CN109054674A - A kind of compound reinforcement damp film of automobile and preparation method thereof - Google Patents
A kind of compound reinforcement damp film of automobile and preparation method thereof Download PDFInfo
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- CN109054674A CN109054674A CN201810669573.1A CN201810669573A CN109054674A CN 109054674 A CN109054674 A CN 109054674A CN 201810669573 A CN201810669573 A CN 201810669573A CN 109054674 A CN109054674 A CN 109054674A
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- 230000002787 reinforcement Effects 0.000 title claims abstract description 79
- 150000001875 compounds Chemical class 0.000 title claims abstract description 69
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000013016 damping Methods 0.000 claims abstract description 52
- 229920001971 elastomer Polymers 0.000 claims abstract description 41
- 239000005060 rubber Substances 0.000 claims abstract description 41
- 238000002156 mixing Methods 0.000 claims abstract description 19
- 238000000926 separation method Methods 0.000 claims abstract description 12
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 30
- 238000001125 extrusion Methods 0.000 claims description 29
- 229920005549 butyl rubber Polymers 0.000 claims description 27
- 229920000459 Nitrile rubber Polymers 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 26
- 230000008569 process Effects 0.000 claims description 26
- 239000003292 glue Substances 0.000 claims description 23
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 20
- 239000003822 epoxy resin Substances 0.000 claims description 20
- 229920000647 polyepoxide Polymers 0.000 claims description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 230000009967 tasteless effect Effects 0.000 claims description 16
- 239000010445 mica Substances 0.000 claims description 15
- 229910052618 mica group Inorganic materials 0.000 claims description 15
- 229920002367 Polyisobutene Polymers 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 14
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims description 14
- 239000012763 reinforcing filler Substances 0.000 claims description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 10
- 238000009490 roller compaction Methods 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 8
- 229910052791 calcium Inorganic materials 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 230000004888 barrier function Effects 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000011297 pine tar Substances 0.000 claims description 6
- 229940068124 pine tar Drugs 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 229920002857 polybutadiene Polymers 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 238000005728 strengthening Methods 0.000 claims description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- 239000004842 bisphenol F epoxy resin Substances 0.000 claims description 2
- 239000011888 foil Substances 0.000 claims description 2
- 239000012943 hotmelt Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 claims 1
- 238000007670 refining Methods 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 230000009467 reduction Effects 0.000 abstract description 5
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 235000015927 pasta Nutrition 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 239000005038 ethylene vinyl acetate Substances 0.000 description 7
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 229910052738 indium Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 241000737241 Cocos Species 0.000 description 2
- 239000005030 aluminium foil Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09J109/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/14—Glass
- C09J2400/143—Glass in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/16—Metal
- C09J2400/163—Metal in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses compound reinforcement damp films of a kind of automobile and preparation method thereof.The compound reinforcement damp film of automobile provided by the invention successively comprises the following structure layer: restraint layer, damping glue-line, separation layer, reinforcing support layer, reinforcement glue-line；It is by mixing of plasticating that each layer is compound.Reinforced rubber sheet prepared by the present invention can be accomplished leading in the industry on multinomial performance, product reinforcing, noise reduction, the feature of environmental protection and weatherability obtain good cooperation, such as low temperature pasta steel plate adhesive property, damped coefficient, anti-impact wash performance, excellent with the solidification adhesive property of substrate, anti-480 hours salt air corrosion performances.
Description
Technical field
The present invention relates to automotive material fields, and in particular to a kind of compound reinforcement damp film of automobile and its preparation side
Method.
Background technique
The research of reinforcement and vibration and noise reducing field for body of a motor car is always that automobile industry improves the important class promoted
Topic, in the prior art, the technological means of automobile industry to achieve the above object are usually that adhering reinforcing rubber sheets vehicle is used to realize vehicle
Body is reinforced, and damping noise reduction is then using stickup damp film or to spray damping paint, but in construction application, the two can only be selected
One of which cannot achieve vibration and noise reducing using reinforcement, cannot achieve vehicle body using damping material and reinforce, therefore urgently
It is a kind of convenient for construct and can be achieved at the same time to body of a motor car reinforce and damping noise reduction material.
Summary of the invention
The object of the present invention is to provide a kind of reinforcement and damping noise reduction effects, multiple convenient for the automobile of construction of capable of realizing simultaneously
Mould assembly reinforcement damp film and preparation method thereof.
The present invention is achieved by the following technical solution:
A kind of compound reinforcement damp film of automobile successively comprises the following structure layer: restraint layer, damping glue-line, isolation
Layer, reinforcing support layer, reinforcement glue-line.Reinforcement glue-line, reinforcing support layer, isolation are disposed with outside motor-car body sheet
Layer, damping glue-line, restraint layer.
Further, in the compound reinforcement damp film of above-mentioned automobile, the damping layer includes following parts by weight of component:
100 parts of butyl rubber, 10-30 parts of polyisobutene, 10-15 parts of SEBS, 20-40 parts of mica powder, 250-350 parts of calcium carbonate, EVA
12-16 parts, 25-35 parts of pine tar；
EVA, that is, the ethylene-vinyl acetate copolymer；SEBS is i.e. using polystyrene as end segment, with polybutadiene plus hydrogen
Obtained ethylene-butene copolymer is the linear tri-block copolymer of intermediate elastic block.
The reinforcement glue-line includes following parts by weight of component: 20-30 parts of nitrile rubber, 10-20 parts of tackified rubber, asphalt mixtures modified by epoxy resin
It is 20-30 parts of rouge, 20-50 parts of reinforcing filler, activated carbon 5-10 parts by weight, curing agent 5-10 parts tasteless；
The separation layer material is pass hot-melt film material；The restraint layer material is glass or metal foil；It is described
Reinforcing support layer material is glass.
For butyl rubber due to containing many pending methyl groups in strand, elastic hysteresis is larger, and energy consumption is obvious, therefore has apparent
Damping action；Tackified rubber can increase the wetting of film face, improve viscosity, and damping glue heat resistance, anti-flammability can be improved in mica；
Reinforcing filler can promote product hardness, reduce cost；After epoxy resin hot setting, glue-line bulk strength and glue-line can be made
It is obviously improved with composite material adhesive strength, reaches maximum 8 times of reinforcement multiplying power；Structure layered relationship of the invention to hinder
Buddhist nun and reinforcement material can give full play to its each self-applying, and easy to produce and in motor-car body sheet surface construction.
It is further preferred that the damping layer includes following parts by weight in the above-mentioned compound reinforcement damp film of automobile
Component: 100 parts of butyl rubber, 15 parts of polyisobutene, 12 parts of SEBS, 35 parts of mica powder, 300 parts of calcium carbonate, 15 parts of EVA, pine
30 parts of tar；
The strengthening course includes following parts by weight of component: including 25 parts of nitrile rubber, 15 parts of tackified rubber, epoxy resin 30
Part, 40 parts of reinforcing filler, 6 parts by weight of activated carbon, 5 parts of tasteless curing agent.
Further, in the compound reinforcement damp film of above-mentioned automobile, the butyl rubber is selected as high Mooney viscosity
The trade mark of middle equisaturation；The SEBS hardness range is 50-70 shore hardness；The mica powder is white mica powder, Mohs
Hardness is 2.5-3.
Further, in the compound reinforcement damp film of above-mentioned automobile, the tackified rubber is polyisobutene, liquid fourth
Any one or a few mixing in nitrile, polybutadiene rubber oil.
Further, high in the acrylonitrile content of the nitrile rubber in the compound reinforcement damp film of above-mentioned automobile
Content 30-40%；The polybutadiene rubber viscosity is 500-4000mPaS；The epoxy resin is bisphenol A epoxide resin
And/or bisphenol F epoxy resin；The epoxy resin epoxy equivalent is 170-200 g/eq；The reinforcing filler is light calcium, institute
The partial size for stating light calcium is 0.5-10 μm；The tasteless curing agent is cumyl peroxide.Cumyl peroxide, that is, tasteless solid
Agent DCP.
Further, in the compound reinforcement damp film of above-mentioned automobile, the separation layer can at a temperature of 140-170 DEG C
It is molten.
The preparation method of the above-mentioned compound reinforcement damp film of automobile comprising steps of
S1. it plasticates: being plasticated under the conditions of temperature is no more than 80 DEG C to butyl rubber and nitrile rubber using open mill；
S2. be kneaded: including two parts, damping glue is kneaded and reinforcement glue is kneaded；
Damping glue is kneaded: using open mill or mixer to after plasticating butyl rubber, polyisobutene, SEBS, filler into
Row is kneaded, and temperature is no more than 80 DEG C；
Reinforcement glue be kneaded: using open mill by the nitrile rubber after plasticating, tackified rubber, epoxy resin, reinforcing filler,
Tasteless curing agent is kneaded, and temperature is no more than 60 DEG C, evenly dispersed each component.
S3. squeeze out and cut: including two parts, damping glue-line extrusion is cut to be cut with reinforcement glue-line extrusion；
Damping glue-line is cut: damping glue is squeezed out by extruder in fact, and extrusion process temperature is 30-50 DEG C, in extrusion process
In with restraint layer and separation layer are compound is bonded, rubber compound squeezes out thickness 1-2mm, and through roller compaction, the communicated cut machine of band is cut out
It cuts into slices；
Reinforcement glue-line is cut: the reinforcement glue material after mixing is squeezed out by extruder, and extrusion process temperature is 40-60 DEG C,
In extrusion process with glass-fiber-fabric and barrier paper are compound is bonded, rubber compound squeezes out thickness 1-2mm, through roller compaction, communicated band
Cut machine is cut in flakes；
Damping glue-line is compound with reinforcement glue-line: pressurize to damping glue-line and reinforcement glue-line using pressure roller compound, so
The film after compound is cut by user's requirement afterwards, is packed.
Further, in the preparation method of above-mentioned automotive sheet reinforced rubber sheet, open mill roll spacing is in the step S1
0.5-2mm；The roll spacing of open mill is 2-10mm in the step S2, and mixing time is 30 ± 5min；After the step S2 is kneaded
Product carry out step S3, the thin logical technique detailed process of rubber compound are as follows: will open again after the thin logical process of rubber compound
Mill roll spacing is adjusted to 1-2mm, carries out thin logical processing to rubber compound.
The compound reinforcement damp film of automobile provided by the invention has the following beneficial effects:
The invention proposes the conceptions of new product, realize reinforcement and damping in body of a motor car simultaneously by one-off construction
Function.This product can effectively promote bodywork safety, promote riding comfort, and design concept is led in automobile industry similar product
First, meet consumer product demand, market application prospect is wide.
Reinforced rubber sheet prepared by the present invention can accomplish leading in the industry, product reinforcing, noise reduction, environmental protection on multinomial performance
Property and weatherability obtain good cooperation, as low temperature pasta steel plate adhesive property, damped coefficient, anti-impact wash performance and substrate
Solidification adhesive property, the performances such as anti-salt air corrosion in 480 hours it is excellent.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the compound reinforcement damp film of automobile provided in an embodiment of the present invention.
Specific embodiment
The present invention will be further described combined with specific embodiments below.The embodiment is only preferred implementation of the invention
Example, is not intended to restrict the invention, for those skilled in the art, the present invention can have various changes and change
Change.All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention
Protection scope within.Butyl rubber selects the trade mark of equisaturation in high Mooney viscosity, carboxy nitrile rubber in each embodiment
Acrylonitrile mass fraction be 20-40%, the epoxide equivalent of used epoxy resin is 170-200g/eq, used work
Property filler partial size be 0.5-10 μm of light calcium, tasteless curing agent is cumyl peroxide.
Embodiment 1
Reinforcement damp film is with production and production instance:
Material mixture ratio:
Damp glue-line 2 to be formulated: butyl rubber IIR1751 counts 100 parts by weight, and polyisobutene PB2400 counts 30 parts by weight,
SEBS counts 10 parts by weight, 20 parts by weight of mica powder meter, 800 mesh calcium carbonate, 350 parts by weight, 15 parts by weight of EVA, 30 weight of pine tar
Measure part；
Reinforcement glue-line 5 is formulated: nitrile rubber NBR3604 counts 20 parts, tackified rubber carboxy nitrile rubber oily 15 parts, epoxy
Resin E51 counts 20 parts, 50 parts of 800 mesh calcium carbonate of reinforcing filler, 10 parts by weight of activated carbon, 5 parts of tasteless curing agent.
The technological process of production:
S1. plasticate: plasticating to butyl rubber IIR1751, nitrile rubber NBR3604, using open mill, temperature not
Butyl rubber, nitrile rubber plasticate 10 times under the conditions of more than 70 DEG C, placed for use, open mill roll spacing is 0.5mm；
S2. it is kneaded:
Damping layer: butyl rubber is kneaded, butyl rubber IIR1751 and polyisobutene after being plasticated using mixer
PB2400, SEBS, mica powder etc. carry out mixing, and temperature is no more than 130 DEG C of guarantees and is uniformly dispersed, and then benefit opens open mill for glue again
Material is kneaded with other auxiliary agents, and last open mill roll spacing is adjusted to 1.5mm, is carried out at small roll spacing mixing to damping rubber compound
Reason, it is evenly dispersed to guarantee that material achievees the purpose that.
Strengthening course: the nitrile rubber NBR3604 after plasticating, be gradually added tackifying liquid rubber N40, epoxy resin E51,
Filler light calcium, activated carbon, tasteless curing agent DCP are kneaded, and temperature is no more than 60 DEG C, and open mill roll spacing is 2mm, are kneaded
30min, achievees the purpose that evenly dispersed, and last open mill roll spacing is adjusted to 1.5mm, carries out small roll spacing mixing to reinforcement rubber compound
Processing, it is evenly dispersed to guarantee that material achievees the purpose that.
S3. squeeze out and cut: including two parts, the damping extrusion of glue-line 2 is cut to be cut with the extrusion of reinforcement glue-line 5.
Damping glue-line 2 is cut: damping glue is squeezed out by extruder in fact, and extrusion process temperature is 45 DEG C, in extrusion process
With 1 aluminium foil of restraint layer and separation layer 3 is compound is bonded, rubber compound squeezes out thickness 1-2mm, and through roller compaction, communicated band is cut
Machine is cut in flakes.
Reinforcement glue-line 5 is cut: the reinforcement glue material after mixing is squeezed out by extruder, and extrusion process temperature is 55 DEG C,
In extrusion process with glass-fiber-fabric and barrier paper are compound is bonded, rubber compound squeezes out thickness 1-2mm, through roller compaction, communicated band warp
Guillotine is cut in flakes.
Damping glue-line 2 is compound with reinforcement glue-line 5: pressurize to damping glue-line 2 and reinforcement glue-line 5 using pressure roller multiple
It closes, then the film after compound is cut by user's requirement, is packed.
Embodiment 2
Reinforcement damp film is with production and production instance:
Material mixture ratio:
Damp glue-line 2 to be formulated: butyl rubber IIR1751 counts 100 parts by weight, and polyisobutene PB2400 counts 15 parts by weight,
SEBS counts 12 parts by weight, 35 parts by weight of mica powder meter, 800 mesh calcium carbonate, 300 parts by weight, 16 parts by weight of EVA, 35 weight of pine tar
Measure part；
Reinforcement glue-line 5 is formulated: nitrile rubber NBR3604 counts 25 parts, tackified rubber carboxy nitrile rubber oily 15 parts, epoxy
Resin E51 counts 30 parts, 40 parts of 800 mesh calcium carbonate of reinforcing filler, 6 parts by weight of cocos active carbon, 5 parts of tasteless curing agent.
The technological process of production:
S1. plasticate: plasticating to butyl rubber IIR1751, nitrile rubber NBR3604, using open mill, temperature not
Butyl rubber, nitrile rubber plasticate 10 times under the conditions of more than 70 DEG C, placed for use, open mill roll spacing is 1mm；
S2. it is kneaded:
Damping layer: butyl rubber is kneaded, butyl rubber IIR1751 and polyisobutene after being plasticated using mixer
PB2400, SEBS, mica powder etc. carry out mixing, and temperature is no more than 130 DEG C of guarantees and is uniformly dispersed, and then benefit opens open mill for glue again
Material is kneaded with other auxiliary agents, and last open mill roll spacing is adjusted to 1.5mm, is carried out at small roll spacing mixing to damping rubber compound
Reason, it is evenly dispersed to guarantee that material achievees the purpose that.
Strengthening course: the nitrile rubber NBR3604 after plasticating, be gradually added tackifying liquid rubber N40, epoxy resin E51,
Filler light calcium, activated carbon, tasteless curing agent DCP are kneaded, and temperature is no more than 60 DEG C, and open mill roll spacing is 8mm, are kneaded
35min, achievees the purpose that evenly dispersed, and last open mill roll spacing is adjusted to 1.5mm, carries out small roll spacing mixing to reinforcement rubber compound
Processing, it is evenly dispersed to guarantee that material achievees the purpose that.
S3. squeeze out and cut: including two parts, the damping extrusion of glue-line 2 is cut to be cut with the extrusion of reinforcement glue-line 5.
Damping glue-line 2 is cut: damping glue is squeezed out by extruder in fact, and extrusion process temperature is 45 DEG C, in extrusion process
With 1 glass-fiber-fabric of restraint layer and separation layer 3 is compound is bonded, rubber compound squeezes out thickness 1-2mm, and through roller compaction, communicated band is through cutting out
The machine of cutting is cut in flakes.
Reinforcement glue-line 5 is cut: the reinforcement glue material after mixing is squeezed out by extruder, and extrusion process temperature is 55 DEG C,
In extrusion process with glass-fiber-fabric and barrier paper are compound is bonded, rubber compound squeezes out thickness 1-2mm, through roller compaction, communicated band warp
Guillotine is cut in flakes.
Damping glue-line 2 is compound with reinforcement glue-line 5: pressurize to damping glue-line 2 and reinforcement glue-line 5 using pressure roller multiple
It closes, then the film after compound is cut by user's requirement, is packed.
Embodiment 3
Reinforcement damp film is with production and production instance:
Material mixture ratio:
Damp glue-line 2 to be formulated: butyl rubber IIR1751 counts 100 parts by weight, and polyisobutene PB2400 counts 10 parts by weight,
SEBS counts 13 parts by weight, 25 parts by weight of mica powder meter, 800 mesh calcium carbonate, 250 parts by weight, 12 parts by weight of EVA, 25 weight of pine tar
Measure part；
Reinforcement glue-line 5 is formulated: nitrile rubber NBR3604 counts 30 parts, tackified rubber carboxy nitrile rubber oily 10 parts, epoxy
Resin E51 counts 25 parts, 25 parts of 800 mesh calcium carbonate of reinforcing filler, 5 parts by weight of cocos active carbon, 10 parts of tasteless curing agent.
The technological process of production:
S1. plasticate: plasticating to butyl rubber IIR1751, nitrile rubber NBR3604, using open mill, temperature not
Butyl rubber, nitrile rubber plasticate 10 times under the conditions of more than 70 DEG C, placed for use, open mill roll spacing is 2mm；
S2. it is kneaded:
Damping layer: butyl rubber is kneaded, butyl rubber IIR1751 and polyisobutene after being plasticated using mixer
PB2400, SEBS, mica powder etc. carry out mixing, and temperature is no more than 130 DEG C of guarantees and is uniformly dispersed, and then benefit opens open mill for glue again
Material is kneaded with other auxiliary agents, and last open mill roll spacing is adjusted to 1.5mm, is carried out at small roll spacing mixing to damping rubber compound
Reason, it is evenly dispersed to guarantee that material achievees the purpose that.
Strengthening course: the nitrile rubber NBR3604 after plasticating, be gradually added tackifying liquid rubber N40, epoxy resin E51,
Filler light calcium, activated carbon, tasteless curing agent DCP are kneaded, and temperature is no more than 60 DEG C, and open mill roll spacing is 5mm, are kneaded
25min, achievees the purpose that evenly dispersed, and last open mill roll spacing is adjusted to 1.5mm, carries out small roll spacing mixing to reinforcement rubber compound
Processing, it is evenly dispersed to guarantee that material achievees the purpose that.
S3. squeeze out and cut: including two parts, the damping extrusion of glue-line 2 is cut to be cut with the extrusion of reinforcement glue-line 5.
Damping glue-line 2 is cut: damping glue is squeezed out by extruder in fact, and extrusion process temperature is 45 DEG C, in extrusion process
With 1 aluminium foil of restraint layer and separation layer 3 is compound is bonded, rubber compound squeezes out thickness 1-2mm, and through roller compaction, communicated band is cut
Machine is cut in flakes.
Reinforcement glue-line 5 is cut: the reinforcement glue material after mixing is squeezed out by extruder, and extrusion process temperature is 55 DEG C,
In extrusion process with glass-fiber-fabric and barrier paper are compound is bonded, rubber compound squeezes out thickness 1-2mm, through roller compaction, communicated band warp
Guillotine is cut in flakes.
Damping glue-line 2 is compound with reinforcement glue-line 5: pressurize to damping glue-line 2 and reinforcement glue-line 5 using pressure roller multiple
It closes, then the film after compound is cut by user's requirement, is packed.
On the body of a car by product of the present invention setting, i.e., reinforcement glue-line 5, reinforcement branch are disposed with outside autobody sheet 6
Support layer 4, separation layer 3, damping glue-line 2, restraint layer 1.
Product prepared by embodiment 1 to 3 detects as follows according to detection performance according to Q/JD 960-2016: non-volatile matter
Measuring content is more than 99.7%, damped coefficient 0.15,3 times of reinforcement multiplying power or more, can be through 180 ° of bendings without layering or cracking phenomena, combustion
Self-extinguishment in 2s is burnt, -5-35 ° of barrier paper fissility peelable no residue glue is equal in -5 ° and 170 ° 20min of outer plate surfaces adaptability
Phenomena such as no tilting falls off, also non-displacement, heat-resistant aging, cold resistance, the reinforcement multiple of heat resistance are qualified.
Claims (9)
1. a kind of compound reinforcement damp film of automobile, which is characterized in that successively comprise the following structure layer:
Restraint layer, damping glue-line, separation layer, reinforcing support layer, reinforcement glue-line.
2. the compound reinforcement damp film of automobile according to claim 1, which is characterized in that
The damping layer includes following parts by weight of component: 100 parts of butyl rubber, 10-30 parts of polyisobutene, and 10-15 parts of SEBS,
20-40 parts of mica powder, 250-350 parts of calcium carbonate, 12-16 parts of EVA, 25-35 parts of pine tar；
The reinforcement glue-line includes following parts by weight of component: 20-30 parts of nitrile rubber, 10-20 parts of tackified rubber, epoxy resin
20-30 parts, it is 20-50 parts of reinforcing filler, activated carbon 5-10 parts by weight, curing agent 5-10 parts tasteless；
The separation layer material is pass hot-melt film material；
The restraint layer material is glass or metal foil；
The reinforcing support layer material is glass.
3. the compound reinforcement damp film of automobile according to claim 2, which is characterized in that
The damping layer includes following parts by weight of component: 100 parts of butyl rubber, 15 parts of polyisobutene, and SEBS12 parts, mica powder 35
Part, 300 parts of calcium carbonate, 15 parts of EVA, 30 parts of pine tar；
The strengthening course includes following parts by weight of component: including 25 parts of nitrile rubber, 15 parts of tackified rubber, 30 parts of epoxy resin,
40 parts of reinforcing filler, 6 parts by weight of activated carbon, 5 parts of tasteless curing agent.
4. the compound reinforcement damp film of automobile according to claim 2 or 3, which is characterized in that
The butyl rubber is selected as the trade mark of equisaturation in high Mooney viscosity；
The SEBS hardness range is 50-70 shore hardness；
The mica powder is white mica powder, mohs hardness 2.5-3.
5. the compound reinforcement damp film of automobile according to claim 2 or 3, which is characterized in that
Any one or a few mixing during the tackified rubber is polyisobutene, liquid butyronitrile, polybutadiene rubber are oily.
6. the compound reinforcement damp film of automobile according to claim 2 or 3, which is characterized in that
High-content 30-40% in the acrylonitrile content of the nitrile rubber；
The polybutadiene rubber viscosity is 500-4000mPaS；
The epoxy resin is bisphenol A epoxide resin and/or bisphenol F epoxy resin；
The epoxy resin epoxy equivalent is 170-200g/eq；
The reinforcing filler is light calcium, and the partial size of the light calcium is 0.5-10 μm；
The tasteless curing agent is cumyl peroxide.
7. the compound reinforcement damp film of automobile according to claim 2, which is characterized in that
The separation layer is fusible at a temperature of 140-170 DEG C.
8. the preparation method of the compound reinforcement damp film of automobile as described in any one of claim 2 to 7, feature
It is, comprising steps of
S1. it plasticates: being plasticated under the conditions of temperature is no more than 80 DEG C to butyl rubber and nitrile rubber using open mill；
S2. be kneaded: including two parts, damping glue is kneaded and reinforcement glue is kneaded；
Damping glue is kneaded: being mixed using open mill or mixer to butyl rubber, polyisobutene, SEBS, the filler after plasticating
Refining, temperature are no more than 80 DEG C；
Reinforcement glue is kneaded: using open mill by the nitrile rubber after plasticating, tackified rubber, epoxy resin, reinforcing filler, tasteless
Curing agent is kneaded, and temperature is no more than 60 DEG C, evenly dispersed each component.
S3. squeeze out and cut: including two parts, damping glue-line extrusion is cut to be cut with reinforcement glue-line extrusion；
Damping glue-line cut: damping glue in fact by extruder squeeze out, extrusion process temperature be 30-50 DEG C, in extrusion process with
Restraint layer and the compound fitting of separation layer, rubber compound squeeze out thickness 1-2mm, and through roller compaction, the communicated cut machine of band is cut into
Piece；
Reinforcement glue-line is cut: the reinforcement glue material after mixing is squeezed out by extruder, and extrusion process temperature is 40-60 DEG C, is being squeezed
During out with glass-fiber-fabric and barrier paper are compound is bonded, rubber compound squeezes out thickness 1-2mm, and through roller compaction, communicated band is through cutting out
The machine of cutting is cut in flakes；
Damping glue-line is compound with reinforcement glue-line: pressurize to damping glue-line and reinforcement glue-line using pressure roller compound, then press
User requires to cut the film after compound, pack.
9. the preparation method of the compound reinforcement damp film of automobile according to claim 9, which is characterized in that
Open mill roll spacing is 0.5-2mm in the step S1；
The roll spacing of open mill is 2-10mm in the step S2, and mixing time is 30 ± 5min；
Product after the step S2 is kneaded carries out step S3 again after the thin logical process of rubber compound, and the rubber compound is thin logical
Technique detailed process are as follows: open mill roll spacing is adjusted to 1-2mm, thin logical processing is carried out to rubber compound.
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Application publication date: 20181221 |