispersion liquid into
Row refluxing extraction 4-5h, filtering, obtains extracting solution；
(2) nanometer hydroxyapatite, calcium sulfate are added into extracting solution obtained by step (1), then tangerine is added in ball milling 20-30min
Obstruct essential oil, horseradish essential oil, fatty acid glyceride, after continuing ball milling 10-20min, is spray-dried, obtains composite powder；
(3) composite powder obtained by step (2) is added in the propylene glycol of 5-8 times of its volume, it is fine that Peppermint essential oil, methylol is added
Plain sodium, olive oil, sodium chloride, carragheen, zinc citrate are tieed up, thick, cooling is milled at 80-82 DEG C, is transferred in 1-2MPa
3-4h is set, is then vacuumized, 1-2h, pressure release are kept.
3. a kind of whitening toothpaste for effectively removing creamy white spot according to claim 1, which is characterized in that step (1) is described
The ion energy of intense pulsed ion beam is 130-134keV, beam current density 90-95A/cm2, pulse width 55-58ns.
4. a kind of whitening toothpaste for effectively removing creamy white spot according to claim 1, which is characterized in that step (2) is described
Nanometer hydroxyapatite partial size is 10-50nm.
5. a kind of whitening toothpaste for effectively removing creamy white spot according to claim 1, which is characterized in that step (2) is described
Nanometer hydroxyapatite is by being activated, specific activation step are as follows: nanometer hydroxyapatite is put into microwave device, microwave
20-30s is handled, is then placed in the ethanol solution that mass fraction is 70-76%, under dispersing after 10-20min under 800-850rpm
30-35min is handled in the magnetizer that frequency is 3.2-3.5MPa, is filtered, it is dry at 100-103 DEG C, then in 210-230
60-70min is calcined at DEG C, is cooled to room temperature.
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| CN201811195111.7A CN109125178A (en) | 2018-10-15 | 2018-10-15 | A kind of whitening toothpaste and preparation method thereof effectively removing creamy white spot |
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2018
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| CN1582889A (en) * | 2004-06-03 | 2005-02-23 | 刘杰 | Nano toothpaste additive |
| CN104784240A (en) * | 2015-04-28 | 2015-07-22 | 广东工业大学 | Rinse solution containing plant essential oil and preparation method of rinse solution |
| CN107362056A (en) * | 2017-07-05 | 2017-11-21 | 汪锦川 | A kind of manufacture of green functional health toothpaste and processing technology |
| CN107375078A (en) * | 2017-08-03 | 2017-11-24 | 何家平 | A kind of herbal toothpaste formula |
| CN107434998A (en) * | 2017-08-29 | 2017-12-05 | 湖南源绿科技有限公司 | A kind of method that high-voltage pulse electric field coordination aqueous enzymatic method prepares camellia seed oil |
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| Title |
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| 梁少华: "《植物油料资源综合利用》", 31 December 2009, 东南大学出版社 * |
| 石岩: "《微笑着读完趣味物理》", 30 April 2012, 金城出版社 * |
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Application publication date: 20190104 |