CN109111716A - A kind of composite material and preparation method for animal ear tag - Google Patents
A kind of composite material and preparation method for animal ear tag Download PDFInfo
- Publication number
- CN109111716A CN109111716A CN201810964369.2A CN201810964369A CN109111716A CN 109111716 A CN109111716 A CN 109111716A CN 201810964369 A CN201810964369 A CN 201810964369A CN 109111716 A CN109111716 A CN 109111716A
- Authority
- CN
- China
- Prior art keywords
- parts
- composite material
- ear tag
- animal ear
- carbon nanotube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Abstract
The invention belongs to composite material and its applied technical fields, in particular to a kind of composite material and preparation method for animal ear tag, the raw material including following parts by weight: 20-30 parts of polycarbonate, 20-30 parts of polypropylene terephthalate, 15-30 parts of hydrogenated butyronitrile glue, 5-10 parts of triphenyl phosphite, 2-4 parts of sodium pyrophosphate, 5-7 parts of acrylic acid, 2-3 parts of titanate coupling agent, 0.5-1 parts of nano zine oxide and 5-6 parts of carbon nanotube；It is excellent that the present invention prepares composite material heat resistance, anti-aging, wear-resistant, is suitable for animal ear tag, can use for a long time, be hardly damaged in complex environment；Preparation method of the invention is simple, is suitable for large-scale production.
Description
Technical field
The invention belongs to composite material and its applied technical field, in particular to a kind of composite material for animal ear tag
And preparation method thereof.
Background technique
Ear tag is one of animal identification, for proving livestock identity, carries the mark of livestock individual information, is affixed by livestock
Ear.Currently, the ear tag that China implements mainly uses two-dimension code ear tag and electron ear tage；Two-dimension code ear tag is using laser in ear tag
Encoded information, electron ear tage application RFID technique are scribed in face, and built-in chip and antenna, encoded information are stored in chip.Due to
RFID has a non-contact, remote, automatic identification mobile object, the readable characteristics such as writeable, some automatic gauges, measurement, calmly
Amount system is promoted the use of in animal husbandry.Currently, the automatic weighing management system of livestock, milk production automatic measurement and management system etc.
A variety of penkeepings and management system are all premised on the use of electron ear tage and basic.
Mechanical property, temperature tolerance of the electron ear tage due to built-in chip and antenna, to the composite material for making ear tag
There can be higher requirement.Chinese patent CN106279613A discloses a kind of animal ear tag materials and processing method, and ingredient is by weight
It is as follows to measure part percentage: poly- hexanedioic acid-glycol ester dihydric alcohol 33-35%；1,5-PD 15-17%；Diisocyanate 48-
50%；It is able to achieve low temperature resistant feature, to be the ear tag of severe cold area using creativeness condition.But the material is easily old
Change, it is easy to wear, it cannot be used for a long time.
Summary of the invention
The present invention solves the above-mentioned technical problems in the prior art, provides a kind of composite material for animal ear tag
And preparation method thereof.
To solve the above problems, technical scheme is as follows:
A kind of composite material for animal ear tag, the raw material including following parts by weight:
20-30 parts of polycarbonate；
20-30 parts of polypropylene terephthalate；
15-30 parts of hydrogenated butyronitrile glue；
5-10 parts of triphenyl phosphite；
2-4 parts of sodium pyrophosphate；
5-7 parts of acrylic acid；
2-3 parts of titanate coupling agent；
0.5-1 parts of nano zine oxide.
Preferably, the composite material for animal ear tag further includes the carbon nanotube of 5-6 parts by weight.
Preferably, the carbon nanotube is hydroxylated multi-walled carbon nanotubes, diameter 8-15nm, length 50-80nm.
Preferably, the diameter of the nano zine oxide is 100-200nm.
Preferably, the composite material for animal ear tag, the raw material including following parts by weight:
25 parts of polycarbonate；
25 parts of polypropylene terephthalate；
22 parts of hydrogenated butyronitrile glue；
7 parts of triphenyl phosphite；
3 parts of sodium pyrophosphate；
6 parts of acrylic acid；
2.5 parts of titanate coupling agent；
0.8 part of nano zine oxide；
5 parts of carbon nanotube.
A kind of preparation method of the composite material for animal ear tag, comprising the following steps:
Step 1, high-speed mixer and mixing is added in the polycarbonate, polypropylene terephthalate, hydrogenated butyronitrile glue
Uniformly, after being warming up to 85-95 DEG C, the triphenyl phosphite is added, mixes 30-60 minutes；
Step 2, the sodium pyrophosphate, acrylic acid, carbon nanotube are uniformly mixed, when being heated to 60-75 DEG C, in high-speed stirring
It mixes down, is slowly added to titanate coupling agent, be heated to 110-130 DEG C, high-speed stirred 15-25 minutes, delayed by nanoscale sieve
Slow addition nano zine oxide, high-speed stirred 60-90 minutes；
Step 3, mixture made from step 2 is slowly added in mixture made of step 1, in 110-130 DEG C of condition
Under, at high-speed mixer and mixing 1-2 hours, the composite material for animal ear tag is made.
Preferably, the mixing speed of the step 2 is 280-320rpm.
Compared with the existing technology, advantages of the present invention is as follows,
The present invention improves polycarbonate and hydrogenation fourth by introducing polypropylene terephthalate and triphenyl phosphite
The compatibility of nitrile glue increases mechanical property by introducing carbon nanotube, enhances carbon nanotube by introducing titanate coupling agent, receives
The dispersibility and compatibility with other components of rice zinc oxide, the manufactured more excellent gloss of product appearance are nano oxidized by introducing
Zinc enhances anti-aging property, by introducing sodium pyrophosphate, acrylic acid, cooperates with work with titanate coupling agent and nano zine oxide
With anti-corrosion performance can be enhanced；It is excellent that the present invention prepares composite material heat resistance, anti-aging, wear-resistant, is suitable for animal ear tag,
It can use for a long time, be hardly damaged in complex environment；Preparation method of the invention is simple, is suitable for large-scale production.
Specific embodiment
In the following example, used carbon nanotube is hydroxylated multi-walled carbon nanotubes, and diameter 8-15nm, length is
50-80nm。
The diameter of used nano zine oxide is 100-200nm.
Embodiment 1:
A kind of preparation method of the composite material for animal ear tag, comprising the following steps:
Raw material (parts by weight)
25 parts of polycarbonate；
25 parts of polypropylene terephthalate；
22 parts of hydrogenated butyronitrile glue；
7 parts of triphenyl phosphite；
3 parts of sodium pyrophosphate；
6 parts of acrylic acid；
2.5 parts of titanate coupling agent；
0.8 part of nano zine oxide；
5 parts of carbon nanotube；
Step 1, high-speed mixer and mixing is added in the polycarbonate, polypropylene terephthalate, hydrogenated butyronitrile glue
Uniformly, after being warming up to 85-95 DEG C, the triphenyl phosphite is added, mixes 30-60 minutes；
Step 2, the sodium pyrophosphate, acrylic acid, carbon nanotube are uniformly mixed, when being heated to 60-75 DEG C, in 280rpm
Under high-speed stirred, it is slowly added to titanate coupling agent, 110-130 DEG C is heated to, 320rpm high-speed stirred 15-25 minutes, passes through
Nanoscale sieve is slowly added to nano zine oxide, and 320rpm high-speed stirred 60-90 minutes；
Step 3, mixture made from step 2 is slowly added in mixture made of step 1, in 110-130 DEG C of condition
Under, at high-speed mixer and mixing 1-2 hours, the composite material for animal ear tag is made.
Above-mentioned composite material is tested for the property:
Bending strength: 151MPa, wear rate 0.57%；
After the accumulative irradiation of ultraviolet light 180 hours, it is tested for the property:
Bending strength: 147MPa, wear rate 0.61%；
After 50-60 DEG C is placed 180 hours, it is tested for the property:
Bending strength: 144MPa, wear rate 0.63%；
After 0 DEG C is placed 180 hours, it is tested for the property:
Bending strength: 146MPa, wear rate 0.60%；
Embodiment 2:
The composite material of animal ear tag is used for the method preparation of embodiment 1, only raw material composition to be different:
For the composite material of animal ear tag, the raw material including following parts by weight:
20 parts of polycarbonate；
20 parts of polypropylene terephthalate；
15 parts of hydrogenated butyronitrile glue；
5 parts of triphenyl phosphite；
2 parts of sodium pyrophosphate；
5 parts of acrylic acid；
2 parts of titanate coupling agent；
0.5 part of nano zine oxide.
Above-mentioned composite material is tested for the property:
Bending strength: 132MPa, wear rate 0.71%；
Embodiment 3:
The composite material of animal ear tag is used for the method preparation of embodiment 1, only raw material composition to be different:
For the composite material of animal ear tag, the raw material including following parts by weight:
30 parts of polycarbonate；
230 parts of polypropylene terephthalate；
30 parts of hydrogenated butyronitrile glue；
10 parts of triphenyl phosphite；
4 parts of sodium pyrophosphate；
7 parts of acrylic acid；
3 parts of titanate coupling agent；
1 part of nano zine oxide；
6 parts of carbon nanotube.
Above-mentioned composite material is tested for the property:
Bending strength: 154MPa, wear rate 0.61%；
Embodiment 4:
It is used for the composite material of animal ear tag with the method preparation of embodiment 1, only omits nano zine oxide in the feed
Addition, composite material obtained is tested for the property:
Bending strength: 149MPa, wear rate 0.59%；
After the accumulative irradiation of ultraviolet light 180 hours, it is tested for the property:
Bending strength: 87MPa, wear rate 3.7%；
After 50-60 DEG C is placed 180 hours, it is tested for the property:
Bending strength: 69MPa, wear rate 3.54%；
Embodiment 5:
It is used for the composite material of animal ear tag with the method preparation of embodiment 1, only omits titanate esters coupling in the feed
The addition of agent is tested for the property composite material obtained:
Bending strength: 139MPa, wear rate 0.65%；
After the accumulative irradiation of ultraviolet light 180 hours, it is tested for the property:
Bending strength: 136MPa, wear rate 0.69%；
After 50-60 DEG C is placed 180 hours, it is tested for the property:
Bending strength: 88MPa, wear rate 2.72%；
Embodiment 6:
It is used for the composite material of animal ear tag with the method preparation of embodiment 1, only omits sodium pyrophosphate in the feed
It is added, composite material obtained is tested for the property:
Above-mentioned composite material is tested for the property:
Bending strength: 136MPa, wear rate 0.62%；
After the accumulative irradiation of ultraviolet light 180 hours, it is tested for the property:
Bending strength: 91MPa, wear rate 1.43%；
After 50-60 DEG C is placed 180 hours, it is tested for the property:
Bending strength: 97MPa, wear rate 0.96%；
After 0 DEG C is placed 180 hours, it is tested for the property:
Bending strength: 64MPa, wear rate 2.71%；
Embodiment 7:
It is used for the composite material of animal ear tag with the method preparation of embodiment 1, only omits adding for acrylic acid in the feed
Enter, composite material obtained be tested for the property:
Bending strength: 154MPa, wear rate 0.64%；
After the accumulative irradiation of ultraviolet light 180 hours, it is tested for the property:
Bending strength: 77MPa, wear rate 2.57%；
It should be noted that above-described embodiment is only presently preferred embodiments of the present invention, there is no for the purpose of limiting the invention
Protection scope, the equivalent substitution or substitution made on the basis of the above all belong to the scope of protection of the present invention.
Claims (7)
1. a kind of composite material for animal ear tag, which is characterized in that the raw material including following parts by weight:
20-30 parts of polycarbonate；
20-30 parts of polypropylene terephthalate；
15-30 parts of hydrogenated butyronitrile glue；
5-10 parts of triphenyl phosphite；
2-4 parts of sodium pyrophosphate；
5-7 parts of acrylic acid；
2-3 parts of titanate coupling agent；
0.5-1 parts of nano zine oxide.
2. being used for the composite material of animal ear tag as described in claim 1, which is characterized in that the answering for animal ear tag
Condensation material further includes the carbon nanotube of 5-6 parts by weight.
3. being used for the composite material of animal ear tag as claimed in claim 2, which is characterized in that the carbon nanotube is hydroxylating
Multi-walled carbon nanotube, diameter 8-15nm, length 50-80nm.
4. being used for the composite material of animal ear tag as described in claim 1, which is characterized in that the diameter of the nano zine oxide
For 100-200nm.
5. being used for the composite material of animal ear tag as described in claim 1, which is characterized in that the answering for animal ear tag
Condensation material, the raw material including following parts by weight:
25 parts of polycarbonate；
25 parts of polypropylene terephthalate；
22 parts of hydrogenated butyronitrile glue；
7 parts of triphenyl phosphite；
3 parts of sodium pyrophosphate；
6 parts of acrylic acid；
2.5 parts of titanate coupling agent；
0.8 part of nano zine oxide；
5 parts of carbon nanotube.
6. the preparation method of the composite material as described in any one in claim 1-5 for animal ear tag, which is characterized in that packet
Include following steps:
It is step 1, the polycarbonate, polypropylene terephthalate, hydrogenated butyronitrile glue addition high-speed mixer and mixing is uniform,
After being warming up to 85-95 DEG C, the triphenyl phosphite is added, mixes 30-60 minutes；
Step 2, the sodium pyrophosphate, acrylic acid, carbon nanotube are uniformly mixed, when being heated to 60-75 DEG C, in high-speed stirred
Under, it is slowly added to titanate coupling agent, is heated to 110-130 DEG C, it is high-speed stirred 15-25 minutes, slow by nanoscale sieve
Addition nano zine oxide, high-speed stirred 60-90 minutes；
Step 3, mixture made from step 2 is slowly added in mixture made of step 1, under the conditions of 110-130 DEG C,
High-speed mixer and mixing 1-2 hours, the composite material for animal ear tag is made.
7. the preparation method for the composite material of animal ear tag as claimed in claim 6, which is characterized in that the step 2
Mixing speed be 280-320rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810964369.2A CN109111716A (en) | 2018-08-23 | 2018-08-23 | A kind of composite material and preparation method for animal ear tag |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810964369.2A CN109111716A (en) | 2018-08-23 | 2018-08-23 | A kind of composite material and preparation method for animal ear tag |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109111716A true CN109111716A (en) | 2019-01-01 |
Family
ID=64860704
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810964369.2A Pending CN109111716A (en) | 2018-08-23 | 2018-08-23 | A kind of composite material and preparation method for animal ear tag |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109111716A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0265754A1 (en) * | 1986-10-23 | 1988-05-04 | Fearing Manufacturing Co., Inc. | Animal ear tag |
| JP2003119363A (en) * | 2001-08-09 | 2003-04-23 | Asahi Kasei Corp | Reinforced thermoplastic resin composition |
| CN101050302A (en) * | 2007-05-21 | 2007-10-10 | 苏州新逸喆电子科技有限公司 | Environmental protective fire retardant PC/PIT plastic alloy |
| CN101180365A (en) * | 2005-05-26 | 2008-05-14 | 通用电气公司 | Mineral filled polyester polycarbonate composition |
| CN102040819A (en) * | 2010-12-29 | 2011-05-04 | 深圳市科聚新材料有限公司 | Polycarbonate (PC) engineering plastics as well as preparation method and application thereof |
| CN102690510A (en) * | 2012-05-15 | 2012-09-26 | 刘庆 | Animal ear tag capable of performing photoluminescence |
| CN107531987A (en) * | 2015-04-30 | 2018-01-02 | 乐天尖端材料株式会社 | Poly carbonate resin composition and use its mechanograph |
| CN107580616A (en) * | 2015-04-30 | 2018-01-12 | 三星电子株式会社 | The method of polymer composition, moulding article and the manufacture moulding article |
-
2018
- 2018-08-23 CN CN201810964369.2A patent/CN109111716A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0265754A1 (en) * | 1986-10-23 | 1988-05-04 | Fearing Manufacturing Co., Inc. | Animal ear tag |
| JP2003119363A (en) * | 2001-08-09 | 2003-04-23 | Asahi Kasei Corp | Reinforced thermoplastic resin composition |
| CN101180365A (en) * | 2005-05-26 | 2008-05-14 | 通用电气公司 | Mineral filled polyester polycarbonate composition |
| CN101050302A (en) * | 2007-05-21 | 2007-10-10 | 苏州新逸喆电子科技有限公司 | Environmental protective fire retardant PC/PIT plastic alloy |
| CN102040819A (en) * | 2010-12-29 | 2011-05-04 | 深圳市科聚新材料有限公司 | Polycarbonate (PC) engineering plastics as well as preparation method and application thereof |
| CN102690510A (en) * | 2012-05-15 | 2012-09-26 | 刘庆 | Animal ear tag capable of performing photoluminescence |
| CN107531987A (en) * | 2015-04-30 | 2018-01-02 | 乐天尖端材料株式会社 | Poly carbonate resin composition and use its mechanograph |
| CN107580616A (en) * | 2015-04-30 | 2018-01-12 | 三星电子株式会社 | The method of polymer composition, moulding article and the manufacture moulding article |
Non-Patent Citations (3)
| Title |
|---|
| 刘西文: "《塑料配混工[中、高级]培训教程》", 31 January 2017, 文化发展出版社 * |
| 汪多仁: "《现代高分子材料生产及应用手册》", 31 May 2002, 中国石化出版社 * |
| 练勇，等: "《机械工程材料与成形技术》", 31 August 2015, 重庆大学出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104059450B (en) | A kind of high temperature resistant heat radiation coating | |
| CN104099065B (en) | Without copper friction materials and preparation method thereof | |
| CN106726625B (en) | A kind of PEEK artificial tooth tooth composite material and preparation method | |
| CN103333514B (en) | Degradable reinforced plant fiber material and preparation method thereof | |
| CN102977667B (en) | Metal antirust paint containing modified water-soluble nanometer silica sol, and its preparation method | |
| CN105802134A (en) | Method for preparing high-strength modified epoxy glass reinforced plastic | |
| CN101293116A (en) | Absorbent bone interface screw nail and preparation method thereof | |
| CN109111716A (en) | A kind of composite material and preparation method for animal ear tag | |
| CN103408927B (en) | Composite fibre modified nylon materials and preparation method thereof | |
| CN104446311B (en) | A kind of weather-resistant and high-strength degree color steel water paint and preparation method | |
| CN102964824A (en) | Preparation process of glass fiber reinforced nylon material compound composition | |
| CN105385118A (en) | High-CTI-value flame-retardant and reinforced PBT (polybutylene terephthalate) composite material | |
| CN104292712A (en) | Environment-friendly plastic steel section material used for doors and windows and prepared from tourmaline powder and preparation method of environment-friendly plastic steel section material | |
| CN106118304A (en) | A kind of young-generating machine internal layer modification antirust paint | |
| CN103571384A (en) | Modified ethylene-vinyl-acetate (eva) resin hot melt adhesive | |
| CN103333561B (en) | Powdery paints of a kind of heat resistance fluorocarbon resin and preparation method thereof | |
| CN106187109A (en) | A kind of anticorrosion ceramic material and preparation method thereof | |
| CN104371499A (en) | Epoxy resin composite material for powder coating and preparation method thereof | |
| CN103937082A (en) | Light stable cable material | |
| CN108042851A (en) | A kind of material of tooth-implanting corona | |
| CN104371278A (en) | Epoxy resin composite material containing rice straw ashes and preparation method of epoxy resin composite material | |
| CN104312054A (en) | High-strength door/window PVC profile and preparation method thereof | |
| CN106366644A (en) | Respirator nylon material and preparing method thereof | |
| CN103571374A (en) | Fireproof hot melt adhesive for automotive upholstery | |
| CN103333578A (en) | Salt spray resistance phenolic resin powder coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190101 |
|
| RJ01 | Rejection of invention patent application after publication |