CN109054979A - A kind of environment-friendly type all-synthetic grinding fluid and preparation method thereof - Google Patents
A kind of environment-friendly type all-synthetic grinding fluid and preparation method thereof Download PDFInfo
- Publication number
- CN109054979A CN109054979A CN201811065609.1A CN201811065609A CN109054979A CN 109054979 A CN109054979 A CN 109054979A CN 201811065609 A CN201811065609 A CN 201811065609A CN 109054979 A CN109054979 A CN 109054979A
- Authority
- CN
- China
- Prior art keywords
- grinding fluid
- agent
- cloud point
- couplant
- synthetic grinding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000227 grinding Methods 0.000 title claims abstract description 91
- 239000012530 fluid Substances 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000013556 antirust agent Substances 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 32
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 32
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 23
- 239000004615 ingredient Substances 0.000 claims abstract description 22
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical group O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 19
- 229920000642 polymer Polymers 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 238000004062 sedimentation Methods 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 10
- 150000007942 carboxylates Chemical class 0.000 claims abstract description 6
- -1 cationic sodium salt Chemical class 0.000 claims description 55
- 239000000203 mixture Substances 0.000 claims description 38
- 150000003628 tricarboxylic acids Chemical class 0.000 claims description 28
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 26
- 229920001296 polysiloxane Polymers 0.000 claims description 21
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical group OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 19
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 17
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 14
- 229920000570 polyether Polymers 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229940008099 dimethicone Drugs 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 238000001802 infusion Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 239000012224 working solution Substances 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 3
- 238000012805 post-processing Methods 0.000 abstract description 2
- 230000006641 stabilisation Effects 0.000 abstract description 2
- 238000011105 stabilization Methods 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 19
- 150000002314 glycerols Chemical class 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 238000005520 cutting process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000006260 foam Substances 0.000 description 6
- 239000000314 lubricant Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 238000012797 qualification Methods 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 239000002173 cutting fluid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000007514 turning Methods 0.000 description 3
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 150000002894 organic compounds Chemical group 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012795 verification Methods 0.000 description 2
- HJVAFZMYQQSPHF-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;boric acid Chemical compound OB(O)O.OCCN(CCO)CCO HJVAFZMYQQSPHF-UHFFFAOYSA-N 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical group COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 229910001141 Ductile iron Inorganic materials 0.000 description 1
- 229910001060 Gray iron Inorganic materials 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005354 coacervation Methods 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 150000004693 imidazolium salts Chemical class 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- WYMSBXTXOHUIGT-UHFFFAOYSA-N paraoxon Chemical compound CCOP(=O)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 WYMSBXTXOHUIGT-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
- C10N2030/44—Boron free or low content boron compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/72—Extended drain
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of environment-friendly type all-synthetic grinding fluid and preparation method thereof, all-synthetic grinding fluid includes the ingredient of following mass percent: antirust agent 20~40%, high cloud point polymer 5~15%, polyethylene glycol 5~15%, stabilizer 0.3~5%, sedimentation agent 0.3~5%, couplant 0.1~1.0%, defoaming agent 0~0.5% and surplus water.All-synthetic grinding fluid of the invention does antirust using the metal carboxylate of not boracic, environmental protection, easily biological-degradable, post-processing is easy, it is done and is lubricated using high cloud point polymer poly ethylene oxide polypropylene oxide monobutyl base ether, greatly reduce the dosage of couplant, and lubricity is more preferable.System is more stable, and reduce existing product smell and cost, cloud point is high, safer stabilization, and compounded with ingredients such as polyethylene glycol, couplant, sedimentation agents, the low bubble of obtained grinding fluid, high sedimentation, extending the working solution service life changes the liquid period up at least a year, without " the imperial robe " phenomenon, lubricity is good, and working solution temperature is low and constant after processing is completed.
Description
Technical field
The present invention relates to technical field of fine, it particularly relates to a kind of environment-friendly type all-synthetic grinding fluid and its system
Preparation Method.
Background technique
Grinding fluid is that the important supplementary material of grinding both occurs between grinding wheel and material in Grinding Process
Delineation and scratching occur again for cutting, generate a large amount of grinding heat, and different from the cutting ways such as turning, milling cutter, turning, milling cutter are cut
The heat for cutting mode about 70%~80%, which is gathered in chip, to flow away, and incoming workpiece accounts for about 10%~20%, is passed to knife
Tool then less than 5%, but grinding due to the metal being cut it is relatively thin, about 60%~90% heat is passed into workpiece,
Heat only less than 10%, which is ground, to be taken away, and produces a large amount of grinding heat, grinding area temperature is up to 400~1000 DEG C of left sides
The right side, at this high temperature, material can deform and burn, and grinding wheel can also be seriously worn, grinding quality decline.Usual
In the case of grinding plus T all can use grinding fluid, a large amount of grinding heat be taken away, the temperature of grinding area is reduced.Mill is efficiently used
Cutting liquid can be improved cutting speed 30%, reduce the temperature to 100~150 DEG C, reduce cutting force l0%~30%, and extending grinding wheel makes
With 4~5 times of the service life.Grinding fluid should have good cooling performance, greasy property, rustless property.
It is currently used for most of grinding fluid of ferrous metal and antirust agent and low cloud point polyethers is done based on borate ester derivative
Lubricant compounding organic acid couplant is made to complete the balance of formula and performance.And have following lack using this grinding fluid
Point: 1) boric acid not easily biological-degradable, by environment constraint and limitation；2) low cloud point polyethers is affected by temperature bigger, the condition of high temperature
Under it is unstable；3) " the imperial robe " scene cannot thoroughly solve.
Summary of the invention
In place of overcoming the shortcomings of the prior art, the present invention provides a kind of environmentally friendly, easy biology
Degradation, greasy property is good, safety and stability, the all-synthetic grinding fluid of nothing " the imperial robe " phenomenon and preparation method thereof.
To achieve the above object, the technical solution taken:
A kind of all-synthetic grinding fluid, the ingredient including following mass percent: antirust agent 20~40%, the polymerization of high cloud point
Object 5~15%, stabilizer 0.3~5%, sedimentation agent 0.3~5%, couplant 0.1~1.0%, disappears at polyethylene glycol 5~15%
The water of infusion 0~0.5% and surplus.
The fully synthetic cutting fluid provided by the invention has excellent greasy property, rustless property and the metal cut out
Quality of materials is very high, is currently used for most of grinding fluid of ferrous metal based on low cloud point polyethers and does lubricant compounding organic acid
Class couplant with complete formula and performance balance, low cloud point polyethers be affected by temperature it is bigger, it is unstable under the condition of high temperature,
The present invention compounds antirust agent and high cloud point polymer, polyethylene glycol, couplant, stabilizer etc. according to specific ratio,
Not only greatly reduce the dosage of couplant, and lubricity is more preferable, system is more stable, and reduce existing product smell and at
This；Effectively solve " the imperial robe " phenomenon in live use process.
Preferably, metal carboxylate antirust agent obtains it is highly preferred that the antirust agent reacts for tricarboxylic acid with triethanolamine
Product or the product of acquisition is reacted with triethanolamine for tricarboxylic acid and the mixed mixture of dicarboxylic acids or is
Tricarboxylic acid and the mixed mixture of dicarboxylic acids react the product obtained with the mixture of triethanolamine and monoethanolamine.
Preferably, the tricarboxylic acid and dicarboxylic acids are 8:2 or 9:1 mixing, the triethanolamine and monoethanolamine in mass ratio
It is mixed in mass ratio for 7:3 or 9:1.Antirust agent be it is a kind of can make liquid rapidly and uniformly penetrate into metal base surface, from
And slow down the reagent of metal erosion speed.Inorganic inhibitor and organic anti-can be divided by the chemical analysis of antirust agent material therefor
Rust two class of agent.Organic corrosion inhibitor, which refers to, to form the organic film of chemisorption or physics on the surface of metal material.To rise
To preventing metal material surface from contacting with corrosive deposit, and then prevent the reagent of metallic material corrosion.Its main feature is that metal itself
Do not have with antirust agent chemical change, maintain its original characteristic.It is organic to common are oxygen-containing organic compound, sulfur-bearing
Compound, organic compounds containing nitrogen and aldehyde radical, amido, imidazolium compounds, heterocyclic compound etc..It is currently used for ferrous metal
Most of grinding fluid antirust agent is done based on borate ester derivative, and boric acid not easily biological-degradable, by environment constraint and limit
System；The present invention does antirust using the metal carboxylate of not boracic, is compounded with high cloud point polymer, polyethylene glycol etc., acquisition
Grinding fluid environmental protection, easily biological-degradable, post-processing are easy.
Preferably, the high cloud point polymer is polyethylene oxide polypropylene oxide monobutyl base ether.The water base cutting of synthesis type
Liquid is due to not oil-containing, with good stability, cooling and cleaning, it has also become one of water-base cutting fluid research is important
Developing direction.Synthesis type water-base cutting fluid is since main body is water, and water viscosity is low, film forming is poor, bearing capacity is low, and rub often place
In boundary lubrication condition, thus fretting wear is serious, in actual use the lubricity to improve synthesis type water-base cutting fluid
Can, it is necessary to lubricant is added, be currently used for most of grinding fluid of ferrous metal be based on borate ester derivative do antirust agent and
Low cloud point polyethers makees lubricant compounding organic acid couplant to complete the balance of formula and performance.However low cloud point polyethers by
Temperature influence is bigger, unstable under the condition of high temperature.The present invention uses high cloud point polymer poly ethylene oxide polycyclic oxygen third
Alkane single-butyl ether does lubricant, greatly reduces the dosage of couplant, and lubricity is more preferable.System is more stable, and reduces
Existing product smell and cost.
Preferably, the stabilizer is glycerol derivatives.
Preferably, the sedimentation agent is cationic sodium salt；It is used as a kind of inorganic flocculating agent synergist.Inorganic flocculation
Agent can provide a large amount of complex ion, and can strong adsorption colloidal particles, by absorption, gantry, crosslinked action, to make
Coacervation of colloid.Physicochemical change also occurs simultaneously, neutralizes the charge on colloidal particles and suspended matter surface, reduces δ current potential,
So that colloidal particles is become attracting from original repelling each other, destroy micelle stability, collide colloidal particles mutually, to be formed
Cotton-shaped coagulating sedimentation, the surface area of precipitating is up to (200~1000) m2/ g, great adsorption capacity.
Preferably, the couplant is medium one or more selected from polyalcohol ethers, alcohols, ethers, what the present invention selected
Couplant is dipropylene glycol, and defoaming agent, also referred to as defomaing agent inhibit foam to generate or eliminate and generated for reducing surface tension
The additive of foam.China, which is permitted workable defoaming agent, has the fatty acid ester compounded object of silicone emulsion, higher alcohols, polyoxyethylene poly-
Oxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerol
7 kinds of ether, dimethyl silicone polymer etc., the present invention is preferably polysiloxanes, dimethicone, silicone emulsion, polyethers-silicon oxygen
At least one of alkyl copolymer.Have the effect of at normal temperature antifoaming speed quickly, foam inhibition it is good.
Preferably, the all-synthetic grinding fluid includes the ingredient of following mass percent: antirust agent 25%, high cloud point are poly-
Closing object 10%, polyethylene glycol 6%, stabilizer 2%, sedimentation agent 0.4%, couplant 0.9%, defoaming agent 0.05%, surplus is
Water.Present inventor passes through verification experimental verification, and under the specific mass percent proportion, grinding fluid effect of the present invention reaches
Most preferably.
Preferably, the all-synthetic grinding fluid includes the ingredient of following mass percent: antirust agent 25~35%, height are turbid
Select polymer 8~12%, polyethylene glycol 6~12%, stabilizer 2~5%, sedimentation agent 0.3~2.5%, couplant 0.1~
0.9%, defoaming agent 0~0.5%, surplus are water.Grinding fluid of the present invention, the proportion of component will affect the effect of grinding fluid of the present invention
Fruit, the study found that within the scope of the preferred mass percent, better effect of the present invention.
Preferably, the cloud point of the high cloud point polymer is greater than 80 DEG C.
The present invention also provides the preparation methods of the grinding fluid, comprising the following steps: 1) couplant will with defoaming agent
It is uniformly mixed with water spare；2) antirust agent, high cloud point polymer, polyethylene glycol successively is added according to formula rate to be uniformly mixed,
Add mixture in step 1)；3) sedimentation agent is added, stabilizer is mixed to get the grinding fluid.
The utility model has the advantages that
Synthesis grinding fluid of the invention is cooked antirust using the metal carboxylate of not boracic, environmental protection, easily biological-degradable, at the later period
Reason is easy, and is done and is lubricated using high cloud point polymer (polyethylene oxide polypropylene oxide monobutyl base ether), greatly reduces couplant
Dosage, and lubricity is more preferable.System is more stable, and reduces existing product smell and cost, and cloud point is high, safer stabilization,
And compounded with ingredients such as polyethylene glycol, couplant, sedimentation agents, the low bubble of obtained grinding fluid, high sedimentation extend work
The liquid service life changes the liquid period up at least a year, and without " the imperial robe " phenomenon, lubricity is good, and working solution temperature is low and permanent after processing is completed
It is fixed.
Detailed description of the invention
Fig. 1 is the workpiece figure of truck brake device assembly；
Fig. 2 is the workpiece figure of truck vibration damper assembly.
Specific embodiment
Below in conjunction with specific embodiment, the invention will be further described.It should be understood that following embodiment is merely to illustrate
The present invention is not for limiting the scope of the invention.Therefore it is all specific as follows according to method described in present patent application range:
In embodiment, used experimental method is conventional method unless otherwise specified, material used, reagent
Deng being commercially available unless otherwise specified.The water is tap water or deionized water.
Embodiment 1
A kind of environment-friendly type all-synthetic grinding fluid of the present embodiment, the ingredient including following mass percent: antirust agent
20%, polyethylene oxide polypropylene oxide monobutyl base ether 5%, polyethylene glycol 5%, glycerol derivatives 2%, cationic sodium salt
0.4%, dipropylene glycol 0.9%, polysiloxanes 0.05% and surplus water.The antirust agent of the present embodiment is tricarboxylic acid and two
First mixed mixture of carboxylic acid reacts the product obtained with triethanolamine.The tricarboxylic acid and dicarboxylic acids presses quality
Than being mixed for 8:2.
The preparation method of the environment-friendly type all-synthetic grinding fluid, comprising the following steps: 1) mix tricarboxylic acid and dicarboxylic acids
Conjunction obtains mixture, then the mixture is reacted 3 hours with triethanolamine at 130 DEG C, is cooled to room temperature test basic parameter
It is spare after qualification；2) dipropylene glycol is uniformly mixed with water spare in advance with polysiloxanes；3) three successively are added according to formula rate
First carboxylate, polyethylene oxide polypropylene oxide monobutyl base ether, polyethylene glycol are uniformly mixed, and add mixture in step 2)；
4) it is uniformly mixed that cationic sodium salt, glycerol derivatives are added, obtain the grinding fluid.The preparation of the present embodiment is 35
DEG C or less and be carried out continuously.
Embodiment 2
A kind of environment-friendly type all-synthetic grinding fluid of the present embodiment, the ingredient including following mass percent: antirust agent
25%, polyethylene oxide polypropylene oxide monobutyl base ether 10%, polyethylene glycol 6%, glycerol derivatives 2%, cationic sodium salt
0.4%, dipropylene glycol 0.9%, polysiloxanes 0.05% and surplus water.The antirust agent of the present embodiment is tricarboxylic acid and three
The reactant of ethanol amine.
The preparation method of the environment-friendly type all-synthetic grinding fluid, comprising the following steps: 1) tricarboxylic acid and triethanolamine exist
It reacts 2.5 hours, is cooled to room temperature spare after testing basic parameter qualification at 150 DEG C；2) dipropylene glycol shifts to an earlier date with polysiloxanes
It is uniformly mixed with water spare；3) tricarboxylic acid ester, polyethylene oxide polypropylene oxide monobutyl base successively is added according to formula rate
Ether, polyethylene glycol are uniformly mixed, and add mixture in step 2)；4) cationic sodium salt, glycerol derivatives mixing is added
It is even, obtain the grinding fluid.The preparation of the present embodiment at 35 DEG C or less and is carried out continuously.
Embodiment 3
A kind of environment-friendly type all-synthetic grinding fluid of the present embodiment, the ingredient including following mass percent: antirust agent
28%, polyethylene oxide polypropylene oxide monobutyl base ether 8%, polyethylene glycol 8%, glycerol derivatives 3%, cationic sodium salt
0.3%, dipropylene glycol 0.1%, polysiloxanes 0.1% and surplus water.The antirust agent of the present embodiment is tricarboxylic acid and binary
The mixed mixture of carboxylic acid reacts the product obtained with triethanolamine.The tricarboxylic acid and dicarboxylic acids presses quality
Than being mixed for 9:1.
The preparation method of the environment-friendly type all-synthetic grinding fluid, comprising the following steps: 1) mix tricarboxylic acid and dicarboxylic acids
Conjunction obtains mixture, then the mixture is reacted 3.5 hours with triethanolamine at 130 DEG C, is cooled to room temperature the basic ginseng of test
It is spare after number is qualified；2) dipropylene glycol is uniformly mixed with water spare in advance with polysiloxanes；3) it is successively added according to formula rate
Tricarboxylic acid ester, polyethylene oxide polypropylene oxide monobutyl base ether, polyethylene glycol are uniformly mixed, and add mixing in step 2)
Object；4) it is uniformly mixed that cationic sodium salt, glycerol derivatives are added, obtain the grinding fluid.The preparation of the present embodiment exists
It 35 DEG C or less and is carried out continuously.
Embodiment 4
A kind of environment-friendly type all-synthetic grinding fluid of the present embodiment, the ingredient including following mass percent: antirust agent
21%, polyethylene oxide polypropylene oxide monobutyl base ether 5%, polyethylene glycol 5%, glycerol derivatives 0.3%, cationic sodium
The water of salt 1.0%, dipropylene glycol 0.9% and surplus.The antirust agent of the present embodiment is that tricarboxylic acid and dicarboxylic acids are mixed
Mixture reacts the product obtained with the mixture of triethanolamine and monoethanolamine.The tricarboxylic acid and dicarboxylic acids is pressed
Mass ratio is 8:2 mixing, and the triethanolamine and monoethanolamine are 7:3 mixing in mass ratio.
The preparation method of the environment-friendly type all-synthetic grinding fluid, comprising the following steps: 1) mix tricarboxylic acid and dicarboxylic acids
Mixture after conjunction reacts 3 hours with triethanolamine and the mixture of monoethanolamine at 130 DEG C, is cooled to room temperature test base
It is spare after this parameter is qualified；2) dipropylene glycol is uniformly mixed with water in advance with polysiloxanes spare；3) successively according to recipe ratio
Example is added tricarboxylic acid ester, polyethylene oxide polypropylene oxide monobutyl base ether, polyethylene glycol and is uniformly mixed, and adds step 2)
Middle mixture；4) it is uniformly mixed that cationic sodium salt, glycerol derivatives are added, obtain the grinding fluid.The system of the present embodiment
It is standby at 35 DEG C or less and to be carried out continuously.
Embodiment 5
A kind of environment-friendly type all-synthetic grinding fluid of the present embodiment, the ingredient including following mass percent: antirust agent
30%, polyethylene oxide polypropylene oxide monobutyl base ether 15%, polyethylene glycol 10%, glycerol derivatives 2%, cationic sodium
The water of salt 1.5%, dipropylene glycol 0.6%, polyether siloxane copolymers 0.3% and surplus.The antirust agent of the present embodiment is three
First carboxylic acid and the mixed mixture of dicarboxylic acids react the product obtained with the mixture of triethanolamine and monoethanolamine.Institute
The tricarboxylic acid and dicarboxylic acids stated are 9:1 mixing in mass ratio, and the triethanolamine and monoethanolamine are 9:1 in mass ratio
Mixing.
The preparation method of the environment-friendly type all-synthetic grinding fluid, comprising the following steps: 1) mix tricarboxylic acid and dicarboxylic acids
Mixture after conjunction reacts 3 hours with triethanolamine and the mixture of monoethanolamine at 130 DEG C, is cooled to room temperature test base
It is spare after this parameter is qualified；2) dipropylene glycol is uniformly mixed with water in advance with polysiloxanes spare；3) successively according to recipe ratio
Example is added tricarboxylic acid ester, polyethylene oxide polypropylene oxide monobutyl base ether, polyethylene glycol and is uniformly mixed, and adds step 2)
Middle mixture；4) it is uniformly mixed that cationic sodium salt, glycerol derivatives are added, obtain the grinding fluid.The system of the present embodiment
It is standby at 35 DEG C or less and to be carried out continuously.
Embodiment 6
A kind of environment-friendly type all-synthetic grinding fluid of the present embodiment, the ingredient including following mass percent: antirust agent
35%, polyethylene oxide polypropylene oxide monobutyl base ether 12%, polyethylene glycol 12%, glycerol derivatives 5%, cationic sodium
Salt 2.5%, dipropylene glycol 0.5%, silicone emulsion 0.2% and surplus water.The antirust agent of the present embodiment is tricarboxylic acid and two
First mixed mixture of carboxylic acid reacts the product obtained with the mixture of triethanolamine and monoethanolamine.The ternary carboxylic
Acid and dicarboxylic acids are 8:2 mixing in mass ratio, and the triethanolamine and monoethanolamine are 9:1 mixing in mass ratio.
The preparation method of the environment-friendly type all-synthetic grinding fluid, comprising the following steps: 1) will be by tricarboxylic acid and dicarboxylic acids
Mixed mixture reacts 3 hours with triethanolamine and the mixture of monoethanolamine at 130 DEG C, is cooled to room temperature test
It is spare after basic parameter is qualified；2) dipropylene glycol is uniformly mixed with water in advance with polysiloxanes spare；3) successively according to formula
Ratio is added tricarboxylic acid ester, polyethylene oxide polypropylene oxide monobutyl base ether, polyethylene glycol and is uniformly mixed, and adds step
2) mixture in；4) it is uniformly mixed that cationic sodium salt, glycerol derivatives are added, obtain the grinding fluid.The present embodiment
Preparation at 35 DEG C or less and is carried out continuously.
Embodiment 7
A kind of environment-friendly type all-synthetic grinding fluid of the present embodiment, the ingredient including following mass percent: antirust agent
40%, polyethylene oxide polypropylene oxide monobutyl base ether 15%, polyethylene glycol 15%, glycerol derivatives 2.5%, cation
Sodium salt 5%, dipropylene glycol 1%, the deionized water of dimethicone 0.2%, silicone emulsion 0.2% and surplus.The present embodiment
Antirust agent is the reactant of tricarboxylic acid and triethanolamine.
The preparation method of the environment-friendly type all-synthetic grinding fluid, comprising the following steps: 1) tricarboxylic acid and triethanolamine exist
It reacts 3 hours, is cooled to room temperature spare after testing basic parameter qualification at 130 DEG C；2) dipropylene glycol and polysiloxanes are shifted to an earlier date
It is uniformly mixed with water spare；3) tricarboxylic acid ester, polyethylene oxide polypropylene oxide monobutyl base successively is added according to formula rate
Ether, polyethylene glycol are uniformly mixed, and add mixture in step 2)；4) cationic sodium salt, glycerol derivatives mixing is added
It is even, obtain the grinding fluid.The preparation of the present embodiment at 35 DEG C or less and is carried out continuously.
Comparative example 1
A kind of grinding fluid of this comparative example, the ingredient including following mass percent: tricarboxylic acid ester 25%, low cloud point
Polyethers 10%, polyethylene glycol 6%, glycerol derivatives 2%, cationic sodium salt 0.4%, dipropylene glycol 0.9%, polysiloxanes
0.05% and surplus water.
The preparation method of the grinding fluid, comprising the following steps: 1) react tricarboxylic acid at 150 DEG C with triethanolamine
It 2.5 hours, is cooled to room temperature spare after testing basic parameter qualification；2) dipropylene glycol mixes with water in advance with polysiloxanes
It is even spare；3) tricarboxylic acid ester, low cloud point polyethers, polyethylene glycol successively is added according to formula rate to be uniformly mixed, adds step
It is rapid 2) in mixture；4) it is uniformly mixed that cationic sodium salt, glycerol derivatives are added, obtain the grinding fluid.
Comparative example 2
A kind of grinding fluid of this comparative example, the ingredient including following mass percent: triethanolamine borate 25%, low
Cloud point polyethers 10%, polyethylene glycol 6%, glycerol derivatives 2%, cationic sodium salt 0.4%, neodecanoic acid 0.9%, poly- silicon oxygen
The water of alkane 0.05% and surplus.
The preparation method of the grinding fluid, comprising the following steps: 1) react tricarboxylic acid at 150 DEG C with triethanolamine
It 2.5 hours, is cooled to room temperature spare after testing basic parameter qualification；2) neodecanoic acid is uniformly mixed with water in advance with polysiloxanes
It is spare；3) tricarboxylic acid ester, low cloud point polyethers, polyethylene glycol successively is added according to formula rate to be uniformly mixed, adds step
2) mixture in；4) it is uniformly mixed that cationic sodium salt, glycerol derivatives are added, obtain the grinding fluid.
Comparative example 3
This comparative example difference from Example 2 is only that, the difference of the content of the ingredient, including following quality
The ingredient of percentage: tricarboxylic acid ester 15%, polyethylene oxide polypropylene oxide monobutyl base ether 20%, polyethylene glycol 6%, third
Triol derivates 2%, cationic sodium salt 0.4%, dipropylene glycol 0.9%, polysiloxanes 0.05% and surplus water.
Embodiment 8
To the performance test of all-synthetic grinding fluid of the present invention
The performance of the all-synthetic grinding fluid prepared respectively to embodiment 1 to 7 and comparative example 1 to 3 is tested, respectively
Test every group of pH (5%W/W) (it is 5% that grinding fluid, which is diluted to mass fraction), rust-preventing characteristic, Reichart test Noise
Reduction, foam, settleability, test result are as shown in table 1:
Wherein pH testing standard quotes GB/T 6144-2010, corrosion testing standard quotes JB/T 9189-2016,
Reichart test Noise Reduction testing standard is the liquid that 5% (W/W) dilution injects Reichart testing machine
In slot, steel ball is filled in the groove of connecting rod, whether detection steel ball and axle sleeve contact well with working solution, under 10kg pressure,
Steel ball is set sufficiently to rub with axle sleeve, the time that record noise disappears, the time is shorter, and lubrication wear resistence is better.Foam testing standard
GB/T 6144-2010 is quoted, settleability test method: (grinding fluid, which is diluted to mass fraction, is in 5% (W/W) dilution
5%) 2g iron powder is added in, uniformly shakes under 10 up and down, the static observation iron powder sedimentation time, record iron powder sinks to bottom completely
Time.
As can be seen from Table 1, the grinding fluid of above-described embodiment 1 to 7 has excellent rustless property, is 0 grade, does not have
Rust spot, and grinding fluid of the present invention disappears substantially in 7s or so foam, shows there is good low bubble, in 40s or so, iron
Powder sinks to bottom completely, has good settleability, and the time that the grinding fluid noise of the embodiment of the present invention 1~7 disappears is than comparison
The time that 1~3 noise of example disappears is short, shows that present invention lubrication wear resistence is better；Comparative example 1 replaces this using low cloud point polyethers
The high cloud point polymer of invention, comparative example 2 makees antirust agent using borate ester derivative and low cloud point polyethers does lubricant compounding
Organic acid couplant, as can be known from the results, the performance of the grinding fluid obtained are not so good as the present invention, and the present invention is using not boracic
Tricarboxylic acid react into amide (ester) with triethanolamine and do antirust；Using high cloud point polymer poly ethylene oxide polycyclic oxygen third
Alkane single-butyl ether, which is done, to be lubricated, and is compounded with couplant, stabilizer etc., not only greatly reduces the dosage of couplant, and lubricate
Property is more preferable, and system is more stable, and reduces existing product smell and cost；It effectively solves existing in live use process " the imperial robe "
As the fractions content of the grinding fluid of comparative example 3 is except the scope of the present invention, and as can be known from the results, and performance is not as good as this
Invention, the present invention is by repeatedly carrying out formula compatibility test, and finishing screen selects the ingredient of grinding fluid and each ingredient contains
Amount is stablized, antirust is good, low bubble, height settle and a kind of grinding fluid of environmental protection.
Application examples 1
Certain full-sized car parts machining enterprise produces truck brake device assembly (such as Fig. 1 workpiece), main material spheroidal graphite
Cast iron and grey cast-iron, processing technology include: turning, milling, grinding, drilling.Using product of the present invention 1 year, reaction was good,
It is especially good to skin adaptability.
Application examples 2
Certain full-sized car parts machining enterprise, main to produce truck vibration damper assembly (following Fig. 2 workpiece), main material
Matter carbon steel, main technique centerless grinding.Using product of the present invention 1 year, reaction was good, instead of certain famous import brand, made
Client comprehensive cost has dropped 10%-15%.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent substitution, improvement and etc. done be should be included within the scope of the present invention.
Claims (10)
1. a kind of all-synthetic grinding fluid, which is characterized in that the ingredient including following mass percent: antirust agent 20~40%, height
Cloud point polymer 5~15%, polyethylene glycol 5~15%, stabilizer 0.3~5%, sedimentation agent 0.3~5%, couplant 0.1~
1.0%, the water of defoaming agent 0~0.5% and surplus.
2. all-synthetic grinding fluid according to claim 1, which is characterized in that the antirust agent is metal carboxylate antirust agent,
Preferably, the antirust agent is that tricarboxylic acid reacts the product obtained with triethanolamine or is that tricarboxylic acid and dicarboxylic acids are mixed
Mixture after conjunction reacted with triethanolamine the product obtained or for tricarboxylic acid and the mixed mixture of dicarboxylic acids with
The product that triethanolamine and the reaction of the mixture of monoethanolamine obtain.
3. all-synthetic grinding fluid according to claim 1, which is characterized in that the high cloud point polymer is polyethylene oxide
Polypropylene oxide monobutyl base ether.
4. all-synthetic grinding fluid according to claim 1, which is characterized in that the stabilizer is glycerol derivatives.
5. all-synthetic grinding fluid according to claim 1, which is characterized in that the sedimentation agent is cationic sodium salt.
6. all-synthetic grinding fluid according to claim 1, which is characterized in that the couplant is dipropylene glycol, described to disappear
Infusion is at least one of polysiloxanes, dimethicone, silicone emulsion, polyether siloxane copolymers.
7. all-synthetic grinding fluid according to claim 1, which is characterized in that the ingredient including following mass percent: anti-
Rust agent 25%, high cloud point polymer 10%, polyethylene glycol 6%, stabilizer 2%, sedimentation agent 0.4%, couplant 0.9%, defoaming
Agent 0.05%, surplus are water.
8. all-synthetic grinding fluid according to claim 1, which is characterized in that the ingredient including following mass percent: anti-
Become rusty agent 25~35%, high cloud point polymer 8~12%, polyethylene glycol 6~12%, stabilizer 2~5%, sedimentation agent 0.3~
2.5%, couplant 0.1~0.9%, defoaming agent 0~0.5%, surplus are water.
9. all-synthetic grinding fluid according to claim 1, which is characterized in that the cloud point of the high cloud point polymer is greater than
80℃。
10. a kind of preparation method of all-synthetic grinding fluid as described in any one of claim 1 to 9, which is characterized in that including with
Lower step: 1) couplant will be uniformly mixed spare with defoaming agent with water；2) antirust agent, high cloud point successively is added according to formula rate
Polymer, polyethylene glycol are uniformly mixed, and add mixture in step 1)；3) addition sedimentation agent, stabilizer are mixed to get described
Grinding fluid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811065609.1A CN109054979B (en) | 2018-09-12 | 2018-09-12 | Environment-friendly fully-synthetic grinding fluid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811065609.1A CN109054979B (en) | 2018-09-12 | 2018-09-12 | Environment-friendly fully-synthetic grinding fluid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109054979A true CN109054979A (en) | 2018-12-21 |
| CN109054979B CN109054979B (en) | 2021-06-29 |
Family
ID=64760451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811065609.1A Active CN109054979B (en) | 2018-09-12 | 2018-09-12 | Environment-friendly fully-synthetic grinding fluid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109054979B (en) |
-
2018
- 2018-09-12 CN CN201811065609.1A patent/CN109054979B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN109054979B (en) | 2021-06-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106118834B (en) | A kind of aluminum alloy cutting fluid with long service life and preparation method thereof | |
| CN100485018C (en) | Rust-proof cutting fluid | |
| CN105861135B (en) | Green metal cutting fluid and preparation method thereof | |
| CN103391992B (en) | Water-soluble working fluid for fixed-abrasive wire saw | |
| CN105001964A (en) | Microemulsified cutting fluid | |
| CN104277902A (en) | Heavy-load metal machining total synthesis cutting fluid as well as preparation method and application thereof | |
| CN103013638A (en) | Water-soluble cooling liquid for fixed abrasive material line cutting, and preparation method thereof | |
| US10041019B2 (en) | Drilling fluid system | |
| CN106800963B (en) | A kind of water soluble oil metalworking fluid raw material and metalworking fluid | |
| CN108998183B (en) | Smart phone frame synthetic type high-light cutting fluid and preparation method thereof | |
| CN106590907A (en) | Graphene-containing metal cutting fluid and preparation method thereof | |
| CN103555392A (en) | Ionic liquid-containing micro-emulsified metal cutting fluid, and preparation method and application thereof | |
| CN109929666A (en) | Water base universal neodymium iron boron emulsification antirust working fluid and preparation method thereof | |
| CN102660366B (en) | Water-based synthetic cutting fluid lubricating agent, and preparation method and application thereof | |
| CN103242944B (en) | Multifunctional water-based environment-friendly recyclable crystal silicon precision cutting liquid | |
| CN114410371B (en) | Water-based fully-synthetic grinding fluid with multiple sedimentation performance and preparation method thereof | |
| CN108949332A (en) | A kind of preparation method and environment-friendly type tapping liquid of the environment-friendly type tapping liquid of automobile air-conditioning filter cover board | |
| CN113201385A (en) | Magnesium-lithium alloy cutting fluid and preparation method thereof | |
| CN109054979A (en) | A kind of environment-friendly type all-synthetic grinding fluid and preparation method thereof | |
| CN110684585B (en) | Micro-emulsion type cutting fluid and preparation method thereof | |
| CN103351936B (en) | Water-soluble cutting fluid and preparation method thereof | |
| CN106221882A (en) | A kind of rust preventive cutting fluid | |
| CN109054977A (en) | Graphene cutting fluid and preparation method thereof | |
| CN108192690B (en) | Application of secondary alcohol polyoxyethylene ether and Guerbet alcohol polyoxyethylene ether as settling agent and settling agent | |
| RU1822197C (en) | Coolant-lubricant liquid concentrate for mechanical treatment of metals |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 511450, No. 15 Xinhuan Middle Road, Dalong Street, Panyu District, Guangzhou City, Guangdong Province Patentee after: Guangzhou Jiajun Lubrication Materials Co.,Ltd. Country or region after: China Address before: 511450 no.15-1, Xinhuan Middle Road, Xinqiao village, Dalong street, Panyu District, Guangzhou City, Guangdong Province Patentee before: GUANGZHOU CITY FANYU DISTRICT JIAJUN CHEMICAL CO.,LTD. Country or region before: China |