CN1091145A - A kind of preparation method of lubricant additive - Google Patents
A kind of preparation method of lubricant additive Download PDFInfo
- Publication number
- CN1091145A CN1091145A CN 94100061 CN94100061A CN1091145A CN 1091145 A CN1091145 A CN 1091145A CN 94100061 CN94100061 CN 94100061 CN 94100061 A CN94100061 A CN 94100061A CN 1091145 A CN1091145 A CN 1091145A
- Authority
- CN
- China
- Prior art keywords
- graphite
- sec
- propyl
- acid ester
- titanic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003879 lubricant additive Substances 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000010439 graphite Substances 0.000 claims abstract description 31
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 31
- 239000006185 dispersion Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011859 microparticle Substances 0.000 claims abstract description 7
- 239000013543 active substance Substances 0.000 claims abstract description 6
- 239000007822 coupling agent Substances 0.000 claims abstract description 5
- -1 isostearoyl Chemical group 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 14
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical group [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052810 boron oxide Inorganic materials 0.000 claims description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical group O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000012528 membrane Substances 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 abstract description 2
- 238000000746 purification Methods 0.000 abstract description 2
- 239000000314 lubricant Substances 0.000 description 22
- 239000007787 solid Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 230000000996 additive effect Effects 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000000470 constituent Substances 0.000 description 7
- 238000005096 rolling process Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 239000010687 lubricating oil Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- 229910000754 Wrought iron Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000002199 base oil Substances 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
A kind of preparation method of lubricant additive, it is characterized in that natural flake graphite is sent after purification, pulverizing, stage treatment with diameter range is 0.1～30 micron graphite microparticles, the graphite microparticles of preferred 1～10 micron diameter, then the Graphite Powder 99 of choosing was toasted under 120 ℃ temperature 1.5～2.5 hours, through overbaking, removed moisture contained in the graphite.Coat with titanate coupling agent then, and mix with dispersion agent, rete stablizer, tensio-active agent, honing is 1～3 hour in the superfine honing machine, has promptly made a kind of lubricant additive compositions of superior performance.
Description
The present invention relates to a kind of preparation method of lubricant additive, especially a kind of preparation method of graphite additive.Belong to the lubricating oil field.
As everyone knows, parts such as the oil-less self-lubricating bearing that turns round under high temperature, high speed load, fastness mating part, senior wear ring and material all require higher intensity and good lubricity.
In technology in the past, the people was once arranged graphite and molybdenumdisulphide (MoS
2) pulvis directly mix in metal-powder, attempt to utilize powder metallurgy sintered moulding process to produce high performance lubricant.The result is undesirable.The someone adopts the method for metal cladding graphite to be used for producing from wetted part again in recent years, does not obtain satisfactory result.As everyone knows.Graphite and MoS
2Wettability to metal is very poor.Graphite and MoS
2Pulvis is as raw material.Intensity is very low after the sinter molding.No matter be cold pressing or Thermocompressed sintering and forming in.Water the knot process through long period high temperature.Graphite, MoS
2Will oxidation.Even nickel cladding graphite utilizes the ordinary sinter moulding process also to can not get effect preferably.The clear 58-17819 of Japanese Patent has invented a kind of solid self-lubricating composite material.It is made of two kinds of components: first component is by MoS
2, WS
2One or more compositions among monomer or complex body lubricant and Cu, Fe, Ni, Co, the Mn constitute; Second component is made of one or more compositions in fourth, fifth, six pair of family's metal or its carbide, the nitride (the 6th pair group-III nitride except).The weight percent of first component and second component is 80: 20～20: 80.This composite material by adopting heat pressure forming process.
In the rolling machining production line of the pipe fitting in modern times, the key step of seamless tube moulding is the rolling wrought iron that has been heated to 1200 ℃-1300 ℃ on a mandrel.
After the roll forming process, mandrel or perhaps mandrel rod are removed and are cooled off from the good pipe of spreading, make mandrel or perhaps mandrel rod be cooled to about 60-100 ℃ from about 150-350 ℃, thereby get ready for next step spreading process.To also need lubricating through the preprocessing of cooling bath refrigerative mandrel or perhaps mandrel rod, the characteristic that this later stage quality to the best " slip " that guarantees to make in the operation of rolling wrought iron on the mandrel rod and pipe is an inner surface of tube is important.
Normally be lubricated with graphitiferous oil, owing to burn the dense smog of generation, its toxic substance causes the harm to environment to this oil when contacting with the mandrel made from red-hot wrought iron.In addition, uncontrollable the burning of this when rolling in the wrought iron damaged the lubricant thin layer on the mandrel, and may damage the internal surface of pipe.
At DES2450716, also recommended application to come down to the fire-resistant lubricants of forming by graphite and alkylidene group polymkeric substance among the special embodiment 5.This lubricant directly is being coated to after the roll forming process on the also uncooled mandrel, forms the partly lubricant layer of waterproof of one deck exsiccant, and the mandrel of Xing Chenging enters cooling bath subsequently like this, and the lubricant that needn't renew again subsequently enters next step operation of rolling.But point out that also because the influence of cooling bath and water, the mechanics load of mandrel damages lubricant film through regular meeting when transportation, thereby again the pipe quality is produced adverse influence.
Dispersing liquid for solid lubricant as lubricant has more comprehensive advantage, promptly have the good extreme boundary lubrication of solid lubricant, good flowability, thermal diffusivity and the perviousness of liquid lubricant concurrently, under condition of boundary lubrication, can reduce the friction and wear of surface of friction effectively.Therefore, dispersing liquid for solid lubricant is widely used as lubricating oil and antifriction additive at automobile, boats and ships, printing and dyeing and other industrial machinery line.
Yet a key problem in technology of dispersing liquid for solid lubricant also is stable dispersion chronically.Because, in lubricated, will send out fault so if solid particulate condenses and sedimentary words in storage and the use.For making the dispersion liquid long-term stability, can be broken into solid particulate as far as possible little size and/or seek good dispersion agent.
Early the dispersion agent that uses has fatty acid soaps, polyhutadiene.The United States Patent (USP) 3,384,580 of application on May 9th, 1967 proposes with ethylene-propylene copolymer, and ethylene-propylene-diene terpolymer is made dispersion agent.The United States Patent (USP) 4,134,844 of on April 3rd, 1978 application is mentioned with the allyl butyrate imide, polymethacrylate, ethylene oxide-propylene copolymer and make dispersion agent with the reactor product of aliphatic amide (or polyamines).
Known various dispersion agent really can help solia particle to disperse in the shattering process of solid particulate, and helps dispersion stable.But to further improve the broken dispersion effect of solid lubricant particle and the permanent stability of dispersion liquid, the dispersing method that also must seek better dispersion agent and adapt with it.
Purpose of the present invention is exactly the preparation method that a kind of lubricant additive will be provided, especially a kind of preparation method of graphite additive.
Another object of the present invention also provides a kind of lubricating oil additive.
The object of the present invention is achieved like this: selecting natural flake graphite for use diameter range after purification, pulverizing, stage treatment is 0.1～30 micron graphite microparticles (better with the 1-10 micron).The Graphite Powder 99 of choosing toasted under 120 ℃ temperature 1.5～2.5 hours,, removed moisture content contained in the graphite through overbaking, reduced the proportion of graphite, through analysis of experiments, proportion can reduce 16%, improved the suspending power of Graphite Powder 99, be difficult for precipitation at base oil.Here graphite purity is at least 95%, and its consumption is that 30～90%(of composition weight is heavy).
In order to make the lubricant for preparing have enough stability; need graphite particulate is wrapped layer protective layer; so that graphite is scattered in the base oil better; this protective layer is a kind of titanate coupling agent; said coupling agent has sec.-propyl three isostearoyl base titanic acid ester sec.-propyl three (lauryl-tetradecyl) titanic acid ester; sec.-propyl distearyl ylmethyl acryl titanic acid ester; sec.-propyl trimethylammonium acryl titanic acid ester; sec.-propyl triacryl titanic acid ester; enedioxy two (dioctyl is phosphate-based) titanium, its addition are that 1.0～10%(of constituent weight is heavy).
For the dispersiveness that improves graphite microparticles with shorten on-the-spot water or water soluble oils is the synthetic time.Select suitable dispersion agent outbalance.The present invention adopts sulfonated alkyl naphathalene as dispersion agent.Because this organic salt can reduce bounding force between particulate or droplet, prevented the poly-or agglomeration of wadding, make material be dispersed in the material that forms colloidal solution in the medium such as water, can conglomeration.This sulfonated alkyl naphathalene can be sodium methylene bis-naphthalene sulfonate, methylene-bis first sodium naphthalene sulfonate.Its addition is that 1%～15%(of constituent weight is heavy).When adopting the dispersion agent of suitable proportion, it has the function of wetting agent again.
In order to improve the high temperature lubricating characteristic of rete, need to add resistant to elevated temperatures rete stablizer in the constituent.The available membrane stabilizer has boron oxide, borax, sodium silicate, silicic acid, phosphoric acid salt or their mixture.Because the material of boracic, phosphorus etc. has the effect of activation lubricity.When temperature reach 500 ℃ respectively, more than 800 ℃ the time, boron or phosphorus etc. shows its activation performance respectively, clads the graphite microparticles secluding air on the one hand, has prolonged because of the graphite high temperature oxidation to lose lubricated performance.It has played the effect that prevents the metal adhesion again in addition.It forms the semi-fluid friction condition, thereby has reduced frictional coefficient, and can cover one deck liquid phase lubricant film once more under rete disruptive situation, thereby makes oildag have high temperature abrasion resistance.The addition of rete stablizer is that 5～40%(of constituent weight is heavy).
In order to make lubricating agent composition have high potential, need to add tensio-active agent.Because promoting agent has obviously improved wetting, diffusion, the emulsifying property of medium.Make the mixed back of constituent water or water soluble oils system just can form dispersion, even, stable graphite suspension in the short period of time.The lubricant of this surface active can make the distribution of film on the metallic surface after the spraying (or dip-coating) have significant molecular orientation.Strengthen the coating performance of suspension on the metallic surface, improved lubricating property.
The tensio-active agent of indication of the present invention is meant fluoroalkyl benzene sulfonate, its weight content 〉=90%.Use this promoting agent to also have fire retardation.Can reduce the smog that the water soluble oils base lubricant occurs in producing use.So in constituent, add the over-all properties that this tensio-active agent has obviously improved the dry powder type lubricant.The add-on of tensio-active agent is that 0.1～5%(of the weight of constituent weighs).
Said components was promptly made a kind of lubricant additive compositions of superior performance in 1-3 hour in the superfine honing.
Lubricating oil additive of the present invention is because contain composite dispersing agent, so have excellent dispersion stability and long term storage stability.In addition, lubricant additive of the present invention also has good high thermal resistance, wear-resistant and extreme pressure property.Additive of the present invention all has favorable applicability and good flowability, thermal diffusivity and perviousness in automobile, boats and ships, steel rolling and calendering operation industry, under condition of boundary lubrication, can reduce the friction and wear of surface of friction effectively.Thereby reach energy saving purposes.
The following examples can be illustrated more clearly in the present invention, but and do not mean that the present invention is made any qualification that scope of the present invention is recorded in claims.
Embodiment 1:
The graphite that with diameter is 12 microns toasted 2 hours in 120 ℃ baking oven; get the Graphite Powder 99 85kg that makes; sec.-propyl three isostearoyl base titanic acid ester 2kg; water glass 2kg; sodium methylene bis-naphthalene sulfonate 4kg puts into reactor and stirs; with triple-roller mill honing three times, promptly obtain uniform and stable lubricant graphite additive.
Embodiment 2
Method according to embodiment 1 prepares the lubricant graphite additive, and the each component consumption is as follows:
Graphite Powder 99 (5 microns of diameters) 40kg, enedioxy two (dioctyl is phosphate-based) titanium 7kg, borax 13kg, fluoroalkyl sulfonate 5kg, methylene-bis first sodium naphthalene sulfonate 35kg
Claims (4)
1, a kind of preparation method of lubricant additive, it is characterized in that natural flake graphite through purifying, pulverize, sending after the stage treatment with diameter range is 0.1～30 micron graphite microparticles, the graphite microparticles of preferred 1～10 micron diameter, then the Graphite Powder 99 of choosing was toasted under 120 ℃ temperature 1.5～2.5 hours, through overbaking, removed moisture contained in the graphite, coat with titanate coupling agent then, and and dispersion agent, the rete stablizer, tensio-active agent mixes, honing is 1～3 hour in the superfine honing machine, has promptly made a kind of lubricant additive compositions of superior performance.
2, method according to claim 1; it is characterized in that said titanate coupling agent is sec.-propyl three isostearoyl base titanic acid ester, sec.-propyl three (lauryl-tetradecyl) titanic acid ester, sec.-propyl distearyl ylmethyl acryl titanic acid ester, sec.-propyl trimethylammonium acryl titanic acid ester, sec.-propyl triacryl titanic acid ester, enedioxy two (dioctyl is phosphate-based) titanium, its consumption is that 1.0～10%(is heavy)
3, method according to claim 1 is characterized in that said membrane stabilizer is boron oxide, borax, water glass, silicic acid, phosphoric acid salt and their mixture, and its consumption is that 5～40%(is heavy).
4, method according to claim 1 is characterized in that said dispersion agent is sodium methylene bis-naphthalene sulfonate, methylene-bis first sodium naphthalene sulfonate, and its consumption is that 1～15%(is heavy).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94100061A CN1037189C (en) | 1994-01-06 | 1994-01-06 | Method for preparation of lubricant additive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94100061A CN1037189C (en) | 1994-01-06 | 1994-01-06 | Method for preparation of lubricant additive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1091145A true CN1091145A (en) | 1994-08-24 |
| CN1037189C CN1037189C (en) | 1998-01-28 |
Family
ID=5029423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94100061A Expired - Fee Related CN1037189C (en) | 1994-01-06 | 1994-01-06 | Method for preparation of lubricant additive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1037189C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1328359C (en) * | 2003-11-11 | 2007-07-25 | 天津市英研技术发展有限公司 | Method for reducing friction coefficient of graphite lubricant |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3513031C1 (en) * | 1985-04-11 | 1986-02-20 | Dow Corning GmbH, 8000 München | Solid lubricant combination and its use in friction linings |
| US4915856A (en) * | 1987-07-10 | 1990-04-10 | Durafilm Corporation | Solid lubricant composition |
| US5180509A (en) * | 1989-10-10 | 1993-01-19 | Jacobs Norman L | Metal-free lubricant composition containing graphite for use in threaded connections |
-
1994
- 1994-01-06 CN CN94100061A patent/CN1037189C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1037189C (en) | 1998-01-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100582204C (en) | Highly effective energy-saving nano anti-wearing agent and its preparation method and uses | |
| CN100534671C (en) | Nano core-shell type copper-nickel bimetal powder body and preparing method and application thereof | |
| CN1332007C (en) | Conducting polymer high-temperature lubricating grease and its preparing method | |
| CN107312598A (en) | A kind of overweight load synthetic gear oil of low temperature | |
| Caixiang et al. | Study on application of CeO2 and CaCO3 nanoparticles in lubricating oils | |
| CN107603706B (en) | Graphene synergistic lubricating anti-rust oil and preparation method thereof | |
| CN1035440C (en) | Lubricating oil composition | |
| CN102226125A (en) | Inorganic high-temperature-resistant dry-film lubricant | |
| CN100357415C (en) | Ultra-thin layered wax film antirust composition for firearm | |
| CN1037189C (en) | Method for preparation of lubricant additive | |
| CN112940836A (en) | High-dispersity nano molybdenum disulfide water-based rolling liquid and preparation method thereof | |
| CN110734804B (en) | Nano cutting oil and preparation method and application thereof | |
| CN100569417C (en) | A kind of metallic nano-particle surface amendment | |
| Johns et al. | Study of tribological properties of tallow modified by graphene and expanded graphite | |
| CN100398632C (en) | Composite aluminum base grease and its preparing method | |
| US5346634A (en) | Lubricant composition for hot plastic working | |
| Yin et al. | Experimental study on the tribological behaviour of CeO2‐diesel blends on the injector body | |
| CN115820332A (en) | Water-based fully-synthetic cutting fluid and preparation method and application thereof | |
| JPH0791551B2 (en) | High temperature lubricant / release agent | |
| CN1007430B (en) | Dry powder type high-temp. lubricant used for metal processing | |
| CN104531306A (en) | Friction-reducing agent and preparation method thereof | |
| JP3159987B2 (en) | Lubricating particles, manufacturing method and lubricant containing such lubricating particles | |
| JPS5819395A (en) | Lubricant for hot molding of steel stock | |
| Pawlak et al. | A hexagonal boron nitride-based model of porous bearings with reduced friction and increased load | |
| Gocman et al. | An evaluation of lubricating properties of CuO and h-boron nitride (h-BN) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C53 | Correction of patent for invention or patent application | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: PATENTEE; FROM: WANG XUESHAO TO: YANTAI CHI-KAI LUBRICANTS CO., LTD. |
|
| CP03 | Change of name, title or address |
Address after: 264000 No. 89, sea route, Yantai Free Trade Zone, Shandong Patentee after: Yantai gallop Lubricating Oil Co., Ltd. Address before: 262804, Pingdu Town, Shandong province is still home Tuan 166 Patentee before: Wang Xueshao |
|
| C53 | Correction of patent for invention or patent application | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: PATENTEE; FROM: YANTAI CHI-KAI LUBRICANTS CO., LTD. TO: QINGDAO SCIENCE AND TECHNOLOGY VENTURE DEVELOPMENT BUSINESS CENTER |
|
| CP02 | Change in the address of a patent holder |
Address after: 602 room 5, 266071 Zhuhai Road, Qingdao Address before: 264000 No. 88, sea route, Yantai Free Trade Zone, Shandong |
|
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Qingdao science and Technology Risk Development Enterprise Center Document name: Deemed not to advise |
|
| ASS | Succession or assignment of patent right |
Owner name: YANTAI CHI-KAI LUBRICANTS CO., LTD. Free format text: FORMER OWNER: QINGDAO SCIENCE AND TECHNOLOGY VENTURE DEVELOPMENT BUSINESS CENTER Effective date: 20040910 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20040910 Address after: 264000 Dongxing Industrial Park, Sheng Quan Industrial Zone, Yantai hi tech Development Zone Patentee after: Yantai gallop Lubricating Oil Co., Ltd. Address before: 602, room 264000, room 5, Zhuhai Road, Qingdao, Shandong Patentee before: Qingdao science and Technology Risk Development Enterprise Center |
|
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Wang Xueshao Document name: Notice of conformity |
|
| PP01 | Preservation of patent right |
Effective date of registration: 20050420 Pledge (preservation): Preservation |
|
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Wang Xueshao Document name: Special business memo review notice |
|
| PD01 | Discharge of preservation of patent |
Date of registration: 20061021 Pledge (preservation): Preservation |
|
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Wang Xueshao Document name: Notification of Termination of Patent Right |
|
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |