CN109097179A - A kind of fully synthetic water-soluble metal of the insoluble oil of hard water resistance type processes cutting fluid - Google Patents

A kind of fully synthetic water-soluble metal of the insoluble oil of hard water resistance type processes cutting fluid Download PDF

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Publication number
CN109097179A
CN109097179A CN201811104284.3A CN201811104284A CN109097179A CN 109097179 A CN109097179 A CN 109097179A CN 201811104284 A CN201811104284 A CN 201811104284A CN 109097179 A CN109097179 A CN 109097179A
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CN
China
Prior art keywords
water
fully synthetic
water resistance
cutting fluid
liquid
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811104284.3A
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Chinese (zh)
Inventor
黄馨卉
陈瑀瑄
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Jiaxing Shuncheng Fine Chemical Co Ltd
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Jiaxing Shuncheng Fine Chemical Co Ltd
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Priority to CN201811104284.3A priority Critical patent/CN109097179A/en
Publication of CN109097179A publication Critical patent/CN109097179A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/56—Boundary lubrication or thin film lubrication
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of fully synthetic water-soluble metals of the insoluble oil of hard water resistance type to process cutting fluid, and the machining of metals liquid is made of components by weight percent distilled water 55-59%, triethanolamine 12-15%, disodium ethylene diamine tetraacetate 1.8-2.3%, carboxylic acid 10-13%, borate 5-8%, AMP-95 auxiliary agent 0.2-0.5%, PAG12-16%, non-formaldehyde release type compound disinfectant > 0.6%.Also disclose the preparation method of the machining of metals liquid.Machining of metals liquid of the invention has water solubility, can blend dilution use, have hard water resistance ability, as metal cutting, turning, shearing, grinding, antirust cooling-lubricant.

Description

A kind of fully synthetic water-soluble metal of the insoluble oil of hard water resistance type processes cutting fluid
Technical field
The invention belongs to machining of metals liquid technical fields, and in particular to a kind of insoluble oil of hard water resistance type is fully synthetic water-soluble Property machining of metals liquid.
Background technique
Traditional machining of metals liquid, to water quality requirement height, is needed when dilution is blent to needing to use a large amount of water Continue to supply the few water of metal ions such as calcium-magnesium-containing with the use of large-scale softening water treatment facilities.Therefore, it is necessary to develop one Kind can adapt to the machining of metals liquid of hard water conditions.
Summary of the invention
In order to solve the above technical problems, the technical solution adopted by the present invention is that: a kind of insoluble fully synthetic water of oil of hard water resistance type Solube metallic process cutting fluid, the machining of metals liquid by components by weight percent distilled water 55-59%, triethanolamine 12-15%, Disodium ethylene diamine tetraacetate 1.8-2.3%, carboxylic acid 10-13%, borate 5-8%, AMP-95 auxiliary agent 0.2-0.5%, PAG12- 16%, non-formaldehyde release type compound disinfectant > 0.6% is constituted.
The machining of metals liquid is by components by weight percent distilled water 55%, triethanolamine 14%, disodium ethylene diamine tetraacetate 2.5%, carboxylic acid 10%, borate 5%, AMP-95 auxiliary agent 0.5%, PAG12%, 1% structure of non-formaldehyde release type compound disinfectant At.
A kind of preparation method of the fully synthetic water-soluble metal processing cutting fluid of the insoluble oil of hard water resistance type, comprising the following steps:
1) distilled water is put into stirred tank, water temperature is higher than 20 DEG C, and it is high that temperature in slot is kept stirring in whole preparation process In 20 DEG C；
2) it puts into EDTA-2Na and all dissolves, so that clear is presented in liquid；
3) triethanolamine, carboxylic acid, borate are sequentially added, is persistently stirred 30 minutes, until liquid presentation is as clear as crystal；
4) AMP95 is added, non-formaldehyde release type compound disinfectant stirs 3 minutes or more, liquid presents colourless to yellowish；
5) it puts into PAG again to stir 20 minutes, it is fully synthetic to get the insoluble oil of hard water resistance type that revolving speed is no more than 1000rpm/min Water-soluble metal processes cutting fluid.
Temperature remains 30 DEG C in stirred tank, and speed of agitator control is in 1000rpm/min after putting into PAG.
In the present invention, distilled water plays solvent action；Triethanolamine can play the role of antirust, lubrication and a kind of storage Standby alkali；Disodium ethylene diamine tetraacetate plays hard water resistance effect, carboxylic acid plays anti-rust action；Borate play anti-rust action, AMP-95 auxiliary agent plays the role of water stabilization as efficient reserve alkali；PAG plays the role of lubrication, film forming；Non-formaldehyde release type Compound disinfectant plays the role of sterilization.
The beneficial effects of the present invention are: machining of metals liquid of the invention has water solubility, dilution can be blent and used, With hard water resistance ability, as metal cutting, turning, shearing, grinding, antirust cooling-lubricant.
Specific embodiment
Embodiment 1
A kind of fully synthetic water-soluble metal of the insoluble oil of hard water resistance type processes cutting fluid, and the machining of metals liquid is by weight Component distilation water 55%, triethanolamine 14%, disodium ethylene diamine tetraacetate 2.5%, carboxylic acid 10%, borate 5%, AMP-95 are helped Agent 0.5%, PAG12%, non-formaldehyde release type compound disinfectant 1% are constituted.
Embodiment 2
A kind of fully synthetic water-soluble metal of the insoluble oil of hard water resistance type processes cutting fluid, and the machining of metals liquid is by weight Component distilation water 50%, triethanolamine 15%, disodium ethylene diamine tetraacetate 1.8%, carboxylic acid 13%, borate 7.4%, AMP-95 Auxiliary agent 0.2%, PAG12%, non-formaldehyde release type compound disinfectant 0.6% are constituted.
Embodiment 3
A kind of fully synthetic water-soluble metal of the insoluble oil of hard water resistance type processes cutting fluid, and the machining of metals liquid is by weight Component distilation water 58%, triethanolamine 12%, disodium ethylene diamine tetraacetate 1.8%, carboxylic acid 10%, borate 5%, AMP-95 are helped Agent 0.4%, PAG12%, non-formaldehyde release type compound disinfectant 0.8% are constituted.
Embodiment 4
A kind of preparation method of the fully synthetic water-soluble metal processing cutting fluid of the insoluble oil of hard water resistance type, comprising the following steps:
1) distilled water is put into stirred tank, temperature remains 30 DEG C in stirred tank in whole preparation process；
2) it puts into EDTA-2Na and all dissolves, so that clear is presented in liquid；
3) triethanolamine, carboxylic acid, borate are sequentially added, is persistently stirred 30 minutes, until liquid presentation is as clear as crystal；
4) AMP95 is added, non-formaldehyde release type compound disinfectant stirs 3 minutes or more, liquid presents colourless to yellowish；
5) it puts into PAG again to stir 20 minutes, speed of agitator control is complete to get the insoluble oil of hard water resistance type in 1000rpm/min Synthesizing water-solubility machining of metals liquid.
The preferred embodiment of the present invention has been described in detail above, it should be understood that those skilled in the art without It needs creative work according to the present invention can conceive and makes many modifications and variations, therefore, all technologies in the art Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea Technical solution, all should be within the scope of protection determined by the claims.

Claims (4)

1. a kind of fully synthetic water-soluble metal of the insoluble oil of hard water resistance type processes cutting fluid, which is characterized in that the intermetallic composite coating is cut Liquid is cut by components by weight percent distilled water 55-59%, triethanolamine 12-15%, disodium ethylene diamine tetraacetate 1.8-2.3%, carboxylic acid 10- 13%, borate 5-8%, AMP-95 auxiliary agent 0.2-0.5%, PAG12-16%, non-formaldehyde release type compound disinfectant > 0.6% It constitutes.
2. the fully synthetic water-soluble metal of the insoluble oil of hard water resistance type processes cutting fluid as described in claim 1, which is characterized in that institute Machining of metals liquid is stated by components by weight percent distilled water 55%, triethanolamine 14%, disodium ethylene diamine tetraacetate 2.5%, carboxylic acid 10%, borate 5%, AMP-95 auxiliary agent 0.5%, PAG12%, non-formaldehyde release type compound disinfectant 1% are constituted.
3. the preparation side that a kind of insoluble fully synthetic water-soluble metal of oil of hard water resistance type as described in claim 1 processes cutting fluid Method, which comprises the following steps:
1) distilled water is put into stirred tank, water temperature is higher than 20 DEG C, and temperature in slot is kept stirring in whole preparation process and is higher than 20 ℃；
2) it puts into EDTA-2Na and all dissolves, so that clear is presented in liquid；
3) triethanolamine, carboxylic acid, borate are sequentially added, is persistently stirred 30 minutes, until liquid presentation is as clear as crystal；
4) AMP95 is added, non-formaldehyde release type compound disinfectant stirs 3 minutes or more, liquid presents colourless to yellowish；
5) it puts into PAG again to stir 20 minutes, it is fully synthetic water-soluble to get the insoluble oil of hard water resistance type that revolving speed is no more than 1000rpm/min Property machining of metals liquid.
4. the preparation method of the fully synthetic water-soluble metal processing cutting fluid of the insoluble oil of hard water resistance type as claimed in claim 3, It is characterized in that, temperature remains 30 DEG C in the stirred tank, and speed of agitator control is in 1000rpm/min after putting into PAG.
CN201811104284.3A 2018-09-21 2018-09-21 A kind of fully synthetic water-soluble metal of the insoluble oil of hard water resistance type processes cutting fluid Pending CN109097179A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111205919A (en) * 2020-01-13 2020-05-29 库勃智能科技(上海)有限公司 Environment-friendly biostable cutting fluid and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10195471A (en) * 1996-12-28 1998-07-28 Neos Co Ltd Water-soluble processing oil agent
EP1474501A1 (en) * 2002-02-11 2004-11-10 Ecolab Inc. Lubricant for conveyor system
JP2005113039A (en) * 2003-10-09 2005-04-28 Kohjin Co Ltd Aqueous cutting liquid and aqueous slurry and method for cutting cutting resistant material having hard and brittle property by using aqueous cutting liquid or aqueous slurry
CN103865622A (en) * 2014-03-11 2014-06-18 东莞市安美润滑科技有限公司 Totally-synthesized water-based stainless steel cutting liquid, and preparation method and using method thereof
CN104927996A (en) * 2014-03-20 2015-09-23 中国石油化工股份有限公司 Completely synthesized cutting liquid composition
CN105482888A (en) * 2015-12-23 2016-04-13 南京科润工业介质股份有限公司 Complete synthesis cutting fluid capable of meeting machining requirements of multiple materials
CN106635369A (en) * 2016-12-20 2017-05-10 武汉航天航科石油化学有限公司 Fully synthetic cutting fluid and production method thereof
CN106675749A (en) * 2016-11-02 2017-05-17 清华大学天津高端装备研究院 Fully-synthetic water-based glass grinding fluid and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10195471A (en) * 1996-12-28 1998-07-28 Neos Co Ltd Water-soluble processing oil agent
EP1474501A1 (en) * 2002-02-11 2004-11-10 Ecolab Inc. Lubricant for conveyor system
JP2005113039A (en) * 2003-10-09 2005-04-28 Kohjin Co Ltd Aqueous cutting liquid and aqueous slurry and method for cutting cutting resistant material having hard and brittle property by using aqueous cutting liquid or aqueous slurry
CN103865622A (en) * 2014-03-11 2014-06-18 东莞市安美润滑科技有限公司 Totally-synthesized water-based stainless steel cutting liquid, and preparation method and using method thereof
CN104927996A (en) * 2014-03-20 2015-09-23 中国石油化工股份有限公司 Completely synthesized cutting liquid composition
CN105482888A (en) * 2015-12-23 2016-04-13 南京科润工业介质股份有限公司 Complete synthesis cutting fluid capable of meeting machining requirements of multiple materials
CN106675749A (en) * 2016-11-02 2017-05-17 清华大学天津高端装备研究院 Fully-synthetic water-based glass grinding fluid and preparation method thereof
CN106635369A (en) * 2016-12-20 2017-05-10 武汉航天航科石油化学有限公司 Fully synthetic cutting fluid and production method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111205919A (en) * 2020-01-13 2020-05-29 库勃智能科技(上海)有限公司 Environment-friendly biostable cutting fluid and preparation method thereof

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Application publication date: 20181228