GB2443263A - Encapsulation of waste for storage - Google Patents
Encapsulation of waste for storage Download PDFInfo
- Publication number
- GB2443263A GB2443263A GB0621418A GB0621418A GB2443263A GB 2443263 A GB2443263 A GB 2443263A GB 0621418 A GB0621418 A GB 0621418A GB 0621418 A GB0621418 A GB 0621418A GB 2443263 A GB2443263 A GB 2443263A
- Authority
- GB
- United Kingdom
- Prior art keywords
- container
- waste material
- inline mixer
- vessel
- lid member
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002699 waste material Substances 0.000 title claims abstract description 102
- 238000005538 encapsulation Methods 0.000 title claims abstract description 72
- 238000003860 storage Methods 0.000 title claims abstract description 57
- 239000010802 sludge Substances 0.000 claims abstract description 60
- 239000011440 grout Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 230000007774 longterm Effects 0.000 claims abstract description 16
- 230000003068 static effect Effects 0.000 claims abstract description 15
- 230000002285 radioactive effect Effects 0.000 claims abstract description 10
- 239000004568 cement Substances 0.000 claims abstract description 9
- 238000012545 processing Methods 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 48
- 239000000463 material Substances 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 14
- 239000002920 hazardous waste Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- 239000012855 volatile organic compound Substances 0.000 claims description 7
- 239000011344 liquid material Substances 0.000 claims description 6
- 238000005086 pumping Methods 0.000 claims description 6
- 239000012056 semi-solid material Substances 0.000 claims description 6
- 238000011144 upstream manufacturing Methods 0.000 claims description 6
- 241000196324 Embryophyta Species 0.000 claims 3
- 240000008042 Zea mays Species 0.000 claims 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims 1
- 235000005822 corn Nutrition 0.000 claims 1
- 238000005516 engineering process Methods 0.000 description 9
- 230000008901 benefit Effects 0.000 description 7
- 239000002910 solid waste Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000013461 design Methods 0.000 description 4
- 230000001143 conditioned effect Effects 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002901 radioactive waste Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/008—Sludge treatment by fixation or solidification
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/16—Processing by fixation in stable solid media
- G21F9/162—Processing by fixation in stable solid media in an inorganic matrix, e.g. clays, zeolites
- G21F9/165—Cement or cement-like matrix
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/16—Processing by fixation in stable solid media
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/28—Treating solids
- G21F9/30—Processing
- G21F9/301—Processing by fixation in stable solid media
- G21F9/302—Processing by fixation in stable solid media in an inorganic matrix
- G21F9/304—Cement or cement-like matrix
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/28—Treating solids
- G21F9/34—Disposal of solid waste
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/006—Radioactive compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/32—Hydrocarbons, e.g. oil
- C02F2101/322—Volatile compounds, e.g. benzene
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/06—Pressure conditions
- C02F2301/063—Underpressure, vacuum
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Treatment Of Sludge (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
An apparatus for encapsulating waste material (e.g radioactive sludge from nuclear processing plant) in a container 104 (e.g Nirex box) for long term storage, comprises: a first storage vessel 106, for holding sludge; a second storage vessel 114, for holding encapsulation medium (e.g. cement based grout); an inline mixer 112 (e.g. a static inline mixer), coupled for receiving sludge, and coupled to the second storage vessel 104, and producing, in use, a mixture of the sludge and grout; wherein the inline mixer is arranged for filling the container. Preferably, a dewatering unit 108 (e.g. HydroTrans based), receives sludge and outputs dewatered sludge to the inline mixer. In a preferred embodiment the inline mixture 112 is disposable and positioned inside the second storage vessel 104 for storage with said vessel.
Description
Encapsulation of waste for storage The present invention relates to the
storage of waste materials, and more particularly to apparatus, methods and systems for encapsulation of waste materials for long term storage.
It is well known that certain waste by products of industrial processes, especially radioactive waste materials generated by nuclear processing plants, and other hazardous waste material, need to be safely and securely disposed of, typically by encapsulation techniques within containers, in a way that is suited to long term storage (e g in a robust containment, until the radioactivity has decayed to non-hazardous levels) More recently, an example of such storage involves mixing the radioactive hazardous waste -typically in the form of wet sludge with a suitable grout, such as cement -in a container such as a metal drum. The mixture is allowed to cure in the drum. The purpose of this is to encapsulate the (radioactive) waste in an (eventually) solid material within the drum; the drums can then be disposed in a suitable storage location, such as an underground storage site A problem with known systems is that an internal paddle is used within the drum for mixing. In the case where the paddle is re-used, cleaning of the paddle is required, which is a time consuming process. In the case where the paddle is left in the drum and disposed of therewith, this incurs undesirable expense, in terms of needing extra parts (paddles) for each drum A further problem is that through the use of moving paddles within the drum, the preloading of the drum with additional solid articles of waste (eg, metal items and fuel element debris, * etc), prior to adding the sludge waste and the grout, is prevented, as the solids would S. S...
* block/hinder the paddles' movement A further problem is that this lack of simultaneous incorporation of solid waste reduces the overall amount of waste stored in the drum, per unit volume * * * S S * IS A further problem is that, with the use of such drums, the amount of stored volume of waste is not optimized The present invention seeks to address the aforementioned and other issues, and provide improved techniques for the encapsulation of waste for long term storage.
According to one aspect of the present invention there is provided apparatus for encapsulating waste material in a container for long term storage, comprising, a first storage vessel, for holding waste material, a second storage vessel, for holding encapsulation medium; an inline mixer, coupled for receiving waste material, and coupled to the second storage vessel, and producing, in use, a mixture of the waste material and encapsulation medium, wherein the inline mixer is arranged for filling the container.
Preferably, the apparatus further includes a dewatering unit, coupled for receiving waste material from the second vessel and outputting dewatered waste material; wherein the inline mixer is coupled to the dewatering unit and to the second storage vessel, for receiving material therefrom and producing a mixture of the dewatered waste material and encapsulation medium. Preferably, the dewatering unit includes a dewatering vessel and a pump for providing a degree of vacuum in the dewatering vessel Preferably, the dewatering unit is operable for concentrating the waste material such that the dewatered waste material output is at about 40% v/v Preferably, the inline mixer comprises a disposable component disposed inside the container or on mounted an internal surface of the container.
In one embodiment, the container comprises a main body and a separate lid member; the lid member being adapted for fixed attachment to the main body of the container, and inline mixer is provided in or on a lid member, such that when the lid member is fixedly attached to the main body of the container, the inline mixer is enclosed within the container.
In another embodiment, the container comprises unitary component with a main body and an integrally formed or fixedly attached lid member. * * * **.
Preferably, the inline mixer comprises a static inline mixer, for example provided with internal * * vanes * *.*.
* Preferably, the apparatus further includes a first pump disposed between the first vessel and ***...
* * the dewatering unit and/or a second pump disposed between the second vessel and the inline mixer Preferably, the apparatus further includes a valve upstream of each of two inlet ports of the inline mixer.
* S.... * .
The waste material may comprise sludge, liquid or semi solid material.
In one embodiment, the waste material comprises radioactive sludge from nuclear processing plant, and the encapsulation medium comprises grout. Preferably, the encapsulation medium is a cement-based grout, for example comprising a mixture of BFS and OPC.
In another embodiment, the waste material comprises VOCs, and the encapsulation medium comprises polymer compound.
According to another aspect of the present invention there is provided a system for encapsulating waste material for long term storage, comprising: the apparatus of any of claims 1 to 14 of the appended claims; and a container, the container comprising (i) a main body and separate lid member, or (ii) a unitary component with a main body and an integrally formed or fixedly attached lid member The container may contain solid hazardous waste.
According to another aspect of the present invention there is provided a container for use in conjunction with the apparatus of any of claims 1 to 14 of the appended claims, or in the system of claim 15 or 16 of the appended claims, the container comprising: (i) a main body and separate lid member, or (ii) a unitary component with a main body and an integrally formed or fixedly attached lid member; wherein the inline mixer is disposed inside the container or on mounted an internal surface of the container, for example on an inner surface of the lid member According to another aspect of the present invention there is provided a method of encapsulating waste material in a container for long term storage, comprising (a) providing a first storage vessel, for holding waste material, (b) providing a second storage vessel, for holding encapsulation medium; (C) providing an inline mixer, coupled for receiving waste material, and coupled to the second storage vessel, (f) mixing the waste material and encapsulation medium in the inline mixer; (g) filling the container with the mixture output from the inline mixer The method preferably further includes (d) providing a dewatering unit, coupled to the second vessel, and (e) dewatering the waste material received from the second vessel and outputting dewatered waste material, wherein the inline mixer is coupled to the dewatering unit and to the second storage vessel, (f) comprises producing a mixture of the dewatered waste material * and encapsulation medium. Preferably, the dewatering unit includes a dewatering vessel and (e) includes using a pump to provide a degree of vacuum in the dewatering vessel.
*. : Preferably, (e) includes concentrating the waste material such that the dewatered waste * material output is at about 40% v/v S..... * S
Preferably, (C) includes providing a container, wherein the inline mixer compnses a disposable component disposed inside the container or on mounted an internal surface of the container In one embodiment, the container compnses a main body and a separate lid member; and (C) includes fixedly attaching the lid member to the main body of the container, and wherein inline mixer is provided in or on a lid member; such that when the lid member is fixedly attached to the main body of the container, the inline mixer is enclosed within the container.
In another embodiment, the container comprises unitary component with a main body and an integrally formed or fixedly attached lid member Preferably, the inline mixer comprises a static inline mixer, for example provided with internal vanes.
The method may further include (h) pumping with a first pump the material output from the first vessel to the dewatering unit, and/or (i) pumping with a second pump the material output from the second vessel to the inline mixer.
The method may further include (j) controlling the flow of material to the inline mixer using a valve upstream of each of two inlet ports of the inhne mixer.
The waste material may comprise sludge, liquid or semi solid material.
In one embodiment, the waste material comprises radioactive sludge from nuclear processing plant, and the encapsulation medium comprises grout. Preferably, the encapsulation medium is a cement-based grout, for example comprising a mixture of BFS and OPC.
In another embodiment, the waste material comprises VOCs, and the encapsulation medium comprises polymer compound.
The method may further include preloading the container with solid hazardous waste.
The inventors have developed a versatile encapsulation plant, for use in the encapsulation of waste, particularly that arising in the Nuclear Industry. The design allows within a single process plant the capacity to condition both solid waste materials and sludge wastes (individually or in combination) into an encapsulated product form suitable for safe, long-term *s....
* : storage S...., * . . : The process provides the equipment necessary to receive sludge wastes streams, dewater * ** the sludge to remove excess water and concentrate the sludge; receive a pre-mixed wet encapsulation medium, or grout, transfer the dewatered sludge and grout into a static in-line mixer, depositing the mixed' sludge/grout stream into a waste container, drum or box suitable for long term storage.
The storage container, drum or box could also have been previously loaded' with solid wastes, thus allowing the encapsulation of these solid wastes using the sludge/grout mixed material.
Once the mixed sludge/encapsulation medium has been transferred into the storage container, drum or box, it is left undisturbed for a number of hours to allow curing'. This results in a container, drum or box containing a single solid mass of encapsulated waste suitable for storage.
The system may employ a standard (NIREX) 3m3 storage box, giving (i) a 20% volume utilisation increase for sludge waste compared to a large drum' lost paddle in-drum mixing system, and (ii) a 60% increase compared with a 4 -500 litre in-drum mixing system.
The design is versatile enough to be capable of filling drums and boxes in a range of sizes.
It has been found that circa 25%wlw sludge solids incorporation can be achieved for sludge type waste streams, compared with c 15%wlw typical with in-drum mixing technology. These two aspects result in a dramatic reduction (greater than 50%) in the number of boxes containing conditioned sludge waste required to be stored, with the consequent large savings in lifetime costs An advantage of the invention is that it minimises the equipment within the cell (box), thus reducing radioactive/contamination area maintenance requirements and increasing availability and reliability A key feature of the use of dewatering technology is, again, that minimal equipment is located within the cell.
An added advantage of the combined technologies is that large elements of the plant(s) may be fabricated off site, minimising the site installation activities, with the consequential : *s* reduction in worker radiation dose uptake during construction sq.. 5LSS
The plant and process may be configured to allow for a variety of different sludge waste * * streams. Both the dewatering plant and the in-line mixers parameters can be changed to allow this high degree of versatility The dewatering technology uses techniques that re-uses water to transfer sludges, and hence minimises the consumption and potential contamination 5I S : of clean water.
S
S..... * V
A further advantage of the invention is the use of a disposable' in-line mixer (i e. the mixer is built into the box and remains in the box, encapsulated) simplifies the cleaning requirements for the process A further advantage of the invention lies in filling a square' box, as opposed to the existing in-drum mixing technologies, this allows much greater storage volumes to be achieved -a 20% volume utilisation increase compared to a large drum' lost paddle in-drum mixing system and a 60% increase compared with a 4 -500 litre in-drum mixing system Also, in addition to the 3m3 Nirex box, waste drums, smaller containers and larger containers can also be used and benefit from this technology.
The process can be integrated with the encapsulation of solid materials. The solid waste would be located in the box prior to encapsulation, the mixed sludge I encapsulation matrix is then added using the in-line mixing technology, thus encapsulating the solids in a sludge matrix compound This ultimately reduces the number of boxes requiring long-term storage significantly, and cannot be provided by current indrum mixing technologies An additional advantage of the invention is that it is not limited to a particular form of encapsulation medium Embodiments of the invention will now be described in detail, by way of example, with reference to the accompanying drawings, in which Figure 1 shows schematically a hazardous waste encapsulation system according to an embodiment of the invention, Figure 2 shows in more detail (a) the main body of the container, and (b) the underside of the lid or of the topside of the container, in the encapsulation system of Fig 1, and Figure 3 depicts part of the encapsulation system of Fig. 1 in more detail, showing the connection of the dewatering system In the description and drawings, like numerals are used to designate like elements Unless indicated otherwise, any individual design features and components may be used in combination with any other design features and components disclosed herein. *S..
Figure 1 shows schematically a hazardous waste encapsulation system according to an embodiment of the invention 5S S.. * S
For solid waste streams, the encapsulation medium, or grout, is prepared in an adjacent *:*. mixing plant and pumped directly to the encapsulation container or box 104.
: For sludge waste streams (as in the embodiment of Fig. 1), the encapsulation apparatus 102
S
according to the invention, in preferred embodiments, makes use of a dewatering unit 108 for conditioning the sludge waste feed, and an in-line static mixer to mix the sludge with a pre-mixed encapsulation medium or grout'. The dewatering unit 108 removes excess water from the sludge is provided to allow the flexibility to receive a wide range of sludge type streams.
The sludge transferred from a transit storage vessel 106 into the dewatering unit 108 via sludge waste feed 110. The dewatering unit suitably includes a pump 109, for providing a degree of vacuum within the container vessel of the dewatering unit 108.
Returning again to Fig 1, a wet encapsulation medium prepared in an adjacent mixing plant 114 is then fed into the other input of the static in line mixer 112. Whilst the most frequent medium to be employed is cement based grout, using combinations of Blast Furnace Slag (BFS) and Ordinary Portland Cement (OPC), the invention may also be used to encapsulate using other encapsulation media such as polymer coumpounds. The latter allows the potential to encapsulate sludges containing organics, i.e. VOCs etc. Both the conditioned sludge feed 110 and encapsulation medium feed 118 are fed simultaneously into the static in-line mixer 112 Flow control systems are employed to ensure strict matching of the two flow rates to maintain the correct sludge to encapsulation medium ratio The process allows the maximum utilisation of the available 3m3 box volume (20% greater than the large in-drum mixing container and 60% greater than a 4 -5001 drum stillage configuration) and an increased incorporation rate (-25 wt%) of the sludge solids in grout As there are rio moving parts within the 3m3 box 104, the sludge bearing encapsulation medium can be used to encapsulate solid waste pre-loaded into the box 104.
Figure 2 shows in more detail (a) the main body of the container, and (b) the underside of the lid or of the topside of the container, in the encapsulation system of Fig. 1 The in line mixer 112 may be located, as in the example shown here, inside the lid 116 of a NIREX 3m3 Box 104 As seen in Fig 2(a), a valve arrangement, generally designated 120, * receives the feeds 110 and 118 (see Fig. 1 with one valve being provided for each feed line) *....: and couples to and input port 122 of the inline mixer 112. * *
The main body 124 of the box 104 is generally cuboid with and upper edge 126 on which are provided guide/retention members 128 at each corner. The guide/retention members 128 assist in receiving and retaining the lid 116 It will be appreciated by persons skilled in the art that while the box 104 may be fabricated, delivered and/or used in the form of separate main body 124 and lid 116, it is also possible that the box 104 is fabricated/provided as an integral container, with the inline mixer mounted on the underside of the topside of the box.
Referring in particular to Fig 2(b), a static in-line mixer 112 is used to mix the sludge and encapsulation medium upon transfer to the box 104. The in-line mixer 112 is for example a Chemineer Kenics Static KMS In-line mixer.
The in-line mixer 112 consists of a tube 130 and has no moving parts or components The in-line rrixer 112 is fed from two pipes, one (110) feeding the sludge, and one (118) feeding the wet encapsulation medium As the sludge and encapsulation medium pass through the tube 130 of the mixer, fixed elements or plates (not shown) inside the in-line mixer 112 cause the two streams to mix together, forming a homogenous stream of combined sludge and encapsulation medium The resultant homogenous material then falls into the box 104, The box is filled to a predetermined level and left for a set period of time for curing The combined sludge/ encapsulation medium then hardens to form a solid mass within the box 104 As will be appreciated by persons skilled in the art, the diameter, length and number of elements within the in-line mixer can all be changed to give the process the versatility to encapsulate differing waste streams. These parameters may be controlled and set following initial proving trials'.
Figure 3 depicts part of the encapsulation system of Fig. 1 in more detail, showing the connection of the dewatering unit 108 The dewatering unit 108 removes excess water from the sludge, employing for example Hydrolrans' technology (see UK patent applications Nos GB2389094A and GB2406293A), using fluid to mobilise and transport solids thus removing supernate from the sludge and concentrating the sludge up to approx. 40%v/v, depending on : ... the properties of the sludge. Next, the conditioned slurry/sludge fed into one input of a static in-line mixer 112 Referring to the dewatering unit 108, as stated previously, this system allows the removal of : excess water from the sludge, thereby concentrating the sludge. The process is referred to * * as the AtmoTrans system. A separate filter system (i e. Dynasep' system), and vortex arrangements can also be employed as necessary to provide, filtration of finer slow settling *....: particles (see the abovementioned UK patent applications) * * For the dewatering unit 108, the selection and sizing of the equipment, vessels, pipework and valves is dependant on the characteristics of the sludge being recovered for encapsulation. A significant advantage of the overall process is its ability to handle waste streams with a wide range of characteristics, concentrations, particle size and make-up. As the dewatering principles are determined and known, this means that for a specific application the system will be tailored to match the sludge feed stream.
Claims (26)
- Claims: 1. An apparatus for encapsulating waste material in a containerfor long term storage, comprising: a first storage vessel, for holding waste material; a second storage vessel, for holding encapsulation methum; an inline mixer, coupled for receiving waste material, and coupled to the second storage vessel, and producing, in use, a mixture of the waste material and encapsulation medium; wherein the inline mixer is arranged for filling the container.
- 2. The apparatus of claim 1, further including a dewaterirtg unit, coupled for receiving waste material from the second vessel and outputting dewatered waste material; wherein the inline mixer is coupled to the dewatering unit and to the second storage vessel, for receiving material therefrom and producing a mixture of the dewatered waste material and encapsulation medium
- 3. The apparatus of claim 2, wherein the dewatering unit includes a dewatering vessel and pump for providing a degree of vacuum in the dewatering vessel.
- 4. The apparatus of claim 2 or 3, wherein the dewatering unit is operable for concentrating the waste material such that the dewatered waste material output is at about 40% v/v.
- 5. The apparatus of any of claims 1 to 4, wherein the inline mixer comprises a disposable component disposed inside the container or on mounted an internal surface of the container. S...
- 6. The apparatus of claim 5, wherein the container comprises a main body and a separate lid member; the lid member being adapted for fixed attachment to the main body of the container, and inline mixer is provided in or on a lid member; , such that when the lid member is fixedly attached to the main body of the container, the inline mixer is enclosed * within the container. *...
- 7. The apparatus of claim 5, wherein the container comprises unitary component with a main body and an integrally formed or fixedly attached lid member.
- 8. The apparatus of any of the preceding claims, wherein the inline mixer comprises a static inline mixer, for example provided with internal vanes.
- 9. The apparatus of any of the preceding claims, further including a first pump disposed between the first vessel and the dewatering unit and/or a second pump disposed between the second vessel and the inline mixer.
- 10. The apparatus of any of the preceding claims, further including a valve upstream of each of two inlet ports of the inline mixer.
- 11. The apparatus of any of the preceding claims, wherein the waste material comprises sludge, liquid or semi solid material.
- 12. The apparatus of claim 11, wherein the waste material comprises radioactive sludge from nuclear processing plant, and the encapsulation medium comprises grout.
- 13. The apparatus of claim 11 or 12, wherein the encapsulation medium is a cement-based grout, for example comprising a mixture of BFS and OPC.
- 14. The apparatus of claim 10, wherein the waste material comprises VOCs, and the encapsulation medium comprises polymer compound.
- 15. A system for encapsulating waste material for long term storage, comprising: the apparatus of any of the preceding claims; and a container, the container comprising (i) a main body and separate lid member, or (ii) a unitary component with a main body and an integrally formed or fixedly attached lid member
- 16. The system of claim 15, wherein the container contains solid hazardous waste.
- 17. A container for use in conjunction with the apparatus of any of claims 1 to 14, or in the system of claim 15 or 16; the containercomprising: : (i) a main body and separate lid member, or (ii) a unitary component with a main body and an integrally formed or fixedly attached lid member; . : wherein the inline mixer is disposed inside the container or on mounted an internal * surface of the container, for example on an inner surface of the lid member. *
- 18. A method of encapsulating waste material in a container for long term storage, comprising: (a) providing a first storage vessel, for holding waste material; (b) providing a second storage vessel, for holding encapsulation medium; (c) providing an inline mixer, coupled for receiving waste material, and coupled to the second storage vessel, (1) mixing the waste material and encapsulation medium in the inline mixer; (g) filling the container with the mixture output from the inline mixer.
- 19. The method of claim 18, further including: (d) providing a dewateriag unit, coupled to the second vessel, and (e) dewatering the waste material received from the second vessel and outputting dewatered waste material; wherein the inline mixer is coupled to the dewateririg unit and to the second storage vessel, (I) comprises producing a mixture of the dewatered waste material and encapsulation medium.
- 20. The method of claim 19, wherein the dewatering unit includes a dewatering vessel and (e) includes using a pump to provide a degree of vacuum in the dewatering vessel.
- 21. The method of claim 19 or 20, wherein (e) includes concentrating the waste matenal such that the dewatered waste material output is at about 40% v/v.
- 22 The method of any of claims 18 to 21, wherein (C) includes providing a container, wherein the inline mixer comprises a disposable component disposed inside the container or on mounted an internal surface of the container.
- 23. The method of claim 22, wherein the container comprises a main body and a separate lid member; and (C) includes fixedly attaching the lid member to the main body of the container, and wherein inline mixer is provided in or on a lid member; such that when the lid member is fixedly attached to the main body of the container, the inline mixer is enclosed within the container.
- 24. The method of claim 22, wherein the container comprises unitary component with a main body and an integrally formed or fixedly attached lid member. ***.
- 25. The method of any of claims 18 to 24, wherein the inline mixer comprises a static * inline mixer, for example provided with internal vanes.S S...
- 26. The method of any of claims 17 to 25, wherein the waste material comprises sludge, liquid or semi solid material.27 The method of claim 26, wherein the waste material comprises radioactive sludge from nuclear processing ptant, and the encapsulation medium comprises grout 28 The method of claim 26 or 27, wherein the encapsulation medium is a cement-based grout, for example comprising a mixture of BFS and OPC 29 The method of claim 26 or 27, wherein the waste material comprises VOCs, and the encapsulation medium comprises polymer compound The system of any of claims 20 to 29, further including preloading the container with solid hazardous waste.31 An apparatus, system or method substantially as hereinbefore described with reference to the accompanying drawings. S.. S...S S.... * SS* S... * . I. * * S * S. * I....26. The method of any of claims 18 to 25, further including: (h) pumping with a first pump the material output from the first vessel to the dewatering unit; and/or (I) pumping with a second pump the material output from the second vessel to the inline mixer.27. The method of any of claims 18 to 26, further including: -11 (j) controlling the flow of material to the inline mixer using a valve upstream of each of two inlet ports of the inline mixer.28. The method of any of claims 18 to 27, wherein the waste material comprises sludge, liquid or semi solid material.29. The method of claim 28, wherein the waste material comprises radioactive sludge from nuclear processing plant, and the encapsulation medium comprises grout.30. The method of claim 28 or 29, wherein the encapsulation medium is a cement-based grout, for example comprising a mixture of BFS and OPC.31 The method of claim 28 or 29, wherein the waste material comprises VOCs, and the encapsulation medium comprises polymer compound.32. The system of any of claims 22 to 31, further including preloading the container with solid hazardous waste.33. An apparatus, system or method substantially as hereinbefore described with reference to the accompanying drawings 0S.S * * * * S.I I... -12-Amendments to the claims have been filed as follows 1. An apparatus for encapsulating waste material in a container for long term storage, comprising a first storage vessel, for holding waste material; a second storage vessel, for holding encapsulation medium; a static vane in-line mixer, coupled for receiving waste material, and coupled to the second storage vessel, and producing, in use, a mixture of the waste material and encapsulation medium; wherein the inline mixer is arranged for filling the container,and wherein the inline mixer comprises a disposable component disposed inside the container mounted on an internal surface of the container 2 The apparatus of claim 1, further including a dewatering unit, coupled for receiving waste material from the first vessel and outputting dewatered waste material; wherein the inline mixer is coupled to the dewatering unit and to the second storage vessel, for receiving material therefrom and producing the mixture of the dewatered waste material and encapsulation medium.3. The apparatus of claim 2, wherein the dewatering unit includes a dewatering vessel and pump for providing a degree of vacuum in the dewatering vessel.4 The apparatus of claim 2 or 3, wherein the dewatering unit is operable for *...concentrating the waste material such that the dewatered waste material output is at about 40% v/v *1**I * * 5. The apparatus of any of the preceding claims, wherein the container comprises a main body and a separate lid member; the lid member being adapted for fixed attachment to ** I * the main body of the container, and inline mixer is provided in or on the lid member; such that *... when the lid member is fixedly attached to the main body of the container, the inline mixer is * . enclosed within the container.6. The apparatus of claim 5, wherein the container comprises unitary component with a main body and an integrally formed or fixedly attached lid member.7 The apparatus of any of the preceding claims, wherein the inline mixer comprises a static inline mixer, for example provided with internal vanes.8. The apparatus of any of the preceding claims, further including a first pump disposed between the first vessel and the dewatering unit and/or a second pump disposed between the second vessel and the inline mixer 9. The apparatus of any of the preceding claims, further including a valve upstream of each of two inlet ports of the inline mixer.The apparatus of any of the preceding claims, wherein the waste material comprises sludge, liquid or semi solid material.11 The apparatus of claim 10, wherein the waste material comprises radioactive sludge from nuclear processing plant, and the encapsulation medium comprises grout.12. The apparatus of claim 10 or 11, wherein the encapsulation medium is a cement-based grout, for example comprising a mixture of BFS and OPC.13 The apparatus of claim 9, wherein the waste material comprises VOCs, and the encapsulation medium comprises polymer compound.14. A system for encapsulating waste material for long term storage, comprising the apparatus of any of the preceding claims; and a container, the container comprising (i) a main body and separate lid member, or (ii) a unitary component with a main body and an integrally formed or fixedly attached lid member p. I. *...15. The system of claim 14, wherein the container contains solid hazardous waste.16. A container for use in conjunction with the apparatus of any of claims 1 to 13, or in : the system of claim 14 or 15; the container comprising.(i) a main body and separate lid member, or (ii) a unitary component with a main body :*. and an integrally formed or fixedly attached lid member; the container incorporating the in-line mixer disposed therein or mounted on an internal surface thereof, for example on an inner surface of the lid member 17. A method of encapsulating waste material in a container for long term storage, corn prising: (a) providing a first storage vessel, for holding waste material; (b) providing a second storage vessel, for holding encapsulation medium; (C) providing an in- line mixer, coupled for receiving waste material, and coupled to the second storage vessel, (f) mixing the waste material and encapsulation medium in the inline mixer; (g) filling the container with the mixture output from the inline mixer, wherein (c) includes providing a container, wherein the inline mixer comprises a disposable component disposed inside the container or on mounted an internal surface of the container.18 The method of claim 17, further including (d) providing a dewatering unit, coupled to the first vessel, and (e) dewatering the waste material received from the first vessel and outputting dewatered waste material, wherein the in-line mixer is coupled to the dewatering unit and to the second storage vessel, (f) comprises producing a mixture of the dewatered waste material and encapsulation medium.19 The method of claim 18, wherein the dewatering unit includes a dewatering vessel and (e) includes using a pump to provide a degree of vacuum in the dewatering vessel.The method of claim 18 or 19, wherein (e) includes concentrating the waste material such that the dewatered waste material output is at about 40% v/v.21 The method of any of claims 17 to 20, wherein the container comprises a main body and a separate lid member, and (c) includes fixedly attaching the lid member to the main body of the container, and wherein inline mixer is provided in or on a lid member; such that when the lid member is fixedly attached to the main body of the container, the inline mixer is enclosed within the container.22. The method of any of claims 17 to 20, wherein the container comprises unitary * component with a main body and an integrally formed or fixedly attached lid member * * 23. The method of any of claims 17 to 22, wherein the inline mixer comprises a static :*. inline mixer, for example provided with internal vanes.24 The method of any of claims 17 to 23, further including (h) pumping with a first pump the material output from the first vessel to the dewatering unit; and/or (i) pumping with a second pump the material output from the second vessel to the inline mixer.25. The method of any of claims 17 to 24, further including: (j) controlling the flow of material to the inline mixer using a valve upstream of each of two inlet ports of the inline mixer.
Applications Claiming Priority (1)
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US86303706P | 2006-10-26 | 2006-10-26 |
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GB2443263A true GB2443263A (en) | 2008-04-30 |
GB2443263B GB2443263B (en) | 2008-12-24 |
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GB0621418A Expired - Fee Related GB2443263B (en) | 2006-10-26 | 2006-10-27 | Encapsulation of waste for storage |
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US (1) | US20100160707A1 (en) |
EP (1) | EP2084714B1 (en) |
JP (1) | JP2010507788A (en) |
AT (1) | ATE475187T1 (en) |
DE (1) | DE602007007977D1 (en) |
GB (1) | GB2443263B (en) |
WO (1) | WO2008049586A1 (en) |
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JP2012225755A (en) * | 2011-04-19 | 2012-11-15 | Mihama Kk | Radioactive contamination water processing system, barge type radioactive contamination water processing facility, radioactive contamination water processing method, and on-barge radioactive contamination water processing method |
JP2013250079A (en) * | 2012-05-30 | 2013-12-12 | Shimizu Corp | Packaging system |
CN103680661B (en) * | 2013-12-09 | 2016-06-22 | 中广核工程有限公司 | Nuclear power station solid waste processing system |
CN113896387B (en) * | 2021-11-03 | 2022-06-28 | 南京工业职业技术大学 | Sludge purification and dehydration structure based on combination of thermal desorption technology and vacuum preloading technology and construction method thereof |
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FR2428304A1 (en) * | 1978-06-09 | 1980-01-04 | Sgn Soc Gen Tech Nouvelle | DEVICE FOR PACKAGING TOXIC WASTE |
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JPH02176499A (en) * | 1988-12-27 | 1990-07-09 | Sumitomo Chem Co Ltd | Apparatus for solidification of radioactive waste and method for circulative washing thereof |
JPH02257099A (en) * | 1988-12-27 | 1990-10-17 | Sumitomo Chem Co Ltd | Device for kneading cement for solidification treatment of radioactive waste |
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JP4612591B2 (en) * | 2006-07-13 | 2011-01-12 | 株式会社東芝 | Method and apparatus for solidifying radioactive waste |
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- 2006-10-27 GB GB0621418A patent/GB2443263B/en not_active Expired - Fee Related
-
2007
- 2007-10-23 DE DE602007007977T patent/DE602007007977D1/en active Active
- 2007-10-23 JP JP2009533719A patent/JP2010507788A/en active Pending
- 2007-10-23 US US12/083,526 patent/US20100160707A1/en not_active Abandoned
- 2007-10-23 WO PCT/EP2007/009195 patent/WO2008049586A1/en active Application Filing
- 2007-10-23 EP EP07819255A patent/EP2084714B1/en not_active Not-in-force
- 2007-10-23 AT AT07819255T patent/ATE475187T1/en not_active IP Right Cessation
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FR2664085A1 (en) * | 1990-06-29 | 1992-01-03 | Commissariat Energie Atomique | Apparatus for the continuous separation of the liquid and solid phases of radioactive waste to be encapsulated |
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Also Published As
Publication number | Publication date |
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GB2443263B (en) | 2008-12-24 |
DE602007007977D1 (en) | 2010-09-02 |
ATE475187T1 (en) | 2010-08-15 |
US20100160707A1 (en) | 2010-06-24 |
WO2008049586A1 (en) | 2008-05-02 |
JP2010507788A (en) | 2010-03-11 |
GB0621418D0 (en) | 2006-12-06 |
EP2084714A1 (en) | 2009-08-05 |
EP2084714B1 (en) | 2010-07-21 |
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732E | Amendments to the register in respect of changes of name or changes affecting rights (sect. 32/1977) | ||
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Effective date: 20121027 |