CN109056403A - A kind of high intensity super electrolytic capacitor diaphragm paper and preparation method thereof - Google Patents
A kind of high intensity super electrolytic capacitor diaphragm paper and preparation method thereof Download PDFInfo
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- CN109056403A CN109056403A CN201811048340.6A CN201811048340A CN109056403A CN 109056403 A CN109056403 A CN 109056403A CN 201811048340 A CN201811048340 A CN 201811048340A CN 109056403 A CN109056403 A CN 109056403A
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- tencel
- slurry
- electrolytic capacitor
- beating degree
- paper
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
- D21D1/00—Methods of beating or refining; Beaters of the Hollander type
- D21D1/02—Methods of beating; Beaters of the Hollander type
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- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
The invention belongs to electrolytic capacitor paper fields, and the present invention relates to a kind of preparation methods of super electrolytic capacitor diaphragm paper.A kind of high intensity super electrolytic capacitor diaphragm paper, the super electrolytic capacitor diaphragm paper is made by copy paper after the tencel slurry A of low beating degree and the tencel slurry B mixing of high beating degree, the beating degree of the tencel slurry A is 5 ~ 50 ° of SR, the beating degree of tencel slurry B is 50 ~ 95 ° of SR, the mass percent of tencel slurry A is 5 ~ 50%, and the mass percent of tencel slurry B is 50 ~ 95%.The diaphragm paper aperture is small and uniform, has good absorbent, while tensile strength with higher, is suitable for use in supercapacitor.
Description
Technical field
The invention belongs to electrolytic capacitor paper fields, and the present invention relates to a kind of preparation sides of super electrolytic capacitor diaphragm paper
Method.
Background technique
Electrolytic capacitor is one of component important in electronics industry, in circuit in addition to having filtering, decoupling and signal
Outside the effect of coupling, special role also is played in special circuit such as circuit for rectifying, power circuit and ac motor start-up circuit.
It is widely used in the fields such as automobile industry, security industry, medical electronics, telecomputer, electronic toy and Industry Control.Electrolysis electricity
Container paper is the gasket material that electrolyte is adsorbed in electrolytic capacitor, its performance directly affects the quality of electrolytic capacitor.
Super electrolytic capacitor is that occur recently as the high speed development of electronics technology and the breakthrough of material science
New power type electronic component.It has higher than general electrolytic capacitor between general electrolytic capacitor and battery
Capacity, thousands of farads can be up to；Higher discharge power more specific than common batteries, discharge current is up to kilo-ampere.Letter
Yan Zhi, it has the capacitance of battery and the fast charging and discharging performance of capacitor, while also with safe and reliable, the scope of application is wide
The features such as.Supercapacitor is in automobile (especially electric car), electric power, railway, communication, national defence and consumer electrical product etc.
Aspect has huge application value and market potential.
Diaphragm paper used in supercapacitor be different from general electrolytic capacitor used in diaphragm paper, due to its use it is special
Tencel fiber be raw material, its intensity is low compared with general electrolytic capacitor diaphragm paper intensity after mashing.Lower tensile strength can be led
It causes to be easy broken end in assembling process, reduces production efficiency, meanwhile, the puncture resistant ability of diaphragm paper can be also reduced, causes to leak electricity
Stream increases, and even results in short circuit.It is therefore desirable to which super electrolytic capacitor diaphragm paper needs higher tensile strength.
Applicant has applied for that Chinese invention patent (CN101696558A) discloses a kind of super electrolytic capacitor paper, this is super
Grade electrolytic capacitor paper be made of pineapple flaxen fiber and tencel fiber copy paper, by weight percentage pineapple flaxen fiber be 10~
80%, tencel fiber is 20~90%.Its paper tightness of super electrolytic capacitor paper of the invention is low, intensity is good, and aperture is small and equal
Even, tightness is low to keep its loss low, not will increase the internal resistance of supercapacitor, and intensity makes it suitable for well the processing of supercapacitor,
The small leakage current that will make supercapacitor in aperture is small, is allowed to be suitble to energy storage, be suitable for use in supercapacitor.
Applicant has applied for that Chinese invention patent (CN108221487A) discloses a kind of low internal resistance super electrolytic capacitor
Paper, the super electrolytic capacitor paper are made of tencel fiber and superfine chemical fiber, and tencel fiber is 10 by weight percentage
~95%, chemical fibre is 5~90%；Chemical fibre used includes polyester fiber, polyolefine fiber, Fypro, polyamides
One of imine fiber, polyacrylonitrile fibre, vinal and spandex fibre or a variety of mixing.
It is all to prepare electrolytic capacitor paper using tencel fiber and other fibers, and illustrating in above-mentioned two patents
Disclosing in book cannot be considered in terms of in intensity, aperture and internal resistance using the electrolytic capacitor paper of independent tencel fiber, therefore individually
Tencel fiber prepares electrolytic capacitor paper and is unable to reach requirement in performance.
Summary of the invention
Present invention aim to address the defects of above-mentioned background technique, first purpose of the invention is to provide a kind of high-strength
Diaphragm of supercapacitor paper is spent, the diaphragm paper aperture is small and uniform, has good absorbent, while anti-tensile with higher
Intensity is suitable for use in supercapacitor.Second purpose of the invention is to provide the preparation of above-mentioned diaphragm of supercapacitor paper
Method.
In order to realize above-mentioned first purpose, present invention employs technical solutions below:
A kind of high intensity super electrolytic capacitor diaphragm paper, the super electrolytic capacitor diaphragm paper by low beating degree tencel slurry
Copy paper is made after the A and tencel slurry B of high beating degree mixing, and the beating degree of the tencel slurry A is 5 ~ 50 ° of SR, tencel slurry
The beating degree for expecting B is 50 ~ 95 ° of SR, and the mass percent of tencel slurry A is 5 ~ 50%, the mass percent of tencel slurry B is 50 ~
95%。
Preferably, the beating degree of the tencel slurry A is 20 ~ 40 ° of SR, the beating degree of tencel slurry B is 80 ~ 90 °
SR。
Preferably, the mass percent of the tencel slurry A is 10 ~ 40%, the mass percent of tencel slurry B is
60~90%。
In order to realize above-mentioned second purpose, present invention employs technical solutions below:
A method of the high-intensitive super electrolytic capacitor diaphragm paper being prepared, this method includes the following steps:
1) original slurry material of concentration mass concentration between 2.5 ~ 5.0% will be made after tencel slurry plus water；
2) obtained tencel original slurry material is beaten respectively through disc mill, obtains tencel slurry A and the height mashing of low beating degree
The tencel slurry B of degree；
3) tencel slurry A and tencel slurry B are uniformly mixed, obtain mixing tencel slurry C；
4) tencel slurry C passes through double cylinder mould machine composite moldings, obtains height after squeezing, drying, curling and cutting after molding
Intensity super electrolytic capacitor diaphragm paper.
The present invention due to the adoption of the above technical solution, by the way that high beating degree tencel fiber and low beating degree tencel is fine
Dimension combines, and provides skeleton structure and intensity using low beating degree tencel fiber, high beating degree tencel fiber obtains lesser
Aperture, to obtain the super electrolytic capacitor diaphragm paper with good absorption, smaller aperture due, while with higher strong
Degree, tensile strength increase 30% or more.
Specific embodiment
Reference example 1
Fiber number is 1.5dtex, and beating degree is 85 ° of SR after the tencel fiber mashing that length is 5mm, is manufactured paper with pulp, is copied using cylinder mould machine
Routinely technique, page detect the indexs such as tightness, thickness, tensile strength, aperture to paper technique, are made into supercapacitor detection capacitor
The indexs such as capacity, leakage current, internal resistance.
Reference example 2
Fiber number is 1.5dtex, and beating degree is 20 ° of SR after the tencel fiber mashing that length is 5mm, is manufactured paper with pulp, is copied using cylinder mould machine
Routinely technique, page detect the indexs such as tightness, thickness, tensile strength, aperture to paper technique, are made into supercapacitor detection capacitor
The indexs such as capacity, leakage current, internal resistance.
Embodiment 1
Tencel fiber fiber number is 1.5dtex, and length 5mm, the tencel fiber beating degree of low beating degree is 20 ° of SR, high beating degree
Tencel fiber beating degree be 85 ° of SR, low beating degree tencel fiber and high beating degree tencel fiber press the weight proportion of 10:90,
It is manufactured paper with pulp using cylinder mould machine, routinely technique, page detect the indexs such as tightness, thickness, tensile strength, aperture, do copy paper technique
The indexs such as capacity, leakage current, internal resistance at supercapacitor detection capacitor.
Embodiment 2
Tencel fiber fiber number is 1.5dtex, and length 5mm, the tencel fiber beating degree of low beating degree is 20 ° of SR, high beating degree
Tencel fiber beating degree be 85 ° of SR, low beating degree tencel fiber and high beating degree tencel fiber press the weight proportion of 20:80,
It is manufactured paper with pulp using cylinder mould machine, routinely technique, page detect the indexs such as tightness, thickness, tensile strength, aperture, do copy paper technique
The indexs such as capacity, leakage current, internal resistance at supercapacitor detection capacitor.
Embodiment 3
Tencel fiber fiber number is 1.5dtex, and length 5mm, the tencel fiber beating degree of low beating degree is 30 ° of SR, high beating degree
Tencel fiber beating degree be 85 ° of SR, low beating degree tencel fiber and high beating degree tencel fiber press the weight proportion of 20:80,
It is manufactured paper with pulp using cylinder mould machine, routinely technique, page detect the indexs such as tightness, thickness, tensile strength, aperture, do copy paper technique
The indexs such as capacity, leakage current, internal resistance at supercapacitor detection capacitor.
Embodiment 4
Tencel fiber fiber number is 1.5dtex, and length 5mm, the tencel fiber beating degree of low beating degree is 30 ° of SR, high beating degree
Tencel fiber beating degree be 85 ° of SR, low beating degree tencel fiber and high beating degree tencel fiber press the weight proportion of 30:70,
It is manufactured paper with pulp using cylinder mould machine, routinely technique, page detect the indexs such as tightness, thickness, tensile strength, aperture, do copy paper technique
The indexs such as capacity, leakage current, internal resistance at supercapacitor detection capacitor.
Embodiment 5
Tencel fiber fiber number is 1.5dtex, and length 5mm, the tencel fiber beating degree of low beating degree is 40 ° of SR, high beating degree
Tencel fiber beating degree be 85 ° of SR, low beating degree tencel fiber and high beating degree tencel fiber press the weight proportion of 30:70,
It is manufactured paper with pulp using cylinder mould machine, routinely technique, page detect the indexs such as tightness, thickness, tensile strength, aperture, do copy paper technique
The indexs such as capacity, leakage current, internal resistance at supercapacitor detection capacitor.
Embodiment 6
Tencel fiber fiber number is 1.5dtex, and length 5mm, the tencel fiber beating degree of low beating degree is 40 ° of SR, high beating degree
Tencel fiber beating degree be 85 ° of SR, low beating degree tencel fiber and high beating degree tencel fiber press the weight proportion of 40:60,
It is manufactured paper with pulp using cylinder mould machine, routinely technique, page detect the indexs such as tightness, thickness, tensile strength, aperture, do copy paper technique
The indexs such as capacity, leakage current, internal resistance at supercapacitor detection capacitor.
The test data of above-mentioned each embodiment is as follows:
Claims (4)
1. a kind of high intensity super electrolytic capacitor diaphragm paper, which is characterized in that the super electrolytic capacitor diaphragm paper is beaten by low
Copy paper is made after the tencel slurry A of the degree of beating and tencel slurry B of high beating degree is mixed, and the beating degree of the tencel slurry A is 5
The beating degree of ~ 50 ° of SR, tencel slurry B are 50 ~ 95 ° of SR, and by dry weight, the mass percent of tencel slurry A is 5 ~ 50%, tencel slurry
The mass percent for expecting B is 50 ~ 95%.
2. a kind of high-intensitive super electrolytic capacitor diaphragm paper according to claim 1, which is characterized in that the tencel
The beating degree of slurry A is 20 ~ 40 ° of SR, and the beating degree of tencel slurry B is 80 ~ 90 ° of SR.
3. a kind of high-intensitive super electrolytic capacitor diaphragm paper according to claim 1, which is characterized in that the tencel
The mass percent of slurry A is 10 ~ 40%, and the mass percent of tencel slurry B is 60 ~ 90%.
4. a kind of side for preparing high-intensitive super electrolytic capacitor diaphragm paper described in claim 1 ~ 3 any one claim
Method, which is characterized in that this method includes the following steps:
1) original slurry material of concentration mass concentration between 2.5 ~ 5.0% will be made after tencel slurry plus water；
2) obtained tencel original slurry material is beaten respectively through disc mill, obtains tencel slurry A and the height mashing of low beating degree
The tencel slurry B of degree；
3) tencel slurry A and tencel slurry B are uniformly mixed, obtain mixing tencel slurry C；
4) tencel slurry C passes through double cylinder mould machine composite moldings, obtains height after squeezing, drying, curling and cutting after molding
Intensity super electrolytic capacitor diaphragm paper.
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| CN201811048340.6A CN109056403A (en) | 2018-09-10 | 2018-09-10 | A kind of high intensity super electrolytic capacitor diaphragm paper and preparation method thereof |
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| CN201811048340.6A CN109056403A (en) | 2018-09-10 | 2018-09-10 | A kind of high intensity super electrolytic capacitor diaphragm paper and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116289335A (en) * | 2022-12-12 | 2023-06-23 | 株洲时代华先材料科技有限公司 | Electrolytic capacitor paper and preparation method thereof |
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| CN101696558A (en) * | 2009-10-23 | 2010-04-21 | 浙江凯恩特种材料股份有限公司 | Super electrolytic capacitor paper |
| WO2017170065A1 (en) * | 2016-03-28 | 2017-10-05 | ニッポン高度紙工業株式会社 | Separator for electrochemical element and electrochemical element |
| WO2018104330A1 (en) * | 2016-12-06 | 2018-06-14 | Re:Newcell Ab | Cellulose fibers |
| CN108172419A (en) * | 2018-01-04 | 2018-06-15 | 浙江凯恩特种材料股份有限公司 | A kind of enhanced super electrolytic capacitor diaphragm paper and preparation method thereof |
| CN108179652A (en) * | 2018-01-04 | 2018-06-19 | 浙江凯恩特种纸业有限公司 | A kind of reinforced electric electrolytic capacitor paper and preparation method thereof |
| CN108203893A (en) * | 2018-01-04 | 2018-06-26 | 浙江凯恩特种纸业有限公司 | A kind of low tightness high intensity electrolytic capacitor paper and preparation method thereof |
| CN108221486A (en) * | 2018-01-04 | 2018-06-29 | 浙江凯恩特种材料股份有限公司 | A kind of corrosion-resistant super electrolytic capacitor diaphragm paper and preparation method thereof |
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2018
- 2018-09-10 CN CN201811048340.6A patent/CN109056403A/en active Pending
Patent Citations (7)
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| CN101696558A (en) * | 2009-10-23 | 2010-04-21 | 浙江凯恩特种材料股份有限公司 | Super electrolytic capacitor paper |
| WO2017170065A1 (en) * | 2016-03-28 | 2017-10-05 | ニッポン高度紙工業株式会社 | Separator for electrochemical element and electrochemical element |
| WO2018104330A1 (en) * | 2016-12-06 | 2018-06-14 | Re:Newcell Ab | Cellulose fibers |
| CN108172419A (en) * | 2018-01-04 | 2018-06-15 | 浙江凯恩特种材料股份有限公司 | A kind of enhanced super electrolytic capacitor diaphragm paper and preparation method thereof |
| CN108179652A (en) * | 2018-01-04 | 2018-06-19 | 浙江凯恩特种纸业有限公司 | A kind of reinforced electric electrolytic capacitor paper and preparation method thereof |
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| CN108221486A (en) * | 2018-01-04 | 2018-06-29 | 浙江凯恩特种材料股份有限公司 | A kind of corrosion-resistant super electrolytic capacitor diaphragm paper and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116289335A (en) * | 2022-12-12 | 2023-06-23 | 株洲时代华先材料科技有限公司 | Electrolytic capacitor paper and preparation method thereof |
| CN116289335B (en) * | 2022-12-12 | 2024-04-02 | 株洲时代华先材料科技有限公司 | Electrolytic capacitor paper and preparation method thereof |
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Application publication date: 20181221 |
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