CN109092850A - A method of solidifying garbage flying ash using chelating agent - Google Patents

A method of solidifying garbage flying ash using chelating agent Download PDF

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Publication number
CN109092850A
CN109092850A CN201810832969.3A CN201810832969A CN109092850A CN 109092850 A CN109092850 A CN 109092850A CN 201810832969 A CN201810832969 A CN 201810832969A CN 109092850 A CN109092850 A CN 109092850A
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CN
China
Prior art keywords
chelating agent
facar
stoste
flying dust
cement
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Pending
Application number
CN201810832969.3A
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Chinese (zh)
Inventor
张期凯
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Anhui Anjiang Environmental Protection Technology Co Ltd
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Anhui Anjiang Environmental Protection Technology Co Ltd
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Priority to CN201810832969.3A priority Critical patent/CN109092850A/en
Publication of CN109092850A publication Critical patent/CN109092850A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B1/00Dumping solid waste
    • B09B1/004Covering of dumping sites

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of methods for solidifying garbage flying ash using chelating agent, are related to flying dust processing technology field.The present invention includes the following steps: S01: preparation FACAR stoste;S02: according to quality proportioning: m (FACAR stoste): m (water)=1:9 prepares chelating agent;S03: according to quality proportioning: m (chelating agent): m (flying dust): m (cement)=2:33:15 carries out 1~3min of mixing to flying dust and obtains stabilizing product;S04: stabilisation product material obtained by solidifying will be kneaded and be transmitted to flying dust maintenance area's maintenance.The present invention has the FACAR stoste of degradation dioxin compounds function by preparation, it carries out FACAR stoste and water to be mixed with chelating agent according to a certain percentage, mixing solidification is carried out by the way that flying dust, cement, the chelating agent prepared to be placed in kneading machine, resulting stable compound is transmitted to flying dust maintenance area and carries out buried processing, flyash curing efficiency and stability are high, solidify at low cost.

Description

A method of solidifying garbage flying ash using chelating agent
Technical field
The invention belongs to flying dust processing technology fields, more particularly to a kind of side for solidifying garbage flying ash using chelating agent Method.
Background technique
Consumer waste incineration processing generates flying dust, and yield is the 3%-5% or so of garbage treatment quantity, and flying dust is moisture content Lower grey powder, winged ash composition are mainly the mineral such as SiO2, NaC1, KCI, CaAl2Si2O8, CaCO3 and CaSO4;Contain The dissolving salt of amount up to 17.9%, also containing the high concentrations of Cd that can be flooded out, Pb, Cu, the various heavies such as Zn, Hg and Cr, Domestic garbage incineration flyash belongs to hazardous waste, it is necessary to pass through certain processing, reduce its risk just can enter landfill later Field carries out security landfill or considers further utilize.
Existing mainly includes generally cement solidification to the mode of the processing of flying dust, chemical agent stabilizes, sour solvent mentions Take with melting and solidification etc., wherein cement solidification is most commonly seen, the flying dust after cement solidification and the life rubbish for containing a large amount of organic matters When rubbish blended landfill, organic matter contained in rubbish can generate nitrogen dioxide gas, organic acid, water-soluble sulfuric acid due to degradation The substances such as salt, the stability of heavy metal after these solidify at branch's reduction, it is seen that cement solidification method is used alone can be with the time Extension have the defects that very big, the stabilizer generallyd use has lime, phosphate, bleaching powder, sulfide, macromolecule stabilizer With ferrite etc., but medicament stabilization can generate high concentration inorganic salt wastewater, need to carry out subsequent processing and increase processing cost, and medicine It is so bulk that agent treated flying dust, which is appointed, large specific surface area, and dioxin is possible to dissolve out, and cannot eliminate the harm to environment, because This is provided in view of the above problems a kind of using chelating agent solidifies the method for garbage flying ash to solve problem above with important meaning Justice.
Summary of the invention
The purpose of the present invention is to provide a kind of methods for solidifying garbage flying ash using chelating agent, have degradation by preparation The FACAR stoste of dioxin compounds function carries out FACAR stoste and water to be mixed with chelating according to a certain percentage Agent carries out mixing solidification by the way that flying dust, cement, the chelating agent prepared to be placed in kneading machine, by resulting stable compound It being transmitted to flying dust maintenance area and carries out buried processing, solve in flying dust treatment process, flyash curing low efficiency, stability is low, Gu Change problem at high cost.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions:
A kind of method being solidified garbage flying ash using chelating agent of the invention, is included the following steps:
S01: preparation FACAR stoste;
S02: according to quality proportioning: m (FACAR stoste): m (water)=1:9 prepares chelating agent;
S03: according to quality proportioning: m (chelating agent): m (flying dust): m (cement)=2:33:15 to flying dust carry out mixing 1~ 3min obtains stabilizing product;
S04: stabilisation product material obtained by solidifying will be kneaded and be transmitted to flying dust maintenance area's maintenance.
Further, the FACAR stoste is using amine compounds and ammonium compounds as raw material, through catalytic polymerization, ammonia famine Liquid aminodithioformic acid type chelating resin made from process.
Further, the step S02 is realized by the following method: by equipped with FACAR stoste tank car to The FACAR stoste prepared is loaded in FACAR stoste storage tank, the FACAR stoste tank bottom passes through water pipe and FACAR stoste It pumps and FACAR stoste is added according to the quality proportioning into chelating agent preparing tank, while by having water pipe and water pump originally Water pot is added certainly into the chelating agent preparing tank according to the quality proportioning from the water service pump of the bottom of the originally water pot Water, is provided with stirring rod in the chelating agent preparing tank, and the stirring rod is stirred 1 to FACAR stoste and tap water~ 2min obtains chelating agent.
Further, the step S03 is realized by the following method: will be configured in chelating agent preparing tank by pipeline Good chelating agent is successively transported to chelating agent and keeps in storage tank, chelating agent weighing hopper, kneading machine, and the chelating agent keeps in storage tank and chela Precise control of flew is carried out by chelating agent constant displacement pump between mixture weighing hopper, is led between the chelating agent weighing hopper and kneading machine It crosses control valve to be controlled, the spray equipment for carrying out uniformly spray covering to chelating agent is provided in the kneading machine;Meanwhile it is logical Cross flying dust hopper through dedicated pipeline, flying dust constant feeder, flying dust weighing hopper, control valve into the kneading machine according to the matter Flying dust is added in amount proportion, by cement hopper through dedicated pipeline, cement constant feeder, cement weighing hopper, control valve to described Cement is added according to the quality proportioning in kneading machine, be equipped in the kneading machine electric stirring axis to the flying dust, cement, Chelating agent is stirred 1~3min and obtains stabilizing product.
Further, the step S04 is realized by the following method: being discharged by installing in the mixing motor spindle The delivery outlet lower section of bucket, the discharge bucket is equipped with screw conveyor, and the output end of the screw conveyor is provided with flying dust and supports Shield area is filled.
The invention has the following advantages:
The present invention has the FACAR stoste of degradation dioxin compounds function by preparation, and FACAR stoste is pressed with water It carries out being mixed with chelating agent according to certain ratio, by the way that flying dust, cement, the chelating agent prepared to be placed in kneading machine and carry out It is kneaded solidification, resulting stable compound is transmitted to flying dust maintenance area and carries out buried processing, in flying dust treatment process, has and flies Grey curing efficiency and stability are high, solidify advantage at low cost.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Detailed description of the invention
In order to illustrate the technical solution of the embodiments of the present invention more clearly, will be described below to embodiment required Attached drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for ability For the those of ordinary skill of domain, without creative efforts, it can also be obtained according to these attached drawings other attached Figure.
Fig. 1 is a kind of flow chart for the method for solidifying garbage flying ash using chelating agent of the present invention;
Fig. 2 is a kind of corresponding system construction drawing of method for solidifying garbage flying ash using chelating agent of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts all other Embodiment shall fall within the protection scope of the present invention.
Refering to Figure 1, a kind of method for being solidified garbage flying ash using chelating agent, is included the following steps:
S01: preparation FACAR stoste;
S02: according to quality proportioning: m (FACAR stoste): m (water)=1:9 prepares chelating agent;
S03: according to quality proportioning: m (chelating agent): m (flying dust): m (cement)=2:33:15 carries out mixing 2min to flying dust It obtains stabilizing product;
S04: stabilisation product material obtained by solidifying will be kneaded and be transmitted to flying dust maintenance area's maintenance.
Wherein, FACAR stoste is to be made using amine compounds and ammonium compounds as raw material through catalytic polymerization, ammonia famine chemical industry sequence Liquid aminodithioformic acid type chelating resin;Amine compounds and ammonium compounds are hydrogen donors, special in the product can be urged Simultaneously room temperature dechlorination reaction occurs for furans with the p- dioxin of more benzos-and phenyl polychloride under the action of agent, so that dioxin Close object removing toxic substances.
As shown in Figure 2, wherein step S02 is realized by the following method: by equipped with FACAR stoste tank car to Load the FACAR stoste prepared in FACAR stoste storage tank, FACAR stoste tank bottom by water pipe and FACAR raw liquor pump to FACAR stoste is added according to quality proportioning in chelating agent preparing tank, while by the originally water pot with water pipe and water pump by certainly Tap water is added according to quality proportioning into chelating agent preparing tank in the water service pump for coming the bottom of water pot, sets in chelating agent preparing tank It is equipped with stirring rod, stirring rod is stirred 1min to FACAR stoste and tap water and obtains chelating agent.
Wherein, step S03 is realized by the following method: by pipeline by chelating configured in chelating agent preparing tank Agent is successively transported to chelating agent and keeps in storage tank, chelating agent weighing hopper, kneading machine, chelating agent keep in storage tank and chelating agent weighing hopper it Between by chelating agent constant displacement pump carry out precise control of flew, controlled between chelating agent weighing hopper and kneading machine by control valve It makes, the spray equipment for carrying out uniformly spray covering to chelating agent is provided in kneading machine;Meanwhile by flying dust hopper through dedicated pipe Flying dust is added according to the quality proportioning into kneading machine in road, flying dust constant feeder, flying dust weighing hopper, control valve, passes through water Water is added according to quality proportioning into kneading machine through dedicated pipeline, cement constant feeder, cement weighing hopper, control valve in pug bucket Mud, electric stirring axis is equipped in kneading machine is stirred 2min to the flying dust, cement, chelating agent and obtain stabilizing product.
Wherein, step S04 is realized by the following method: by being kneaded motor spindle installation discharge bucket, discharge bucket Screw conveyor is installed, the output end of screw conveyor is provided with flying dust maintenance area and is filled below delivery outlet.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the invention In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example. Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification, It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only It is limited by claims and its full scope and equivalent.

Claims (5)

1. a kind of method for solidifying garbage flying ash using chelating agent, which comprises the steps of:
S01: preparation FACAR stoste;
S02: according to quality proportioning: m (FACAR stoste): m (water)=1:9 prepares chelating agent;
S03: according to quality proportioning: m (chelating agent): m (flying dust): m (cement)=2:33:15 carries out 1~3min of mixing to flying dust It obtains stabilizing product;
S04: stabilisation product material obtained by solidifying will be kneaded and be transmitted to flying dust maintenance area's maintenance.
2. a kind of method for solidifying garbage flying ash using chelating agent according to claim 1, which is characterized in that described FACAR stoste is using amine compounds and ammonium compounds as raw material, through two sulphur of liquid amino made from catalytic polymerization, ammonia famine chemical industry sequence For formic acid type chelating resin.
3. a kind of method for solidifying garbage flying ash using chelating agent according to claim 1, which is characterized in that the step S02 is realized by the following method: being loaded by the tank car equipped with FACAR stoste into FACAR stoste storage tank and is prepared FACAR stoste, the FACAR stoste tank bottom is by water pipe and FACAR raw liquor pump into chelating agent preparing tank according to described Quality proportioning is added FACAR stoste, while by the originally water pot with water pipe and water pump by the bottom of the originally water pot Tap water is added according to the quality proportioning into the chelating agent preparing tank in water service pump, is arranged in the chelating agent preparing tank There is stirring rod, the stirring rod is stirred 1~2min to FACAR stoste and tap water and obtains chelating agent.
4. a kind of method for solidifying garbage flying ash using chelating agent according to claim 1, which is characterized in that the step S03 is realized by the following method: chelating agent configured in chelating agent preparing tank being successively transported to chelating by pipeline Storage tank, chelating agent weighing hopper, kneading machine are kept in agent, and the chelating agent, which is kept in, passes through chelating agent between storage tank and chelating agent weighing hopper Constant displacement pump carries out precise control of flew, is controlled between the chelating agent weighing hopper and kneading machine by control valve, described mixed The spray equipment that uniformly spray covering is carried out to chelating agent is provided in mill;Meanwhile by flying dust hopper through dedicated pipeline, fly Flying dust is added according to the quality proportioning into the kneading machine in grey constant feeder, flying dust weighing hopper, control valve, passes through cement Hopper is through dedicated pipeline, cement constant feeder, cement weighing hopper, control valve into the kneading machine according to the quality proportioning Cement is added, electric stirring axis is installed in the kneading machine, is stirred by 1~3min and is obtained for the flying dust, cement, chelating agent To stabilisation product.
5. a kind of method for solidifying garbage flying ash using chelating agent according to claim 1, which is characterized in that the step S04 is realized by the following method: by installing discharge bucket, the delivery outlet lower section of the discharge bucket in the mixing motor spindle Screw conveyor is installed, the output end of the screw conveyor is provided with flying dust maintenance area and is filled.
CN201810832969.3A 2018-07-26 2018-07-26 A method of solidifying garbage flying ash using chelating agent Pending CN109092850A (en)

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CN201810832969.3A CN109092850A (en) 2018-07-26 2018-07-26 A method of solidifying garbage flying ash using chelating agent

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Application Number Priority Date Filing Date Title
CN201810832969.3A CN109092850A (en) 2018-07-26 2018-07-26 A method of solidifying garbage flying ash using chelating agent

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110201966A (en) * 2019-04-12 2019-09-06 中山市天乙能源有限公司 A kind for the treatment of process of garbage incinerating power plant diafiltration concentrated liquor

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201997537U (en) * 2011-03-09 2011-10-05 上海康恒环境工程有限公司 Stabilizing treatment device for flying ash in waste incineration
CN102824718A (en) * 2012-09-07 2012-12-19 桂林市产品质量监督检验所 Compound catalytic dechlorinating agent
CN104874587A (en) * 2015-05-27 2015-09-02 石狮市鸿峰环保生物工程有限公司 System for treatment of fly ash from waste incineration
CN105968349A (en) * 2016-05-27 2016-09-28 上海京尔环保科技有限公司 Chelating agent for waste incineration and application thereof
CN106345369A (en) * 2016-09-21 2017-01-25 光大环保技术研究院(深圳)有限公司 Fly ash stabilized granulating integrated system of waste incineration power plant

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201997537U (en) * 2011-03-09 2011-10-05 上海康恒环境工程有限公司 Stabilizing treatment device for flying ash in waste incineration
CN102824718A (en) * 2012-09-07 2012-12-19 桂林市产品质量监督检验所 Compound catalytic dechlorinating agent
CN104874587A (en) * 2015-05-27 2015-09-02 石狮市鸿峰环保生物工程有限公司 System for treatment of fly ash from waste incineration
CN105968349A (en) * 2016-05-27 2016-09-28 上海京尔环保科技有限公司 Chelating agent for waste incineration and application thereof
CN106345369A (en) * 2016-09-21 2017-01-25 光大环保技术研究院(深圳)有限公司 Fly ash stabilized granulating integrated system of waste incineration power plant

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110201966A (en) * 2019-04-12 2019-09-06 中山市天乙能源有限公司 A kind for the treatment of process of garbage incinerating power plant diafiltration concentrated liquor

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Application publication date: 20181228

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