CN109092034A - It is a kind of to eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing - Google Patents

It is a kind of to eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing Download PDF

Info

Publication number
CN109092034A
CN109092034A CN201811011105.1A CN201811011105A CN109092034A CN 109092034 A CN109092034 A CN 109092034A CN 201811011105 A CN201811011105 A CN 201811011105A CN 109092034 A CN109092034 A CN 109092034A
Authority
CN
China
Prior art keywords
steam generator
preparation
hydrogenperoxide steam
clothing
spray
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811011105.1A
Other languages
Chinese (zh)
Inventor
何占航
杨李富
王大智
王永刚
唐明生
王楠
魏东辉
李中军
刘清朝
王建设
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhengzhou University
Original Assignee
Zhengzhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhengzhou University filed Critical Zhengzhou University
Priority to CN201811011105.1A priority Critical patent/CN109092034A/en
Publication of CN109092034A publication Critical patent/CN109092034A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/106Peroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

Landscapes

  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Detergent Compositions (AREA)

Abstract

It eliminates the unusual smell the preparation method of spray the invention discloses a kind of for stench workplace personnel's clothing.It is configured to hydrogenperoxide steam generator first;Part hydrogenperoxide steam generator is taken, weighed silver salt dissolution is added, obtains solution A;Part hydrogenperoxide steam generator is taken, weighed stabilizer is added and synergist is dissolved, obtains solution B;Remaining hydrogenperoxide steam generator, obtained solution A and obtained solution B three are mixed, after being sufficiently mixed uniformly, product is obtained and eliminates the unusual smell spray for stench workplace personnel's clothing.Technical solution of the present invention using particular job or Work places staff as target group, provide it is a kind of it is easy to carry, using efficiently spray, can be effectively reduced or eliminate the maladorous smell of itself clothing contamination.The technical solution adopted in the present invention has many advantages, such as that simple production process, raw material sources are extensive, at low cost, is relatively easy to realize industrial production.

Description

It is a kind of to eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing
One, technical field:
It eliminates the unusual smell spray, more particularly to a kind of eliminates the unusual smell spray for stench workplace personnel's clothing the present invention relates to one kind The preparation method of agent.
Two, background technique:
Under normal circumstances, the gas that can generate unpleasant feeling is commonly referred to as foul gas, and stench is various smells The general name of (peculiar smell) can be analyzed and be judged by the perception of people.Watt moral Mike classification is according to odoring substance structure And odoring substance is divided into 9 classes: ethers, aromatics, flower class or face cream class, amber class, fragrant-flowered garlic to the sensory features of odoring substance by people Dish or garlic class, empyreuma, goat are smelly, unhappy smelly and emetic smelly.Present on the earth in more than 200 ten thousand kinds of compounds, 1/5 has gas Taste is important odorant there are about 10,000 kinds.It can be divided into following 5 class by chemical composition.
(1) compound of sulfur-bearing, such as hydrogen sulfide, sulfur dioxide, mercaptan, thioether class;
(2) contain nitrogen compound, such as amine, ammonia, acid amide, indoles;Halogen and derivative, such as halogenated hydrocarbons;
(3) organic matter of oxygen, such as alcohol, phenol, aldehyde, ketone, acid, ester;
(4) hydro carbons, such as alkane, alkene, alkynes and aromatic hydrocarbon.
(5) outside vulcanisation hydrogen and ammonia, odorant is mostly organic matter.These organic matters have low boiling point, high volatility Feature, we are called volatile organic compounds again.
The source of odorant is quite extensive, can be divided mainly into animal and plant body secretion pollution sources, domestic pollution source and industry Pollution sources three classes.Animal and plant body secretion pollution sources refer mainly to foot odour, underarm odor, halitosis etc..Domestic pollution source is mainly from lavatory, rubbish The places such as rubbish bucket, sewer.Industrial pollution source is the main source that odor pollution occurs.Sewage treatment plant, meat product processing Factory, paper mill and petrochemical enterprise can all generate serious stench.See Table 1 for details for the classification of odorant and its stink property.
The classification and stink property of 1 odorant of table
It is generally believed that the smell of chemical substance and its molecular structure, functional group's composition are closely related, such as organic odorant Often contain carboxyl (- OH), carbonyl (C=O), carboxyl (- COOH), amino (- NH2), the functional groups such as sulfydryl (- SH).Variety classes The odor qualities that substance generates have very big difference, and aromatic odor is mainly presented in benzene homologues, using hydrogen sulfide as the sulfide of representative Main to generate rotten egg smell, nitrogenous compound generates the smell of irritating ammonia, and aldehydes and esters are with floral type and Fruity type Based on, acids is then based on sweat odor.Most odorant threshold values is lower, representative malodor substance threshold reference result such as table Shown in 2.
2 representative malodor substance threshold reference (volume fraction) 10 of table-6
Times river odor pollution, 50~sixties of 20th century, odor pollution problem large area occur for summer in 1858, Britain It appears in developed country, after the 1980s, gradually starts to occur in developing country, and have been developed as seven big public hazards One of.Japan discloses " odor prevention method " in June, 1971, is revised successively later, there is 22 kinds of odorants at present. China alsies specify the discharge standard of related odorant in GB14554.But it is always arranged mainly for Concetrated control place is easier to Mouthful discharge, to work produce in odorant limitation shorter mention.Especially for specific workplace odorant It is practical also to formulate effective relevant criterion then without relevant criterion.For example, criminal prospecting scene, the city of casualties occurs City's public restroom, work or the operation field such as sewer and septic tank dredging, farm.It, can not be to evil because of its special nature Sordes matter is effectively prevented.After construction, contamination is brought greatly to the residual odors smell on clothing to practitioner It is inconvenient.
Patent CN107137742A discloses a kind of deodorizing methods and deodorant, and main component is ferrate, secondary chlorine Acid and permanganate.Obvious pollution, such as Mn will be brought using deodorant described in this method2+Pollution, use After remain it is larger, it is more difficult to degrade.Patent CN106512713A discloses a kind of deodorant and its preparation method and application, the patent The middle main component using substances such as fermentation by saccharomyces cerevisiae liquid, vitamin B, citric acids as formula.The deodorant preparation process Complexity, for example need the techniques such as sterilizing, high temperature and pressure.And CN106309214A then uses diatomite not soluble in water, kaolinite Soil and active carbon etc. are used as principal component, remain greatly after use, easily cause secondary pollution.CN106283619A discloses a kind of clothes Dress deodorant, used main matter are the fragrance such as santal, radix saposhnikoviae, the fruit of summer cypress.Its principle is to hide using other tastes Original foul smell is covered, smell substance can not be completely removed, and the ingredient that this method uses is water-insoluble and difficult to degrade Substance, have larger residual after use.Patent CN160714850A discloses a kind of deodorant and deodorizing products.The product packet The crystalline zinc oxide for having contained zinc oxide and alumina composite imitates sulphur system gas and sour gas with good deodorization Fruit.It because this product is solid, and is not easy to spray clothing in operation field, is only applicable to the malodor source of larger area, such as dirty Water treatment plant etc..
In addition, there are also the deodorant that similar other methods are prepared to be reported, there is system to a certain extent Preparation Method is complicated, remains the disadvantages of big after inconvenient to use and use.
Three, summary of the invention:
The technical problem to be solved by the present invention is based in the prior art in terms of the deodorization technology existing for deficiency Place, the present invention provides a kind of to eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing.The present invention eliminates the unusual smell spray Agent is handled for itself remaining maladorous smell after above-mentioned or other similar workplace staff field operation, So as to make staff that the foul odour of itself contamination be greatly decreased in the case where that need not slough or change work on the spot clothes, Substantially eliminate thus bring negative effect.Spray of the present invention live can spray, and be not necessarily to any pretreatment procedure, and without residual after use It stays, it is harmless, it is used convenient for carrying.
To solve the above-mentioned problems, the technical solution adopted by the present invention is that:
The present invention provide it is a kind of eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing, the preparation side Method the following steps are included:
A, it is configured to the hydrogenperoxide steam generator that mass percentage concentration is 0.3~3% first, and the hydrogen peroxide of preparation is molten Liquid is placed in containers for future use;Then silver salt, stabilizer and synergist are weighed;
With Ag+Meter, the proportionate relationship of additional amount is 5~50mg between the silver salt and the hydrogenperoxide steam generator of preparation: 1kg;The mass fraction that the additional amount of the stabilizer accounts for the hydrogenperoxide steam generator of preparation is 3.5 ‰~10 ‰;The synergist Additional amount account for preparation hydrogenperoxide steam generator mass fraction be 1.5 ‰~7.5 ‰;
B, the hydrogenperoxide steam generator for taking part steps a to prepare, is then added weighed silver salt and is dissolved, after completely dissolution Gained silver salt solution ie in solution A is spare;
C, the hydrogenperoxide steam generator for taking part steps a to prepare, is then added weighed stabilizer and synergist is dissolved, It is spare that solution B is obtained after completely dissolution;
D, the solution B three for obtaining the obtained solution A of step a remaining hydrogenperoxide steam generator, step b and step c It is mixed, after being sufficiently mixed uniformly, obtains product and eliminate the unusual smell spray for stench workplace personnel's clothing.
It is eliminated the unusual smell the preparation method of spray according to above-mentioned for stench workplace personnel's clothing, silver described in step a Salt is silver nitrate, silver sulfate or silver perchlorate.
It is eliminated the unusual smell the preparation method of spray according to above-mentioned for stench workplace personnel's clothing, it is steady described in step a Determining agent is phosphoric acid, magnesium gluconate, sodium gluconate, iminodisuccinic acid, 1-hydroxy ethylidene-1,1-diphosphonic acid HEDP, ethylenediamine tetramethyl Pitch at least one of Alendronate EDTMPS, diethylene triamine pentamethylene phosphonic DETPMP and fatty alcohol polyoxyethylene ether AEO.
It is eliminated the unusual smell the preparation method of spray according to above-mentioned for stench workplace personnel's clothing, is increased described in step a Effect agent is at least one of mannitol, glycerol, polyethylene glycol PEG400 and polyethylene glycol PEG6000.
Positive beneficial effect of the invention:
1, technical solution of the present invention provides a kind of carrying using particular job or Work places staff as target group Conveniently, using efficiently spray, it can be effectively reduced or eliminate the maladorous smell of itself clothing contamination.It is of the present invention Technical solution has many advantages, such as that simple production process, raw material sources are extensive, at low cost, is relatively easy to realize industrial production.
2, raw material used by technical solution of the present invention has the characteristics that green non-poisonous, from a wealth of sources, buying is convenient.
3, method used by technical solution of the present invention is easy to operate, one-time investment is small, easy to industrialized production.
4, the product that technical solution of the present invention obtains, which has, carries and uses conveniently, free from extraneous odour, the features such as effect is obvious.
5, the product universality that technical solution of the present invention obtains is strong, is suitable for a variety of workplaces and operation field.
6, the product that technical solution of the present invention obtains can targetedly to remaining smell substance on body surface and clothing into Row oxygenolysis, and skin and the natural or staple fibre for constituting clothing itself are had no significant effect.
7, the product that technical solution of the present invention obtains has no stimulation to human skin, is sprayed onto and is exposed on outer skin It will not adversely affect.
8, the product that technical solution of the present invention obtains is fast to oxidation operation speed, such as the rate of typical acid alcohol substance Constant is 109More than, it is far longer than O3Equal oxidants (typically not greater than 10).
Four, Detailed description of the invention:
Fig. 1: the gas chromatogram of sprinkling odorant clothing;
Fig. 2: the gas chromatogram after placing for 24 hours naturally;
Fig. 3: the gas chromatogram after 72h is placed naturally;
Fig. 4: the gas chromatogram in embodiment 1 after product treatment;
Fig. 5: the gas chromatogram in embodiment 2 after product treatment;
Fig. 6: the gas chromatogram in embodiment 3 after product treatment;
Fig. 7: the gas chromatogram in embodiment 4 after product treatment.
Five, specific embodiment:
The present invention is further explained with reference to embodiments, but is not intended to limit the range of technical solution of the present invention protection.
The hydrogen peroxide and additive used in following embodiment is pharmaceutical grade or food-grade;Sprayed odorant Clothing (material group becomes 85% cotton and 15% chemical fibre) gas-chromatography total peak area is 475.26.
Embodiment 1:
The present invention eliminates the unusual smell the preparation method of spray for stench workplace personnel's clothing, the detailed step of the preparation method It is rapid as follows:
A, it is configured to the hydrogenperoxide steam generator 1000g that mass percentage concentration is 2.0% first, and by the hydrogen peroxide of preparation Solution 1000g is placed in containers for future use;
0.055g silver nitrate is weighed (with Ag+It counts, Ag in silver nitrate+The proportionate relationship of additional amount between hydrogenperoxide steam generator For 35mg:1kg);Weigh phosphoric acid 3.5g, sodium gluconate 1.0g, magnesium gluconate 1.0g, iminodisuccinic acid 1.0g, HEDP 0.5g, EDTMPS 0.5g, DETPMP 0.5g and AEO 0.5g, above each total dosage of stabilizer account for hydrogenperoxide steam generator The 8.5 ‰ of quality;Weigh mannitol 1.0g, 60000 1.0g of glycerol 1.0g, PEG 400 1.0g and PEG, above each synergy The total dosage of agent accounts for the 4.0 ‰ of hydrogenperoxide steam generator quality;
B, the hydrogenperoxide steam generator for taking 100g step a to prepare, is then added weighed silver nitrate and is dissolved, and sufficiently dissolves Gained silver salt solution ie in solution A is spare afterwards;
C, the hydrogenperoxide steam generator for taking 150g step a to prepare, is then added weighed each stabilizer and each synergist carries out Dissolution, it is spare to obtain solution B after completely dissolution;
D, the solution B three for obtaining the obtained solution A of step a remaining hydrogenperoxide steam generator, step b and step c It is mixed, after being sufficiently mixed uniformly, obtains product and eliminate the unusual smell spray for stench workplace personnel's clothing.
Product made from embodiment 1 handles (using the spraying form of spray bottle the clothing for having sprayed odorant Carry out), it is detected after acting on 5min.The result shows that: S2-It is not detected, other each substance gas-chromatography total peak areas are 0.81, total removal rate is about 99.83%.Subjective smelling the results are shown in Table 3.Blank control experiment is done simultaneously, that is, is sprayed with malodorant Certain time is placed under the clothes natural conditions of matter, it is detected.The result shows that: after placing for 24 hours, S2-It is not detected, other Substance total peak area is 169.78, and removal rate 64.28%, after placing 72h, peak area still has 93.80, and removal rate is 80.26%.Naturally the subjective smelling for placing clothing the results are shown in Table 3.
Embodiment 2:
The present invention eliminates the unusual smell the preparation method of spray for stench workplace personnel's clothing, the detailed step of the preparation method It is rapid as follows:
A, it is configured to the hydrogenperoxide steam generator 1000g that mass percentage concentration is 0.3% first, and by the hydrogen peroxide of preparation Solution 1000g is placed in containers for future use;
0.015g silver nitrate is weighed (with Ag+It counts, Ag in silver nitrate+The proportionate relationship of additional amount between hydrogenperoxide steam generator For 10mg:1kg);Weigh phosphatase 11 .5g, sodium gluconate 0.8g, magnesium gluconate 1.0g, iminodisuccinic acid 0.5g, HEDP 0.3g, EDTMPS 0.3g, each 0.3g of DETPMP 0.3g and AEO, it is molten that above each total dosage of stabilizer accounts for hydrogen peroxide The 5.0 ‰ of liquid quality;Weigh mannitol 0.5g, glycerol 0.5g, PEG400 0.5g, PEG6000 0.01g, above each synergist Total dosage accounts for the 1.51 ‰ of hydrogenperoxide steam generator quality;
B, the hydrogenperoxide steam generator for taking 100g step a to prepare, is then added weighed silver nitrate and is dissolved, and sufficiently dissolves Gained silver salt solution ie in solution A is spare afterwards;
C, the hydrogenperoxide steam generator for taking 150g step a to prepare, is then added weighed each stabilizer and each synergist carries out Dissolution, it is spare to obtain solution B after completely dissolution;
D, the solution B three for obtaining the obtained solution A of step a remaining hydrogenperoxide steam generator, step b and step c It is mixed, after being sufficiently mixed uniformly, obtains product and eliminate the unusual smell spray for stench workplace personnel's clothing.
Product made from embodiment 2 handles (using the spraying form of spray bottle the clothing for having sprayed odorant Carry out), it is detected after acting on 5min.The result shows that: S2-It is not detected, other each substance gas-chromatography total peak areas are 4.89, total removal rate is about 98.97%.Subjective smelling the results are shown in Table 3.Blank control experiment is done simultaneously, that is, is sprayed with malodorant Certain time is placed under the clothes natural conditions of matter, it is detected.The result shows that: after placing for 24 hours, S2-It is not detected, other Substance total peak area is 169.78, and removal rate 64.28%, after placing 72h, peak area still has 93.80, and removal rate is 80.26%.Naturally the subjective smelling for placing clothing the results are shown in Table 3.
Embodiment 3:
The present invention eliminates the unusual smell the preparation method of spray for stench workplace personnel's clothing, the detailed step of the preparation method It is rapid as follows:
A, it is configured to the hydrogenperoxide steam generator 1000g that mass percentage concentration is 1.5% first, and by the hydrogen peroxide of preparation Solution 1000g is placed in containers for future use;
Silver nitrate 0.024g is weighed (with Ag+It counts, Ag in silver nitrate+The proportionate relationship of additional amount between hydrogenperoxide steam generator For 15mg:1kg);Weigh phosphatase 11 .5g, sodium gluconate 0.8g, magnesium gluconate 1.0g, iminodisuccinic acid 0.5g, HEDP 0.6g, EDTMPS 0.6g, DETPMP 0.6g and AEO 0.6g, above each total dosage of stabilizer account for the peroxidating of preparation The 6.2 ‰ of hydrogen solution gross mass;Weigh mannitol 1.5g, glycerol 1.5g, PEG400 1.0g, PEG6000 0.01g is above each The total dosage of synergist accounts for the 4.01 ‰ of the hydrogenperoxide steam generator gross mass of preparation;
B, the hydrogenperoxide steam generator for taking 100g step a to prepare, is then added weighed silver nitrate and is dissolved, and sufficiently dissolves Gained silver salt solution ie in solution A is spare afterwards;
C, the hydrogenperoxide steam generator for taking 150g step a to prepare, is then added weighed each stabilizer and each synergist carries out Dissolution, it is spare to obtain solution B after completely dissolution;
D, the solution B three for obtaining the obtained solution A of step a remaining hydrogenperoxide steam generator, step b and step c It is mixed, after being sufficiently mixed uniformly, obtains product and eliminate the unusual smell spray for stench workplace personnel's clothing.
Product made from embodiment 3 handles (using the spraying form of spray bottle the clothing for having sprayed odorant Carry out), it is detected after acting on 5min.The result shows that: S2-It is not detected, other each substance gas-chromatography total peak areas are 4.34, total removal rate is about 99.09%.Subjective smelling the results are shown in Table 3.Blank control experiment is done simultaneously, that is, is sprayed with malodorant Certain time is placed under the clothes natural conditions of matter, it is detected.The result shows that: after placing for 24 hours, S2-It is not detected, other Substance total peak area is 169.78, and removal rate 64.28%, after placing 72h, peak area still has 93.80, and removal rate is 80.26%.Naturally the subjective smelling for placing clothing the results are shown in Table 3.
Embodiment 4:
The present invention eliminates the unusual smell the preparation method of spray for stench workplace personnel's clothing, the detailed step of the preparation method It is rapid as follows:
A, it is configured to the hydrogenperoxide steam generator 1000g that mass percentage concentration is 3.0% first, and by the hydrogen peroxide of preparation Solution 1000g is placed in containers for future use;
Silver nitrate 0.077g is weighed (with Ag+It counts, Ag in silver nitrate+The proportionate relationship of additional amount between hydrogenperoxide steam generator For 50mg:1kg);Weigh phosphatase 11 .5g, sodium gluconate 0.8g, magnesium gluconate 1.0g, iminodisuccinic acid 0.3g, HEDP 0.6g, EDTMPS 0.6g, DETPMP 0.6g and AEO0.6g, above each total dosage of stabilizer account for the hydrogen peroxide of preparation The 6.0 ‰ of solution gross mass;Weigh mannitol 1.5g, glycerol 1.5g, PEG400 1.0g, PEG6000 0.01g, above each increasing The effect total dosage of agent accounts for the 4.01 ‰ of the hydrogenperoxide steam generator gross mass of preparation;
B, the hydrogenperoxide steam generator for taking 100g step a to prepare, is then added weighed silver nitrate and is dissolved, and sufficiently dissolves Gained silver salt solution ie in solution A is spare afterwards;
C, the hydrogenperoxide steam generator for taking 150g step a to prepare, is then added weighed each stabilizer and each synergist carries out Dissolution, it is spare to obtain solution B after completely dissolution;
D, the solution B three for obtaining the obtained solution A of step a remaining hydrogenperoxide steam generator, step b and step c It is mixed, after being sufficiently mixed uniformly, obtains product and eliminate the unusual smell spray for stench workplace personnel's clothing.
Product made from embodiment 4 handles (using the spraying form of spray bottle the clothing for having sprayed odorant Carry out), it is detected after acting on 5min.The result shows that: S2-It is not detected, other each substance gas-chromatography total peak areas are 0.76, total removal rate is about 99.84%.Subjective smelling the results are shown in Table 3.Blank control experiment is done simultaneously, that is, is sprayed with malodorant Certain time is placed under the clothes natural conditions of matter, it is detected.The result shows that: after placing for 24 hours, S2-It is not detected, other Substance total peak area is 169.78, and removal rate 64.28%, after placing 72h, peak area still has 93.80, and removal rate is 80.26%.Naturally the subjective smelling for placing clothing the results are shown in Table 3.
The subjective smelling result of table 3
Note: √ is represented without obvious peculiar smell;★ represents extremely slight peculiar smell;X representative is difficult to receive stench.

Claims (4)

1. a kind of eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing, which is characterized in that the preparation side Method the following steps are included:
A, it is configured to mass percentage concentration first and is 0.3~3% hydrogenperoxide steam generator, and the hydrogenperoxide steam generator of preparation is set In containers for future use;Then silver salt, stabilizer and synergist are weighed;
With Ag+Meter, the proportionate relationship of additional amount is 5~50mg:1kg between the silver salt and the hydrogenperoxide steam generator of preparation;It is described The mass fraction that the additional amount of stabilizer accounts for the hydrogenperoxide steam generator of preparation is 3.5 ‰~10 ‰;The additional amount of the synergist The mass fraction for accounting for the hydrogenperoxide steam generator of preparation is 1.5 ‰~7.5 ‰;
B, the hydrogenperoxide steam generator for taking part steps a to prepare, is then added weighed silver salt and is dissolved, after completely dissolution gained Silver salt solution ie in solution A is spare;
C, the hydrogenperoxide steam generator for taking part steps a to prepare, is then added weighed stabilizer and synergist is dissolved, sufficiently It is spare that solution B is obtained after dissolution;
D, the solution B three for obtaining the obtained solution A of step a remaining hydrogenperoxide steam generator, step b and step c carries out Mixing after being sufficiently mixed uniformly, obtains product and eliminates the unusual smell spray for stench workplace personnel's clothing.
2. according to claim 1 eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing, feature Be: silver salt described in step a is silver nitrate, silver sulfate or silver perchlorate.
3. according to claim 1 eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing, feature Be: stabilizer described in step a is phosphoric acid, magnesium gluconate, sodium gluconate, iminodisuccinic acid, hydroxy ethylidene two Phosphonic acids HEDP, ethylene diamine tetra methylene phosphonic acid sodium EDTMPS, diethylene triamine pentamethylene phosphonic DETPMP and aliphatic alcohol polyethenoxy At least one of ether AEO.
4. according to claim 1 eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing, feature Be: synergist described in step a is at least one in mannitol, glycerol, polyethylene glycol PEG400 and polyethylene glycol PEG6000 Kind.
CN201811011105.1A 2018-08-31 2018-08-31 It is a kind of to eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing Pending CN109092034A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811011105.1A CN109092034A (en) 2018-08-31 2018-08-31 It is a kind of to eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811011105.1A CN109092034A (en) 2018-08-31 2018-08-31 It is a kind of to eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing

Publications (1)

Publication Number Publication Date
CN109092034A true CN109092034A (en) 2018-12-28

Family

ID=64864574

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811011105.1A Pending CN109092034A (en) 2018-08-31 2018-08-31 It is a kind of to eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing

Country Status (1)

Country Link
CN (1) CN109092034A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101023753A (en) * 2006-02-21 2007-08-29 上海威理消毒剂有限公司 Oxidation-type disinfecting sterilizing agent and preparing method
CN105594740A (en) * 2016-01-21 2016-05-25 上海宇昂新材料科技有限公司 Automotive air disinfecting and refreshing spray and process for preparing same
KR20170108587A (en) * 2016-03-18 2017-09-27 이종호 Eco-friendly disinfection and deodorant compositions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101023753A (en) * 2006-02-21 2007-08-29 上海威理消毒剂有限公司 Oxidation-type disinfecting sterilizing agent and preparing method
CN105594740A (en) * 2016-01-21 2016-05-25 上海宇昂新材料科技有限公司 Automotive air disinfecting and refreshing spray and process for preparing same
KR20170108587A (en) * 2016-03-18 2017-09-27 이종호 Eco-friendly disinfection and deodorant compositions

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
张流波等: "《医学消毒学最新进展》", 31 December 2015, 人民军医出版社 *
方景礼: "《金属材料抛光技术》", 31 January 2007, 国防工业出版社 *
潘长华等: "《实用小化工生产大全 第一卷无机化工产品 复混肥料 农药 兽药》", 31 January 1999, 化学工业出版社 *
黄圣明等: "《回顾与展望•中国啤酒工业》", 31 January 2005, 呼和浩特:内蒙古人民出版社 *

Similar Documents

Publication Publication Date Title
ES2427352T3 (en) Use of fragrance compositions to restrict the formation of indole from dirt based on fecal substances and urine
CN104307019A (en) Plant extract deodorizer for removing harmful gases
CN106729860A (en) A kind of environment-friendly high-efficiency deodorant and preparation method thereof
JP2015081237A (en) Agent of inhibiting odors caused by sotolon
CN101959536A (en) Aromatic agent composition for openable storage space
CN105311660A (en) Plant-sourced deodorant capable of inhibiting and killing bacteria
JP2006223646A (en) Deodorant composition and method for deodorization
CN104784727A (en) Biological deodorant and using method thereof
WO2007125216A1 (en) Method of treating purification sludge and odour neutralizing composition for implementing this method
CN109092034A (en) It is a kind of to eliminate the unusual smell the preparation method of spray for stench workplace personnel's clothing
JPH0669478B2 (en) Deodorant and deodorant spray
JP2001178806A (en) Deodorant composition
CN108114588A (en) A kind of plant type deodorant compositions and paper for daily use
JPH0240339B2 (en)
KR101781657B1 (en) Deodorant composition comprising essential oil from plant
KR102466766B1 (en) Eco-friendly deodorant using arrowroot stem
JP5405621B2 (en) Fragrance composition
JP2007031605A (en) Perfume composition
JP2804823B2 (en) Deodorants
CN103055341A (en) Control agent of peculiar smell molecule
JP3458808B2 (en) Deodorants
JP2000325453A (en) Deodorant
JPH11221272A (en) Deodorant and deodorant composition
JPH0479961A (en) Deodorant
JP2021040701A (en) Deodorant composition

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20181228

RJ01 Rejection of invention patent application after publication