CN109082311B - 一种绿色环保的汽油添加剂 - Google Patents

一种绿色环保的汽油添加剂 Download PDF

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CN109082311B
CN109082311B CN201811071227.XA CN201811071227A CN109082311B CN 109082311 B CN109082311 B CN 109082311B CN 201811071227 A CN201811071227 A CN 201811071227A CN 109082311 B CN109082311 B CN 109082311B
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扣璇
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Liaoning Zhongyi automobile new energy technology Co.,Ltd.
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Abstract

本发明公开了一种绿色环保的汽油添加剂。包括如下重量份数的组分：乙二醇叔丁基醚8‑12份，聚丙二醇醚10‑15份，尼泊金丙酯钠6‑8份，防爆剂1‑3份，金属腐蚀抑制剂1‑3份，助溶剂2‑5份，抗氧化剂1‑3份。本发明的汽油添加剂，可以添加到各种型号的汽油产品中，可以降低汽油燃烧产生的HC、CO和NOx有害气体，增加汽油的燃烧值，防爆剂的添加可以防止汽油剧烈燃烧产生爆炸事故，金属腐蚀抑制剂可以有效缓解汽油对于汽车发动机和邮箱的腐蚀及积垢。

Description

一种绿色环保的汽油添加剂
技术领域
本发明属于石油化工技术领域，具体涉及一种绿色环保的汽油添加剂。
背景技术
随着经济的发展，汽车的普及，汽油的使用量逐年增加。在石油提炼汽油的过程中，普遍采用催化裂化的技术，生产的汽油含有少量有机酸和有机碱，时间长了，汽油中会产生酸碱沉淀，汽油中的烯烃和烯醇长时间会产生氧化反应生成胶状物质，这些物质附着在邮箱或发动机内，会产油垢，影响发动机的性能，并造成高油耗。汽油的燃烧会产生HC、CO和NOx，这些有害物质释放到大气中，造成雾霾，损害人的身体健康。
为了弥补汽油存在的缺陷、改善油品质量和提高其使用性能，已经研发出抗爆剂、抗氧化剂、分散剂、防腐剂、抗静电剂、防胶剂、抗磨剂、抗烧蚀剂、助燃剂、表面活性剂、润滑剂、消烟剂等多种化学添加剂。但是，其使用效果还没有达到绿色环保的要求，如抗爆剂中加有四乙基铅、二茂铁，这些重金属元素导致环境的二次污染。
专利201610977662.3公开了一种汽油添加剂及其制备方法。，其组份按重量份数包括甲基叔丁基醚3-12份、丁醇10-15份、石脑油10-20份、吐温80 3-6份、松香提取液15-25份、异丁烷3-6份、石油醚15-25份、清净分散剂10-25份、月桂醇聚氧乙烯醚10-25份、表面活性剂4-10份以及二乙醇单丁醚10-25份，该汽油添加剂虽然环保无污染，能够提高汽油的燃烧效率，节省汽油，但是，该汽油添加剂燃烧时剧烈，容易发生爆炸，其也没有解决汽油在邮箱和发动机中的积垢问题。
发明内容
本发明的目的在于提供一种绿色环保的汽油添加剂。
一种绿色环保的汽油添加剂，包括如下重量份数的组分：乙二醇叔丁基醚8-12份，聚丙二醇醚10-15份，尼泊金丙酯钠6-8份，防爆剂1-3份，金属腐蚀抑制剂1-3份，助溶剂2-5份，抗氧化剂1-3份。
上述汽油添加剂的制备方法为：在常温条件下取上述原料组分，混合，搅拌20-30min，制成。
所述防爆剂为异辛烷，异丁醇，磷酸甲基苯二苯酯中的一种或一种以上。
所述金属腐蚀抑制剂为吡唑酮，甲基丙烯酸酯低聚物，甲基苯并三氮唑，三聚磷酸铝，硬脂酸丁酯中的一种或一种以上。
所述助溶剂为2-甲基-2戊醇，琥珀酸酯，蓖麻油，三乙醇胺中的一种或一种以上。
所述抗氧化剂为BHT501，4-甲氧基邻苯二胺，苯酚，二甲酚，2,6-二叔丁基对甲基苯酚中的一种或一种以上。
所述汽油添加剂还包括羧基封端的丁二烯均聚物与甲基丙烯酸的酯化物3-8份。
所述汽油添加剂还包括钽酸锂1-3份。
所述汽油添加剂还包括碳酸二酰氯与4,4'-亚环己烷基二苯酚的聚合物1-3份。
本发明的有益效果：本发明的汽油添加剂，可以添加到各种型号的汽油产品中，可以降低汽油燃烧产生的HC、CO和NOx有害气体，增加汽油的燃烧值，防爆剂的添加可以防止汽油剧烈燃烧产生爆炸事故，金属腐蚀抑制剂可以有效缓解汽油对于汽车发动机和邮箱的腐蚀及积垢。
具体实施方式
下面结合具体实施例对本发明做进一步说明。
实施例1
一种绿色环保的汽油添加剂，包括如下重量份数的组分：乙二醇叔丁基醚10份，聚丙二醇醚12份，尼泊金丙酯钠7份，异辛烷2份，吡唑酮2份，2-甲基-2戊醇3份，二甲酚2份。
实施例2
一种绿色环保的汽油添加剂，包括如下重量份数的组分：乙二醇叔丁基醚8份，聚丙二醇醚10份，尼泊金丙酯钠6份，异丁醇1份，甲基丙烯酸酯低聚物1份，琥珀酸酯2份，BHT501 1份。
实施例3
一种绿色环保的汽油添加剂，包括如下重量份数的组分：乙二醇叔丁基醚12份，聚丙二醇醚15份，尼泊金丙酯钠8份，磷酸甲基苯二苯酯3份，甲基苯并三氮唑1份，三聚磷酸铝1份，硬脂酸丁酯1份，三乙醇胺5份，2,6-二叔丁基对甲基苯酚3份。
实施例4
一种绿色环保的汽油添加剂，包括如下重量份数的组分：乙二醇叔丁基醚10份，聚丙二醇醚12份，尼泊金丙酯钠7份，异辛烷2份，吡唑酮2份，2-甲基-2戊醇3份，二甲酚2份，羧基封端的丁二烯均聚物与甲基丙烯酸的酯化物5份。
实施例5
一种绿色环保的汽油添加剂，包括如下重量份数的组分：乙二醇叔丁基醚10份，聚丙二醇醚12份，尼泊金丙酯钠7份，异辛烷2份，吡唑酮2份，2-甲基-2戊醇3份，二甲酚2份，钽酸锂2份。
实施例6
一种绿色环保的汽油添加剂，包括如下重量份数的组分：乙二醇叔丁基醚10份，聚丙二醇醚12份，尼泊金丙酯钠7份，异辛烷2份，吡唑酮2份，2-甲基-2戊醇3份，二甲酚2份，碳酸二酰氯与4,4'-亚环己烷基二苯酚的聚合物2份。
实施例7
一种绿色环保的汽油添加剂，包括如下重量份数的组分：乙二醇叔丁基醚10份，聚丙二醇醚12份，尼泊金丙酯钠7份，异辛烷2份，吡唑酮2份，2-甲基-2戊醇3份，二甲酚2份，平灰藓提取物5份。
所述平灰藓提取物的提取方法为：取平灰藓，晒干，打为粗粉，置于蒸馏容器内，加8倍重量份数的水，浸润2小时；快速加热至沸腾，保持30min，连接回流冷凝管收集冷凝液，得到蒸馏液，蒸干蒸馏液，得到粉末状物质，制成。
实施例8
一种绿色环保的汽油添加剂，包括如下重量份数的组分：乙二醇叔丁基醚10份，聚丙二醇醚12份，尼泊金丙酯钠7份，异辛烷2份，吡唑酮2份，2-甲基-2戊醇3份，二甲酚2份，牛角藓提取物5份。
所述平灰藓提取物的提取方法为：取牛角藓，晒干，打为粗粉，置于蒸馏容器内，加8倍重量份数的水，浸润2小时；快速加热至沸腾，保持30min，连接回流冷凝管收集冷凝液，得到蒸馏液，蒸干蒸馏液，得到粉末状物质，制成。
对比例1
一种绿色环保的汽油添加剂，包括如下重量份数的组分：乙二醇叔丁基醚10份，聚丙二醇醚12份，异辛烷2份，吡唑酮2份，2-甲基-2戊醇3份，二甲酚2份。
实验例1：节油测试
以GB/T 14951-2007《汽车节油技术评定方法》和GB/T 25348-2010《汽车节油产品使用技术条件》检测根据实施例1-8及对比例1制备的汽油添加剂的节油性能，统计节油率，见表1：
表1
Figure BDA0001799546850000061
注：*代表与实施例1组比较P<0.05。
由表1可以看出，实施例1-3，实施例5的节油率相当，没有明显差异，实施例4，实施例6-8，对比例1的节油率显著高于实施例1，对比例1的节油率显著低于实施例1。
实验例2：金属腐蚀性能实验
采用M30甲醇汽油，添加本发明实施例1-8及对比例1的汽油添加剂，添加量为1.5％，本实验参照ASTM G31-72“金属实验室沉浸腐蚀试验的推荐规范”和国家标准GB378-64《发动机燃料铜片腐蚀试验法》，将尺寸为40X13×2mm已处理过的45#钢、H65黄铜标准试样，分别浸入到M30甲醇汽油、添加本发明
实施例1-8及对比例1的添加剂的M30甲醇汽油中，用橡胶塞封口，外接冷凝管与大气接通，每组平行试样3个。试验温度控制为(25±1)℃，时间为200h。测试结果见表2-3：
表2
Figure BDA0001799546850000071
注：*代表与M30甲醇汽油组比较P<0.05。
表3
Figure BDA0001799546850000072
注：*代表与实施例1组比较P<0.05。
由表2可以看出，实施例1-3的添加剂汽油的45#钢腐蚀率和H65黄铜腐蚀率均显著低于M30甲醇汽油无添加剂组，证明本发明的添加剂能显著降低汽油对金属的腐蚀；由表3可以看出，实施例4，实施例8和对比例1与实施例1的45#钢腐蚀率和H65黄铜腐蚀率相当，没有显著差异，实施例5-7的45#钢腐蚀率和H65黄铜腐蚀率均显著低于实施例1。

Claims (7)

1.一种绿色环保的汽油添加剂，其特征在于，包括如下重量份数的组分：乙二醇叔丁基醚8-12份，聚丙二醇醚10-15份，尼泊金丙酯钠6-8份，防爆剂1-3份，金属腐蚀抑制剂1-3份，助溶剂2-5份，抗氧化剂1-3份。
2.根据权利要求1所述绿色环保的汽油添加剂，其特征在于，所述防爆剂为异辛烷，异丁醇，磷酸甲基苯二苯酯中的一种或一种以上。
3.根据权利要求1所述绿色环保的汽油添加剂，其特征在于，所述金属腐蚀抑制剂为吡唑酮，甲基丙烯酸酯低聚物，甲基苯并三氮唑，三聚磷酸铝，硬脂酸丁酯中的一种或一种以上。
4.根据权利要求1所述绿色环保的汽油添加剂，其特征在于，所述助溶剂为2-甲基-2戊醇，琥珀酸酯，蓖麻油，三乙醇胺中的一种或一种以上。
5.根据权利要求1所述绿色环保的汽油添加剂，其特征在于，所述抗氧化剂为BHT501，4-甲氧基邻苯二胺，苯酚，二甲酚，2,6-二叔丁基对甲基苯酚中的一种或一种以上。
6.根据权利要求1所述绿色环保的汽油添加剂，其特征在于，所述汽油添加剂还包括羧基封端的丁二烯均聚物与甲基丙烯酸的酯化物3-8份。
7.根据权利要求1所述绿色环保的汽油添加剂，其特征在于，所述汽油添加剂还包括钽酸锂1-3份。
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