CN104292712A - Environment-friendly plastic steel section material used for doors and windows and prepared from tourmaline powder and preparation method of environment-friendly plastic steel section material - Google Patents

Environment-friendly plastic steel section material used for doors and windows and prepared from tourmaline powder and preparation method of environment-friendly plastic steel section material Download PDF

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Publication number
CN104292712A
CN104292712A CN201410623512.3A CN201410623512A CN104292712A CN 104292712 A CN104292712 A CN 104292712A CN 201410623512 A CN201410623512 A CN 201410623512A CN 104292712 A CN104292712 A CN 104292712A
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CN
China
Prior art keywords
steel section
powder
section material
parts
tourmaline powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410623512.3A
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Chinese (zh)
Inventor
陈学军
方圆
吴浩然
喻勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Province San Le Door And Window Curtain Wall Engineering Co Ltd
Original Assignee
Anhui Province San Le Door And Window Curtain Wall Engineering Co Ltd
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Publication date
Application filed by Anhui Province San Le Door And Window Curtain Wall Engineering Co Ltd filed Critical Anhui Province San Le Door And Window Curtain Wall Engineering Co Ltd
Priority to CN201410623512.3A priority Critical patent/CN104292712A/en
Publication of CN104292712A publication Critical patent/CN104292712A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention relates to an environment-friendly plastic steel section material used for doors and windows and prepared from tourmaline powder. The section material is prepared from the following raw materials in parts by weight: 4-6 parts of tourmaline powder, 1-1.5 parts of polybutylene terephthalate, 5-8 parts of sandalwood wood powder, 2-3 parts of aluminium hydroxide, 3-5 parts of silicon resin, 0.1-0.2 part of acrylamide, 0.1-0.2 part of polytetrafluoroethylene, 0.4-0.6 part of titanate coupling agents, 0.2-0.3 part of shea butter, 0.7-1 part of nanometer titanium dioxide, 90-100 parts of SG-5PVC, 10-14 parts of reinforcing additives, and 20-30 parts of water. The tourmaline powder is added to the plastic steel section material disclosed by the invention, so that far infrared rays and negative ions can be emitted, the air can be purified, and the plastic steel section material is beneficial to healthy bodies; the sandalwood wood powder is added, so that the section material has fragrance; the reinforcing additives are used, so that the strength, the toughness and the ageing-resistant performance of the plastic steel section material can be improved.

Description

A kind of tourmaline powder Environment protecting door or window plastic-steel section bar and preparation method thereof
Technical field
The invention belongs to plastic-steel section bar field, particularly relate to a kind of tourmaline powder Environment protecting door or window plastic-steel section bar and preparation method thereof.
Background technology
Plastic-steel section bar is called for short plastic-steel, and main chemical compositions is PVC, is therefore also PVC profile.Be a kind of novel material of construction be widely used, because its physicals is as rigidity, elasticity, corrosion-resistant, ageing resistance is excellent, and being typically used as is the good surrogate of the non-ferrous metals such as copper, zinc, aluminium.
In building construction, be mainly used in push-and-pull, the application of horizontally-opening windows and doors, guardrail, tubing and ceiling material, be also widely used in motor car engine protecting sheet aspect by new technical process process; not only lightweight; and good toughness, there is firm advantageous property, be sometimes also referred to as alloy plastic-steel.
Although plastic-steel material widespread use, along with the progress of society, its performance be improved constantly, the performances such as such as intensity, toughness, thermotolerance, heat retaining property, sound-proofing, static resistance, ultra-violet resistance.
And China's plastic-steel section bar overwhelming majority section bar inferior uses lead salt stabilizer, finished product lead tolerance is between 0.6%-1.2%.Lead is a kind of harmful material, when section bar inferior is aging, can separate out leaded dust, lead content in blood can be made to exceed standard, even lead poisoning after Long Term Contact.Therefore need the security improving plastic-steel section bar, do not raise the cost simultaneously.
Summary of the invention
The object of the present invention is to provide a kind of tourmaline powder Environment protecting door or window plastic-steel section bar and preparation method thereof, this plastic-steel section bar can launch far ir ray and negative ion, can purify air, and is conducive to healthy, has fragrance.
Technical scheme of the present invention is as follows:
A kind of tourmaline powder Environment protecting door or window plastic-steel section bar, is characterized in that being made up of the raw material of following weight part: tourmaline powder 4-6, butylene terephthalate 1-1.5, santal wood powder 5-8, aluminium hydroxide 2-3, silicone resin 3-5, acrylamide 0.1-0.2, tetrafluoroethylene 0.1-0.2, titanate coupling agent 0.4-0.6, shea butter 0.2-0.3, nano titanium oxide 0.7-1, SG-5PVC90-100, reinforcing aids 10-14, water 20-30;
Described reinforcing aids is made up of the raw material of following weight part: polynite 6-8, silane coupling agent kh-550 0.3-0.4, four acicular type zinc oxide crystal whisker 5-6, SG-5PVC powder 3-4, nano titanium oxide 2-3, carbon nanotube 0.4-0.6, nanometer boron fibre 0.3-0.5, tetraethoxy 2-3, ethanol 20-25, water 10-13; Preparation method is: be added to the water by silane coupling agent kh-550, add polynite after stirring, and adds nano titanium oxide, carbon nanotube while stirring, magnetic agitation 1-2 hour, dries, pulverizes, cross 100 mesh sieves, obtain powder; Added in ethanol by tetraethoxy and dissolve, then add described powder and other remaining components, magnetic agitation 30-40 minute, is heated to 80-90 DEG C, does not stop to be stirred to ethanol and evaporates completely, pulverizes, to obtain final product.
The preparation method of described tourmaline powder Environment protecting door or window plastic-steel section bar, is characterized in that comprising the following steps:
(1) santal wood powder, tourmaline powder are added to the water, add titanate coupling agent, shea butter again after stirring, warming while stirring to 75-85 DEG C, then adds nano titanium oxide, and stirring reaction 2-3 hour, spraying dry, obtained particle;
(2) particle that (1) step obtains is mixed with other remaining components, with high-speed mixer mixing 5-7 minute at 110-120 DEG C, be cooled to room temperature, discharging, obtain Preblend;
(3) twin screw extruder is sent in the Preblend (2) step obtained, and extruder screw speed adjustment is 10-15 rev/min, and barrel and head temperature are 160-180 DEG C, extrusioning shaping, and water-cooled process, obtains section bar;
(4) section bar (3) step obtained sends into-15 to-30 DEG C, cools 15-20 second under vacuum environment, then through traction, shaping, to obtain final product.
Beneficial effect of the present invention
Plastic-steel section bar of the present invention with the addition of tourmaline powder, can launch far ir ray and negative ion, can purify air, and is conducive to healthy; By adding santal wood powder, section bar is made to have fragrance; The application of the invention reinforcing aids, the intensity of plastic-steel section bar, toughness and ageing-resistant performance can be increased.
Embodiment
A kind of tourmaline powder Environment protecting door or window plastic-steel section bar, is made up of the raw material of following weight part (kilogram): tourmaline powder 4-6, butylene terephthalate 1.3, santal wood powder 6, aluminium hydroxide 2.5, silicone resin 4, acrylamide 0.1, tetrafluoroethylene 0.1, titanate coupling agent 0.5, shea butter 0.3, nano titanium oxide 0.9, SG-5PVC95, reinforcing aids 13, water 25;
Described reinforcing aids is made up of the raw material of following weight part (kilogram): polynite 7, silane coupling agent kh-550 0.3, four acicular type zinc oxide crystal whisker 5.5, SG-5PVC powder 3.5, nano titanium oxide 2.5, carbon nanotube 0.5, nanometer boron fibre 0.4, tetraethoxy 2.5, ethanol 23, water 12; Preparation method is: be added to the water by silane coupling agent kh-550, add polynite after stirring, and adds nano titanium oxide, carbon nanotube while stirring, magnetic agitation 1.5 hours, dries, and pulverizes, and crosses 100 mesh sieves, obtains powder; Added in ethanol by tetraethoxy and dissolve, then add described powder and other remaining components, magnetic agitation 35 minutes, is heated to 85 DEG C, does not stop to be stirred to ethanol and evaporates completely, pulverizes, to obtain final product.
The preparation method of described tourmaline powder Environment protecting door or window plastic-steel section bar, comprises the following steps:
(1) santal wood powder, tourmaline powder are added to the water, add titanate coupling agent, shea butter again, warming while stirring to 80 DEG C, then add nano titanium oxide after stirring, stirring reaction 2.5 hours, spraying dry, obtains particle;
(2) particle that (1) step obtains is mixed with other remaining components, at 115 DEG C, mix 6 minutes with high-speed mixer, be cooled to room temperature, discharging, obtain Preblend;
(3) twin screw extruder is sent in the Preblend (2) step obtained, and extruder screw speed adjustment is 13 revs/min, and barrel and head temperature are 170 DEG C, extrusioning shaping, and water-cooled process, obtains section bar;
(4) section bar (3) step obtained sends into-20 DEG C, cools 18 seconds under vacuum environment, then through traction, shaping, to obtain final product.
Experimental data:
After tested, the bending elastic modulus of this plastic-steel section bar is 2790MPa, and simple beam impact strength is 23J/ ㎡, and Dimensional shrinkage under heat is 1.3%, bubble-free, pit, slight crack in 150 DEG C of heating temperatures tests.

Claims (2)

1. a tourmaline powder Environment protecting door or window plastic-steel section bar, is characterized in that being made up of the raw material of following weight part: tourmaline powder 4-6, butylene terephthalate 1-1.5, santal wood powder 5-8, aluminium hydroxide 2-3, silicone resin 3-5, acrylamide 0.1-0.2, tetrafluoroethylene 0.1-0.2, titanate coupling agent 0.4-0.6, shea butter 0.2-0.3, nano titanium oxide 0.7-1, SG-5PVC90-100, reinforcing aids 10-14, water 20-30;
Described reinforcing aids is made up of the raw material of following weight part: polynite 6-8, silane coupling agent kh-550 0.3-0.4, four acicular type zinc oxide crystal whisker 5-6, SG-5PVC powder 3-4, nano titanium oxide 2-3, carbon nanotube 0.4-0.6, nanometer boron fibre 0.3-0.5, tetraethoxy 2-3, ethanol 20-25, water 10-13; Preparation method is: be added to the water by silane coupling agent kh-550, add polynite after stirring, and adds nano titanium oxide, carbon nanotube while stirring, magnetic agitation 1-2 hour, dries, pulverizes, cross 100 mesh sieves, obtain powder; Added in ethanol by tetraethoxy and dissolve, then add described powder and other remaining components, magnetic agitation 30-40 minute, is heated to 80-90 DEG C, does not stop to be stirred to ethanol and evaporates completely, pulverizes, to obtain final product.
2. the preparation method of tourmaline powder Environment protecting door or window plastic-steel section bar according to claim 1, is characterized in that comprising the following steps:
(1) santal wood powder, tourmaline powder are added to the water, add titanate coupling agent, shea butter again after stirring, warming while stirring to 75-85 DEG C, then adds nano titanium oxide, and stirring reaction 2-3 hour, spraying dry, obtained particle;
(2) particle that (1) step obtains is mixed with other remaining components, with high-speed mixer mixing 5-7 minute at 110-120 DEG C, be cooled to room temperature, discharging, obtain Preblend;
(3) twin screw extruder is sent in the Preblend (2) step obtained, and extruder screw speed adjustment is 10-15 rev/min, and barrel and head temperature are 160-180 DEG C, extrusioning shaping, and water-cooled process, obtains section bar;
(4) section bar (3) step obtained sends into-15 to-30 DEG C, cools 15-20 second under vacuum environment, then through traction, shaping, to obtain final product.
CN201410623512.3A 2014-11-07 2014-11-07 Environment-friendly plastic steel section material used for doors and windows and prepared from tourmaline powder and preparation method of environment-friendly plastic steel section material Pending CN104292712A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410623512.3A CN104292712A (en) 2014-11-07 2014-11-07 Environment-friendly plastic steel section material used for doors and windows and prepared from tourmaline powder and preparation method of environment-friendly plastic steel section material

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Application Number Priority Date Filing Date Title
CN201410623512.3A CN104292712A (en) 2014-11-07 2014-11-07 Environment-friendly plastic steel section material used for doors and windows and prepared from tourmaline powder and preparation method of environment-friendly plastic steel section material

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CN104292712A true CN104292712A (en) 2015-01-21

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104558969A (en) * 2015-01-29 2015-04-29 居泽林 Insect prevention wood plastic interior door and preparation method thereof
CN104804160A (en) * 2015-05-04 2015-07-29 芜湖市宝艺游乐科技设备有限公司 Environment-friendly oxidized graphene melamine resin and preparation method thereof
CN106043157A (en) * 2016-06-27 2016-10-26 蚌埠市鑫晟新材料科技有限公司 Automobile engine guard plate and preparation method thereof
CN111558295A (en) * 2020-05-11 2020-08-21 上海天家医院管理有限公司 Preparation method of negative oxygen ion air purifying agent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101033317A (en) * 2006-05-24 2007-09-12 卓玉国 Preparation of multifunctional wood-plastic composite material
JP2008045012A (en) * 2006-08-14 2008-02-28 Hino Jushi:Kk Soft vinyl chloride-based resin composition
CN101550755A (en) * 2009-05-08 2009-10-07 王树升 Wood-plastic microcellular foamed anion ecological floor and process for producing same
CN102558715A (en) * 2012-02-03 2012-07-11 上海韬鸿化工科技有限公司 Anionic ecological imitation wood floor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101033317A (en) * 2006-05-24 2007-09-12 卓玉国 Preparation of multifunctional wood-plastic composite material
JP2008045012A (en) * 2006-08-14 2008-02-28 Hino Jushi:Kk Soft vinyl chloride-based resin composition
CN101550755A (en) * 2009-05-08 2009-10-07 王树升 Wood-plastic microcellular foamed anion ecological floor and process for producing same
CN102558715A (en) * 2012-02-03 2012-07-11 上海韬鸿化工科技有限公司 Anionic ecological imitation wood floor

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104558969A (en) * 2015-01-29 2015-04-29 居泽林 Insect prevention wood plastic interior door and preparation method thereof
CN104558969B (en) * 2015-01-29 2017-01-11 居泽林 Insect prevention wood plastic interior door and preparation method thereof
CN104804160A (en) * 2015-05-04 2015-07-29 芜湖市宝艺游乐科技设备有限公司 Environment-friendly oxidized graphene melamine resin and preparation method thereof
CN106043157A (en) * 2016-06-27 2016-10-26 蚌埠市鑫晟新材料科技有限公司 Automobile engine guard plate and preparation method thereof
CN111558295A (en) * 2020-05-11 2020-08-21 上海天家医院管理有限公司 Preparation method of negative oxygen ion air purifying agent

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Application publication date: 20150121